Oil Weathering Research Articles

Multimedia fate modeling of oil spills in ice-infested waters: An exploration of the feasibility of fugacity-based approach

The increasing demand for energy and the high probability of finding vast reserves have shifted offshore exploration and production activity into colder and harsher environments. Offshore activity increases risk of oil spills in these colder and harsher marine environments. The development of a spill contingency plan requires the prediction of fate and transport of oil. Oil spill trajectory and fate modeling in cold marine environments is an exceedingly complex problem, in which variability of physical environment and oil-ice interactions must be addressed. This paper explores the usefulness of the fugacity approach for spill fate and transport modeling in ice-infested waters through a simulation model that combines surface oil weathering algorithms with Level IV fugacity models. Four bulk compartments are used for modeling: air, ice cover, water and sediment. Weathering of surface oil on and under the ice cover is represented by a system of differential equations. Unsteady state mass balance equations are also developed for each of the four bulk phases. The outputs of the multimedia fate model are time-dependent profiles of oil slick area, fraction evaporated, water content in oil, viscosity, and concentration of oil in air, ice cover, water, and sediment. The application of the proposed model is illustrated through the simulation of a hypothetical oil spill in the Labrador Sea. The proposed model is simple but has the promise that it can be further developed to become directly useful to the simulation of spill behavior in ice-infested waters.

IMPACTS OF WASHOVER EVENTS ON FATE AND DISTRIBUTION OF MC252 OIL IN A COASTAL SYSTEM

Washover events on coastal headland beaches occur when storm surge from cold fronts, high tides, tropical storms, and hurricanes move across the beach, reworking and depositing sand in the back marshes and shallow mudflat areas. On Fourchon Beach, Louisiana, a 9-mile coastal headland beach impacted by the Deepwater Horizon oil spill, these washover events have intermittently moved oil from the subtidal and intertidal portion of the beach to the supratidal mudflats and marsh areas. In order to determine the impacts of washover events on oil fate, 4 complementary studies are being undertaken. First, washover areas (N=56) have been mapped and sampled for PAHs and n-alkanes in the most heavily impacted area eastern end of Fourchon Beach. Samples indicate the most heavily impacted segments were in areas where a physical breach of the beach developed. Second, characteristics of specific washover events and locations are being studied to establish typical categories of events (i.e., breaches, remobilization of oil on the beach and mobilization of subtidal oil mats) as well as the characteristics of oil mobilized by each category. As an example, presence of MC252 oil was mapped using soil cores in a washover mudflat behind a breach, which developed during TS Isaac in 2011. MC252 oil was present at an average of 6 – 12 cm below the surface. Concentrations of PAHs in this layer ranged from 1.2 to 16 mg/kg consisting primarily of C1-C4 phenanthrenes, C2 and C3 dibenzothiophenes and C1-C2 chrysenes. Third, the chemical signature of crude oil including a range of petrogenic PAHs and n-alkanes relative to poorly biodegradable C30-hopane is being used at these locations to assess the relative weathering of oil at various stages in the washover process. Finally, a laboratory microcosm study is being conducted to understand the biogeochemical controls on oil biodegradation in the new environment (washover mudflat) and how these controls impact its ability to degrade naturally. Anaerobic treatments consistent with the flooded mudflat areas are amended with N and sulfate in various combinations to determine if nutrients or electron acceptors are limiting in the washover environment. Results to date indicate that most PAHs are stable under the flooded conditions with the exception of C1-phenanthrenes. These studies will be discussed in the context of remedial measures during the emergency response phase used on Fourchon Beach to prevent washover impacts.

