Water Treatment Practices Research Articles

Geochemistry of urban waters and their evolution within the urban landscape

Urban populations and the sprawl of urban environments are increasing in the United States as well as globally. The local hydrologic cycle is directly impacted by urban development through greater generation of surface runoff and export of water through subterranean pipes networks to surface water bodies. These pipe networks carry waters that have potentially dramatic effects on the chemistry of groundwater and surface water bodies. In this work, we sampled waters from the Olentangy River and two subterranean outfalls that flow into the river in Columbus, Ohio United States. We measured the major ion, nutrient, and dissolved silica concentrations of each water source to identify how the urban landscape impacts the chemistry of a river that travels from an agricultural landscape to an urban environment. The outfalls had elevated concentrations of all major ions (Na+, K+, Mg2+, Ca2+, Cl−, SO42-) and H4SiO4. However, the Olentangy river typically had greater NO3− and soluble reactive phosphorus (SRP) concentrations. Sources of elevated ion export include road salts and combined storm runoff (Na+, Cl−), municipal water treatment practices (K+, Na+, SO42-), and concrete pipe weathering (Ca2+, Mg2+, K+, H4SiO4, SO42-). Utilizing stable isotopes of water, δ18O and δ2H, we identified that the water in the pipe networks is typically a mix of multiple precipitation events, but there is evidence of flushing following high-volume precipitation events. The contribution of high TDS waters from subterranean urban outfalls modified the ion abundance in the Olentangy river and produces a tendency towards freshwater salinization syndrome. This is particularly apparent when comparing the chemistry of the urban Olentangy to the agricultural corridor of the river and its other source waters. This research details the transformation of a river as it flows from an agricultural to urban landscape and provides data on the chemistry of source waters that facilitate the river’s chemical changes.

Assessment of Groundwater Quality Using Water Quality Indices in Illegal Mining Communities: A Case Study of the Atwima-kwanwoma District and Obuasi East Metropolis, Ghana

This study investigated groundwater quality in illegal mining zones within the Atwima-Kwanwoma District and Obuasi East Metropolis of the Ashanti Region, Ghana, employing both the Canadian Council of Ministers of the Environment Water Quality Index (CCME-WQI) and Nemerow's Pollution Index (NPI). The analysis revealed severe contamination across multiple parameters, including heavy metals, microbial indicators, and physicochemical parameters. The CCME-WQI values for the five towns consistently indicated "Poor" water quality, ranging from 26.8 to 31.1, reflecting significant deviations from acceptable water quality standards. Notably, Town A exhibited a cyanide concentration of 11.25 mg/L, while Town B recorded lead levels at 118.73 μg/L, both far exceeding permissible limits set by health authorities. The presence of Escherichia coli further exacerbates health risks, underscoring the urgent need for improved water treatment and management practices. This study demonstrates that the integrated use of NPI and CCME-WQI provides a comprehensive assessment of groundwater quality, revealing significant environmental and public health challenges. Immediate intervention, including regulatory enforcement, sustainable mining practices, and remediation strategies, is crucial to safeguard groundwater resources. The findings contribute uniquely to the understanding of water quality dynamics in mining-affected regions and advocate for a coordinated approach to mitigate environmental degradation.

Spray-Deposited TiO2 Layers on Aluminum Foil for Sustainable Water Remediation

In this study, we developed TiO2-coated aluminum (TiO2/Al) surfaces using eco-friendly methods to create efficient and environmentally friendly photoactive materials with the potential to enhance water purification systems. TiO2 particles were deposited onto aluminum foil surfaces via a spray method, followed by heat treatment at 200 °C for 15 min. The morphology of the TiO2/Al surfaces, both before and after photocatalytic treatment, was characterized using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The photocatalytic properties of these modified surfaces were evaluated through the degradation of rhodamine B (RB), methylene blue (MB), and methyl orange (MO) under simulated solar and UV–LED irradiation. Among the dyes tested, MO exhibited the highest degradation, influenced by factors such as absorption maximum, molecular structure, charge, and the number of condensed rings. The computational study of interactions between dye molecules and the combined nanoparticle revealed that the binding was the strongest in the case of MO dye. This study also explored the influence of varying the number of TiO2/Al surfaces in solution (one, five, and ten) on the photodegradation efficiency. The solution with five TiO2/Al surfaces demonstrated optimal performance, achieving a 16% degradation of RB. The reusability of the TiO2/Al surfaces was confirmed through five successive runs of RB degradation. The results indicate that TiO2/Al surfaces are a promising solution for addressing water contamination challenges and advancing sustainable water treatment practices.

