Wear Mechanisms Research Articles

Influence of laser remelting on the microstructure and properties of Mo2FeB2 ternary boride coatings prepared by laser cladding

This study investigated the impact of laser remelting on the microstructure and properties of Mo₂FeB₂ coatings on AISI 1045 steel substrate. Different laser remelting powers were applied to pre-deposited Mo₂FeB₂ coatings. The cross-sectional morphology, phase composition, microstructure, microhardness, residual stress, fracture toughness, and wear resistance of the coatings were systematically analyzed. Compared to the untreated coatings, the remelted coatings exhibited reduced height and significantly refined microstructure. The primary phase observed in the coating was Mo₂FeB₂, accompanied with minor phases such as Cr₃C₂. Optimal microhardness (1209.4 HV0.5), fracture toughness (14.5 MPa·m1/2), and wear rate (5.4× 10−5 mm3/N·m) were achieved at a remelt power of 1200 W. Additionally, the residual stress in the coatings decreased with increasing power, reaching a minimum of 268 MPa at 1500 W. The wear mechanism transitioned from adhesive wear to abrasive wear with increasing remelting power. These findings highlight the beneficial effects of laser remelting in enhancing the performance of Mo₂FeB₂ coatings for industrial applications.

Time-efficient model predictive control for autonomous tugs with adaptive input constraints

The marine autonomous surface ship (MASS) has gained significant attention because of its wide application in waterborne transportation in recent years. The trajectory control of the MASS is crucial in ensuring safety, particularly in narrow navigation areas and urgent encounter situations. Model predictive control (MPC) is well known as a sufficient method to solve the tracking problem considering the actuator saturation with model uncertainties and environmental disturbances. However, due to the constraints on computing resources and hardware limits, the controller may fail to find a feasible solution for MPC within a reasonable amount of time, especially when the system models are coupled and complex. To improve the solution efficiency, this paper introduces adaptive constraints to reduce search space for optimization, i.e., the current tracking point’s speed is transformed into input constraints in the MPC formulation to decrease the computation burden, as well as reduce mechanical wear on the thrusters with smaller amplitudes of control actions. Simulations are carried out to evaluate the effectiveness of the proposed method with different MPC forms.

Enhanced abrasion resistance of NR/BR/TBIR composites through the synergistic reinforcement of carbon black and graphene oxide: Structural influence and mechanistic insights

AbstractCarbon black (CB) with different structural parameters together with graphene oxide were formed into uniformly dispersed filler network for enhancing the abrasion resistance of natural rubber/cis‐1,4‐polybutadiene rubber/trans‐1,4‐poly(isoprene‐butadiene) rubber blended composites. It showed that the CB structural parameters, such as specific surface area, surface activity and structural degree affected the formation of bound rubber. With the increase of bound rubber content, the homogeneity of filler network structure was improved and the filler‐rubber interaction was enhanced, resulting in a remarkable increase in the mechanical properties, thermal performance and abrasion resistance of the composites. Among the different types of CB, the composites filled with high‐structural‐degree CB of N134 had DIN wear volume as low as 76 mm3 and exhibited 19.5% higher abrasion resistance than N330. Wear surface observations and wear mechanism analyses showed that the increase in abrasion resistance was related to the improvement in tear resistance, hardness and thermal properties of the composites. Multiple linear regression analyses yielded that the structural degree in the structural parameters of CB had a significant correlation effect on the formation of bound rubber, and there was a strong linear relationship between the abrasion resistance of the composites and the content of bound rubber.Highlights Trans‐1,4‐poly(isoprene‐butadiene) rubber as compatibilizer for NR/BR blends. Synergistic enhancement of rubber using carbon black and graphene oxide. Carbon black with high structural degree promotes the formation of bound rubber. Described correlation between CB structural parameters and abrasion resistance of rubber.