DEVELOPMENT AND APPLICATION OF DTox: A QUANTITATIVE DATABASE OF THE TOXICITY OF DISPERSANTS AND CHEMICALLY DISPERSED OIL

ABSTRACT The Deepwater Horizon oil spill revived discussions on the use of dispersants as an oil spill countermeasure. One of the greatest concerns regarding the use of dispersants deals with potential exposure of water column organisms to high concentrations of oil. While toxicity data on dispersants and physically and chemically dispersed oil have been generated for decades under controlled laboratory conditions, the practical use of this information has been limited by the lack of a centralized data repository. As a result, the Dispersant and Chemically Dispersed Oil Toxicity Database (DTox) was created to address that shared need of unrestricted and rapid access to toxicity data. DTox is a quantitative database that gathers existing toxicity data through a careful review and compilation of data extracted from the peer-review and gray literature. Through a rigorously evaluation of the quality of each data source, this database contains pertinent information including species scientific name, life stage tested, dispersant name, exposure type, oil weathering stage, exposure duration, etc. More importantly, this database contains effects concentrations reported on measured or nominal basis. Within the database, each data source is assigned an applicability score based on their relevance to oil spills. Key criteria in the determination of source applicability include exposure type, reported effects concentrations, and reported analytical chemistry. Information in DTox has been further integrated into a user-friendly tool that allows for on-the-fly data searches and data plotting in the form of Species Sensitivity Distributions. To date, +400 papers have been evaluated for potential inclusion into the database, and data extracted from +170 sources. Despite inherent limitations, existing toxicity data are of great value to the oil spill scientific community. Although toxicity data will never be enough to answer all toxicity questions regarding the use of dispersants, this centralized data repository can help inform decisions on dispersant use and can help identify data needs and gaps. The ultimate goal of this tool is its contribution to a better understanding of the biological effects of dispersants and oil in the aquatic environment.

Naphthenic Acids in Coastal Sediments after the Hebei Spirit Oil Spill: A Potential Indicator for Oil Contamination

Naphthenic acids (NAs) as toxic components in most petroleum sources are suspected to be one of the major pollutants in the aquatic environment following oil spills, and the polarity and persistence of NAs make it a potential indicator for oil contamination. However, the contamination and potential effects of pollutants in oil spill affected areas remain unknown. To investigate NAs in oil spill affected areas, a sensitive method was first established for analysis of NAs, together with oxy-NAs in sediment samples by UPLC-QTOF-MS. Then the method was applied to determine the NA mixtures in crude oil, weathered oil, and sediments from the spilled sites after the Hebei Spirit oil spill, Taean, South Korea (Dec. 2007). Concentrations of NAs, O3-NAs, and O4-NAs were found to be 7.8-130, 3.6-44, and 0.8-20 mg kg(-1) dw in sediments from the Taean area, respectively, which were much greater than those measured in the reference sites of Manlipo and Anmyundo beaches. Concentrations of NAs were 50-100 times greater than those (0.077-2.5 mg kg(-1) dw) of PAHs in the same sediment samples, thus the ecological risk of NAs in oil spill affected areas deserves more attention. The sedimentary profiles of oil-derived NAs and background NAs centered around compounds with 21-35 and 12-21 carbons, respectively, indicating that the crude-derived NA mixtures originating from the 2007 oil spill were persistent. Acyclic NAsn=5-20 were easily degraded compared to cyclic NAsn=21-41 during the oil weathering processes, and the ratio of oxy-NAsn=21-41 relative to NAsn=21-41 could be a novel index to estimate the degree of oil weathering in sediments. Altogether, the persistent oil-derived NAsn=21-41 could be used as a potential indicator for oil-specific contamination, as such compounds would not be much affected by the properties of coastal sediments possibly due to the high sorption of the negatively charged compounds (NAs) in sediment.

Molecular Evidence of Heavy-Oil Weathering Following the M/V Cosco Busan Spill: Insights from Fourier Transform Ion Cyclotron Resonance Mass Spectrometry

Recent studies have highlighted a critical need to investigate oil weathering beyond the analytical window afforded by conventional gas chromatography (GC). In particular, techniques capable of detecting polar and higher molecular weight (HMW; > 400 Da) components abundant in crude and heavy fuel oils (HFOs) as well as transformation products. Here, we used atmospheric pressure photoionization Fourier transform ion cyclotron resonance mass spectrometry (APPI FT-ICR MS) to identify molecular transformations in oil-residue samples from the 2007 M/V Cosco Busan HFO spill (San Francisco, CA). Over 617 days, the abundance and diversity of oxygen-containing compounds increased relative to the parent HFO, likely from bio- and photodegradation. HMW, highly aromatic, alkylated compounds decreased in relative abundance concurrent with increased relative abundance of less alkylated stable aromatic structures. Combining these results with GC-based data yielded a more comprehensive understanding of oil spill weathering. For example, dealkylation trends and the overall loss of HMW species observed by FT-ICR MS has not previously been documented and is counterintuitive given losses of lower molecular weight species observed by GC. These results suggest a region of relative stability at the interface of these techniques, which provides new indicators for studying long-term weathering and identifying sources.

