Water Vapor Abundance Research Articles

Linking Outer Disk Pebble Dynamics and Gaps to Inner Disk Water Enrichment

Abstract Millimeter continuum imaging of protoplanetary disks reveals the distribution of solid particles and the presence of substructures (gaps and rings) beyond 5–10 au, while infrared (IR) spectra provide access to abundances of gaseous species at smaller disk radii. Building on recent observational findings of an anti-correlation between the inner disk water luminosity and outer dust disk radius, we aim here at investigating the dynamics of icy solids that drift from the outer disk and sublimate their ice inside the snow line, enriching the water vapor that is observed in the IR. We use a volatile-inclusive disk evolution model to explore a range of conditions (gap location, particle size, disk mass, and α viscosity) under which gaps in the outer disk efficiently block the inward drift of icy solids. We find that inner disk vapor enrichment is highly sensitive to the location of a disk gap, yielding for each particle size a radial “sweet spot” that reduces the inner disk vapor enrichment to a minimum. For pebbles of 1–10 mm in size, which carry the most mass, this sweet spot is at 7–15 au, suggesting that inner gaps may have a key role in reducing ice delivery to the inner disk and may not allow the formation of Earths and super-Earths. This highlights the importance of observationally determining the presence and properties of inner gaps in disks. Finally, we argue that the inner water vapor abundance can be used as a proxy for estimating the pebble drift efficiency and mass flux entering the inner disk.

Tropospheric and stratospheric NO retrieved from ground-based Fourier-transform infrared (FTIR) measurements

Abstract. Nitric oxide (NO) is a key active trace gas in the atmosphere, which contributes to form harmful ozone in the troposphere and to the destruction of ozone in the stratosphere. In this study, we present the NO retrieval from ground-based Fourier-transform infrared (FTIR) solar absorption spectrometry measurements at a polluted site (Xianghe, China) and a background site (Maïdo, Reunion Island). The degree of freedom (DOF) of the NO retrieval is 2.3±0.4 (1σ) at Xianghe and 1.3±0.1 at Maïdo. By looking at the FTIR NO retrievals at Xianghe and Maïdo, we find that the stratospheric NO partial column is large in summer as compared to winter at both sites, and the seasonal variation in the FTIR stratospheric NO partial columns is consistent with that observed by the co-located Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) satellite measurements. A large diurnal variation in the stratospheric NO partial column is observed by the FTIR measurements at Maïdo, with an increase from the early morning to about 14:00 local time and a decrease thereafter. Due to the low NO concentration near the surface, the FTIR NO retrieval is only sensitive to the stratosphere at Maïdo. The high NO mole fraction near the surface at Xianghe allows us to derive tropospheric and stratospheric NO partial columns separately, although the tropospheric column is very difficult to retrieve in summer (June–August) because of the high water vapor abundance. A good correlation is found between the NO observed by the FTIR measurements and other air pollutants (NO2 and CO) in the troposphere at Xianghe. It is the first study of a successful analysis of NO in the troposphere from a ground-based FTIR site. The tropospheric and stratospheric NO retrieval might be possible at other potential FTIR sites inside or near large cities with enhanced levels of NO near the surface.

Multiple Moist Climate Equilibrium States on Arid Rocky M-dwarf Planets: A Last-saturation Tracer Analysis

Abstract Terrestrial-type exoplanets orbiting nearby red dwarf stars (M dwarfs) are the first potentially habitable exoplanets suitable for atmospheric characterization in the near future. Understanding the stability of water in cold-trap regions on such planets is critical because it directly impacts transmission spectroscopy observations, the global energy budget, and long-term surface water evolution. Here we diagnose the humidity distribution in idealized general circulation model simulations of terrestrial-type exoplanets. We use the “tracer of last saturation” technique to study the saturation statistics of air parcels. We find that on synchronously rotating planets the water vapor abundance in the nightside upper troposphere depends weakly on planetary rotation, while more water vapor builds up in the nightside lower troposphere on fast-rotating planets. We then discuss how last-saturation statistics can elucidate the multiple moist climate equilibrium states on synchronously and asynchronously rotating arid planets. We show that the multiple moist climate states arise from the cold-trapping competition between the substellar upper atmosphere and cold surface regions. We find that fast synchronously rotating planets tend to trap surface water on the nightside as a result of their weak atmospheric and strong surface cold traps compared to the slow-rotating case. These results elucidate the nature of the water cycle on arid rocky exoplanets and will aid interpretation of atmospheric observations in the future.