Comparison of high-temperature friction and wear behaviours of Ti6Al4V produced by additive manufacturing and casting

Additive manufacturing (AM) methods, especially selective laser melting (SLM), have recently attracted attention because they enable the quick and easy production of complex parts that cannot be produced with traditional manufacturing methods. However, residual stresses in the fabricated components impact their mechanical characteristics and may necessitate additional heat treatments. In this study, SLM-produced Ti6Al4V parts were subjected to a stress relief treatment under argon gas at 790°C for 2 h. The microstructure, microhardness and high-temperature tribological properties were examined comparatively with the traditional casting method. Dry sliding tribological experiments were carried out at different temperatures up to 600°C to compare high-temperature performance. It has been determined that the microstructure of samples produced by casting and SLM comprised β and α phases. The casting sample had 66.02% α grains, whereas the SLM sample had 59.02% α grains. The average microhardness in the SLM sample was marginally higher than that in the casting due to the formation of martensitic α. The results showed that wear rates increased with temperature for each sample. SLM samples exhibited slightly higher wear rates at each test temperature compared to the casting sample, which is attributed to the oxidative wear mechanism. The higher percentage of oxygen in the triboxide layers in the casting sample increased the wear resistance. When examining friction coefficients, an increase in average friction coefficients was observed at a test temperature of 300°C, while a decrease was observed at a test temperature of 600°C.

Microstructure and high temperature tribological behavior of nickel-based superalloy with addition of revert

The recycling of revert plays a crucial role in cost-efficiency and green manufacturing of superalloy. In this study, optical microscopy, scanning electron microscopy coupled with energy dispersive spectroscopy, tensile test, and tribological analysis were employed to investigate the microstructure, mechanical properties, and tribological behaviors of vacuum induction melted superalloys of 100% original material (Sample 1) and 40% original material + 60% revert (Sample 2). Dry sliding tests were conducted at 300 and 730 °C. The addition of revert promotes microstructure refinement, hardness increase, and carbide formation, at the cost of 18.5% ductility loss. During the high-temperature dry sliding process, abrasive, adhesive, and oxidative wear mechanisms were observed on the contact surfaces. Sample 2 exhibited a lower wear rate and coefficient of friction at both 300 and 730 °C. Additionally, a more continuous and wear-resistant tribolayer was formed on the wear track of Sample 2, effectively mitigating matrix oxidation compared to Sample 1. At 730 °C, a thick tribolayer developed on the wear surface of Sample 2, characterized by a hard and wear-resistant glaze layer on the outermost surface. The continuous sliding induced matrix heating, which facilitates recrystallization in the subsurface of Sample 2, induced by increased inclusions and carbides from the revert. The analysis of wear debris further illustrated the variations of wear mechanism at different temperatures. These findings are meaningful for understanding the high-temperature behavior of superalloys and optimizing alloy recycling process.

Synergistic regulation of microstructure, properties, and abrasive wear mechanism of a medium carbon dual phase steel for plowshares

In this study, a new medium carbon dual phase (DP) steel for plowshares is prepared. The quenching and partitioning process of the medium carbon steel is designed and optimised using the constrained carbon equilibrium model. The optimised process parameters are quenching temperature of 880 °C, quenching bath temperature of 190 °C and partitioning temperature of 350 °C. The microstructure of the acicular martensite matrix with 13% retained austenite was prepared, so that the good mechanical properties of tensile strength of 2007 MPa, yield strength of 1689 MPa, elongation of 11% and impact energy of 12 J are obtained. The multi-scale characterisation and abrasive wear experiments are carried out to investigate its microstructural evolution and wear mechanism under simulated working conditions. The results show that the coordinated deformation of retained austenite and martensite, as well as the trip effect, endows it with ultra-high strength and good plasticity. The recurring process of formation and spalling of the hardened layer is the main wear pattern of this medium carbon DP steel. The synergism of twinning formation and (Ti, Mo)C precipitation enhances wear resistance of this medium carbon DP steel.

Effect of annealing temperature on the microstructure and mechanical properties of Al0.2CrNbTiV lightweight refractory high-entropy alloy

