Wavelength Response Research Articles

Strain effect on the electronic and optical characteristics of FAGeX3 (X=Cl, Br, and I) perovskite materials: DFT analysis

This study investigates the electronic and optical properties of a perovskite material known as Formamidinium Germanium Halide (FAGeX3), where X represents the elements Chlorine (Cl), Bromine (Br), and Iodine (I). We explore the bandgap, density of state (DOS), and partial density of state (PDOS) to understand their electronic properties. We use two methods, PBE and HSE-06, to determine the bandgap. Further, we investigate the optical properties by investigating the real and imaginary functions of the dielectric constant, refractive index, electron energy loss function, and absorption coefficient. Our research extends to the impact of biaxial strain, both tensile and compressive, in the −6% to +6 % range. Without strain, the materials exhibit direct bandgaps at the R point, with FAGeCl3 showing the highest bandgap (2.1359 eV), followed by FAGeBr3 (1.7325 eV), and FAGeI3 with the lowest (1.2581 eV). Our results reveal that applying tensile strain increases the bandgap and induces a blueshift, shifting the optical responses to shorter wavelengths, while compressive strain reduces the bandgap and causes a redshift, enhancing longer wavelength responses. Our findings demonstrate that FAGeX3 perovskites exhibit highly tunable electronic and optical properties under strain, making them exceptional candidates for advanced optoelectronic applications.

A highly specific red-emitting fluorescent probe for monitoring of Cu2+ in living cells and zebrafish.

A novel seminaphthorhodafluor-based fluorescent probe was designed and prepared. It exhibited an outstanding off-on fluorescence response (about 45-fold enhancement) to Cu2+ because the structure changed from a spirocyclic form to a ring-open state. It showed satisfactory detection performances for Cu2+ with fast response speed, high selectivity and anti-interference, and a low detection limit (22.9nM) due to its long emission wavelength and off-on fluorescence response mode. This probe was also satisfactorily applied for the monitoring of Cu2+ in living cells and zebrafish.

High-precision fiber-optic salinity sensor by micro-cavity and intensity demodulation

In this paper, a hollow-core fiber based micro-cavity Mach-Zehnder interferometer is realized and demonstrated by arc-discharged large lateral-offset splicing. The transmission spectra are investigated and compared with respects to loss and extinction ratio, also the cavity length and offset are theoretically and experimentally optimized. The obtained results show that the concentration of salinity can affect the wavelength response, the average salinity and temperature sensitivities are −2.275 nm/‰ and 1.71 nm/°C, respectively. Moreover, more than 5-fold improvement of the real detection limit is gained by a narrow line-width tunable laser based intensity-demodulation system. And the detection limit of 0.031 ‰ is experimentally witnessed with a time-response of ∼280 ms.

Spectroscopy and luminescence dynamic of Ce3+ and Sm3+ ions in Na3Y(BO3)2

Ce3+, Sm3+ singly-doped and Ce3+-Sm3+ co-doped sodium yttrium borate Na3Y(BO3)2 phosphors are prepared using a high temperature solid-state reaction route, in order to investigate their spectroscopic properties, luminescence dynamic and energy transfer mechanisms. The weak electron-vibrational interaction (EVI) between Ce3+ ions and their surroundings is demonstrated according to measured spectra and theoretical analysis. The mechanism of the Ce3+ → Sm3+ energy transfer in the host is investigated via luminescence dynamic models. In addition, the potential application of Ce3+-Sm3+ co-doped Na3Y(BO3)2 phosphors in the optical anti-counterfeiting is demonstrated according to the luminescence regulation of excitation wavelength response.

