Wear Behavior Research Articles

Enhanced Fracture Toughness of WC-CoCr Thermally Sprayed Coatings by the Addition of NiCrFeSiBC and Mo and Its Influence on Sliding Wear Behavior

Wear is a major issue in industry, particularly with metal components. Therefore, it is crucial to investigate methods that offer increased resistance to this phenomenon. In this research, three coating systems (pure WC-CoCr and WC-CoCr/NiCrFeSiBC+Mo, 88:12 and 83:17 wt.%) were thermally sprayed on an AISI 1018 steel substrate through the High-Velocity Oxygen Fuel (HVOF) process. The coatings were characterized using a field emission scanning electron microscope (FESEM) equipped with the energy dispersive spectroscope (EDS) and X-ray diffractometry (XRD). An analysis of the wear rate for ball-on-flat linear reciprocating sliding tribological tests for the coatings was also carried out. The coating microstructure presents well-dispersed NiCrFeSiBC splats. The WC-CoCr/NiCrFeSiBC+Mo, 88:12, system has the highest wear resistance, decreasing by 30.2% at high loads compared to commercial WC-CoCr CERMETs, and also exhibits the highest fracture toughness. Analysis of wear tracks shows that the material removal at all charges occurred mainly by an abrasive wear mechanism.

Synergistic Effect of Ex Situ and In Situ Reinforcements on the Dry Reciprocating Wear Behavior of AA6061-B4C Composite Fabricated Using Varying K2TiF6 Flux Content

Synergistic Effect of Ex Situ and In Situ Reinforcements on the Dry Reciprocating Wear Behavior of AA6061-B4C Composite Fabricated Using Varying K2TiF6 Flux Content

Characterization of Graphite and ZrO2 Reinforced Aluminium Metal Matrix Composite For Enhanced Mechanical Properties in Electronics Applications

Abstract The objective of this work is to examine the wear properties of a hybrid Metal Matrix Composite (MMC) consisting of 92 weight percent (wt. %) Aluminium Alloy 6061 (AA6061), 2 wt. % Graphite (C), and 6 wt. % Zirconium Dioxide (ZrO2). It was previously determined that this composition was ideal for improved metallurgical and mechanical properties. Nine specimens of the same composition were fabricated for this continuation work and put through wear tests with different applied load, sliding velocity, and sliding distance settings. To evaluate the performance of the composite, measurements were made of the wear rate and Coefficient of Friction (COF). According to the results, the wear rate typically increased as the applied load and sliding velocity increased. At the lowest load (10 N) and velocity (2 m/s), the lowest wear rate (50.90 µg) and COF (0.197) were noted. Specimens with lower wear rates had smoother surfaces and less wear, as revealed by SEM analysis of the worn surfaces; specimens with higher wear rates showed more significant surface damage, such as deeper cuts and serrations. In specimens with less wear, XRD analysis verified the presence of crystalline aluminium, indicating a strong correlation between wear resistance and the crystalline structure of the composite. Linear regression equations were created to predict wear behavior under different conditions. According to the results, the composite's wear characteristics are greatly influenced by the sliding velocity and applied load. ZrO2 and C together have lubricating and strengthening properties that, under certain circumstances, reduce wear. The composite exhibits potential for usage in electronics applications, especially in components where wear resistance and mechanical durability are critical due to its favorable wear characteristics and mechanical properties.

Study of fretting wear mechanisms of complete contacts

The Ti-6Al-4V fretting wear of complete contacts on a proving ring-like rig is investigated in this paper. Under this contact configuration, the Ti-6Al-4V alloy exhibited distinctive fretting wear behaviors. Especially in the continuous wear zones of the fretting specimen and pad, a paired continuous pit and peak were formed, respectively, and moved inward as the continuous wear zones expanded. To explain these fretting wear behaviors of the fretting configuration, a novel phenomenological fretting wear model is proposed in this paper. Additionally, due to the failure of the conventional FE method with a constant wear coefficient to simulate the fretting wear, a new local wear coefficient model, which is position-dependent and time-dependent fretting, is also proposed in this paper.