The DSC analysis and heat treatment of the newly proposed Al0.2CrNbTiV lightweight refractory high-entropy alloy prepared by vacuum arc melting was investigated, and the evolutions of the microstructure and mechanical properties of the alloy after homogenization annealing at 650 °C, 850 °C and 1050 °C for 12 h were analyzed. The results show that the Al0.2CrNbTiV high-entropy alloy could maintain stable BCC solid solution structure from room temperature to 800 °C. The alloy annealed at 650 °C exhibited simple BCC structure with coarse equiaxed grains; after annealing at 850 °C, fine acicular and irregular block-like C14 Laves phases were uniformly precipitated in the grain and grain boundaries, meanwhile, the C14 Laves phase get coarser with the annealing temperature increased to 1050 °C. With the increase of annealing temperature, the microhardness of the Al0.2CrNbTiV alloy increased first and then decreased, reaching the maximum value of 692 HV after annealing at 850 °C. Due to the high dislocation density and the formation of kink bands, the alloy annealed at 650 °C showed a good combination of plastic and strength, with the work hardening ability strengthened simultaneously, the compressive yield strength could be up to 1454 MPa, with strain >50 %. Due to the precipitation of the hard and brittle C14 Laves phase, the load-bearing capacity of the alloy was reduced after annealing at 850 °C and 1050 °C. However, the wear resistance of the alloy also improved with the presence of the hard phase. The friction coefficient of Al0.2CrNbTiV alloy annealed at 650 °C is 0.67, with the abrasive wear acting as the main wear mechanism, and the alloy after annealing at 850 °C shew the best wear resistance, with the friction coefficient of 0.63, and delamination wear mechanism.

High-Temperature Wear Behavior and Mechanisms of Self-Healing NiCrAlY-Cr3C2-Ti2SnC Coating Prepared by Atmospheric Plasma Spraying

High-Temperature Wear Behavior and Mechanisms of Self-Healing NiCrAlY-Cr3C2-Ti2SnC Coating Prepared by Atmospheric Plasma Spraying

New insights on impact wear of polycrystalline diamond compact: Effect of interface state on kinetic response and damage behavior

The impact wear of polycrystalline diamond compact (PDC) cutters caused by the discontinuous cutting during the drilling process significantly affects the lifespan and efficiency of the drilling tools. Different PDC impact contact interface states are realized through the selection of impact mating materials. Understanding the effects of different interface states on the kinetic response, damage behavior and impact wear mechanism of PDC is significant in guiding the practical design of material structures with excellent impact wear resistance. Therefore, the kinetic response and damage behavior of PDC impact with different mating materials are investigated. The results show that the kinetic response and damage behavior of PDC are correlated with the mechanical properties of the mating material and physicochemical changes at the impact surface interface. Adhesion and filling resulting from strong covalent bonding and filling effects mitigate the interfacial stress and reduce the average impact force of SiC and Al2O3. Moreover, brittle fracture and filling effects increase the consumption of kinetic energy of SiO2, resulting in an energy absorption of up to 86 %. In addition, the strong covalent bonding effects exacerbated the damage to the PDC interfaces, leading to the internal fracture of diamond particles and detachment at grain boundaries. Furthermore, the filling effect formed plays a specific protective role for diamonds. However, it increases the energy absorption rate and reduces the mating material damage efficiency. In this work, the relationship between impact interface state and impact wear mechanism has been established by understanding the kinetic response, damage morphology, and structural evolution.

Enhancing lubrication of electrified interfaces by inert gas atmosphere

Abstract Considering the growing interest in increasing performance and efficiency of driveline components of modern electric vehicles, this work aims to analyze and report the wear mechanisms and notable enhancement of the lubrication of electrified contact interfaces by inert gas atmospheres. Systematic tribological studies were conducted on AISI 52100 steel test pairs using driveline lubricants under unelectrified and electrified conditions in ambient air and dry N2. Test results showed that in ambient air and electrification, the formation of iron oxides (in particular hematite) was most dominant and gave rise to severe abrasive wear regardless of the lubricant type being used. In dry N2, however, the tribo-oxidation was suppressed but the formation of a carbon-rich tribofilm was favored (especially under electrified conditions). Such a shift from surface oxidation to carbonaceous film formation resulted in dramatic reductions (by factors of 8 to 10) in the wear of test pairs.

Wear Mechanics of the Female Locust Digging Valves: The “Good Enough” Principle

AbstractAdult female desert locusts (Schistocerca gregaria) dig underground to lay their eggs, ensuring optimal conditions for successful hatching. Digging is performed using the two pairs of oviposition valves at the tip of the female's abdomen. These valves are subjected to considerable shear forces during the repeated digging cycles, potentially leading to wear over time. The resilience of the valves is investigated by analyzing the relationship between digging experience and valve damage and wear throughout the female locust's life. The findings reveal the ability of the valves to withstand the significant shear forces encountered during digging. Despite this resilience, however, perceptible limitations in the valves’ mechanical durability against wear are observed. Toward the end of the female locust's life, the valves show substantial signs of wear, indicating effective performance but with limited longevity, i.e., a designated life span that enables successful oviposition for ca. four oviposition cycles. A comparison of the valve material with that of the animals’ mandibles, which are used continuously throughout their life and show remarkable wear‐resistance, further highlights the evolutionary adaptation of the valve materials to their specific function, suggesting a trade‐off between energetic investment and the sufficient, or “good‐enough”, performance that is required for survival.

