Weld Material Research Articles

Selected properties of X120Mn12 steel welded joints by means of the plasma-MAG hybrid method

The article describes properties of welds made of high wear resistance X120Mn12 steel obtained by the hybrid PTA-MAG (plasma transferred arc – metal active gas) method. The specimens were 8 mm thick rectangular (200 mm × 350 mm) sheets metal. The analyzed butt welds were made with the parameters selected according to the criterion of smallest cross-sectional area of welds and the narrowest HAZ (heat affected zone). The outcome of metallographic tests of weld, HAZ and parent material, hardness distribution and XRD (X-ray diffraction) patterns of selected areas are presented. The IIT (Instrumented Indentation Test) method was used to describe the distribution of mechanical properties shaped by thermal cycle annealing of the welding process. The investigation shows that the application of the PTA-MAG hybrid heat source for welding manganese steel enables the use of the filler material ER307 (AWS-A5.9). The hybrid PTA-MAG welding system has the relatively high potential to be an efficient alternative to welding standard processes for X120Mn12 steel due to the HAZ overheating limitation. The zone of high-risk weld cracking is the part of the HAZ close to the fusion area that has been reheated during weldment formation. Heat input about 0.6 kJ/mm is needed to provide full deep penetration butt weld without defects and with a vapor capillary of wide enough to cover the weld gap. The increase of hardness in the welded joint is smooth distributed and going up to 10% compared to the base material. The width of HAZ was <1 mm. Intensive carbides precipitation in HAZ has been avoided successfully.

Circular economy as applied to refractory materials.

The closed-loop economy concerning refractory materials is implemented through systematic involvement in post-operational usage in thermal, including metallurgical, units as secondary (by-product) raw materials. This is one of today's trends in resource and energy economics, reducing carbon footprint and CO2 emissions, decreasing waste with subsequent disposal in landfills. Purified scrap of refractory materials is used as supplementary materials in metallurgical processes, commonly referred to as scrap utilization when used as fluxes to adjust slag composition in metallurgical units, molded materials for welding in converters, refractory fillers in the production of unformed materi-als for sections lining working outside the aggressive influence of molten metal and slag, etc. For these purposes, the scrap is sorted into grades, crushed and screened, occasionally incorporating other products. Refractory scrap after ser-vice in metallurgical units usually has higher impurity content, higher porosity, and contains fragmented remnants of the refractory structure. Recycling refractory scrap may additionally involve technological methods for extracting impurities (enrichment) with subsequent use of the recyclate directly in refractory production, partially replacing primary raw materials. In this case, research work with involvement of qualified specialists and the entire body of knowledge in creating new refractory materials is necessary. Practice has shown that qualified involvement of recyclate in manufacturing processes of high-quality refractories is accompanied by solving non-standard tasks and requires a special approach, including the issue of removing introduced or formed foreign materials in refractory material during its operation. Enrichment is an effective direction for cleaning refractory scrap, extracting quality materials during processing of waste from mining enterprises, materials of technogenic origin to obtain recyclate of necessary quality. The enrichment technology is selected based on the set tasks. Recyclate quality for use alongside primary raw materials must guarantee refractory manufacturers meet the corresponding requirements of end-users. An original technology of recyclate enrichment during its selective grinding with product separation using air-gravitational and centrifugal-air classification has been developed