Study on the Effect of Pressure on the Microstructure, Mechanical Properties, and Impact Wear Behavior of Mn-Cr-Ni-Mo Alloyed Steel Fabricated by Squeeze Casting

ZG25MnCrNiMo steel samples were prepared by squeeze casting under pressure ranging from 0 to 150 MPa. The effects of pressure on the microstructure, low-temperature toughness, hardness, and impact wear performance of the prepared steels were experimentally investigated. The experimental results indicated that the samples fabricated under pressure exhibited finer grains and a significant ferrite content compared to those produced without pressure. Furthermore, the secondary dendrite arm spacing of the sample produced at 150 MPa decreased by 45.3%, and the ferrite content increased by 39.1% in comparison to the unpressurized sample. The low-temperature impact toughness of the steel at −40 °C initially increased and then decreased as the pressure varied from 0 MPa to 150 MPa. And the toughness achieved an optimal value at a pressure of 30 MPa, which was 65.4% greater than that of gravity casting (0 MPa), while the hardness decreased by only 6.17%. With a further increase in pressure, the impact work decreased linearly while the hardness increased slightly. Impact fracture analysis revealed that the fracture of the steel produced without pressure exhibited a quasi-cleavage morphology. The samples prepared by squeeze casting under 30 MPa still exhibited a large number of fine dimples even at −40 °C, indicative of ductile fracture. In addition, the impact wear performance of the steels displayed a trend of initially decreasing and subsequently increasing across the pressure range of 0–150 MPa. The wear resistance of samples prepared without pressure and at 30 MPa was superior to that at 60 MPa, and the wear resistance deteriorated when the pressure increased to 60 MPa, after which it exhibited an upward trend as the pressure continued to rise. The wear mechanisms of the samples predominantly consisted of impact wear, adhesive wear, and minimal abrasive wear, along with notable occurrences of plastic removal, furrows, and spalling.

Microstructure, mechanical and wear behavior of AlxTi(1−x)CoCrFeNi (x = 0.875, 0.75) high-entropy coatings fabricated via HVOF and post-annealing

AlxTi(1−x)CoCrFeNi (x = 0.875, 0.75) high-entropy coatings (HECs) were prepared using High-Velocity Oxygen-Fuel technology, and then underwent vacuum annealing at 500 ℃, 700 ℃, 900 ℃, and 1100 ℃, respectively. The sprayed coatings exhibited BCC phase, with the hardness increasing as the Ti content added. The wear mechanism of the HECs included abrasive, adhesion and oxidation wear. The microstructure and phase structure of the HECs annealed at 500 ℃ were basically consistent with the as-sprayed coatings. The Al0.75Ti0.25CoCrFeNi HEC nanohardness reached the peak (19.6 ± 1.1 GPa) and had the best wear resistance (1.8 ×10−5 mm3 N−1 m−1) due to the grain boundary dislocation source strengthening. With the annealing temperature increasing, the BCC to FCC phase transition occurred, the grains coarsened, the hardness decreased, and oxidation wear were intensified.

Wear Prediction of Functionally Graded Composites Using Machine Learning.

This study focuses on the production of functionally graded composites by utilizing magnesium matrix waste chips and cost-effective eggshell reinforcements through centrifugal casting. The wear behavior of the produced samples was thoroughly examined, considering a range of loads (5 N to 35 N), sliding speeds (0.5 m/s to 3.5 m/s), and sliding distances (500 m to 3500 m). The worn surfaces were carefully analyzed to gain insights into the underlying wear mechanisms. The results indicated successful eggshell particle integration in graded levels within the composite, enhancing hardness and wear resistance. In the outer zone, there was a 25.26% increase in hardness over the inner zone due to the particle gradient, with wear resistance improving by 19.8% compared to the inner zone. To predict the wear behavior, four distinct machine learning algorithms were employed, and their performance was compared using a limited dataset obtained from various test operations. The tree-based machine learning model surpassed the deep neural-based models in predicting the wear rate among the developed models. These models provide a fast and effective way to evaluate functionally graded magnesium composites reinforced with eggshell particles for specific applications, potentially decreasing the need for extensive additional tests. Notably, the LightGBM model exhibited the highest accuracy in predicting the testing set across the three zones. Finally, the study findings highlighted the viability of employing magnesium waste chips and eggshell particles in crafting functionally graded composites. This approach not only minimizes environmental impact through material repurposing but also offers a cost-effective means of utilizing these resources in creating functionally graded composites for automotive components that demand varying hardness and wear resistance properties across their surfaces, from outer to inner regions.