Martian water loss to space enhanced by regional dust storms

Mars has lost most of its initial water to space as atomic hydrogen and oxygen. Spacecraft measurements have determined that present-day hydrogen escape undergoes large variations with season that are inconsistent with long-standing explanations. The cause is incompletely understood, with likely contributions from seasonal changes in atmospheric circulation, dust activity and solar extreme ultraviolet input. Although some modelling and indirect observational evidence suggest that dust activity can explain the seasonal trend, no previous study has been able to unambiguously distinguish seasonal from dust-driven forcing. Here we present synoptic measurements of dust, temperature, ice, water and hydrogen on Mars during a regional dust event, demonstrating that individual dust events can boost planetary H loss by a factor of five to ten. This regional storm occurred in the declining phase of the known seasonal trend, establishing that dust forcing can override this trend to drive enhanced escape. Because similar regional storms occur in most Mars years, these storms may be responsible for a large fraction of Martian water loss and represent an important driver of Mars atmospheric evolution. Multi-spacecraft observations of temperature, dust and water ice opacities, water vapour abundances, and thermospheric hydrogen in the atmosphere of Mars during a local dust storm show that even such regional events, much more frequent than global dust storms, can boost global atmospheric escape by a factor of five to ten.

Enhanced water loss from the martian atmosphere during a regional-scale dust storm and implications for long-term water loss

Lower atmosphere variations in the martian water vapour and hydrogen abundance during the late southern summer regional-scale dust storm from LS = 326.1°–333.5° Mars Year34 (18th-31st January 2019) and their associated effect on hydrogen escape are investigated using a multi-spacecraft assimilation of atmospheric retrievals into a Martian global circulation model. The dusty conditions led to an elevation of the hygropause and associated increase in middle atmosphere hydrogen at the peak of the dust storm, which was particularly intense in Mars Year34. This response has an important effect on water loss during this time period, quantification of which can provide a more robust calculation of the integrated loss of water through time on Mars and better insight to planetary evolution. The influx of water vapour to higher altitudes led to an associated increase in hydrogen through photolysis of water vapour and a hydrogen escape rate of around 1.0×109 cm−2s−1, meaning the late southern summer regional-scale dust storm in Mars Year34 enhanced water loss rates on Mars to levels observed during global-scale dust storms. The water loss rate during the late southern summer regional-scale dust storm, also known as a C storm, led to around 15% of the total annual water loss during only 5% of the year and was at least three times stronger than the much less dusty C storm event in Mars Year30. These results demonstrate that interannual variations in the strength of the late southern summer regional-scale dust storm must be considered when calculating the integrated loss of water on Mars, an important quantity to constrain in relation to the potential habitability of Mars.

Water activity in Venus’s uninhabitable clouds and other planetary atmospheres

The recent suggestion of phosphine in Venus’s atmosphere has regenerated interest in the idea of life in clouds. However, such analyses usually neglect the role of water activity, which is a measure of the relative availability of water, in habitability. Here we compute the water activity within the clouds of Venus and other Solar System planets from observations of temperature and water-vapour abundance. We find water-activity values of sulfuric acid droplets, which constitute the bulk of Venus’s clouds, of ≤0.004, two orders of magnitude below the 0.585 limit for known extremophiles. Considering other planets, ice formation on Mars imposes a water activity of ≤0.537, slightly below the habitable range, whereas conditions are biologically permissive (>0.585) at Jupiter’s clouds (although other factors such as their composition may play a role in limiting their habitability). By way of comparison, Earth’s troposphere conditions are, in general, biologically permissive, whereas the atmosphere becomes too dry for active life above the middle stratosphere. The approach used in the current study can also be applied to extrasolar planets. Calculations of water activity reveal that this parameter can be a substantial barrier to habitability for clouds of Solar System planets. In particular, water activity within droplets of Venus’s clouds is more than 100-fold below the threshold for biotic activity of known extremophiles.