Greenhouse gases generated from the anaerobic biodegradation of natural offshore asphalt seepages in southern California

Significant offshore asphaltic deposits with active seepage occur in the Santa Barbara Channel offshore southern California. The composition and isotopic signatures of gases sampled from the oil and gas seeps reveal that the coexisting oil in the shallow subsurface is anaerobically biodegraded, generating CO2 with secondary CH4 production. Biomineralization can result in the consumption of as much as 60% by weight of the original oil, with 13C enrichment of CO2. Analyses of gas emitted from asphaltic accumulations or seeps on the seafloor indicate up to 11% CO2 with 13C enrichment reaching +24.8‰. Methane concentrations range from less than 30% up to 98% with isotopic compositions of –34.9 to –66.1‰. Higher molecular weight hydrocarbon gases are present in strongly varying concentrations reflecting both oil-associated gas and biodegradation; propane is preferentially biodegraded, resulting in an enriched 13C isotopic composition as enriched as –19.5‰. Assuming the 132 million barrels of asphaltic residues on the seafloor represent ~40% of the original oil volume and mass, the estimated gas generated is 5.0×1010 kg (~76×109 m3) CH4 and/or 1.4×1011 kg CO2 over the lifetime of seepage needed to produce the volume of these deposits. Geologic relationships and oil weathering inferences suggest the deposits are of early Holocene age or even younger. Assuming an age of ~1,000 years, annual fluxes are on the order of 5.0×107 kg (~76×106 m3) and/or 1.4×108 kg for CH4 and CO2, respectively. The daily volumetric emission rate (2.1×105 m3) is comparable to current CH4 emission from Coal Oil Point seeps (1.5×105 m3/day), and may be a significant source of both CH4 and CO2 to the atmosphere provided that the gas can be transported through the water column.

Oil spill modelling methods: application to the south–eastern part of the Baltic Sea

The state-of-art in oil spill modelling methods is summarized, focusing on development since 2000. Some recommendations for possible application of these methods to the south–eastern part of the Baltic Sea are prepared. Particular attention is paid on the methods of parameterization of volume of oil spill and calculation of advection of the oil spills. Consideration is also given to methods used in oil weathering models.

A cross-scale numerical modeling system for management support of oil spill accidents

A flexible 2D/3D oil spill modeling system addressing the distinct nature of the surface and water column fluids, major oil weathering and improved retention/reposition processes in coastal zones is presented. The system integrates hydrodynamic, transport and oil weathering modules, which can be combined to offer different-complexity descriptions as required by applications across the river-to-ocean continuum. Features include accounting for different composition and reology in the surface and water column mixtures, as well as spreading, evaporation, water-in-oil emulsification, shoreline retention, dispersion and dissolution. The use of unstructured grids provides flexibility and efficiency in handling spills in complex geometries and across scales. The use of high-order Eulerian–Lagrangian methods allows for computational efficiency and for handling key processes in ways consistent with their distinct mathematical nature and time scales. The modeling system is tested through a suite of synthetic, laboratory and realistic-domain benchmarks, which demonstrate robust handling of key processes and of 2D/3D couplings. The application of the modeling system to a spill scenario at the entrance of a port in a coastal lagoon illustrates the power of the approach to represent spills that occur in coastal regions with complex boundaries and bathymetry.

Composition of natural bitumens from the Ural-Volga region

Natural bitumen (viscous, viscoplastic, and solid) cannot be extracted by methods commonly used in oil production, and it is usually a disregarded reserve of hydrocarbon resources. A sharp difference between the properties of Permian bitumens from the Ural-Volga Region and Carboniferous and Devonian oils in the fields of Tatarstan was demonstrated. This difference is caused by the predominance of asphaltenes and alcohol-benzene tars enriched in hydroxyl and ester oxygen in them; that is, natural bitumen in rocks, especially above the local basis of erosion, is a product of the deep biochemical oxidation and weathering of oils. Other mechanisms of the transformation of oils into natural bitumen in the deep layers of Devonian and Carboniferous sandstones were also reflected in the composition and properties natural bitumens.

Weathering of Petroleum Biomarkers: Review in Tropical Marine Environment Impacts

Weathering of biomarkers is a physical, geochemical and biological process that alters the oil components. Whether in petroleum geochemistry or environmental impact studies, knowledge of mechanisms, residence times and chemical intermediates is essential to describe the scientific and technical bases of oil deterioration. This report attempts to review the concepts of oil weathering and its biomarkers specifically, in order to inform studies related to the impact of spills in marine environments.