Circular economy as applied to refractory materials

The closed-loop economy concerning refractory materials is implemented through systematic involvement in post-operational usage in thermal, including metallurgical, units as secondary (by-product) raw materials. This is one of today's trends in resource and energy economics, reducing carbon footprint and CO2 emissions, decreasing waste with subsequent disposal in landfills. Purified scrap of refractory materials is used as supplementary materials in metallurgical processes, commonly referred to as scrap utilization when used as fluxes to adjust slag composition in metallurgical units, molded materials for welding in converters, refractory fillers in the production of unformed materi-als for sections lining working outside the aggressive influence of molten metal and slag, etc. For these purposes, the scrap is sorted into grades, crushed and screened, occasionally incorporating other products. Refractory scrap after ser-vice in metallurgical units usually has higher impurity content, higher porosity, and contains fragmented remnants of the refractory structure. Recycling refractory scrap may additionally involve technological methods for extracting impurities (enrichment) with subsequent use of the recyclate directly in refractory production, partially replacing primary raw materials. In this case, research work with involvement of qualified specialists and the entire body of knowledge in creating new refractory materials is necessary. Practice has shown that qualified involvement of recyclate in manufacturing processes of high-quality refractories is accompanied by solving non-standard tasks and requires a special approach, including the issue of removing introduced or formed foreign materials in refractory material during its operation. Enrichment is an effective direction for cleaning refractory scrap, extracting quality materials during processing of waste from mining enterprises, materials of technogenic origin to obtain recyclate of necessary quality. The enrichment technology is selected based on the set tasks. Recyclate quality for use alongside primary raw materials must guarantee refractory manufacturers meet the corresponding requirements of end-users. An original technology of recyclate enrichment during its selective grinding with product separation using air-gravitational and centrifugal-air classification has been developed

Study of The Microstructure and Mechanical Property Relationships of Gas Metal Arc Welded Dissimilar Protection 600T, DP450 and S275JR Steel Joints

The need for combining dissimilar materials is steadily increasing in the manufacturing industry, and the resulting products are expected to always have high performance. While there are various methods available for joining such material pairs, one of the commonly preferred techniques is fusion welding. In this study, three different steel materials (Protection 600T, DP450, and S275JR) were joined using gas metal arc welding (GMAW) in different combinations (similar/dissimilar). The microstructure and mechanical properties of the joints were evaluated. Tensile test, Vickers microhardness (HV 0.1), bending, Charpy V-notch impact testing, and microstructure examinations were conducted to analyze the weld and heat-affected zone. The tensile strengths of the base metal materials Protection 600T, DP450, and S275JR were found to be 1524.73 ± 18.7, 500.8 ± 10.4, and 508.5 ± 9.5 MPa, respectively. In welded samples of similar materials, the highest efficiency was found to be 103.05% for DP450/DP450, while in dissimilar welded joints, it was 105.5% for the DP450/S275JR pair. Hardness values for the base materials Protection 600T, DP450, and S275JR were measured as 526.5 ± 10.5, 153.8 ± 1.8, and 162.5 ± 5.2, respectively. In all welded samples, there was an increase in hardness in the weld zone (due to the welding wire) and the heat-affected zone (due to grain size refinement). While the impact energy values of similar material pairs were close to the base material impact energy values, the impact energy values of dissimilar material pairs varied according to the base materials. In addition, in joints made with similar materials, the bending force was close to the base materials, while a decrease in bending force was observed in joints formed with dissimilar materials. As a result, the welding of DP450 and S275JR materials was carried out efficiently. Protection 600T was welded with other materials, but its welding strength was limited to the strength of the material with low mechanical properties.

Comparison of fatigue crack growth design curves on GMAW and EBW joints of high strength steels

There is a growing demand in the industrial sector for the use of high-strength structural steels (HSSSs), which can achieve a significant weight reduction in structures. These structural steels are usually produced by quenching and tempering (Q + T) or thermomechanical treatment (TM), and their applications in welded structures pose several challenges for the users. In industrial practice, gas metal arc welding (GMAW) is basically the most commonly used fusion welding process, which has a relatively high heat input. However, at HSSSs, there is a need for low heat input but, at the same time, productive welding processes. High-energy density welding processes, e.g., electron beam welding (EBW), offer a unique opportunity to weld these steels. The widespread use of HSSSs is also hampered by the fact that the benefits of high strength can be exploited primarily under static loading. At the same time, different welded structures made of HSSSs are often subjected to cyclic loading, and possible weld defects and material discontinuities are major risks in this case. During our experiments, GMAW and autogenous EBW processes were applied to make welded joints from S960 Q + T and TM structural steels. The fatigue resistance of the welded joints was characterized by fatigue crack growth (FCG) tests, considering the increased crack sensitivity of HSSSs. A statistical approach was followed both in the design of the experiments and in the evaluation of their results. Based on the test results fatigue crack propagation design curves were determined for the investigated GMAW and EBW welded joints. The design curves were compared with each other, with design curves of lower strength material (S690QL) and with the recommended fatigue crack growth laws of BS 7910.