Effect of SiC Contents on Wear Resistance Performance of Electro-Codeposited Ni-SiC Composite Coatings

This paper focuses on the wear resistance performance of Ni-SiC composite coatings with various contents of SiC particles. The coatings were characterized via a scanning electron microscope (SEM), X-ray diffractometer (XRD), and transmission electron microscopy (TEM), and the wear behaviors of different coatings were tested. The results show that SiC particle incorporation results in a nanocrystalline metal matrix and nanotwins in nickel nanograins. The microhardness and wear resistance Ni-SiC composite coatings increased with the increasing SiC content. Microhardness was improved due to the grain-refinement strengthening effect and the presence of a nanotwin structure. The dominant wear mechanism was described in two stages: the first stage involves the interaction of SiC particles/the counter ball, and the second stage involves the formation of the oxide film its breaking up into wear debris. A higher SiC content increased the duration of the first stage and slowed down the rate of breaking up into debris, thereby decreasing the wear rate.

Study of the Differential Wear of Wheel Profiles on Motor Cars and Trailers of High-Speed Trains

As the operation speed of China’s high-speed trains continues to increase, a variety of complex wheel wear problems continue to emerge. Many line tests show that the differential wheel wear of the motor car and trailer car is obvious. The aim of this paper is to explore the differential wear mechanism of motor cars and trailers and their effect on dynamic performance. Firstly, this paper established a high-speed train model, which consists of two motor cars and two trailers. Then the causes of differential wear of the high-speed train from the perspective of wheel-rail contact and wheel wear were analyzed, and the Jendel wear model was used for wheel wear prediction. The wear model was verified through measured wheel wear data. Lastly, the dynamic performance of the differential wear of the high-speed train was analyzed. The results showed that the different distribution of the adhesive sliding zone in the contact patch, the different wheel-rail normal force, and tangential forces are the reasons for the differential wear. The established dynamic model and wear model can effectively predict the differential wear of the motor cars and trailer, and the maximum wear depths of the motor car and the trailer wheel were 0.886 mm and 0.721 mm. This verified the validity of the simulation model. When wheel differential wear occurs, the overall dynamic performance of the trailer is superior to that of the motor cars.

Mechanism analysis and prediction of bull-nose cutter wear in multi-axis milling of Ti6Al4V with TiAlN coated inserts

Cutter wear is an unavoidable issue during the milling of difficult-to-machine materials such as Ti6Al4V, which severely affects cutting performance and surface quality. Especially in multi-axis milling, the complex and irregular contact area between cutter and workpiece increases the difficulty of wear prediction. This paper proposes a flank wear prediction model of bull-nose cutter in the multi-axis milling process of Ti6Al4V with TiAlN coated inserts. The cutter workpiece engagement (CWE) zone is analyzed and the wear contact length of cutting edge is obtained, which reveals the uneven distribution characteristics of flank wear. After that, by analyzing the geometric profile properties of cutter wear in multi-axis milling, abrasive and adhesive wear, a flank wear prediction model that takes coating hardness and cutting temperature model into account is established. The proposed model is calibrated and validated by the multi-axis milling experiment of Ti6Al4V with TiAlN coated inserts. The results show that the novel wear model has high accuracy with an average percentage error of 12.76 % and can accurately and quickly predict flank wear in multi-axis milling of Ti6Al4V. Finally, the cutter wear mechanism and chip formation are analyzed, which show that the main wear mechanism is abrasive wear and adhesive wear, and there was no obvious oxidation wear.