Deep orthogonal multi-wavelength fusion for tomogram-free diagnosis in diffuse optical imaging

Novel portable diffuse optical tomography (DOT) devices for breast cancer lesions hold great promise for non-invasive, non-ionizing breast cancer screening. Critical to this capability is not just the identification of lesions but rather the complex problem of discriminating between malignant and benign lesions. To accurately reconstruct the highly heterogeneous tissue of a cancer lesion in healthy breast tissue using DOT, multiple wavelengths can be leveraged to maximize signal penetration while minimizing sensitivity to noise. However, these wavelength responses can overlap, capture common information, and correlate, potentially confounding reconstruction and downstream end tasks. We show that an orthogonal fusion loss regularizes multi-wavelength DOT leading to improved reconstruction and accuracy of end-to-end discrimination of malignant versus benign lesions. We further show that our raw-to-task model significantly reduces computational complexity without sacrificing accuracy, making it ideal for real-time throughput, desired in medical settings where handheld devices have severely restricted power budgets. Furthermore, our results indicate that image reconstruction is not necessary for unbiased classification of lesions with a balanced accuracy of 77% and 66% on the synthetic dataset and clinical dataset, respectively, using the raw-to-task model. Code is available at https://github.com/sfu-mial/FuseNet.

Measurement of light absorption by chromophoric dissolved organic matter using a type-II liquid capillary waveguide: assessment of an achievable accuracy

Light absorption by chromophoric dissolved organic matter (CDOM) in the ocean is often measured using liquid waveguide capillary cells coupled to spectral array detectors. This type of optical setup is affected by several sources of uncertainties related to the waveguide and the detector. Uncertainties from the waveguide arise from errors in the effective path length and the effects of water salinity, while errors related to the detector are due to the non-linearity in the response, internal stray light, and wavelength accuracy. Here, uncertainties in the measurements of the spectral absorption coefficient of CDOM due to the optical setup itself were investigated in detail. The related systematic errors were very often significant (2–15%) and larger than expected from simple measurement uncertainty (±1%). However, they can be corrected by characterizing the detector’s response for non-linearity and stray light, regularly performing calibrations for the detector’s wavelength response, and routinely measuring the waveguide’s effective path length. Including such corrections and timely calibrations reduces the uncertainties related to the spectrophotometric measurements to about ±2%. Uncertainties related to the necessary handling of samples are not included here.

Film dosimetry for occupant exposure monitoring within Far-UVC installations.

Far-UVC radiation between 200 and 230 nm is a promising technology for reducing airborne disease transmission. Previous work with far-UVC lamps has demonstrated the efficacy of far-UVC radiation to inactivate bacteria and viruses while presenting minimal human health hazards. While far-UVC intentionally exposes the occupied space, effectively disinfecting air between occupants, installations must still ensure that occupant eye and skin exposure is within the recommended daily limits. This study examines far-UVC-sensitive films for measuring the dose received by occupants within two real-world far-UVC installations. The film is characterized for accuracy, angular response, wavelength response, and sources of uncertainty in film response, and used to obtain individual exposure doses that account for both the non-uniform irradiance and the unique motion of individuals within the space. Dosimetry results using the films, which account for the time-weighted average exposure of an occupant, ranged from 10% to 49% of the maximum calculated stationary dose based on peak irradiance measurements. Results from this study spotlight the need to incorporate time-weighted average considerations into the design and safety assessment of far-UVC installations to ultimately operate far-UVC technology with its full potential to prevent the spread of potentially fatal infectious diseases.

Generalized channel separation algorithms for accurate camera-based multi-wavelength PTT and BP estimation

Single-site multi-wavelength (MW) pulse transit time (PTT) measurement was recently proposed using contact sensors with sequential illumination. It leverages different penetration depths of light to measure the traversal of a cardiac pulse between skin layers. This enabled continuous single-site MW blood pressure (BP) monitoring, but faces challenges like subtle skin compression, which importantly influences the PPG morphology and subsequent PTT. We extended this idea to contact-free camera-based sensing and identified the major challenge of color channel overlap, which causes the signals obtained from a consumer RGB camera to be a mixture of responses in different wavelengths, thus not allowing for meaningful PTT measurement. To address this, we propose novel camera-independent data-driven channel separation algorithms based on constrained genetic algorithms. We systematically validated the algorithms on camera recordings of palms and corresponding ground-truth BP measurements of 13 subjects in two different scenarios, rest and activity. We compared the proposed algorithms against established blind source separation methods and against previous camera-specific physics-based method, showing good performance in both PTT reconstruction and BP estimation using a Random Forest regressor. The best-performing algorithm achieved mean absolute errors (MAEs) of 3.48 and 2.61 mmHg for systolic and diastolic BP in a leave-one-subject-out experiment with personalization, solidifying the proposed algorithms as enablers of novel contact-free MW PTT and BP estimation.

