In this paper we study the 6d localized charged matter spectrum of F-theory directly on a singular elliptic Calabi-Yau 3-fold, i.e. without smoothing via resolution or deformation of the entire fibration. Given only the base surface, discriminant locus, and the SL(2, ℤ) local system, we propose a general prescription for determining the charged matter spectrum localized at intersections of seven-branes, using the technology of string junctions. More precisely, at each codimension-2 collision of seven-branes, we determine the local seven-brane content and compute the number of massless string junctions modulo the action of the SL(2, ℤ) monodromy. We find agreement with the predicted results from 6d anomaly cancellation in all cases considered. Examples include a generic Weierstrass model with arbitrary Kodaira fiber intersecting an I1, as well as cases with jointly charged matter localized at intersections of non-abelian seven-branes.
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