Safe water treatment practices: A qualitative study on point-of-use chlorination in Nigeria

Safe water treatment practices: A qualitative study on point-of-use chlorination in Nigeria

Advancements in Biopolymer‐Derived Graft Copolymers: A Comprehensive Review on Their Application in Sustainable Wastewater Treatment

ABSTRACTRising concerns over water pollution and the depletion of non‐renewable resources have propelled the exploration of eco‐friendly and sustainable wastewater treatment alternatives. Biopolymer‐derived graft copolymers emerge as a promising solution, offering biodegradability, cost‐effectiveness, versatility, and enhanced functionality. This review provides a comprehensive overview of the latest developments in utilizing these copolymers as eco‐friendly flocculants for wastewater treatment. It covers synthesis methods for functionalized biopolymer‐based flocculants, diverse flocculation mechanisms, and their efficacy in solid–liquid separation. The article explores applications for removing pollutants, emphasizing biodegradability, cost‐effectiveness, and versatility. Special attention is given to the environmental impact, critically analyzing how these copolymers contribute to sustainable water treatment practices. The review also discusses potential future prospects and advancements in addressing global water pollution challenges using biopolymer‐derived graft copolymers.

Water Treatment Practices and Misperceived Social Norms among Women Living with Young Children in Rural Uganda.

Access to water safe for consumption is critical for health and well-being, yet substantial structural barriers often necessitate household action to make water safer. Social norms about water treatment practices are understudied as a driver of personal water treatment practice. This study assesses reported and perceived water treatment practices among women in a rural, water insecure setting. We used cross-sectional data from a population-based study of women living with children under 5 years old across eight villages in southwest Uganda. Participants reported their typical household water treatment practices and what they perceived to be the common practices among most other women with young children in their own village. Modified multivariable Poisson regression models estimated the association between individual behavior and perceptions. Of 274 participants (78% response rate), 221 (81%) reported boiling water and 228 (83%) reported taking at least one action to make water safer. However, 135 (49%) misperceived most women with young children in their village not to boil their water, and 119 (43%) misperceived most to take no action. Participants who misperceived these norms were less likely to practice safe water treatment (e.g., for boiling water, adjusted relative risk = 0.80; 95% CI 0.69-0.92, P = 0.002), adjusting for other factors. Future research should assess whether making actual descriptive norms about local water treatment practices visible and salient (e.g., with messages such as "most women in this village boil their drinking water") corrects misperceived norms and increases safe water treatment practices by some and supports consistent safe practices by others.

Resourceful exploitation of sedimentary clay: Designing a dual-chambered borosilicate glass reactor system for the efficient treatment of malachite green and phenol through SCRT adsorption and 5%Fe@SRCT catalysis via CWPO, with evaluation of seed germination and fish survival.