Analysis of photodiode and barrier properties of CoPc/n-Ge heterojunction under various illumination wavelengths

The present investigation reports the analysis of barrier parameters of the CoPc/n-Ge heterojunction photodiode under varied illumination wavelengths from 500 nm to 1200 nm in steps of 25 nm. The efficiency of this photodiode was also summarized using responsivity, detectivity and quantum efficiency for different illumination wavelengths. The photocurrent seems to be maximum for 850 nm and 1175 nm and shows higher responsivity of 1.72 A/W and 2.38 A/W at 775 nm and 1125 nm wavelength respectively. The quantum efficiency of the photodiode was found to be 275 % at illumination wavelength of 775 nm and 263 % at 1125 nm. For the selective illumination wavelengths (775 nm, 850 nm, 1125 nm and 1175 nm), the electrical properties of the CoPc/n-Ge photodiode were studied. Noticeable variation in the barrier parameters of the photodiode is observed with illumination than compared to dark. Significantly, the series resistance was found to be decreased and shunt resistance is increased with illumination wavelength than compared to dark. Current conduction mechanisms were also investigated in both the forward and reverse bias of the photodiode. The forward current transport processes show that at moderately high bias the current conduction might be associated with TCLC. It is also evidenced from the reverse conduction mechanism that at low reverse voltages PFE is found to be dominant whereas SE is dominant at high reverse voltages. The reduced interface state densities at the CoPc/n-Ge interface were observed under illumination than compared to dark.

Single-pixel p-graded-n junction spectrometers.

Ultra-compact spectrometers are becoming increasingly popular for their promising applications in biomedical analysis, environmental monitoring, and food safety. In this work, we report a single-pixel-photodetector spectrometer with a spectral range from 480 nm to 820 nm, based on the AlGaAs/GaAs p-graded-n junction with a voltage-tunable optical response. To reconstruct the optical spectrum, we propose a tailored method called Neural Spectral Fields (NSF) that leverages the unique wavelength and bias-dependent responsivity matrix. Our spectrometer achieves a high spectral wavelength accuracy of up to 0.30 nm and a spectral resolution of up to 10 nm. Additionally, we demonstrate the high spectral imaging performance of the device. The compatibility of our demonstration with the standard III-V process greatly accelerates the commercialization of miniaturized spectrometers.

Structural dependence of transmission characteristics for photonic crystal fiber with circularly distributed air-holes

Abstract In this study, design and transmission characteristics of a special type of photonic crystal fiber (PCF) geometry namely, circular-lattice photonic crystal fiber (C-PCF) structure are presented. The cladding of the structure consists by a cylindrically symmetrical distribution of air-holes in the silica background and the core is created by omitting one air-hole at the center. The structure provides high degree of flexibility in the fiber design and hence tailorable modal properties. Structural dependence of transmission characteristics of the geometry is numerically investigated by using finite difference mode convergence algorithm. The wavelength responses of fiber parameters, such as effective refractive index, chromatic dispersion, mode-effective area, and nonlinear coefficient of the structure are systematically investigated. Besides, effective V-parameter and single-mode operation of the fiber are also evaluated and discussed. The simulation results show the possibility of large negative dispersion and dispersion flattened nature of the geometry.