Investigation on friction and wear behavior of wheel material of wheel-rail: a case study of addis ababa light rail transit

Investigation on friction and wear behavior of wheel material of wheel-rail: a case study of addis ababa light rail transit

Investigation of Mechanical Properties, Fretting Wear, and Corrosion Behaviour of AA6063/Si3N4 Nanocomposites Fabricated via Friction Stir Processing

Investigation of Mechanical Properties, Fretting Wear, and Corrosion Behaviour of AA6063/Si3N4 Nanocomposites Fabricated via Friction Stir Processing

Clinical features, risk factors and outcomes of contact lens-related bacterial keratitis in Nottingham, UK: a 7-year study.

To examine the clinical characteristics, risk factors and outcomes of contact lens-related bacterial keratitis (CLBK) in a large UK tertiary referral centre. A retrospective analysis of all patients who presented to the Queen's Medical Centre, Nottingham, UK, with suspected CLBK between October 2015 to September 2022 (a 7-year period) was performed. Relevant data on demographic factors, CL wear behaviour, causes, clinical characteristics, and outcomes were analysed. We included 138 patients with CLBK; the mean age was 42.0 ± 17.8 years and 74 (53.6%) patients were male. Most CLBK were related to soft CL wear (94.5%), particularly monthly disposable (42.5%) and daily disposable (24.4%) CLs. Poor CL wear behaviour/hygiene was documented in 57.1% cases. Among the 64 (46.4%) microbiological-positive cases (n = 73 organisms), Pseudomonas aeruginosa (36, 49.3%) and Staphylococcus spp. (16, 21.9%) were most commonly identified. Six (4.3%) cases were polymicrobial. Most (97.0%) patients were successfully treated with topical antibiotics alone, with 80.6% achieving good final corrected-distance-visual-acuity (CDVA) of ≥ 0.30 logMAR. Poor visual outcome (final CDVA < 0.30 logMAR) was significantly associated with presenting CDVA < 0.6 logMAR (p = 0.002) and central ulcer (p = 0.004). Poor corneal healing (complete healing of > 30 days from initial presentation) was significantly associated with age > 50 years (p = 0.028), female gender (p = 0.020), and infiltrate size >3 mm (p = 0.031). Poor CL wear behaviour/hygiene is commonly observed in CLBK, highlighting the importance of improved counselling and awareness regarding CL use and hygiene. When presented early and managed appropriately, most patients are able to achieve good clinical outcomes with medical treatment alone.

Effect of laser energy on the fretting wear resistance of femtosecond laser shock peened Ti6Al4V

Femtosecond laser shock peening (FsLSP) is performed on engineering alloys to improve their wear resistance in dry and oil-lubricated sliding conditions. In this study, the influence of FsLSP on the fretting wear behavior of Ti6Al4V alloy is studied. For this purpose, FsLSP treatment, with laser energies of 50, 100, 150, and 200 μJ, is performed on a Ti6Al4V sample which mainly consists of α-phase. Topographical investigations using white light interferometry reveal that with increase in the laser energy, the coverage area of laser-induced periodic surface structures (LIPSSs) decreases, and the extent of surface pitting damage increases, leading to higher surface roughness. While surface hardness also initially increases with increasing laser energy, it remains invariant when the energy is increased beyond 150 μJ. Sub-surface microstructural investigations and kernel average misorientation maps obtained from electron backscatter diffraction reveal that FsLSP treatment leads to the formation of severely deformed and mildly deformed layers along the depth of the alloy surface. Surface hardening due to FsLSP is attributed to the activation of prismatic <a>, basal <a> slip systems, and 101¯2, 112¯3 tensile twins in the severely deformed zone along with grain refinement, which is an outcome of dynamic recrystallization. Fretting wear tests indicate that the coefficient of friction (CoF) of FsLSP treated alloys is consistently lesser than that of its as-received counterpart, whose CoF is 0.38. In contrast, the wear resistance, quantified by the wear rate, wear volume and wear depth, is highest in the sample treated with laser energy of 100 μJ but lower for the as-received as well as 150 and 200 μJ laser treated samples. These results are explained on the basis of the differences in the contact area, formation of surface hardening layer and the size and integrity of asperities on the surface, which in turn influences the dominant fretting wear mechanism.