Navigation of autonomous vehicles for oil spill cleaning in dynamic and uncertain environments

In the context of oil spill cleaning by autonomous vehicles in dynamic and uncertain environments, this paper presents a multi-resolution algorithm that seamlessly integrates the concepts of local navigation and global navigation based on the sensory information; the objective here is to enable adaptive decision making and online replanning of vehicle paths. The proposed algorithm provides a complete coverage of the search area for clean-up of the oil spills and does not suffer from the problem of having local minima, which is commonly encountered in potential-field-based methods. The efficacy of the algorithm is tested on a high-fidelity player/stage simulator for oil spill cleaning in a harbour, where the underlying oil weathering process is modelled as 2D random-walk particle tracking.

Spatial distribution and concentration assessment of total petroleum hydrocarbons in the intertidal zone surface sediment of Todos os Santos Bay, Brazil

The primary objective of this study was to investigate the concentrations and spatial distribution of the total petroleum hydrocarbons (TPHs) in the intertidal zone surface sediment of Todos os Santos Bay, Brazil, to assess the distribution and degree of contamination by TPHs, measure the level of TPH degradation in the surface sediment, and identify the organic matter sources. The surface sediment used in this study was collected in 50 stations, and TPHs, isoprenoid alkanes (pristane and phytane), and unresolved complex mixture (UCM) were analyzed by gas chromatography with a flame ionization detector. The total concentrations ranged from 0.22 to 40,101μgg(-1) dry weight and showed a strong correlation with the total organic carbon (TOC) content. The highest TPH concentrations were observed in samples from the mangrove sediments of a river located near a petroleum refinery. Compared with other studies in the world, the TPH concentrations in the intertidal surface sediment of Todos os Santos Bay were below average in certain stations and above average in others. An analysis of the magnitude of UCM (0.11 to 17,323μgg(-1) dry weight) and the ratios nC17/Pr and nC18/Ph suggest that an advanced state of oil weathering, which indicates previous contamination. The molar C/N ratios varied between 5 and 43, which indicate organic matter with a mixed origin comprising marine and continental contributions.

Dispersant and salinity effects on weathering and acute toxicity of South Louisiana crude oil

Chemical dispersants are an important technology in the remediation of oil spills in the aquatic environment, facilitating degradation of crude oil and salinity is an important factor in dispersant effectiveness. The aim of the present study was to explore the role of salinity on the degradation chemistry of crude oil polycyclic aromatic hydrocarbons (PAHs) and acute toxicity of the water accommodated fraction (WAF) of the dispersant COREXIT 9500A and chemically dispersed crude oil on a common estuarine fish. Laboratory microcosms were designed at salinities of 4 parts per thousand (ppt), 12 ppt, or 18 ppt and spiked with crude oil, COREXIT 9500A, or a combined exposure to crude oil and COREXIT and allowed to biodegrade for 1 wk, 4 wk, and 16 wk. The WAF was harvested for analytical PAH analysis and acute toxicity testing in juvenile Fundulus grandis. Compared with undispersed oil, COREXIT exponentially increased the PAH concentrations in the WAF for up to 16 wk; hopane-normalized concentrations indicated that biodegradation was slowed for the first 4 wk. Dispersed crude oil and COREXIT were acutely toxic following 1 wk of biodegradation with no correlation between PAH concentrations and crude oil WAF mortality. Both dispersant and dispersant oil mixtures remained toxic for at least 4 wk at the lowest salinity tested, suggesting increased sensitivity or reduced biodegradation of toxic components in low-saline environments. At the lowest salinity, oil dispersed with COREXIT was more toxic than either the COREXIT alone or oil alone, even after 16 wk of biodegradation.

Chemometric assessment of enhanced bioremediation of oil contaminated soils

Bioremediation is a promising technique for reclamation of oil polluted soils. In this study, six methods for enhancing bioremediation were tested on oil contaminated soils from three refinery areas in Iran (Isfahan, Arak, and Tehran). The methods included bacterial enrichment, planting, and addition of nitrogen and phosphorous, molasses, hydrogen peroxide, and a surfactant (Tween 80). Total petroleum hydrocarbon (TPH) concentrations and CHEMometric analysis of Selected Ion Chromatograms (SIC) termed CHEMSIC method of petroleum biomarkers including terpanes, regular, diaromatic and triaromatic steranes were used for determining the level and type of hydrocarbon contamination. The same methods were used to study oil weathering of 2 to 6 ring polycyclic aromatic compounds (PACs). Results demonstrated that bacterial enrichment and addition of nutrients were most efficient with 50% to 62% removal of TPH. Furthermore, the CHEMSIC results demonstrated that the bacterial enrichment was more efficient in degradation of n-alkanes and low molecular weight PACs as well as alkylated PACs (e.g. C3–C4 naphthalenes, C2 phenanthrenes and C2–C3 dibenzothiophenes), while nutrient addition led to a larger relative removal of isoprenoids (e.g. norpristane, pristane and phytane). It is concluded that the CHEMSIC method is a valuable tool for assessing bioremediation efficiency.