Study on the tensile properties and deformation mechanism of high-temperature resistant nitrogen-containing nickel-based welding material deposited metal

This article uses a new type of nitrogen-containing nickel-based flux cored welding wire as the experimental material to study the tensile properties and deformation mechanism of the deposited metal from room temperature to 900 °C. The results show that the tensile strength gradually decreases with the temperature. The plasticity gradually increases, but the lowest value appears at 700 °C, which is the phenomenon of intermediate temperature brittleness. M23C6 carbides begin to decompose at 700 °C. More carbonitrides are precipitated within the crystal with temperature. In the low-temperature zone (T ≤ 600 °C), the main deformation mechanism is the unit dislocation a/2<110> cutting precipitation phase. In the medium-temperature zone (600 °C < T ≤ 750 °C), initiation of Orowan bypass mechanism for dislocations. In the high-temperature zone (800 °C ≤ T ≤ 900 °C), the slip and climbing mechanism of dislocation is the main deformation mechanism.

Characterisation of a New Generation of AlMgZr and AlMgSc Filler Materials for Welding Metal–Ceramic Composites

When manufacturing the welded joints of components made of metal–ceramic composites of the Al-Si/SiC type, we encounter significant difficulties. This is related to the presence of a ceramic phase in the aluminium alloy matrix. The interaction between the molten metal matrix and the ceramic particles in the weld pool influences a complex of physicochemical phenomena resulting in, among other things, the structure of the welded joint. This is particularly true of the effect of the distribution of ceramic particles and their influence on the crystallisation process in the weld pool. An important issue is the influence of the reinforcing particles on the susceptibility of the aluminium matrix to both hot and cold cracking. The scope of the research included the development of the chemical composition of an additive material for the TIG welding of aluminium–ceramic composites. This material was made in the form of so-called sticks, cast from alloys containing elements such as magnesium, scandium or zirconium in addition to aluminium. The appropriate composition of the mass content of the individual components was intended to change the crystallisation mode of the weld pool and to obtain strengthening precipitates. The most favourable structure was obtained in the case of a modification of the AlMg5 alloy by the addition of scandium. Minor dispersions of Al3Sc became the nucleation pads of fine grains, which improved the mechanical properties of the alloy. Also, in the case of the addition of zirconium, the crystallisation shifted from dendritic to fine-grain growth. In this paper, the basic strength properties of the developed materials were tested and the most favourable chemical compositions of the filling materials were selected.

Corrosion behavior of austenitic stainless steel and nickel-based welded joints in underwater wet welding

Marine structures such as ports, bridges, pipelines, vessels, and platforms are an essential part of modern infrastructure, where the use of higher-strength steel provides savings in logistics and construction. However, the repair of higher-strength steels can be challenging, especially underwater. Wet shielded metal arc welding is the most widely used and least expensive method for underwater welding repairs, but is very susceptible to hydrogen-induced cracking. Thus, researchers and welding engineers aim to reduce the amount of hydrogen in the weld material. Recent success has been achieved through the use of austenitic welding consumables, such as austenitic stainless steel and nickel-based electrodes. The use of these consumables drastically reduces the amount of diffusible hydrogen in the weld metal. However, these austenitic materials usually have different corrosion potential as compared to the structural steel the weld beads are applied to. This creates the risk of severe galvanic corrosion. In the presented study, the corrosion behavior of welds created with austenitic stainless steel and nickel-based electrodes were studied. Samples were aged for 1.5 years in the Baltic Sea. Simultaneously, the effectiveness of corrosion protection systems such as coating and Impressed Current Cathodic Protection (ICCP) were evaluated. Localized corrosion occurred in the heat-affected zone when austenitic electrodes were used in the corrosive environment. The localized corrosion depth after 1.5 years in the Baltic Sea and in the salt spray layer was approximately 250 µm and 390 µm, respectively. The ICCP system and the use of a coating were effective in preventing localized corrosion. The low pitting corrosion density of 2.5 × 103 m−2 corresponds to grade A1 according to the standard and was found to be negligible as compared to the localized corrosion in the heat-affect zone.