Synergistic approach to wear rate forecasting in AZ31/5% Yttria stabilized zirconia reinforced composite through response surface methodology-genetic algorithm integration

In this work, the wear behavior of a novel AZ31 magnesium alloy reinforced with 5% yttria-stabilized zirconia (YSZ) composite was evaluated using a hybrid Response Surface Methodology (RSM) and Genetic Algorithm (GA) approach. The composite was fabricated using ultrasonic-assisted stir squeeze casting technique, ensuring homogeneous distribution of spherical YSZ particles, as validated by the scanning electron microscope integrated with energy dispersive spectroscope. Wear tests were carried out according to the ASTM standards using a pin-on-disc (POD) tribometer, with applied load (AL), sliding speed (SS), and sliding distance (SD) as the main parameters. An empirical wear rate regression model was developed using RSM/Box-behnken design, and Genetic Algorithm was deployed for parametric optimization, achieving a minimal wear rate of 0.0144 g/m under a load of 30 N, sliding speed of 260 rpm, and sliding distance of 400 m. Confirmation tests were performed to validate the GA predictions. The wear mechanisms were observed, showing reduced wear in GA-optimized samples due to optimized load distribution resulting minimized ploughing, grooving and delamination. This work highlights the efficacy of the hybridized RSM / GA for the wear performance in advanced magnesium alloy matrix composites.

High-temperature fretting wear behavior and microstructure stability of a laser-cladding Ti-Al-C-N composite coating meditated by variable cycle conditions

Ti-6Al-4 V titanium alloy is used for low-pressure compressor blades of aero-engine due to its high specific strength, excellent corrosion resistance and high-temperature stability. Low-pressure compressor blades are subject to fretting wear in service, which may lead to fracture failure of the blades. The preparation of wear-resistant coatings is currently an effective solution in solving the problem of fretting wear on Ti-6Al-4 V titanium alloy. However, the fretting wear resistance and microstructure stability of the coating under variable cycle fretting conditions require more attention. In this work, the fretting wear performance and microstructure stability of the Ti-Al-C-N composite coating under variable cycle fretting conditions are investigated. The results show that the parameters of variable cycle operating conditions have a notable effect on the coefficient of friction (COF). The variable frequency and variable temperature working conditions result in the alteration of the fretting operation mechanism. Whereas the variable stroke amplitude and the variable load conditions do not cause changes in the fretting operation mechanism, and both are in the gross slip region (GSR). The lowest wear rate occurs under variable stroke amplitude conditions. The wear rate is the maximum under the variable cycle temperature condition. According to the dissipated energy calculation, the difference between the two different stroke amplitudes is the biggest among all the conditions. EBSD and TEM analyses show that the subsurface of variable stroke amplitude worn scar has a more uniform strain distribution, and reveals a unique subsurface structure with a transformation from crystalline to amorphous, which contributes to improving the wear resistance. This work provides insights into coating microstructure stability and wear mechanisms under variable cycle conditions.

Investigating a novel and highly efficient approach for the fabrication of diamond profile rollers using Wire Electrical Discharge Conditioning (WEDC)

The fabrication of high-precision and high-performance profile rollers represents the main challenge of utilizing profile rollers as dressers to condition conventional grinding wheels. This results in high demands for an efficient process to manufacture profile rollers (form dressing wheels). Conventionally, diamond profile rollers have been produced through infiltration or negative electroplating methods. Nevertheless, these manufacturing methods suffer significant drawbacks, including extended production times and substantial costs. This study presents an innovative approach to fabricating diamond profile rollers using Wire Electrical Discharge Conditioning (WEDC). The WED-Conditioning emerges as an effective alternative to profile metal-bonded rotary diamond dressing tools. This innovative method leads to the production of diamond profile rollers in significantly shorter timeframes and at a more economical cost compared to the conventional manufacturing method with comparable quality. The research delves into the influence of profile roller specifications and conditioning strategies on the achievable profile accuracy and topography of the profile rollers. Also, the wear behavior of the WEDC-conditioned profile roller over long-term conditioning of conventional grinding wheels was studied. The findings highlight the significant contribution of the appropriate selection of WEDC strategies to the profile accuracy, with the potential to achieve profile accuracies comparable with conventional profile rollers. As well, grain size emerges as the primary determinant of achievable profile accuracy for profile rollers. The findings of this study could provide insights into optimizing the manufacturing process for super abrasive diamond profile rollers, thereby enabling their widespread use in the grinding industry.