Ultra-high sensitivity surface plasmon U-channel photonic crystal fiber for hemoglobin sensing

In order to increase the wavelength response range of the U-channel sensor, a numerical study has been conducted and then the sensing structure has been optimized. A sensor in photonic crystal fiber (PCF) is proposed in which a layer of titanium dioxide is coated on the surface of the U-channel and then coated with a gold film. These two different metal films are mainly used to control the Surface plasmon resonance (SPR) peak and the corresponding resonance wavelength, thus changing the sensor performance. Just below the metal layer are two special air holes on either side. They form a leakage window in the center. In the following sections, the effects of these variables on the sensor will be studied in detail by COMSOL. The modal transmission characteristics of this fiber optic sensor are analyzed in this paper. By analyzing the obtained loss spectrum, the energy variation in the surface plasmon polariton (SPP) mode and the influence of the core mode on the sensing performance of the fiber optic sensor presented, the general rule of the optimized PCF-SPR sensor is deduced. In addition, we can make subtle adjustments to the sensor to improve its sensitivity. We found with the refractive index (RI) ranging from 1.26 to 1.42, the maximum wavelength sensitivity is 7500 nm/RIU, which corresponds to a full width at half maximum (FWHM) of 11.83 nm，a figure of merit (FOM) of 634.1 RIU−1. In addition, we also have discussed the sensor and different concentrations of hemoglobin aqueous solution to detect its RI. It is evident from the results that the sensor demonstrates excellent sensitivity and a wide detection range, which is highly desirable for practical diagnostic purposes. The potential of this sensor for clinical trials and its application to medical diagnostics is promising. Compared with complex traditional methods, the PCF has obvious advantages such as clear structure, simple manufacture, high sensitivity and strong environmental adaptability. Moreover, it has the advantage of wide wavelength response range and has a clear development prospect in the field of biochemical sensing. It has foreseeable potential practical value.

A novel methodology for characterizing DFB laser wavelength response (WR) in wavelength modulation spectroscopy (WMS)

A novel methodology to directly characterize the wavelength response (WR) of a DFB laser in wavelength modulation spectroscopy (WMS) is proposed. This method circumvents the cumbersome etalon signal peak counting process which brings in manual errors easily. The particle swarm optimization (PSO) algorithm was employed to effectively address the challenges encountered during the fitting process, which involved as many as 7 parameters in the WR. The WR with different combinations of frequencies of scan and modulation, as well as modulation amplitudes were characterized by this method. And it is shown that there exist negligible differences when comparing the results with those by traditional etalon peaking counting method. In order to verify the accuracy of this method, two tunable diode lasers emitting near 7185.59 cm−1 and 7444.35 cm−1 were employed to perform the measurements of temperature above a burner with calibration-free WMS-2f/1f and direct absorption spectroscopy (DAS), respectively. The temperature measured by two techniques shows great accordance, which indicates the accuracy of WR deduced by the proposed method.

A multi-laser hybrid absorption sensor for simultaneous measurement of NH3, NO, and temperature in denitrification flue gas

The real-time monitoring of NH3, NO, and flue gas temperatures is critical to controlling NOx emissions from coal-fired power plants, reducing ammonia slip, and realizing accurate ammonia injection. However, few previous studies have utilized laser absorption sensors to measure these three indicators simultaneously. In this paper, a multi-laser hybrid sensor is designed based on tunable diode laser absorption spectroscopy (TDLAS) for simultaneous measurement of NH3, NO, and flue gas temperature. The sensor uses a distributed feedback (DFB) laser to target the NH3 and the H2O lines, and a quantum cascade laser (QCL) is used to target the NO line. In the measurements of NH3 and NO using calibration-free wavelength-modulated spectroscopy (CF-WMS), we employ a method to obtain the laser wavelength response by fitting the demodulated signal of a standard gas. Additionally, temperature measurements are obtained using the time-division multiplexing (TDM) strategy and direct absorption spectroscopy (DAS) techniques with the help of the absorption spectrum of H2O. Under static conditions, the relative accuracy of NH3 and NO detected by the sensor is 4.2% and 2%, respectively, and the maximum relative standard deviation of temperature is 1.3%. When tested under flowing conditions, the sensor can accurately capture NH3, NO, and temperature changes. The relative accuracy of NH3 and NO is 4.7% and 2.2%, and the relative standard deviation of temperature is 0.9%. The sensor has great potential in optimizing denitrification processes in thermal power plants.

