In this study, laser-induced breakdown spectroscopy (LIBS) was utilized to classify Radix Bupleuri from six origins to acquire good results. Several feature variable selection methods have been used to preprocess the experimental data on the LIBS. Machine learning and deep learning algorithms were used to build classification models, respectively. The accuracy of all four classification models on the prediction set is higher than 99%. Among them, the classification model constructed by the residual neural network (ResNet) algorithm demonstrated the optimal prediction accuracy both in the full waveform and feature variable selection. For the independent prediction set, the ResNet classification model still demonstrated optimal prediction with 88.33% accuracy. On the importance ranking of feature variables, the elements as Cl, Mg, Fe, Ba, Li, O, and He were considered to play an important role in the identification of the origin of Radix Bupleuri. This study demonstrated that LIBS combined with deep learning and machine learning algorithms can provide a more efficient and reliable method for the origin identification of Radix Bupleuri. In addition, it can be found that the application of deep learning algorithms can realize the prediction output more efficiently and accurately for the analysis of high-dimensional data of LIBS.
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