Investigation of the synergetic effect of oleophilic textured surfaces and MoS2 at different loads on the tribological performance of Ti64 alloy

In this research study, surface modification of Ti64 alloy was carried out using laser surface texturing (LST). The investigation aims to explore the effects of loads, oleophilic textured surfaces, and MoS2 as a solid lubricant on the friction and wear reduction of Ti64 alloy and AISI 52100 steel tribo-pairs. Three types of LST textures (Circular, triangular, and square textures) were created on the Ti64 alloy. Subsequently, tribological experiments were performed using a ball-on-disc universal tribometer at loads of 5, 10, and 15N with a 15 Hz frequency. The worn surface was analyzed using various methods, including optical microscopy, 3D-profilometer, FESEM, EDAX analysis, and Raman spectroscopy. The study compared the coefficient of friction (COF) and wear behavior of non-textured surfaces (NTS) with those of textured surfaces (TS) under both dry sliding conditions (DSC) and lubricated sliding conditions (LSC). The results demonstrated a significant reduction in the COF and wear coefficients on the TS. Specifically, the circular texture (CiT) exhibited a remarkable reduction of 39.3%, 63.83%, and 83.6% in wear coefficients compared to the NTS tested under DSC and LSC (using pure PAO-4 and PAO-4 + 1% wt MoS2) with sliding load of 15N. DSC showed abrasion, adhesion, and delamination wear, while LSC displayed mild adhesion, delamination, and tribo-layer formation on NTS and TS. The analysis indicated that the use of LST and solid lubricant nanoparticles on a Ti64 alloy would result in improved service life and better endurance in cutting tools and tribo-mating parts.

Influence of Ni content on electrochemical corrosion and tribological behavior of Cu-10Sn coatings by laser cladding

In this work, Cu-10Sn-xNi (x = 0, 3, 6, 9, and 12 wt%) alloy coatings were prepared using laser cladding technology. The influence of Ni content on the phase composition, microstructure, crystallographic characteristics, microhardness, electrochemical corrosion, dry sliding wear and corrosive wear behavior of the coatings were studied. The results indicated that the coatings formed good metallurgical bond with the substrate. The coatings were composed primarily of the α-Cu matrix and small γ precipitates. The Ni element effectively reduced component segregation, and with the increased of Ni content, the grain size in the coating was significantly refined, resulting in fine equiaxed grains. Under the effect of fine grain strengthening, the Cu-10Sn-12Ni (C12NS) coating achieved a higher microhardness of approximately 222.9 ± 5.3 HV0.2. In the electrochemical corrosion test, the increased in the number of grain boundaries significantly reduced the corrosion resistance of the Cu-10Sn-xNi coatings. The Cu-10Sn-6Ni (C6NS) coating exhibited excellent corrosion resistance, with an Icorr of only 1.37 μA/cm2. The results of the dry sliding wear test showed that under the influence of the hardness gradient between the hard precipitate phase and the soft matrix of the coating, the C6NS coating achieved satisfactory wear resistance with a specific wear rate of 3.30 × 104 μm3/Nm. Meanwhile, due to the good corrosive resistance, the C6NS coating showed the best tribological performance in 3.5 wt% NaCl environment, and the specific wear rate was 1.58 × 104 μm3/Nm.