All optical modulation in vertically coupled indium tin oxide ring resonator employing epsilon near zero state

We present an innovative approach to achieve all-optical modulation within an ITO-based vertically coupled ring resonator. This method leverages the material's enhanced nonlinear response in the near-infrared wavelengths, particularly within the epsilon-near-zero (ENZ) state. To enhance the interaction between light and the material while minimizing scattering losses, our approach employs an ITO-based vertically connected ring resonator. The vertical arrangement eliminates the need for etching fine gaps to separate the ring and bus waveguide. The novel waveguide design addresses the necessity of high sensitivity, non-linear effects and compact size opening the possibilities for all-optical signal processing. This unique resonator structure effectively facilitates the coupling of a high-intensity pump wavelength into the ITO-based micro-ring resonator. Consequently, this optical pumping induces electron heating within the ITO material, leading to a significant increase in its nonlinear optical properties. This, in turn, results in a noteworthy alteration of ITO's refractive index, specifically in the unity order, thereby modifying the complex effective index of the optical beam propagating at 1550 nm. Our experimental findings demonstrate an impressive extinction ratio of 18 dB for a 30 µm long device, which highlights the efficiency of our approach in achieving all-optical modulation through the optical pumping of an ITO-based vertically coupled ring resonator. The proposed all-optical modulator has outperformed as compared to conventional waveguide-based modulators in terms of extinction ratio and footprint. This novel technique holds immense potential for advancing high-speed data communication systems in the future. As the demand for advanced processing capabilities, such as artificial intelligence, continues to grow, all-optical modulation emerges as a groundbreaking technology poised to revolutionize the next generation of computing and communication systems.

Degradation Evolution of Perovskite Solar Cells via In Situ Real‐Time Optical Observation

AbstractUnderstanding the degradation kinetics of perovskite materials in operating perovskite solar cells (PSCs) is critical for developing methods to further enhance their device stability. However, it remains a challenge to capture the details and characteristics of the perovskite degradation process inside operating PSCs under different environmental conditions in real‐time at the microscopic scale. Herein, a novel, nondestructive real‐time in situ monitoring method based on a tapered seven‐core fiber optic sensor is demonstrated. The fiber‐optic sensor can be facilely inserted near the surface of the perovskite layer of a working PSCs to monitor its degradation kinetics without interfering with the performance of the device. Stable and reproducible correlations between real‐time material degradation and optical wavelength response under different humidity and temperature conditions are observed and quantified. This new measurement tool allows real‐time access to the detailed degradation evolution of PSCs, which not only guides the design of more stable devices but also offers the possibility to monitor the health status of PSCs in field applications.

Electrical characterization of optical resonance effects in laterally-nanostructured organic photodetectors.

Optoelectronic devices based on organic semiconductor materials are on the rise for sensing applications due to their integrability with a variety of substrates - including flexible substrates for wearables. For sensing applications often narrowband absorption is desired with suppression of light at other wavelengths. Here, we investigate narrowband absorption enhancement of organic photodetectors (OPD) with an integrated lateral nanostructure. We show with finite-element simulations, that resonant excitation of low absorbing wavelength regimes allow for up to 3 times the absolute absorption at wavelengths on resonance compared to wavelengths off resonance. We present experimental results for CuPc/C60 OPDs fabricated on grating nanostructures with periods of 350 nm and 400 nm and a grating depth of 140 nm as well as a grating period of 370 nm and grating depths of 30 nm. Angle-resolved transmission spectra clearly show the optical resonance effects. In order to evaluate the electrical resonance effects a measurement system is introduced based on angular laser excitation. An angular resolution of 0.1° is achieved in the analysis of the OPD photocurrent response. Using the measurement setup an increase of the photocurrent by up to 50% is observed for the TE-resonance. It is demonstrated that the resonance wavelength is tuned simply by adjusting the grating period without changes in the layer thicknesses. This opens up new opportunities in realizing pixels of different wavelength response next to each other employing a single active stack design.