Determination of optical properties of single crystal diamond substrates grown via welding-assisted microwave plasma enhanced chemical vapour deposition

Lab grown single crystal diamonds (SCDs) offer unrivalled hardness, a wide range of optical transparency, and supremely high thermal conductivity reliable materials to be a part of devices run at high frequency, temperature, and power. Effective synthesis techniques are essential in enhancing the potential applications of high-quality SCDs. This study aims to decrease the thermal contact resistance between diamond seeds and the molybdenum holder by utilizing welding material. Quality of grown diamond substrates (plates) were assessed by analysing optical properties through Raman, UV-Vis, and FT-IR spectroscopic methods. The findings revealed that the grown single-crystal diamonds have excellent transmittance (>70%) and absorption at 270 nm. Calculations also showed an average absorption coefficient of 1.1 cm−1, indicating the high quality of the grown SCDs with nitrogen impurities below 10 ppm. The absorption observed in the FTIR spectra, ranging from 1600 cm−1 to 2700 cm−1 with a peak at 2354.13 cm−1, is referred to as the “two phonon region,” which is a distinctive feature of the diamond phase.

Enhancement mechanism of shear properties for SiO2 ceramics by laser welding with Al2O3/SiO2 powder

The laser direct fusion welding of SiO2 ceramics was a global challenge in the manufacture of radome. The paper explored the laser direct fusion welding of SiO2 ceramics, investigated the influence of filling powder addition and welding material composition on the formation of weld. The findings revealed that the addition of welding material effectively addressed the issue of weld formation in laser direct fusion welding SiO2 ceramic. However, the abundance of internal bubbles within the weld emerged as a significant impediment to further enhancing weld strength. The addition of SiO2/Al2O3 mixed powder not only significantly reduced the quantity and size of internal bubbles within the weld but also generated the strengthening phase Al2SiO5, leading to a substantial increase in weld shear strength, reaching a maximum of 106 % of the base material. The research results provided a new solution for direct melting welding of ceramics.

Friction welding of UFG copper using the W2Mi prototype machine

When welding ultra-fine-grained metals using conventional methods, the microstructure in the joint area is degraded (mainly due to recrystallization) in the heat-affected zone and a significant deterioration of mechanical properties, including joint strength. The aim of the research presented in this article was to identify the possibility of obtaining joints with strength close to initial material using friction welding of metal materials with ultra-fine grain. For this purpose, UFG (ultra-fine-grained) material was produced from technically pure M1Ez4 copper using a hybrid SPD (severe plastic deformation) process. The welding process was carried out on a machine with a prototype design that allows minimizing the welding time, while generating high force. The process parameters used on the prototype machine resulted in an increase in the hardness of the material by 4% in the joint area. The strength of the joint compared to the base material decreased slightly by 2%. The tests carried out proved that, using appropriate process parameters, it is possible to obtain a UFG metal joint without a decrease in its mechanical strength.

Enhanced strength and ductility of aluminum alloy laser welded joints through Ca micro˗alloyed welding materials

Aluminum alloy is widely used in high˗speed train bodies. However, compared with the base material, the tensile strength and elongation of its laser welded joints are significantly reduced, which limits the lightweight application of the next generation of high˗speed trains. The research in this article indicates that laser welding with Ca micro˗alloyed 5356 filler metal has changed the mechanical properties and microstructure of the weld seam. Without the Ca in the filler metal, the strength and elongation of the laser welded joint are only 215.5 MPa and 3.1 %. When the Ca content in the filler metal reaches 0.04 wt%, the laser welded joint has high tensile strength and maximum elongation, which are 251.5 MPa and 9.7 %, respectively. As the Ca content increases, the grain size of the welded joint gradually decreases, and the limiting effect of Ca element on the growth of α˗Al grains is the main reason for grain refinement. In addition, the addition of Ca transforms the coarse Fe˗rich phase in the weld into a fine˗grained second phase, while promoting the formation of deformable nanoparticles γ˗Al12Mg17, leading to the accumulation of dislocations and successfully improving the strength and plasticity of laser welded joints. When the Ca content further increases, the second phase grows, and the tensile strength and plasticity of the joint slightly decrease, but are still higher than that of the joint without Ca.