Water vapor retrieval using the Airborne Multiangle SpectroPolarimetric Imager

The Airborne Multiangle SpectroPolarimetric Imager (AirMSPI) acquires radiance measurements in eight spectral bands centered at 355, 380, 445, 470*, 555, 660*, 865*, and 935 nm, three of which also measure linear polarization (denoted by asterisks). A two-step retrieval approach is developed to retrieve total precipitable water vapor (PWV) abundance: a) the first step is a fast estimate of water vapor obtained by comparing the ratio of observed radiance in the near-infrared (NIR) bands L935nm/L865nm at multiple view angles against pre-calculated lookup table values as a function of PWV abundance, on the assumption of no aerosols and a moderately bright land surface; (b) the second step refines the estimated solution by accounting for aerosol loading, particle properties, and surface reflection, which are retrieved from AirMSPI measurements in its ultraviolet to NIR aerosol bands. Our retrieval is tested using 27 AirMSPI datasets with low to moderately high aerosol loadings and PWV up to about 3.5 cm, acquired during four NASA field campaigns plus one AirMSPI engineering test flight. Comparison of the retrieved total PWV amount against AERONET reference data shows a mean percentage difference 8.6%. The quantities that inform the second step of the PWV retrieval—namely, aerosol optical depth (AOD), aerosol single scattering albedo (SSA), and aerosol effective radius—are also compared to the AERONET reference data. The mean absolute differences (MADs) are less than 0.0253 and less than 0.036 for AOD and SSA in the visible, respectively. The MADs are 0.036 μm and 1.232 μm for the effective radius of fine and coarse mode aerosols, respectively. Comparison to data from the Cloud Physics Lidar places the MAD of aerosol layer height at about 360 m.

Role of Boundary Layer Jet in the Occurrence and Development of Warm-sector Heavy Rainfall over South China: a Case Study

Warm-sector heavy rainfall which occurred at the coastal area of southern China on 8 June 2015 was associated with a boundary layer jet (BLJ). The initiation and maintenance mechanism of the BLJ is further investigated based on the Weather Research and Forecasting (WRF) model simulations and reanalysis data. The results showed that the BLJ developing at night transported moisture to the coastal area of Guangxi in southern China, which lead to the instability of the atmosphere over the coastal areas of Guangxi. The terrain blocking and lifting the southerly with abundance of water vapor is the major trigger mechanism in present case. As the BLJ weakened and vanished after midday, the amount of rainfall decreased correspondingly. Based on the numerical model sensitivity test with different parameterization schemes, the key role of the BLJ for the occurrence and development of the warm-sector heavy rainfall is further verified.

Two‐Year Observations of the Jupiter Polar Regions by JIRAM on Board Juno

AbstractWe observed the evolution of Jupiter's polar cyclonic structures over two years between February 2017 and February 2019, using polar observations by the Jovian InfraRed Auroral Mapper, JIRAM, on the Juno mission. Images and spectra were collected by the instrument in the 5‐μm wavelength range. The images were used to monitor the development of the cyclonic and anticyclonic structures at latitudes higher than 80° both in the northern and the southern hemispheres. Spectroscopic measurements were then used to monitor the abundances of the minor atmospheric constituents water vapor, ammonia, phosphine, and germane in the polar regions, where the atmospheric optical depth is less than 1. Finally, we performed a comparative analysis with oceanic cyclones on Earth in an attempt to explain the spectral characteristics of the cyclonic structures we observe in Jupiter's polar atmosphere.

Missing water in Class I protostellar disks

Context. Water is a key volatile that provides insight into the initial stages of planet formation. The low water abundances inferred from water observations toward low-mass protostellar objects may point to a rapid locking of water as ice by large dust grains during star and planet formation. However, little is known about the water vapor abundance in newly formed planet-forming disks. Aims. We aim to determine the water abundance in embedded Keplerian disks through spatially-resolved observations of H218O lines to understand the evolution of water during star and planet formation. Methods. We present H218O line observations with ALMA and NOEMA millimeter interferometers toward five young stellar objects. NOEMA observed the 31,3–22,0 line (Eup∕kB = 203.7 K) while ALMA targeted the 41,4–32,1 line (Eup∕kB = 322.0 K). Water column densities were derived considering optically thin and thermalized emission. Our observations were sensitive to the emission from the known Keplerian disks around three out of the five Class I objects in the sample. Results. No H218O emission is detected toward any of our five Class I disks. We report upper limits to the integrated line intensities. The inferred water column densities in Class I disks are NH218O < 1015 cm−2 on 100 au scales, which include both the disk and envelope. The upper limits imply a disk-averaged water abundance of ≲10−6 with respect to H2 for Class I objects. After taking the physical structure of the disk into account, the upper limit to the water abundance averaged over the inner warm disk with T > 100 K is between ~10−7 and 10−5. Conclusions. Water vapor is not abundant in warm protostellar envelopes around Class I protostars. Upper limits to the water vapor column densities in Class I disks are at least two orders of magnitude lower than values found in Class 0 disk-like structures.