Physics‐Informed Machine Learning for Inverse Design of Optical Metamaterials

Optical metamaterials manipulate light through various confinement and scattering processes, offering unique advantages like high performance, small form factor and easy integration with semiconductor devices. However, designing metasurfaces with suitable optical responses for complex metamaterial systems remains challenging due to the exponentially growing computation cost and the ill‐posed nature of inverse problems. To expedite the computation for the inverse design of metasurfaces, a physics‐informed deep learning (DL) framework is used. A tandem DL architecture with physics‐based learning is used to select designs that are scientifically consistent, have low error in design prediction, and accurate reconstruction of optical responses. The authors focus on the inverse design of a representative plasmonic device and consider the prediction of design for the optical response of a single wavelength incident or a spectrum of wavelength in the visible light range. The physics‐based constraint is derived from solving the electromagnetic wave equations for a simplified homogenized model. The model converges with an accuracy up to 97% for inverse design prediction with the optical response for the visible light spectrum as input, and up to 96% for optical response of single wavelength of light as input, with optical response reconstruction accuracy of 99%.

Defect Driven Opto-Critical Phases Tuned for All-Solar Utilization.

Materials imbued with uniformly dispersed, photo-responsive nanoparticles are instrumental in sustainable energy and photonic applications. Conventional methods, however, constrain their all-solar response. An innovative alternative is proposed: submerged photo-synthesis of crystallites (SPsC). It is shown that strategic doping with copper and oxygen vacancies can induce opto-critical phases from the non-stoichiometric tungstic acids (WO3 ·H2 O). These opto-critical phases enable a dynamic equilibrium shift in lattice defect stabilization, facilitating an unprecedented a whole solar wavelength response. This response manifests as photothermal, photo-assisted water evaporation, and photo-electrochemical characteristics. Harnessing all-solar energy, this one-pot SPsC strategy may steer the design and development of advanced oxide materials, enhancing functionality across diverse application domains. This article is protected by copyright. All rights reserved.

In-line open-cavity Mach-Zehnder interferometric refractive-index sensors based on inter-mode and inter-core-mode interferences

We experimentally demonstrated in-line Mach-Zehnder interferometric sensors based on inter-mode interference (IMI) and inter-core-mode interference (ICMI) for refractive index (RI) measurements. The structure of the IMI-based sensor consisted of a C-shaped fiber spliced between two multi-mode fibers (MMF) with the opposite ends spliced to lead-in and lead-out single-mode optical fibers. The ICMI-based sensor has a similar structure as the IMI-based sensor but with an additional in-house fabricated three-core multi-core fiber (MCF) spliced between the MMF and C-shaped fiber. The performance of the two RI sensors was evaluated and compared using water-glycerol solutions with RI values ranging from 1.333 to 1.338. The RI sensitivity, as well as other characteristic properties such as free spectral range and extinction ratio in relation to three lengths of the C-shaped fiber of 2, 2.5 and 3 mm, were investigated in both structures. The open-cavity characteristic of the C-shaped fiber allows the solution to interact with the optical path of the sensors, hence improving their RI measurement sensitivities. Both types of sensors exhibit linear wavelength responses with variation in RI. The RI sensitivity of the IMI-based sensor exhibits minor variations when the length of the C-shaped fiber is altered, with a maximum sensitivity of -7999.76 nm/RIU. In contrast, the RI sensitivity of ICMI-based sensor exhibits variability when changing the C-shaped fiber length, potentially due to variations in the RI distribution among the cores within the MCF, with its maximum sensitivity being -6211.98 nm/RIU. The temperature sensitivity of all the tested sensors was around 0.7 nm/ °C, denoting a low temperature cross-sensitivity of -7.427 × 10−5 RIU/ °C. This work experimentally exhibits a comparison of two sensing effects in the same configuration. The long length (longer than 2 mm) of the sensing element facilitates the fabrication process, and the open-cavity present in the proposed sensors yields a high sensitivity, which is in the same order of magnitude as the IMI-based sensors and is one order of magnitude higher than the ICMI-based sensors, emphasizing their promising candidacy for label-free optical sensing of chemical and biological samples.