In this investigation, two laser-based welding techniques, autogenous laser welding (ALW) and laser welding assisted with a cold wire (LWACW), were applied to join thick plates of a structural steel (A36) in a horizontal narrow gap butt joint configuration. The main practical parameters including welding method and laser power were varied to get the sound weld with a requirement to achieve a full penetration with the reinforcement at the back side of weld in just one pass. The weld-bead shape, cross-section and mechanical properties were evaluated by profilometer, micro-hardness test and optical microscope. In order to investigate the stability of laser-induced plasma plume, the emitted optical spectra was detected and analyzed by the spectroscopy analysis. It was found that at the laser power of 7kW a fully penetrated weld with a convex back side of weld could be obtained by the LWACW. The microstructural examinations showed that for the ALW the acicular ferrite and for the LWACW the pearlite were formed in the heat affected zone (HAZ). The prediction of microstructure based on continuous cooling transformation (CCT) diagram and cooling curves obtained by thermocouple measurement were in good agreement with each other. According to the plasma ionization values obtained from the spectroscopy analysis the plume for both processes was recognized as dominated weakly ionized plasma including the main vaporized elemental composition. At the optimum welding condition (LWACW at the laser power of 7kW) the fluctuation of the electron temperature was reduced. The spectroscopy analysis demonstrated that at the higher laser power more of the elemental compositions such as Mn and Fe were evaporated.
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