Detections of Water Vapor Increase Over the North Polar Troughs on Mars as Observed by CRISM

AbstractThe Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) onboard the Mars Reconnaissance Orbiter has been observing the north polar layered deposits (NPLD) of Mars. Polar wind circulations are instrumental in shaping the NPLD. In particular, the downslope (katabatic) flows help carve the spiral‐shaped geological depressions, known as the polar troughs, and appropriate environmental conditions develop katabatic jumps that favor substantial water abundance changes over the troughs. Utilizing CRISM retrievals, we report the first observational evidence of the sharp increase in the water vapor abundance over polar troughs on Mars at high resolution (~320 m). This has a direct influence on the dynamic evolution of ice migration in the northern polar cap, the major source of atmospheric water on Mars.

The diurnal transport of atmospheric water vapor during major dust storms on Mars based on the Mars Climate Database, version 5.3

In recent studies of the Martian atmosphere, strong diurnal variation in the dust was discovered in the southern hemisphere during major dust storms, which provides strong evidence that the commonly recognized meridional transport process is driven by thermal tides. This process, when coupled with deep convection, could be an important part of the short-term atmospheric dynamics of water escape. However, the potential of this process to alter the horizontal distribution of moist air has not been systematically investigated. In this work, we conducted pre-research on the horizontal transport of water vapor associated with the migrating diurnal tide (DW1) at 50 Pa in the upper troposphere during major dust storms based on the Mars Climate Database (MCD) 5.3, a state-of-the-art database for Martian atmospheric research that has been validated as simulating the relevant short-period atmospheric dynamics well. We found westward-propagating diurnal patterns in the global water vapor front during nearly all the major dust storms from Martian years (MYs) 24 to 32. Statistical and correlation analyses showed that the diurnal transport of water vapor during global and A-season regional dust storms is dominated by the DW1. The effect of the tidal transport of water vapor varies with the types of dust storms in different seasons. During regional dust storms, the tidal transport induces only limited diurnal motion of the water vapor. However, the horizontal tidal wind tends to increase the abundance of daytime water vapor at mid- to low latitudes during the MY 28 southern summer global dust storm while decreasing it during the MY 25 southern spring global dust storm. The tidal transport process during these two global dust storms can induce opposite effects on water escape.

Water Vapor Vertical Profiles on Mars in Dust Storms Observed by TGO/NOMAD

AbstractIt has been suggested that dust storms efficiently transport water vapor from the near‐surface to the middle atmosphere on Mars. Knowledge of the water vapor vertical profile during dust storms is important to understand water escape. During Martian Year 34, two dust storms occurred on Mars: a global dust storm (June to mid‐September 2018) and a regional storm (January 2019). Here we present water vapor vertical profiles in the periods of the two dust storms (Ls = 162–260° and Ls = 298–345°) from the solar occultation measurements by Nadir and Occultation for Mars Discovery (NOMAD) onboard ExoMars Trace Gas Orbiter (TGO). We show a significant increase of water vapor abundance in the middle atmosphere (40–100 km) during the global dust storm. The water enhancement rapidly occurs following the onset of the storm (Ls~190°) and has a peak at the most active period (Ls~200°). Water vapor reaches very high altitudes (up to 100 km) with a volume mixing ratio of ~50 ppm. The water vapor abundance in the middle atmosphere shows high values consistently at 60°S‐60°N at the growth phase of the dust storm (Ls = 195°–220°), and peaks at latitudes greater than 60°S at the decay phase (Ls = 220°–260°). This is explained by the seasonal change of meridional circulation: from equinoctial Hadley circulation (two cells) to the solstitial one (a single pole‐to‐pole cell). We also find a conspicuous increase of water vapor density in the middle atmosphere at the period of the regional dust storm (Ls = 322–327°), in particular at latitudes greater than 60°S.