Cryogenic tribological behavior of coarse, ultrafine grained and heterogeneous Fe-18Cr-8Ni austenitic stainless steel

Commonly used austenitic stainless steels (ASSs) have some limitation in sliding wear conditions due to their relatively low yield strength and hardness. To improve the wear resistance, three kinds of microstructure (coarse grain (CG), heterogeneous structure (HS), and ultrafine grain (UFG)) are prepared, to investigate the grain size on the dry sliding tribological behavior, as well as wear mechanisms of Fe-18Cr-8Ni ASSs at room temperature (RT) and cryogenic temperature (−120 °C). The results indicate that at RT the UFG specimen exhibits the lowest wear rate during the wear tests, where the wear mechanisms are mainly oxidation wear and abrasive wear. While, when tested at −120 °C, the CG specimen exhibits the best wear resistance compared with that of the other two specimens due to its superior plastic deformation ability and strain hardening ability. Moreover, the HS specimen exhibits the lowest coefficient of friction (CoF), which is due to the abrasive particles generated on the contact surface provide a certain level of friction reduction, while the wear rate increases as these particles serve as third-party abrasives, which further removing material.

The effect of temperature during plasma nitriding on the properties of IN718 additively manufactured by laser beam powder bed fusion

The IN718 superalloy has become a strategic alloy for applications in critical components in aerospace, oil, and gas, or power generation. Commercially, IN718 is produced by conventional casting processes. However, manufacturing is evolving towards 3D printing, which allows the manufacturing of near-net-shape parts and complex designs, thus optimizing manufacturing steps, reducing production costs, and adding other advantages to the final product. However, high corrosion resistance and mechanical strength are required in applications such as oil and gas, whereas IN718 superalloys have limitations. Surface hardening by applying plasma nitriding can protect against corrosion by increasing mechanical strength and wear resistance. For this, plasma nitriding has been widely applied for surface hardening of IN718; however, little is found on the effects of surface treatments (coating or nitriding) of additively manufactured alloys. The effects of temperature during plasma nitriding on the surface properties of IN718 superalloy 3D printed by the Laser Beam Powder Bed Fusion (LB-PBF) method are reported here. Samples of IN718 fabricated by 3D printing were plasma nitrided at fixed temperatures between 500 and 650 °C in a semi-industrial reactor, their effects are analyzed and correlated with their microstructural characteristics, the mechanical properties at the micro- and nanoscale, and the tribological responses in a pin-on-disk configuration.

Effect of WC particle size on the microstructural evolution and tribological properties of laser cladding Ti-bearing Co-based WC reinforced coating

To improve the wear resistance of 300 M steel under reciprocating wear in landing gear shock strut, Ti-bearing Co-based WC reinforced coatings with three different WC particle sizes (280 mesh, 200 mesh, and 150–300 mesh) were successfully fabricated by laser cladding method. The effect of WC particle size on phase composition, microstructure, microhardness and tribological properties were systematically investigated. The results show that the phase composition of these coatings consists mainly of γ-Co, TiC, WC, Cr23C6 and CrCo, and that varying the WC particle size changes the morphologies of the second phases. With the increase of WC particle size, the morphology of TiC is dendritic, ellipsoidal and block, respectively; the morphology of Cr23C6 changes from discontinuous fine particles to grid-like at grain boundaries. And the TiC-WC composite phases appear when the particle size of the added WC particles is a mixture. The coating with a mixture of 150–300 mesh WC particles, has the highest hardness range, the lowest average friction coefficient of 0.372, and the lowest wear rate of 9.61 × 10−5 mm3/N·m. The wear mechanisms of all three coatings are abrasive wear and oxidation wear, and the oxide film on the worn surface of the coatings gradually becomes denser and more continuous with increasing WC particle size.

Simultaneous improvement in mechanical properties, corrosion resistance and antibacterial properties of Ti-Ag sintered alloy with gradient nanostructure

Bioinert titanium (Ti) with antibacterial properties is crucial for bone implantations. Alloying Ag can endow Ti with antibacterial properties, while the mechanical, corrosion and antibacterial properties of Ti-Ag alloys are not satisfactorily balanced. In this work, Ti-x wt%Ag alloys (x=0.5, 1 and 3) were sintered by spark plasma sintering and then subjected to a surface mechanical rolling treatment (SMRT). The Ti-Ag alloys are composed of Ti, Ti-Ag and Ti2Ag phases. After SMRT, a gradient nanostructured (GNS) layer formed on the Ti-Ag surface, the mean grain size is ∼ 6 nm at the top surface and increases gradually with depth. The GNS layer endows Ti-Ag alloys with better wettability, higher nano-roughness and compressive residual stress. Incorporating limited Ag (≤1 wt%) in Ti can effectively enhance its mechanical (surface hardness, wear resistance and compressive strength) and anti-corrosion properties, and they can be further improved by forming a GNS layer. The antibacterial efficiency of Ti-Ag is positively proportional to Ag content, and they are significantly enhanced after surface nanocrystallization. The bacteriostatic mechanism is the synergistic interaction between leach Ag+ and nano Ag-containing phases of GNS Ti-Ag alloy. Both Ti-Ag and GNS Ti-Ag alloys possess good cytocompatibility, the GNS layer has the potential to encourage early differentiation of osteoblasts. The GNS Ti-Ag alloy with 1 wt% Ag has excellent comprehensive properties, which shows larger potential in orthopedic applications.