A systematic study on wear behavior of TiCrNbTaWx refractory high-entropy alloy: Inducing amorphization to achieve anti-wear

Refractory high-entropy alloys (RHEAs) possess exceptional properties at elevated temperatures. However, their limited wear resistance at room temperature (RT) hinders their widespread application. In this work, based on compositional modulation and surface engineering strategies, two TiCrNbTaWx (x = 0, 0.5) RHEAs were prepared using spark plasma sintering. The results show that the addition of W can effectively improve the hardness (10.3 GPa) and deformation resistance of the BCC matrix, alleviating the severe adhesion and the fracture behavior. In addition, the friction-induced oxidized amorphous layer with high hardness (12.3 GPa) can further improve the anti-wear properties. Because of these, the TiCrNbTaW0.5 alloy has a low wear rate of 9 × 10−5 mm−3·N−1·m−1, which is 67 % lower than the pristine TiCrNbTa alloy. In conclusion, our design strategy provides a new idea for designing RT wear-resistant RHEAs.

Microstructure and tribological behavior of Al–TiC composite strips fabricated by a multi-step densification method

This study aims to enhance the tribological properties of automotive applications by examining the effects of TiC content on the microstructure, mechanical properties, and wear behavior. This study investigates the production of Al–TiC composite strips using a novel multi-step densification process combining mechanical alloying and hot rolling with TiC concentrations ranging from 0 to 12 vol%. The novelty of this work lies in its comprehensive approach to developing and analyzing Al–TiC composite strips using a multistep densification method. This study integrates microstructural analysis, mechanical property evaluation, and detailed tribological behavior assessment under different wear loads (5–25 N). A key innovation is the application of the Abbott Firestone method to analyze worn surfaces, providing insights into optimal wear conditions. The study reveals that increasing the TiC content to 12 vol% significantly improves densification, hardness (up to 268.8% increase), and wear resistance (up to 95% improvement at a 5N load). Dry ball-on-flat sliding wear tests at loads of 5–25N demonstrate that TiC particles hindered complete delamination wear in the composite strips. The Abbott Firestone method analysis of worn surfaces indicated an optimal exploitation zone in the Al-6 vol% TiC composite at both low and high wear loads. This comprehensive approach provides valuable insights into optimizing Al–TiC composites for enhanced performance in automotive components that require improved wear resistance.

Thermal and Mechanical Mechanisms of Polymer Wear at the Nanoscale.

Wear is a ubiquitous phenomenon that limits the life of many engineered components with sliding interfaces through the gradual removal of material. The wear of polymers is crucial in many applications, ranging from bearings to orthopedic implants to nanolithography processes. The wear rate of polymers is strongly affected by the stress and temperature at the interface. The effects of temperature and stress are often described empirically since the wear process involves complex interactions between multiple asperities on rough surfaces over a range of length scales. Nanoscale tribology experiments at the single-asperity level have provided new insights into the underlying mechanisms of wear. Experiments on hard covalently bonded materials, including silicon and diamond, have demonstrated that wear is an atomic attrition wear process that can be modeled using stress-assisted transition state theory. Here, we examine the wear of a common polymer, polymethylmethacrylate (PMMA), at the nanoscale as a function of stress and temperature and show that the polymer wear is controlled by a combination of atomic attrition and viscoelastic relaxation. While the wear experiments are conducted at the nanoscale via atomic force microscopy, the results show that accounting for the local stress distribution at the contact interface is critical to understanding the wear behavior, an effect that was not considered in earlier studies on hard materials. Using a model that accounts for the stress distribution, we demonstrate the ability to predict the wear volume within 8%.

Establishing high temperature tribological performance and wear mechanism map of engineered in-situ TiB2 reinforced Mg-RE metal matrix composites

The high temperature sliding wear behavior of microstructurally engineering in-situ sub-micron sized TiB2 reinforced ZE41 composite was studied and compared with it’s base counterpart at varying loading conditions. The wear mechanism maps were constructed by correlating the microstructures of worn surfaces with different test parameters. The severe and catastrophic wear mechanisms like delamination and melt wear were wider in base and composite, while in the case of engineered composite, these zones are significantly narrow down. Due to the presence of thermally stable in-situ TiB2 particles and bimodal precipitates in engineered composite, the material showed sufficient resistance against wear induced deformation. Furthermore, the study established scientific knowhow on high-temperature wear induced deformation behavior by analyzing microstructural evolution in wear subsurface zone.