A study on effect of laser overlay welding parameters of stainless steel 301 LN: tensile test, microstructure analysis and microhardness evaluation

This study investigates the effects of laser overlay welding parameters on the performance of stainless steel 301 LN. The correlation between welding conditions and material characteristics was explored through systematic experiments involving tensile testing, microstructure analysis and microhardness evaluation. The study reveals that optimizing welding parameters, such as laser power, laser speed and oscillation amplitude, significantly enhances both the mechanical strength and microstructural features of stainless steel 301 LN. The results show the maximum strength was achieved using a power of 3 kW, 2 m/min speed, oscillation amplitude of 1.5 mm and focal position of 6 mm. The microhardness results displayed a significant drop in the centre of the welded zone due to thermal dynamics. Additionally, the findings of fractography results highlighted how minimum and maximum welding parameters affect the fracture characteristics and integrity of welded joints. The study also revealed a complex range of microstructures, including skeletal, vermicular and lathy ferrite formations. The microstructural images provide valuable insights into the size and distribution of lathy ferrites, and the transformation of delta-ferrite to austenite, contributing to a comprehensive understanding of the welding process. Overall, this research contributes to the ongoing efforts to refine manufacturing processes and applications for stainless steel.

Two fatigue fracture modes at different temperatures of 10%Cr heat-resistant steel weldment filled with Ni-based alloy

9–12%Cr heat-resistant steels are widely used as ultra-supercritical thermal power generation components for their excellent high temperature performance and economic applicability. In order to overcome the problems of welding cracking and carbon migration of 9–12%Cr heat-resistant steels’ welded joints, Ni-based alloy welding materials are being more and more widely used. However, a very distinct interface will form between 9–12%Cr heat-resistant steels and Ni-based alloy welding materials due to their different chemical compositions and microstructures. In this work, the microstructure of the interfacial transition zone between a 10%Cr heat-resistant steel and Ni-based alloy welding material is investigated. The influence of temperatures on the fatigue behavior of the welded joint is studied. Two fatigue fracture modes at different temperatures are found, and the underlying mechanism of the different fracture modes are discussed in detail.

Extrinsic-Riveting Friction Stir Lap Welding of Al/Steel Dissimilar Materials.

To obtain high-quality joints of Al/steel dissimilar materials, a new extrinsic-riveting friction stir lap welding (ERFSLW) method was proposed combining the synthesis advantages of mechanical riveting and metallurgical bonding. SiC-reinforced Al matrix composite bars were placed in the prefabricated holes in Al sheets and steel sheets, arranged in a zigzag array. The bars were stirred and mixed with Al sheets under severe plastic deformation (SPD), forming composite rivets to strengthen the mechanical joining. SiC particles were uniformly dispersed in the lower part of the welding nugget zone (WNZ). The smooth transition between the SiC mixed zone and extrinsic-riveting zone (ERZ) ensured the metallurgical bonding. The maximum tensile shear load of the joints reached 7.8 kN and the maximum load of the weld per unit length was 497 N/mm. The fracture occurred at the interface between the rivets and steel sheets rather than the conventional Al/steel joining interface. Moreover, ERFSLW can prolong the service life of joints due to three fracture stages. This method can be further extended to the welding of other dissimilar materials that conform to the model of "soft/hard".

Applicability investigation on failure assessment diagram of ASME code section XI - Appendix H for ferritic nuclear piping

The failure assessment diagram (FAD) is a widely used tool for evaluating the fracture acceptance of structural components. In addition to linear elastic fracture mechanics, elastic-plastic fracture mechanics, and limit load analysis, the ASME Code incorporated FAD as an alternative safety evaluation method for flaws in nuclear pipes starting from 2004 edition. This paper conducts a series of finite element elastic-plastic fracture mechanics analyses to establish the specific J–based FAD curves considering various loading and geometry conditions for ferritic pipes containing various circumferential flaws. By comparing with the suggested FAD of ASME Code Section XI - Appendix H, it is found that the radius-to-thickness ratio of pipes and the flaw depth influence the applicability of FAD, but with minor effects of crack length. In addition, the effects of material properties between base metal and weld materials on FAD are also discussed. The result of this work could be a reference when applying the FAD to evaluate the flawed piping for nuclear power plants.

Effect of Preheating and Post-Heating on the Microstructures and Mechanical Properties of TC17-Ti2AlNb Joint with Electron Beam Welding.

To enhance welding quality and performance, preheating and post-heating are usually employed on high-temperature materials, concurrently with welding. This is a novel technique in vacuum chamber electron beam welding (EBW). TC17 and Ti2AlNb alloys are the hot topics in aero-engine parts, and the welding of dissimilar materials is also a broad prospect. To settle welding cracks of Ti2AlNb, EBW with preheating and post-heating was investigated on TC17 and Ti2AlNb dissimilar alloy, which improved the manufacturing technology on high-temperature materials. The dissimilar joint no longer had cracks after preheating, which exhibited excellent welding stability and metallurgical homogeneity, and preheating and annealing had an important effect on mechanical properties. The joint strength after 630 °C annealing is higher than that of TC17 alloy base metal (BM) and other annealing temperatures, reaching 1169 MPa at room temperature and 894 MPa at 450 °C tensile condition. The joint plasticity after 740 °C annealing is equivalent to TC17 BM. EBW with preheating improved the microstructure characteristics and enhanced the plasticity of Ti2AlNb alloy weld and dissimilar joint, which would contribute to the application of Ti2AlNb alloy and Ti2AlNb dissimilar parts.

Effect of Welding Time Variation in Resistance Spot Welding on Mechanical Properties of Dissimilar Joints on Mild Steel and AISI 304 Stainless Steel

Resistance spot welding plays an important role in the automotive industry for working on car bodies or frames. Welding with two different steel materials is used in automotive structures. However, the low strength of the joints of different steel materials is a major problem, limiting the scope of its application. The quality of the welding connection Resistance spot welding is influenced by several factors, namely, time, welding current, and electrode pressure applied during welding and post-welding treatment. In this research, mild steel plate with AISI 304 stainless steel is welded by Resistance spot welding with different variations of welding time, material hardness and tensile testing that will be investigated. The results showed that the highest Rockwell Hardness time was obtained at a welding time variation of 8 seconds with a current of 6000 Ampere was 112.2 so the higher the welding time, the higher the hardness obtained. welding 8 seconds with a welding current of 6000 Ampere obtained a maximum tensile strength of 20.4 kgf/mm2 so the greater the welding current, the tensile strength will increase.

Dual‐beam lasers meet challenges of the automotive industry

AbstractThe challenges of transport electrification require the adoption of new manufacturing techniques. Lasers excel in most difficult tasks due to their ability to deliver energy with great precision, and their temporal and spatial control. Dual‐beam, adjustable mode beam (AMB) technology enables the versatile spatial control of laser energy deposition, providing wide process windows for defect‐free welding and focal spot positioning. The AMB technology improves process quality and speed in dissimilar material welding, copper welding and in structural aluminum welding across many applications in the automotive industry – from the production of batteries and drivetrains to structural body parts.

Rotating Sonotrode Design for Ultrasonic-Assisted Arc Welding of Metal Materials.

In the process of the ultrasonic-assisted arc welding of metal materials, traditional ultrasonic application methods, such as the low-frequency impact of ultrasonic horns on a base material, can easily cause the non-fusion defect. In order to solve this problem, a rotating sonotrode with a groove and double thin ends was designed in this study. The ultrasonic vibration is transmitted into the weld pool by the rolling of the sonotrode on both sides of the weld. The resonant frequency was set at 50 kHz. Firstly, based on the Mindlin theory, a rotating sonotrode without a groove was designed by solving the frequency equation and by conducting a finite element simulation. Secondly, the effects of the groove, perforation, and transition mode on the resonant frequency, stress distribution, and amplification factor were investigated by finite element simulation. Finally, the optimum rotating sonotrode with a groove was obtained. The results show that the size of a rotating sonotrode that has a small frequency error can be obtained by using the discrete interval solver method combined with finite element simulation. The groove can significantly reduce the resonant frequency. The stress concentration can be effectively reduced by using the elliptical transition mode. The resonant frequency and amplification factor of a rotating sonotrode with a groove could be effectively adjusted by a method of double-position joint perforation. The final resonant frequency was 49.721 kHz and the amplification factor was 3.02. This study provides an effective design method for a sonotrode with double thin ends and a groove structure.