Exploring ambient and elevated temperature fretting wear behavior of laser-cladding (FeCrCoNi)84AlxNby high-entropy alloy coatings

In this work, (FeCrCoNi)84AlxNby (x = 12, 8, 4 and y = 4, 8, 12 (at. %)) high-entropy alloy (HEA) coatings were successfully deposited on 316 stainless steel via laser cladding (LC). FCC/BCC + Laves structure was introduced into FeCrCoNi HEA system by designing different Al/Nb ratios, aiming to improve the fretting wear resistance. The phase constituents, microstructure, and fretting wear resistance of (FeCrCoNi)84AlxNby HEA coatings at ambient temperature and 285 °C were respectively analyzed. Results confirmed that the microstructure of three HEA coatings displayed the interdendritic (IR) - dendritic (DR) structure. With the Al/Nb ratio decreased from 3/1 to 1/3, the phase constituents of HEA coatings transformed from the BCC solution to FCC solution and Laves phase, and the content of the Laves phase gradually increased. Moreover, the average grain size decreased from 16.9 μm to 4.6 μm, while the average geometrically necessary dislocations (GNDs) density increased from 1.842 × 1010 m−2 to 2.821 × 1010 m−2. The microhardness of the HEA coatings was improved from 210 HV0.2 to 361–647 HV0.2 compared with that of the substrate. The decrement of Al/Nb ratio improved the fretting wear resistance of HEA coatings both at ambient temperature and 285 °C, especially at 285 °C. The wear volume decreased from 0.8 × 105 μm3 to 0.39 × 105 μm3 and the fretting wear mechanism changed from severe fatigue wear to slight abrasive wear at 285 °C. In the Al4Nb12 HEA coating, the soft structure (FCC) and the hard structure (Laves) were combined into a wear-resistant skeleton, and the Laves structure was massively distributed along the FCC phase to prevent the FCC phase from further slipping in the fretting wear process, which in turn minimizes the fretting damage. The present work provides a theoretical basis for the related research on the fretting wear characteristics of laser cladding HEA coatings.

Effects of C content on the microstructure and properties of CoCrFeNiTi0.5Mo0.5Cx high-entropy alloy coatings by laser cladding

In order to deeply investigate the influence mechanism of different contents of non-metallic element C on the microstructure, microhardness, wear resistance and corrosion resistance of high-entropy alloy coatings. CoCrFeNiTi0.5Mo0.5Cx high-entropy alloy coating was prepared on the surface of AISI 1045 steel by laser cladding technology. The results show that the microstructure of CoCrFeNiTi0.5Mo0.5 without C addition consists of FCC phase, BCC phase, intermetallic compound phase and σ-phase structure, and the carbide phases (M7C3 and TiC) start to appear after the addition of C element. The microhardness of the coating increases and then decreases with the increase of C content, and the average hardness is the highest when x = 0.03, 495.3HV0.5, which is 27.6% higher than that of C0. The abrasion resistance of the CoCrFeNiTi0.5Mo0.5Cx high-entropy alloy coatings is gradually increased and then decreased with the increase of C content, and the wear amount decreases from 0.0813 mm3 to 0.0514 mm3, and the main frictional wear mechanisms are adhesive wear, abrasive wear and oxidative wear. With the increase of C content, the corrosion resistance of the coating is gradually improved and then reduced, when the C content is 0.03, the highest corrosion potential is −0.818V, the lowest corrosion current is 1.382E-4 A/cm2, at this time, the passivation film on the surface of the coating is the most stable and dense, with the best corrosion resistance. The results of this paper provide a theoretical reference for the effect of adding non-metallic elements on the microstructure and properties of high-entropy alloy coatings.