This study presents an innovative double-walled borosilicate glass reactor system for the efficient treatment of liquid and gaseous wastewater. This reactor system allows precise temperature control, continuous pH monitoring, and controlled dosing of reagents to optimize reaction conditions. Detailed characterization was carried out by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), BET (specific surface area) analysis, point of zero charge (PZC), and scanning electron microscopy (SEM) for the SCR, SCRT, and 5%Fe@SCRT materials. For Malachite Green adsorption, SRCT demonstrated a maximum adsorption capacity of 39.78 ±0.5mg/g using the Langmuir isotherm model and followed pseudo-second-order kinetics. Optimum conditions for adsorption were found to be: an initial concentration of 50 ppm, an adsorbent dosage of 1g/l, a pH of 8.5, and a temperature of 50°C. For the catalytic oxidation of phenol, 5%Fe@SRCT achieved a remarkable removal rate of 99.9±0.1% under optimum conditions (50 ppm phenol, 1g/l catalyst dosage, pH3.5, H2O2 concentration 8.7mM, and temperature 70°C). Intermediates identified during the reaction included hydroquinone, benzoquinone, catechol, and resorcinol, with degradation occurring over a 60-minute reaction period. The 5%Fe@SCRT material showed excellent reusability in the removal of phenol by catalytic oxidation, with no significant loss of efficiency over three cycles, while the SRCT underwent three cycles of regeneration for the adsorption of Malachite Green. Scavenger tests confirmed the involvement of hydroxyl radicals in the catalytic oxidation process. In addition, fish survival tests after catalytic oxidation of phenol by 5%Fe@SRCT showed no impact on fish, underlining the environmental safety of this process. In addition, germination tests after decolorization of MG by SRCT demonstrated a good effect with no negative impact, reinforcing the ecological value of this innovative technology. These results highlight the innovative use of SCRT and 5%Fe@SCRT as versatile materials for environmental remediation, exploiting their effective adsorption capacities and efficient catalytic oxidation performance within the proposed double-walled borosilicate glass reactor system. PRACTITIONER POINTS: The study demonstrates the effectiveness of an innovative reactor system employing SRCT adsorbent and Fe@SRCT catalyst for efficient removal of malachite green and phenol from wastewater. Environmental impact assessment, including seed germination and fish survival evaluation, validates the method's eco-friendly potential. Implementation of this approach could significantly contribute to sustainable water treatment practices.

Exploring the influence of aquatic phosphate on Fe floc dynamics in water treatment

The formation of flocs is crucial in the coagulation process of water treatment. However, the nature of ligand exchange on the surface of primary nanoparticles (PNPs) during floc formation requires further investigation to enhance our understanding of the coagulation mechanism. Phosphate (P) is a ubiquitous nutrient ion in aquatic surface water, in this study, the impact of P on floc growth under different pH conditions were investigated. The results revealed that floc growth patterns depended on both P dosage and pH. The mode of ligand exchange between P and in-situ formed ferric hydroxide within a pH range of 5 to 10 was further explored, and remarkable disparities in pH changes induced by P addition were observed. At lower pH levels, OH− release occurred relatively slowly, stabilizing with continued P addition. At neutral pH, OH− release was comparatively higher with P addition, while under alkaline conditions, both the quantity of OH− and its release rate decreased. It was deduced that Fe–OH21/2+ sites function as "active sites," while Fe–OH1/2− sites act as "inert sites" on the surface of PNPs formed during flocculation. These sites are crucial in the interconnections between flocs formed during coagulation and in floc growth. Analyses of Fe PNPs by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM), with and without P addition, revealed that the introduction of P inhibits or interferes with the self-crystallization of Fe PNPs through chemical coordination reactions. The results offer deeper insights into the coagulation mechanism and the transformation of Fe flocs in raw waters containing P during water treatment practices.

Geospatial insights into groundwater contamination from urban and industrial effluents in Faisalabad