On the impact of future climate change on tropopause folds and tropospheric ozone

Abstract. Using a transient simulation for the period 1960–2100 with the state-of-the-art ECHAM5/MESSy Atmospheric Chemistry (EMAC) global model and a tropopause fold identification algorithm, we explore the future projected changes in tropopause folds, stratosphere-to-troposphere transport (STT) of ozone, and tropospheric ozone under the RCP6.0 scenario. Statistically significant changes in tropopause fold frequencies from 1970–1999 to 2070–2099 are identified in both hemispheres, regionally exceeding 3 %, and are associated with the projected changes in the position and intensity of the subtropical jet streams. A strengthening of ozone STT is projected for the future in both hemispheres, with an induced increase in transported stratospheric ozone tracer throughout the whole troposphere, reaching up to 10 nmol mol−1 in the upper troposphere, 8 nmol mol−1 in the middle troposphere, and 3 nmol mol−1 near the surface. Notably, the regions exhibiting the largest changes of ozone STT at 400 hPa coincide with those with the highest fold frequency changes, highlighting the role of the tropopause folding mechanism in STT processes under a changing climate. For both the eastern Mediterranean and Middle East (EMME) and Afghanistan (AFG) regions, which are known as hotspots of fold activity and ozone STT during the summer period, the year-to-year variability of middle-tropospheric ozone with stratospheric origin is largely explained by the short-term variations in ozone at 150 hPa and tropopause fold frequency. Finally, ozone in the lower troposphere is projected to decrease under the RCP6.0 scenario during MAM (March, April, and May) and JJA (June, July, and August) in the Northern Hemisphere and during DJF (December, January, and February) in the Southern Hemisphere, due to the decline of ozone precursor emissions and the enhanced ozone loss from higher water vapour abundances, while in the rest of the troposphere ozone shows a remarkable increase owing mainly to the STT strengthening and the stratospheric ozone recovery.

Effects of the MY34/2018 Global Dust Storm as Measured by MSL REMS in Gale Crater

The Rover Environmental Monitoring Station (REMS) instrument that is onboard NASA's Mars Science Laboratory (MSL) Curiosity rover. REMS has been measuring surface pressure, air and ground brightness temperature, relative humidity, and UV irradiance since MSL's landing in 2012. In Mars Year (MY) 34 (2018) a global dust storm reached Gale Crater at Ls ~190°. REMS offers a unique opportunity to better understand the impact of a global dust storm on local environmental conditions, which complements previous observations by the Viking landers and Mars Exploration Rovers. All atmospheric variables measured by REMS are strongly affected albeit at different times. During the onset phase, the daily maximum UV radiation decreased by 90% between sols 2075 (opacity ~1) and 2085 (opacity ~8.5). The diurnal range in ground and air temperatures decreased by 35K and 56K, respectively, with also a diurnal-average decrease of ~2K and 4K respectively. The maximum relative humidity, which occurs right before sunrise, decreased to below 5%, compared with pre-storm values of up to 29%, due to the warmer air temperatures at night while the inferred water vapor abundance suggests an increase during the storm. Between sols 2085 and 2130, the typical nighttime stable inversion layer was absent near the surface as ground temperatures remained warmer than near-surface air temperatures. Finally, the frequency-domain behavior of the diurnal pressure cycle shows a strong increase in the strength of the semidiurnal and terdiurnal modes peaking after the local opacity maximum, also suggesting differences in the dust abundance inside and outside Gale.

Predicted diurnal variation of the deuterium to hydrogen ratio in water at the surface of Mars caused by mass exchange with the regolith

Regolith on Mars exchanges water with the atmosphere on a diurnal basis and this process causes significant variation in the abundance of water vapor at the surface. While previous studies of regolith-atmosphere exchange focus on the abundance, recent in-situ experiments and remote sensing observations measure the isotopic composition of the atmospheric water. We are therefore motivated to investigate isotopic water exchange between the atmosphere and the regolith and determine its effect on the deuterium to hydrogen ratio (D/H) of the atmosphere. We model transport of water in the regolith and regolith-atmosphere exchange by solving a transport equation including regolith adsorption, condensation, and diffusion. The model calculates equilibrium fractionation between HDO and H2O in each of these processes. The fractionation in adsorption is caused by the difference in the latent heat of adsorption, and that of condensation is caused by the difference in the vapor pressure. Together with a simple, bulk-aerodynamic boundary layer model, we simulate the diurnal variation of the D/H near the planetary surface. We find that the D/H can vary by 300–1400‰ diurnally in the equatorial and mid-latitude locations, and the magnitude is greater at a colder location or season. The variability is mainly driven by adsorption and desorption of regolith particles, and its diurnal trend features a drop in the early morning, a rise to the peak value during the daytime, and a second drop in the late afternoon and evening, tracing the water vapor flow into and out from the regolith. The predicted D/H variation can be tested with in-situ measurements. As such, our calculations suggest stable isotope analysis to be a powerful tool in pinpointing regolith-atmosphere exchange of water on Mars.

