The silicone waterproof material and waterbased capillary inorganic waterproofer possess the advantages of rapid film formation and significant hydrophobic effect. In this study, the material composition and mixing ratio of the silicone waterproofing material and waterbased capillary inorganic waterproofing were investigated by multiple performance tests. The results indicated that a white coating was formed on the surface when the mixing ratio of isobutyl-triethoxy-silane and isooctyl-triethoxy-silane was more than 69 %. When the content of sodium and potassium methyl silicate exceeded 0.5 %, respectively, there was an upward trend of contact angle while the reduction in water absorption gradually decreased. Meanwhile, the contact angle and water absorption height of silicone waterproof material were tested. The results showed that the coating performance and hydrophobicity were the best when the mixing ratio of isobutyl-triethoxy-silane, isooctyl-triethoxy-silane, sodium methyl silicate, and potassium methyl silicate was 1.5:0.2:1:0.5. When the matrix mortar specimen was made of Cementitious Capillary Crystalline Waterproofing Materials (CCCW), the lowest water absorption height and water absorption of the experimental group consisted of sodium silicate, sodium tetraborate, sodium phosphate, and sodium hydroxyethyl cellulose were 316.7 % and 39%, respectively. The lowest water absorption height and water absorption of the experimental group consisted of sodium silicate, sodium tetraborate, nano-silica, and sodium hydroxyethyl cellulose were 215.4 % and 28 %, respectively. The results showed that CCCW combined with the experimental group consisted of sodium silicate, sodium tetraborate, sodium phosphate, and sodium hydroxyethyl cellulose had better waterproofing effect.