An optically pumped molecular laser system with a transverse excitation scheme has been used to observe 77 guide wavelengths associated with the modes of an oversized waveguide laser resonator. These guide wavelengths, spanning from 102.6 to 990.6 μm, were generated by a variety of lasing media, including methanol along with several symmetric- and asymmetric-top molecules. The guide wavelengths displayed several consistent characteristics when compared with their respective fundamental laser emissions: their wavelengths were about 0.47 % larger and their relative powers were at least a factor of ten weaker. The properties of these guide wavelengths were used to assess frequency and wavelength measurements associated with known far-infrared laser emissions. For several of these laser emissions, this prompted a reinvestigation and subsequent revision of their measured values. Five far-infrared laser frequencies were also measured for the first time.