MGS TES observations of the water vapor in the martian southern polar atmosphere during spring and summer

We report retrievals of atmospheric water vapor abundances in and around the South Polar Region (SPR) of Mars during spring and summer of Mars Years (MY) 24–26 (1999–2003). The retrieval utilizes infrared spectra collected by the Thermal Emission Spectrometer (TES) aboard the Mars Global Surveyor (MGS) spacecraft. Modifications to the existing retrieval algorithm enable the first retrievals of water vapor abundances over regions covered by the seasonal CO2 frost during spring.We present polar maps of water vapor variability in the SPR for the time periods Ls = 195°–345° in MY24–26. Water vapor behavior in the SPR in MY24 and MY26 exhibits substantial similarity in spatial distribution for the same dates and in temporal variability. Water vapor behavior in MY25 is significantly different from that in MY24 and MY26 with abundances ~30% lower around summer solstice (Ls = 270°). We hypothesize that water vapor behavior in MY25 was affected by the Global Dust Storm (GDS) that started at Ls ~185° of that year and significantly affected the atmosphere of the whole planet. We speculate that the reduction in the observed vapor abundances in MY25 could have resulted from disruption of the southward atmospheric vapor transport from mid-latitudes by the GDS or from reduction of the rate of desorption of vapor from thawed circumpolar terrains due to changes in surface temperature during the GDS.Through most of the spring, highest vapor abundances are observed just northward of the retreating edge of the seasonal CO2 cap, with generally low abundances over the seasonal cap. Repeated cycles of condensation and re-sublimation of water vapor on the edge of the retreating cap could be responsible for this build-up of vapor near the cap edge. Relatively high vapor abundances that are systematically observed over some regions of the cap in late spring could be associated with venting of the mixture of water vapor, CO2 gas and dust from underneath the seasonal cap through fractures in the frost.We explore the evolution of the water vapor in the SPR during spring and summer using two 1-dimenional models representing two limiting cases that attribute observed changes to either atmospheric transport or surface sources. The atmospheric transport model appears to be more consistent with observations, suggesting that atmospheric transport plays the dominant role in the water vapor cycle in the SPR. However, activity of surface processes such as desorption of vapor from the regolith cannot be excluded.Comparison of the water vapor cycle during spring and summer in the SPR and the Northern Polar Region (NPR) shows that, besides the difference in the highest observed abundances, the evolution of the vapor abundances shows remarkable qualitative similarity, despite the presence of a large source of vapor during summer in the north in the form of the North Polar Residual Cap (NPRC). This suggests that the processes shaping the water cycle in the polar regions are similar in nature and differ only in strength. The new data on water vapor in the SPR, together with our previous retrievals of water vapor in the NPR, constitute a new dataset that enables testing of Martian Global Circulation Models close to the planet's poles, and enables better understanding of the difference between the Martian polar regions.

Martian dust storm impact on atmospheric H2O and D/H observed by ExoMars Trace Gas Orbiter.