Numerical Simulation of Oil Spill Behavior in the Persian Gulf

The aim of this research is to simulate oil spill behavior in the Persian Gulf due to the wind andtidal currents. This is achieved by coding an oil spill mathematical model consisting of several major submodels including hydrodynamic model, oil slick dynamic model and oil weathering model. The base of all of them is Eulerian approach and they are coupled together to simulate spill incident in the Persian Gulf. Thehydrodynamic model provided to simulate the tidal current is based on two dimensional depth averagedequations of shallow water discretized by finite volume method that is applied on rectangular structured mesh. The tidal current in the Gulf is made by imposing tidal fluctuation to the main open boundary at the Hormuz Strait. This model verification is carried out by comparison the resultant predictions of model with the available measured data and it shows a good agreement. Oil slick transport on the sea surface is simulated by an advection-diffusion model. Also, the most effective natural processes on oil fate and their effect on oil properties are estimated by an oil weathering model. Then, a test case including analytical solution is chosen to ensure the model capability on oil spill simulation. Finally, the model is implemented for a spillage event in the Persian Gulf. By explanation of the presented results, oil fate, the slick transport and other predicted data are demonstrated. The results show the model capability on modelling of an oil spill incident in marine environment.

The effects of oil exposure and weathering on black-needle rush (Juncus roemerianus) marshes along the Gulf of Mexico

Oil exposure has been shown to be detrimental to several salt marsh plants however little information is available for Juncus roemerianus. Thirty-two mesocosms were established with J. roemerianus sod and replicate marshes were exposed to Louisiana sweet crude oil to test oil dose (6, 12, and 24Lm−2) and weathering (oil weathered for 0days, 3days, and 3weeks). Juncus were monitored following oil exposure for culm survival, photosynthetic rates, and C-assimilation rates. Oil dosage had a significant effect among wetlands with low-dose (6Lm−2) mesocosms having higher culm survival, photosynthetic rates, and C-assimilation rates than medium or high dose wetlands (12 or 24Lm−2). Oil weathering did not elicit significant differences between treated wetlands however full strength wetlands (un-weathered oil) consistently had the lowest culm survivorship, photosynthetic rates, and C-assimilation rates. From our results, J. roemerianus marshes may be very susceptible to oil exposure.

Evaluation of artificially-weathered standard fuel oil toxicity by marine invertebrate embryogenesis bioassays

Weathering of petroleum spilled in the marine environment may not only change its physical and chemical properties but also its effects on the marine ecosystem. The objective of this study was to evaluate the toxicity of the water-accommodated fraction (WAF) obtained from a standard fuel oil following an environmentally realistic simulated weathering process for a period of 80d. Experimental flasks with 40gL−1 of fuel oil were incubated at 18°C with a 14hlight:10hdark photoperiod and a photosynthetically active radiation (PAR) intensity of 70μEm−2s−1. Samples were taken at four weathering periods: 24h, 7, 21 and 80d. WAF toxicity was tested using the sea urchin (Paracentrotus lividus) and mussel (Mytilus galloprovincialis) embryo–larval bioassays and the aromatic hydrocarbons levels (AH) in the WAF were measured by gas chromatography/mass spectrometry. In contrast with the classic assumption of toxicity decrease with oil weathering, the present study shows a progressive increase in WAF toxicity with weathering, being the EC50 after 80d eightfold lower than the EC50 at day1, whereas AH concentration slightly decreased. In the long term, inoculation of WAF with bacteria from a hydrocarbon chronically-polluted harbor slightly reduced toxicity. The differences in toxicity between fresh and weathered fuels could not be explained on the basis of the total AH content and the formation of oxidized derivatives is suggested to explain this toxicity increase.