Groundwater remains the most dependable resource for various essential uses such as drinking, cleansing, agricultural irrigation, and industrial applications. In urban areas, the dependency on groundwater to meet water demands is significant. However, this resource faces threats from overuse and poor management, leading to a degradation in quality primarily due to the unchecked release of industrial and household wastes. The escalation of industrial activities and rapid urban growth have amplified the volume of wastewater, adversely affecting the purity of freshwater sources within aquifers. This investigation focuses on evaluating the impact of industrial and urban effluents on groundwater quality in the city of Faisalabad. The main contributors to groundwater pollution include the indiscriminate disposal of industrial and urban effluents through unlined drains and the extensive application of chemical agents in agriculture, such as fertilizers, and pesticides. To understand the physiochemical properties of both, drain and groundwater, samples were collected at various distances 50 m, 100 m, and 150 m from drain outlets. This study utilized Geographic Information Systems (GIS) to accurately map and analyze the distribution and impact of contaminants. Parameters such as pH, electrical conductivity (EC), total dissolved solids (TDS), total hardness, bicarbonates, calcium and magnesium hardness, and chloride levels were examined. The findings indicated that contaminant levels were highest in drain water and increased in concentration the closer they were to the drainage sources, with the exception of pH levels. All samples exceeded the World Health Organization's (WHO) safe limits, deeming them unfit for use. This finding indicates widespread contamination, posing significant public health risks and highlighting the urgent need for improved waste management and water treatment practices in Faisalabad. It underscores the critical importance of implementing effective pollution control measures to safeguard public health and ensure water security in the region. However, a notable correlation was observed between the concentration of pollutants in drain water and key indicators such as EC, TDS, total hardness, and magnesium hardness, highlighting their role in deteriorating aquifer water quality. Moreover, groundwater samples collected 50 m from drains exhibited the highest pollutant concentrations compared to those taken further away, at 100 m and 150 m distances.

Synthesis and Application of Eco-Friendly Adsorbent for Treatment of Congo Red and KMnO4 Dye Aqueous Solution

The use of natural resources as environmentally acceptable adsorbents for wastewater treatment was investigated in two research. The first concentrated on using bamboo leaves as an inexpensive adsorbent to remove the dye KMnO4. Bamboo leaves were carefully synthesised, spectrophotometrically analysed, and showed different adsorption capabilities according to unit adsorbent concentration. The second study used a systematic synthesis procedure and spectrophotometric characterization to remove Congo red dye from mango leaves. The Mangifera indica adsorbent demonstrated a noteworthy 88.27% adsorption peak at a dye concentration of 50 mg/L. Both programmes emphasised the potential of renewable resources and focused on low-cost, environmentally friendly methods to address the problem of water contamination. The research emphasised the adaptability and effectiveness of natural adsorbents, underscoring the significance of sustainable approaches in the treatment of wastewater. These findings contribute significantly to developing green solutions, showcasing the feasibility of utilizing bamboo and mango leaves in addressing diverse dye contaminants. Further optimization and mechanistic understanding are crucial for enhancing the efficiency of these eco-friendly adsorbents, paving the way for environmentally conscious water treatment practices.

Association Between Demographic Characteristics of Users’ and Overall Satisfaction with Water Supply Service

Water constitutes an indispensable resource for various aspects of daily life, encompassing essential needs such as drinking, cooking, sanitation, and irrigation. Beyond household applications, diverse livelihood activities, including livestock management, gardening, crop cultivation, food processing, aquaculture, and fisheries, also rely on water. The assessment of customer satisfaction holds paramount significance in driving performance enhancements for service providers, even within government-owned entities offering critical services like water supply. This research aims to scrutinize the interplay between overall satisfaction with water services and its determinants, including satisfaction with water quality, and various parameters such as water supply hours, tap pressure, supplied water quantity, management responsiveness and communication, and water tariff. Anticipatedly, water supply hours, quantity, and quality are expected to exert a crucial influence on user satisfaction. Although users express a satisfaction level above neutral, it falls short of reaching a fully satisfactory level. Key contributors to user satisfaction involve aspects such as water supply hours, pressure, quantity, and quality, while complaints about water supply yield slightly lower satisfaction. Satisfaction with water service hours, quantity, and quality emerges as a driving force for overall satisfaction. The analysis reveals no significant association between overall satisfaction and demographic variables such as occupation, gender, age, education, and the main income source. However, a noteworthy association exists between satisfaction with water pressure and the water collection method, and a robust link is observed between satisfaction with water quality and respondents' water treatment practices. The provision for complaints is significantly associated with satisfaction regarding management responsiveness and communication. Multiple regression analysis underscores a positive relationship between overall satisfaction with water services and satisfaction with water quality and supply hours, indicating that higher satisfaction with these factors enhances overall satisfaction with water services.

Microplastic Human Dietary Uptake from 1990 to 2018 Grew across 109 Major Developing and Industrialized Countries but Can Be Halved by Plastic Debris Removal.