Global dust storms on Mars are rare1,2 but can affect the Martian atmosphere for several months. They can cause changes in atmospheric dynamics and inflation of the atmosphere3, primarily owing to solar heating of the dust3. In turn, changes in atmospheric dynamics can affect the distribution of atmospheric water vapour, with potential implications for the atmospheric photochemistry and climate on Mars4. Recent observations of the water vapour abundance in the Martian atmosphere during dust storm conditions revealed a high-altitude increase in atmospheric water vapour that was more pronounced at high northern latitudes5,6, as well as a decrease in the water column at low latitudes7,8. Here we present concurrent, high-resolution measurements of dust, water and semiheavywater (HDO) at the onset of a global dust storm, obtained by the NOMAD and ACS instruments onboard the ExoMars Trace Gas Orbiter. We report the vertical distribution of the HDO/H2O ratio (D/H) from the planetary boundary layer up to an altitude of 80 kilometres. Our findings suggest that before the onset of the dust storm, HDO abundances were reduced to levels below detectability at altitudes above 40 kilometres. This decrease in HDO coincided with the presence of water-ice clouds. During the storm, an increase in the abundance of H2O and HDO was observed at altitudes between 40 and 80 kilometres. We propose that these increased abundances may be the result of warmer temperatures during the dust storm causing stronger atmospheric circulation and preventing ice cloud formation, which may confine water vapour to lower altitudes through gravitational fall and subsequent sublimation of ice crystals3. The observed changes in H2O and HDO abundance occurred within a few days during the development of the dust storm, suggesting a fast impact of dust storms on the Martian atmosphere.

A Migration Model for the Polar Spiral Troughs of Mars

AbstractMars' iconic polar spiral troughs are 400–1,000‐m‐deep depressions in the north polar layered deposits. As the north polar layered deposits accumulate, troughs migrate approximately poleward, anti‐parallel to the local wind patterns. Insolation is suspected to drive ice retreat through sublimation. Sublimation at the trough wall produces a growing sublimation lag that modulates further retreat; however, winds move material off the retreating slope faces, thinning the lag. Discontinuities in stratigraphy seen by radar highlight Trough Migration Paths (TMPs), which provide a record of the troughs' position, formation, and evolution to the present day. We investigate two adjacent troughs presently near 87°N to evaluate the mass balance conditions at those sites. We constrain the contribution of insolation‐induced sublimation to the migration in the observed TMPs. We present a phenomenological model that combines our simulations of the sublimation conditions at paleo‐trough surfaces with accumulation rates to create synthetic TMPs that are tunable to the observations. Models using nominal values of lag diffusivity, albedo, and atmospheric water vapor abundance and in which the trough walls have been covered in a lag on the order of millimeters thick and formed ~2.3 Myr ago match the observed trough migration and align with expectations of trough ages. Thicker lags, and/or older troughs, would generate TMPs of constant slope, which does not match the observed paths. We demonstrate the viability of our new theoretical model for predicting conditions that lead to trough migration, allowing us to connect observable TMPs to Martian climate processes.

Water delivery in the inner solar nebula

Context.Endogenous or exogenous, dry or wet, various scenarios have been depicted for the origin of water on the rocky bodies in our solar system. Hydrated silicates found in meteorites and in interplanetary dust particles, together with observations of abundant water reservoirs in the habitable zone of protoplanetary disks, are evidence that support aqueous alteration of silicate dust grains by water vapor condensation in a nebular setting.Aims.We investigate the thermodynamics (temperature and pressure dependencies) and kinetics (adsorption rates and energies, surface diffusion and cluster formation) of water adsorption on surfaces of forsterite grains, constraining the location in the solar nebula where aqueous alteration of silicates by water vapor adsorption can occur efficiently and leads to the formation of phyllosilicates. We analyze the astrophysical conditions favorable for such hydration mechanism and the implications for water on solid bodies.Methods.The protoplanetary disk model (ProDiMo) code is tuned to simulate the thermochemical disk structure of the early solar nebula at three evolutionary stages. Pressure, temperature, and water vapor abundance within 1 au of the protosun were extracted and used as input for a Monte Carlo code to model water associative adsorption using adsorption energies that resemble the forsterite [1 0 0] crystal lattice.Results.Hydration of forsterite surfaces by water vapor adsorption could have occurred within the nebula lifetime already at a density of 108cm−3, with increasing surface coverage for higher water vapor densities. Full surface coverage is attained for temperatures lower than 500 K, while for hotter grain surfaces water cluster formation plays a crucial role. Between 0.5 and 10 Earth oceans can arise from the agglomeration of hydrated 0.1μm grains into an Earth-sized planet. However, if grain growth occurs dry and water vapor processes the grains afterward, this value can decrease by two orders of magnitude.Conclusions.This work shows that water cluster formation enhances the water surface coverage and enables a stable water layer to form at high temperature and low water vapor density conditions. Finally, surface diffusion of physisorbed water molecules shortens the timescale for reaching steady state, enabling phyllosilicate formation within the solar nebula timescale.