The weathering of oil after the Deepwater Horizon oil spill: insights from the chemical composition of the oil from the sea surface, salt marshes and sediments

The oil released during the Deepwater Horizon (DWH) oil spill may have both short- and long-time impacts on the northern Gulf of Mexico ecosystems. An understanding of how the composition and concentration of the oil are altered by weathering, including chemical, physical and biological processes, is needed to evaluate the oil toxicity and impact on the ecosystem in the northern Gulf of Mexico. This study examined petroleum hydrocarbons in oil mousse collected from the sea surface and salt marshes, and in oil deposited in sediments adjacent to the wellhead after the DWH oil spill. Oil mousses were collected at two stations (OSS and CT, located 130 and 85 km away from the wellhead, respectively) in May 2010, and two sediment samples from stations SG and SC, within 6 km of the wellhead, in May 2011. We also collected oil mousse from salt marshes at Marsh Point (MP), Mississippi, 186 km away from the wellhead in July 2010. In these samples, n-alkanes, polycyclic aromatic hydrocarbons (PAHs), alkylated PAHs, BTEX (collective name of benzene, toluene, ethylbenzene and p-, m-, and o-xylenes), C3-benzenes and trace metals were measured to examine how the oil was altered chemically. The chemical analysis indicates that the oil mousses underwent different degrees of weathering with the pattern of OSS < CT < MP. This pattern is consistent with the projected oil mousse movement from the accident site to salt marshes. Also, the contents of trace metals Al, V, Cr, Fe, Mn, Ni, Co, Cu, As and Pb in the oil mousse generally increased along the way to the salt marshes, indicating that these trace metals were perhaps aggregated into the oil mousse during the transport. Petroleum hydrocarbon data reveal that the oil deposited in sediments underwent only light to moderate degradation one year after the DWH oil spill, as supported by the presence of short-chained n-alkanes (C10–C 15), BTEX and C 3-benzenes. The weathering of oil in sediment may result from biological degradation and dissolution, evidenced by the preferential loss of mid-chained n-alkanes C16–C 27, lower ratios of n-C 17/Pr and n-C 18/Ph , and preferential loss of PAHs relative to alkylated PAHs.

Oil Weathering after the Deepwater Horizon Disaster Led to the Formation of Oxygenated Residues

Following the Deepwater Horizon disaster, the effect of weathering on surface slicks, oil-soaked sands, and oil-covered rocks and boulders was studied for 18 months. With time, oxygen content increased in the hydrocarbon residues. Furthermore, a weathering-dependent increase of an operationally defined oxygenated fraction relative to the saturated and aromatic fractions was observed. This oxygenated fraction made up >50% of the mass of weathered samples, had an average carbon oxidation state of -1.0, and an average molecular formula of (C(5)H(7)O)(n). These oxygenated hydrocarbon residues were devoid of natural radiocarbon, confirming a fossil source and excluding contributions from recent photosynthate. The incorporation of oxygen into the oil's hydrocarbons, which we refer to as oxyhydrocarbons, was confirmed from the detection of hydroxyl and carbonyl functional groups and the identification of long chain (C(10)-C(32)) carboxylic acids as well as alcohols. On the basis of the diagnostic ratios of alkanes and polycyclic aromatic hydrocarbons, and the context within which these samples were collected, we hypothesize that biodegradation and photooxidation share responsibility for the accumulation of oxygen in the oil residues. These results reveal that molecular-level transformations of petroleum hydrocarbons lead to increasing amounts of, apparently recalcitrant, oxyhydrocarbons that dominate the solvent-extractable material from oiled samples.

Oil spreading in instantaneous and continuous spills on rotating earth

The effect of the Coriolis force on the oil spill spreading in the gravity-viscous regime is examined. A new shallow water model for the transport and spreading of oil slick of arbitrary shape is described in which the Coriolis force is included in the momentum equations and the oil–water friction is parameterized in a frame of the boundary layer theory including the Ekman friction. The numerical Lagrangian method based on smoothed particle dynamics is described. New similarity solutions of the model equations are obtained for unidirectional and axisymmetric spreading in gravity-viscous, gravity-turbulent and gravity-viscous-rotational regimes for instantaneous as well as continuous releases. The numerical simulation extends these results for the case of continuous release in the presence of currents. It was shown that Coriolis term in the momentum equation can be omitted if slick thickness is much less of the laminar Ekman layer thickness. However, the Ekman friction should be retained for slicks of any thickness for larger times. The Ekman friction results in the essential slowdown of the spreading as well as in the deflection of the oil spreading velocity at 45° from the direction of velocity in the non-rotation case. Numerical simulations of large-scale spills showed that after the 2 days the slick area with the Coriolis effect was approximately less than half of that without rotation. Therefore, the earth rotation can be also important in the oil weathering.