Microplastics (MPs), plastic particles smaller than 5 mm, are now a growing environmental and public health issue, as they are detected pervasively in freshwater and marine environments, ingested by organisms, and then enter the human body. Industrial development drives this environmental burden caused by MP formation and human uptake by elevating plastic pollution levels and shaping the domestic dietary structure. We map the MP human uptake across 109 global countries on five continents from 1990 to 2018, focusing on the world's major coastlines that are affected by plastic pollution that affects the United Nations' Sustainable Development Goals (SDGs): SDG 6 (Clean Water and Sanitation), SDG 14 (Life Below Water), and SDG 15 (Life on Land). Amid rapid industrial growth, Indonesia tops the global per capita MP dietary intake at 15 g monthly. In Asian, African, and American countries, including China and the United States, airborne and dietary MP uptake increased over 6-fold from 1990 to 2018. Eradicating 90% of global aquatic plastic debris can help decrease MP uptake by more than 48% in Southeast Asian countries that peak MP uptake. To reduce MP uptake and potential public health risks, governments in developing and industrialized countries in Asia, Europe, Africa, and North and South America should incentivize the removal of free plastic debris from freshwater and saltwater environments through advanced water treatment and effective solid waste management practices.

Simulation and Modeling of Water Treatment Plant with GPS-X Software for Health and Water Quality

Background: Waterborne diseases are infectious in nature, significantly impacting global health related to water quality and disease prevalence globally. In this study, GPS-X was used to design and simulate water treatment plants to determine the effectiveness of different mechanisms in water treatment. Method: The GPS-X water treatment software was utilized to evaluate raw and treated water performance at the Al-Kadhmaya Water Treatment Plant. Three scenarios were designed to assess the impact of varying flow rates and water parameters such as pH, alkalinity, turbidity, total dissolved solids (TDS), and total suspended solids (TSS) on the plant's performance. Results: The evaluation of the operational performance of the water treatment plant revealed that the concentrations of all contaminants in the effluent water consistently met the established Iraqi and WHO standards across all scenarios. This indicated the effectiveness of the plant's treatment processes in producing safe drinking water. The findings of this study held significance for water authorities, decision-makers in Iraq, and national and international environmental agencies, providing valuable information for improving water treatment practices and ensuring compliance with water quality standards. Conclusion: The study demonstrated the effectiveness of the GPS-X water treatment software in assessing the performance of the Al-Kadhmaya Water Treatment Plant. The results highlighted the plant's ability to consistently meet water quality standards, underscoring the importance of robust water treatment processes. These findings contributed to the body of knowledge regarding water treatment plant design and operation, offering insights that can inform decision-making processes to enhance water quality and ensure public health.

Turbidity Removal Performance of Selected Natural Coagulants for Water Treatment in Colombian Rural Areas

Despite the recognized efficiency of natural coagulants, their widespread adoption in the water treatment industry remains low. Our study evaluates the effectiveness of three natural coagulants—Moringa Oleifera, Yausa (Abutilon Insigne Planch), and Breadfruit (Artocarpus Altilis)—in reducing water turbidity levels of 40–50 NTU. Among these, two are native plant species potentially applicable in rural Colombian areas, where there are evident disparities in water infrastructure. This research contributes to the development of these coagulants, exploring their integration with existing water treatment methods, determining their optimal concentrations, and efficiencies in turbidity removal. Our findings reveal significant turbidity removal efficiencies: 88.9% for Moringa Oleifera, 83.3% for Yausa, and 67.2% for Breadfruit. These results indicate the feasibility of these agents as sustainable replacements for traditional chemical coagulants, exhibiting a level of effectiveness alike to that observed in Moringa Oleifera. However, challenges in practical implementation and sustainability, covering technical, environmental, economic, and social aspects, are notable obstacles. The aim of this study is to not only demonstrate the effectiveness of these natural coagulants but also to encourage their broader acceptance and integration into sustainable water treatment practices incorporating two unstudied plant species, such as Yausa and Breadfruit, furthering research to overcome existing challenges. