Duplex Stainless Steel Welds Research Articles

Experimental Investigation of Temperature Field, Fusion Zone Microstructure and Mechanical Properties During Dissimilar Laser Welding of Nickel-Base Alloy and Duplex Stainless Steel

Experimental Investigation of Temperature Field, Fusion Zone Microstructure and Mechanical Properties During Dissimilar Laser Welding of Nickel-Base Alloy and Duplex Stainless Steel

Flux-bound TIG welding on UNS S32760 super duplex stainless steel using activating fluxes

In this article, the effect of activating flux powders viz., Silicon Dioxide (SiO2), Chromic Oxide (Cr2O3), Titanium Dioxide (TiO2) and Vanadium Pentoxide (V2O5) on Flux-Bound TIG (FB-TIG) welding of UNS S32760 Super Duplex Stainless Steel (SDSS) is investigated. Also, conventional TIG welding is done for a comparative study with the FB-TIG welds. The macrographs of the welds are obtained to analyze the depth, width and aspect ratio. The depths obtained with all the fluxes are found to be superior relative to the conventional TIG welds. The highest penetration of 6 mm is obtained for V2O5 welds. Then the microstructure and composition of the welds are analyzed using Optical Microscopy and Area-Mapping analysis. The authors observed the presence of three forms of austenite viz., Grain Boundary Austenite, Intragranular Austenite and Widmanstatten Austenite in the weldment zones. The micro-hardness profiles of the welds are also analyzed, and the profiles obtained with all the FB-TIG welds are found to be relatively smoother without any abrupt variations. Through this investigation, it is delineated that FB-TIG welding can increase the overall productivity in the welding of SDSS, as the penetration obtained is up to thrice relative to the conventional TIG welding.

Phase quantification in a duplex stainless steel welds using NDT techniques

ABSTRACT Duplex stainless steels are composed of ferrite and austenite in equal volume fractions of these phases, which provides an excellent combination of mechanical properties and corrosion resistance, especially when compared with conventional stainless steel grades. When these steels are welded, there are significant changes in the austenite-to-ferrite ratio therefore in their final properties. Nowadays, the ferritoscope is the unique non-destructive technique used to quantify these two phases content in situ. This tester instrument is limited to the evaluation of large areas, is not suitable for the heat affected zone and is also very sensitive to the surface finish, being considered an intermediate precision technique. So, it is necessary to develop more reliable field techniques. In this research, thermoelectric power measurements and induced current techniques are proposed to evaluate the phase quantification in S32205 welds. According to the results, both techniques are reliable and highly sensitive to phase changes in the weld bead, heat affected zone and base metal. For the thermoelectric power technique, a probe with nickel tip should be used to obtain the highest sensitivity and for the induced current technique, a probe type-pencil with a central frequency of 6 MHz should be used.

Electrochemical behavior and microstructure of diffusion welding of zirconium alloy and super duplex stainless steel

In this study, the effect of welding temperature on interface microstructure, mechanical properties, and electrochemical behavior of diffusion welded joints (DWJs) of zirconium alloy (ZrA, Zr702 grade) and super duplex stainless steel (2205 duplex stainless steel grade) were investigated. Alloys were welded in a vacuum atmosphere at four different temperatures (800, 850, 900, and 925 °C) for 75min under 4MPa compressive pressure. The optical, scanning electron microscopy, electron probe micro-analyzer, and X-ray diffraction techniques were used to characterize the interfacial microstructure of the DWJs. Layers of intermetallics were formed along the welded interface at 850 °C and above welding temperatures. At 850 °C, a single reaction layer (phase mixture of ZrFe2+ZrCr2) was observed; however, bilayers (ZrFe2+ZrCr2 and Fe2Zr+FeZr3 phase mixtures), and triple layers (ZrFe2+ZrCr2, Fe2Zr+FeZr3, and β-Zr+FeZr3 phase mixtures) were observed at the welded interface of the joints processed at 900 and 925 °C, respectively. Width of the reaction layer (phase mixtures) increases with an increase in the welding temperature. The DWJs processed at 900 °C reach the maximum joint strength of ~312MPa along with ~6.4% ductility. For corrosion analysis, studies of the base alloys and DWJs in 0.1mol/L HCl and 0.1mol/L NaOH solutions separately using electrochemical techniques, such as open circuit potential, electrochemical impedance spectroscopy, and potentiodynamic polarization were undertaken.

Influence of arc energy on the microstructure and corrosion behavior of ER2209 duplex stainless steel deposited on Q345B low-alloy steel by GMAW

In order to eliminate the complex effects of thermal cycling and the thermal effects of the next pass on multi-layer multi-pass welding of low-alloy steel and duplex stainless steel, ER2209 welding wire was single-layer single-pass deposited on the surface of Q345B hot-rolled plate by gas metal arc welding (GMAW). The microstructure and corrosion resistance of welded joints were studied by different arc energies. The results showed that the arc energy had a significant impact on the “tongue-shaped” morphology and the width of heat affect zone in the welded joint, which in turn affected the corrosion performance of the welded joints. Due to the least distribution of “tongue-shaped” morphology and minimum width of heat affected zone in the welded joint with arc energy of 0.645kJ/mm, it owned the best corrosion resistance. The weld metals of the welded joints were composed of ferrite and austenite phases. The ferrite phases were distributed along grain boundaries and intergranular. As the heat input increases, the distribution of ferrite phase along grain boundaries gradually decreased. The corrosion products and corrosion morphology of the welded joint were also investigated and the corrosion mechanism was discussed in detail. The research results of this article provide a theoretical basis for improving the corrosion performance of multi-layer multi-pass welded joints of low-alloy and duplex stainless dissimilar steels.

Evolution of phase ratio and its effect on residual stress for 2205 duplex stainless steel multipass welded joints by thermo-metallurgical-mechanical model

The control of phase ratio and residual stress is a crucial subject for the structural integrity of duplex stainless steel welded components. Therefore, this paper aims to clarify the evolution of phase ratio and its effect on residual stress for duplex stainless steel multipass welded joints by a thermo-metallurgical-mechanical coupled welding model, alongside the crucial experiments which contribute to the development and validation of the coupled model. The developed model takes both the precipitation and dissolution behavior of austenite under repeated thermal cycles into consideration, thereby demonstrating a remarkable ability to predict the distribution of phase ratio and residual stress. The influencing mechanism of solid-state phase transformation on residual stress is discussed extensively. The results reveal that, for the duplex stainless steel welded joints by gas tungsten arc welding, excessive austenite is often formed within the welding zone particularly for the middle passes, while it is the occurrence of ferritization at the heat affected zone. The effect of phase transformation on residual stress is mainly presented by the change of mechanical properties and phase volume. The overtransformation from ferrite to austenite tends to induce a higher tensile residual stress, vice versa, compressive stress. In addition, it is challenging to achieve phase balance through heat input alone. However, a smaller heat input is recommended to minimize residual stress while ensuring welding penetration. This paper serves as a theoretical foundation for controlling the phase ratio and mitigating residual stress during the welding of duplex stainless steel, thereby contributing to the enhancement of weld quality and structural reliability.

Predicting Weld Quality in Duplex Stainless Steel Butt Joints During Laser Beam Welding: A Hybrid DNN-HEVA Approach

Duplex stainless steel (DSS) welding is critical for producing structures and components in a variety of industries. Because traditional optimization approaches cannot manage the complexity of welding, additional solutions must be investigated. This study addresses the need for a systematic exploration of the welding parameters affecting the quality and performance of DSS butt joints, specifically employing fiber laser welding. This study focuses on butt joints in UNS S32304 and 304L using a fiber laser. Welding process parameters were systematically varied, including laser power, scanning speed, beam diameter, and focal position. To efficiently examine the parameters in the design space, the response surface methodology (RSM) with Box–Behnken design (BBD) was used. The combination of the specific parameter values used in the 7th run (Laser Power: 1600 W, Scanning Speed: 2000 mm/min, Beam Diameter: 1.5 [Formula: see text]m, Focal Position: 30 mm) led to better yield point stress (YPS), maximum tensile stress (MTS), break stress (BS) and reduction in area (RA). ANOVA and lack of fit analysis confirmed the significance of the experiment. In particular, the selected welding parameters significantly influenced all responses. A hybrid machine learning method of deep neural network (DNN) and human eye vision algorithm (HEVA) was used for predicting weld quality during laser beam welding (LBW). The hybrid DNN-HEVA consistently outperformed other optimization methods (RSM-BBD, FNN, CNN, and RNN) across key welding quality parameters. High [Formula: see text]2 values (0.9922, 0.9962, 0.9983, and 0.9907) indicated a strong correlation between predicted and actual values for all calculated responses. Lower RMSE, MSE, and MAE values were also highlighted in the precision of predicted values to the experimental data.

Effect of cold metal transfer on corrosion properties of Duplex Stainless-Steel welds

Effect of cold metal transfer on corrosion properties of Duplex Stainless-Steel welds

The relationship between austenite stabiliser element and post-weld heat treatment on the corrosion behaviour of the welded duplex stainless steel made by gas tungsten arc welding

The corrosion behaviour and the influence of nickel and post-weld heat treatment (PWHT) on the susceptibility to corrosion in welded duplex stainless steels were investigated. After PWHT, the amount of nickel for the weld region increases resulting in the generation of austenite and consequently, helping to obtain a favourable ferrite-to-austenite ratio. Comparing the experimental outcomes, it is noticed that the pits initiate and propagate in HAZ indicating this area is more susceptible to corrosion resistance compared to the fusion zone. The pitting resistance equivalent number alone is not sufficient reason to study the complex corrosion phenomenon, and the influence of other parameters namely microstructural evolution on the breakdown of passivity by pitting and the existence of intermetallic phases should be determined together.

Influence of inconel interlayer on microstructural, mechanical and electrochemical characteristics in single-pass ATIG welding of dissimilar austenitic and duplex stainless steel

This study investigates the impact of Inconel 625 interlayer on dissimilar welded low nickel austenitic stainless steel (LNiASS) and super duplex stainless steel (S32760) using activated tungsten inert gas (ATIG) welding. Two weldments were prepared: with and without (autogenous) interlayer. Geometrical investigation of the weld cross sections revealed that interlayer-based welding significantly increased the depth of penetration and decreased weld width as compared to autogenous welding at the same welding current. The dual microstructure was observed in the weld zone (WZ) of autogenous weldment while fully austenitic structure with few intermetallics was observed in the WZ of interlayer-based weldment. Mechanical properties, particularly impact strength observed to be improved in the case of interlayer-based weldment (91 ± 2 J) compared to autogenous weldment (68 ± 2 J). Lower microhardness was noticed for the WZ of interlayer-based weldment (258 ± 3 HV0.2) than WZ of autogenous (279 ± 2 HV0.2) weldment due to the presence of higher content of Ni. However, UTS of interlayer-based weldment (654 MPa), falls short in comparison to the autogenous weldment (693 MPa), indicating a compromised joint efficiency of 5.96%. The corrosion resistance was observed to be higher for the WZ of interlayer-based weldment attributed to the higher content of Ni and Mo. The sensitization study revealed 47.33% degree of sensitization in the WZ of autogenous weldments due to dual microstructure, while interlayer-based weldments showed no sensitization.

In situ chemical analysis of duplex stainless steel weld by laser induced breakdown spectroscopy

The high corrosion resistance and good mechanical properties of duplex stainless steel (DSS) are due to its special chemical composition, which is a balanced phase ratio of ferrite (α) and austenite (γ). Many industrial applications require the integration of DSS components. For this, Gas tungsten arc welding (GTAW) is an excellent choice, as it allows an automated operation with high reproducibility. However, when the weld pool solidifies, critical ratios of α- and γ- phases can occur, which lead to solidification cracking, increased susceptibility to corrosion, and a decrease in ductility and critical strength. Previous studies have shown that these defects can be caused by the accumulation of manganese and chromium in the heat affected zone (HAZ), requiring ongoing monitoring of this accumulation. A suitable method for such monitoring is laser-induced breakdown spectroscopy (LIBS), which can be used in two operating modes: calibration using standard reference samples and calibration-free. Unlike conventional quantitative LIBS measurements, which require reference samples to generate a calibration curve, calibration-free LIBS (CF-LIBS) allows chemical compositions to be determined solely from the emission spectrum of the plasma. Numerous publications show that CF-LIBS is a fast and efficient analytical method for the quantitative analysis of metal samples. In this work, CF-LIBS is applied to spectra obtained during GTAW DSS welding and the result is compared with those obtained by PLS analysis. A good correlation was found between both types of analysis, demonstrating the suitability of the CF-LIBS method for this application. The CF-LIBS method has a significant advantage over conventional LIBS due to the rapid in situ measurement of concentrations of major alloying elements without calibration procedure. This, combined with fast feedback and appropriate adjustment of welding parameters, helps prevent welding defects.

Physical simulation of low temperature phase separation during multipass welding of super duplex stainless steel

This study aimed to investigate the degree of low-temperature phase separations and 475 °C -embrittlement in physically simulated multipass super duplex stainless steel (SDSS) welds. A single bead weld was produced using gas metal arc welding and multiple thermal cycles with different peak temperatures were applied using a Gleeble physical simulator with fixed and moving jaws to simulate the influence of constrained designs, to mimic the welding of thick SDSS components. The samples were studied using atom probe tomography and the results were correlated with toughness and ferrite microhardness. The results showed that the microhardness of the ferrite in the constrained simulated multipass reheated weld increased from 304 HV to 374 HV after 5 min aging at 475 °C. The amplitude of the Cr concentration of the same sample, showing the level of Fe-Cr phase separation, increased from 1.025 to 1.045 after 5 min aging at 475 °C. Despite the clear development of phase separation in the ferrite, the toughness did not drop. It can be concluded that reheated SDSS welds are not susceptible to 475 °C -embrittlement during short fabrication times of up to 5 min for the austenite level of 50%.

Microstructural and mechanical properties of electron beam welded super duplex stainless steel

The electron beam welding of super duplex stainless steels is associated with challenges due to the concentrated heat input and the nitrogen loss that result in a predominantly ferritic structure after the solidification. This study presents an approach to overcome this issue by feeding nickel-based filler wire into the melt pool in welding of 2507 super duplex stainless steel. Results showed that the high-frequency beam oscillation combined with a multi-beam technique led a good mixing between the base metal and the filler wire, even at a large depth-to-width ratio. Additionally, the weld geometry was characterized by near-parallel fusion lines and a narrow heat-affected zone. The nickel addition resulted in a balanced microstructure in the weld metal with ferrite fractions of 35–55 %, despite a significant nitrogen loss, consequently leading to impact energy values of 215 ± 15 J and hardness values of 285 ± 15 HV. The findings of this investigation allow fabricators to effectively design electron beam welding processes for producing thick-walled super duplex stainless steel components.

Distribution and Characteristics of Residual Stresses in Super Duplex Stainless Steel Pipe Weld

This paper explores the distribution and features of residual stresses formed by super duplex stainless steel pipe welding. Experimental investigations, which encompass an elevated temperature tensile test and metallographic observation along with a hardness test and residual stress measurement, were first conducted to obtain the mechanical properties at high base metal temperatures and to confirm whether or not the duplex stainless steel undergoes martensitic phase development during the welding process. Finally, experiments were performed to scrutinize the residual stress evolution through the metallurgical phase transformation in the weld region and its vicinity. A sequentially coupled 3D thermal, mechanical and metallurgical finite element (FE) model capable of incorporating the experimental consequences was established next. A 3D FE simulation of the girth welding process was conducted, and the axial and hoop residual stress profiles along the girth were evaluated. The results substantiate that martensitic phase evolution occurs in the process of cooling during the welding of super duplex stainless steel, and they also highlight the significance of taking the metallurgical phase transformation into account in the numerical reproduction of the girth welding process for the accurate expression of weld-induced residual stresses, which is especially important for precisely predicting hoop residual stresses.

Numerical modeling of the temperature distribution and melt flow in dissimilar fiber laser welding of duplex stainless steel 2205 and low alloy steel

The research outlined in this paper pertains to the computational modeling and experimental investigation of laser keyhole welding between duplex stainless steel 2205 and low carbon steel (A516). A crucial aspect of keyhole welding entails predicting the phase transition behavior of the materials involved. The vaporized metal generates a recoil pressure and distorts the interface between the liquid and vapor phases, thus forming a vapor capillary. A multiphysics model employing the finite volume method was proposed to achieve a highly accurate simulation of the temperature and velocity fields. The findings demonstrate that the resulting weld bead relies heavily on the keyhole's structural characteristics. Additionally, analysis of the temperature distribution at a specific temporal and spatial point reveals that duplex stainless steel exhibits elevated temperatures owing to low thermal penetration at a distance of 5 mm from the juncture of the two components compared to A516. The numerical simulation results were in good agreement with experimental results for prediction of temperature filed and melt flow that have impact on weld bead and melt pool geometry. The weld bead width changes according to variation of welding speed and laser power has been in good agreement with the temperature distribution at upper surface of the workpiece extracted from simulation results. The melt pool geometry predicted from the simulation results (melt flow and temperature field) has been in good agreement with the melt pool geometry of the experiment. The temperature distribution from simulation results has a good correlation with the microstructural changes of the melt pool region according to the melting, solidification and temperature gradient at the melt pool region and adjacent HAZ of base metals.

Microstructure Formation and Its Effect on Mechanical Properties for Duplex Stainless Steel 2205 Plasma Arc Welded Joint

The control of phase balance has always been a tough challenge for the welding of duplex stainless steel, which heavily restricts its optimal serving performance in engineering. The microstructure development and mechanical characteristics of SAF2205 plasma arc welded joints were thoroughly examined in this paper. It was proven that the phase balance can be well controlled by plasma arc welding, and the austenite content of the welded joints was about 60%. Despite successful phase control, there was still grain coarsening and distortion; i.e., at the center of the welded zone, the gain size was about eight times that of the base metal, and the austenite was mainly in the form of grain boundary austenite and intragranular austenite, while more Widmanstatten austenites were found in the heat-affected zone. In addition, a transition region between the heat affected zone and the center exhibited columnar ferritic grains. Furthermore, the plasticity and toughness of the welded joints were significantly decreased, especially the elongation in the longitudinal direction, which is about 10% lower than that of the base metal, and transversal tensile strength remained comparable to the base metal, with only a slight reduction in longitudinal tensile strength. Lastly, the formation mechanism of microstructure and its correlation with mechanical properties were revealed. This investigation offers valuable insights into the structural integrity of duplex stainless steel welded joints in engineering applications.

Improving Welding Penetration and Mechanical Properties via Activated-Flux Smearing by Tungsten Inert Gas Arc Welding

For the welding process of thick-walled structural components in liquid rocket engines, the activated-flux TIG method can effectively address issues such as the formation of intermetallic phases in the weld seams, thereby enhancing mechanical performance. The present study investigates the activated-flux TIG welding technique on 10mm thick 1Cr21Ni5Ti duplex stainless steel plates. Various activated-flux, including -SiO2, TiO2, V2O5, NiO, MnO2, CaO, AlCl3, CaF2, B2O3 Cr2O3, and Al2O3, were examined to understand their impact on the weld-bead geometry. The aim was to determine the optimal activator ratio for the effective welding of 1Cr21Ni5Ti duplex stainless steel. The weld-shift experiment confirmed that the deep penetration observed in flux-assisted welding is attributed to Marangoni convection in the molten pool. Comprehensive evaluations and analyses were performed on the microstructure and mechanical properties of the normal welded joint and the A-TIG welded joint. Finally, the study delves into a discussion on the factors influencing changes in the weld penetration, microstructure, and mechanical properties of the weld.

Kinetics of Intermetallic Phase Precipitation in Manual Metal Arc Welded Duplex Stainless Steels.

The article presents the influence of heat treatment on the kinetics of transformations in lean duplex LDX2101 steel and a weld made of standard duplex 2209 material, which was welded by manual metal arc welding. Changes in the microstructure, hardness, and magnetic phase content were analyzed after heat treatment was conducted at a temperature of 800 °C for a period ranging from 15 to 1440 min. Light and scanning microscopy, Vickers hardness measurements, and magnetic phase content measurements using a ferritoscope were used for the research. In the LDX2101 steel, the presence of δ-ferrite and γ austenite was identified and additional Cr2N nitrides were observed in the heat-affected zone. After heat treatment, the decomposition of δ ferrite into γ2 austenite and Cr2N nitrides was observed in both areas. In the case of weld made by the coated electrode in 2209 grade, a ferritic-austenitic microstructure with allotriomorphic austenite (γA), Widmanstätten austenite (γW), and idiomorphic austenite (γI) and δ-ferrite area with "bee swarms" of fine precipitations of chromium nitrides Cr2N and non-metallic inclusions (NMIs) of slag, formed during the welding process, are observed in the as-welded state. After heat treatment, the presence of the χ phase (after 15 min of annealing) and the σ phase (after 120 min of annealing) was additionally identified. The kinetics of intermetallic phase evolution in welds made from 2209 material were presented. The obtained results of hardness measurements and metallographic tests were correlated, which allowed for a quick check of the precipitation processes on the used element.

The Effects of ArC Voltage and Shielding Gas Type on the Microstructure of Wire ArC Additively Manufactured 2209 Duplex Stainless Steel

Abstract Duplex stainless steels (DSSs) are widely used due to their corrosion resistance. Austenite and ferrite determine the excellent properties. Ferrite provides strength and good corrosion resistance, while austenite provides toughness and weldability. During our research, samples were produced with ER 2209 duplex steel wire using wire arc additive manufacturing (WAAM). Two different 17 V and 19 V arc voltages were used during the production. Two shielding gases were used for each voltage: M12-ArC-2.5 and M12-ArHeC-20/2. The research aimed to determine the ferrite ratio as a function of the welding parameters. The ferrite (or austenite) content must be between 30% and 70% for duplex stainless steel welds, according to the ISO 17781 standard. Based on our research, it can be stated that the austenite ratio increases as the voltage increases, thus failing to fulfill the standard's requirements. The helium content reduced the ferrite ratio even when the 17 V voltage was used due to the gas's higher ionization potential. During the metallographic examination, our welded samples met the standard requirements for the austenite content for 17 V arc voltage and M12-ArC-2.5 shielding gas. The ferrite content in the entire sample cross-section fell between 30-42% during feritscope and image analysis measurements. These welding parameters can be recommended for industrial applications.

Underwater wet laser welding of duplex stainless steel under various water depths

Reports on experiments of underwater wet laser welding (UWLW) are scarce because of the poor forming quality of weldments. To address the key manufacturing challenges such as failure of welding with water depth exceeding 7 mm and the generation of pores and cracks which caused by the rapid water cooling, a specific self-designed flux assisted welding at different water depths (0–30 m) was innovatively proposed in this study. The microstructure, phase distribution, and properties of underwater wet laser welded duplex stainless steel joints were examined. The welding process successfully produced joints free from pores or cracks, even when performed within a 15 m water depth. In conjunction with thermodynamic calculation, the evolution process of welds and the effect of nickel from the flux on phases structure were analyzed. As the water depth increases and the welding speed decreases, the number of pores inside welds increase significantly, and no cracks are found. The penetration of all welds made in deep water is obviously smaller than that of shallow water and increased heat input does not seem to contribute to the increase of weld penetration. With the increase of water depth, a large amount of coarsened austenite consisted of columnar grains and cellular grains appear in weld zone. Texture and dislocation of the weld made in shallow water were investigated. Many dislocations including edge dislocations and dislocation entanglements arranged in austenite phase, while seldom dislocations appear in ferrite phase.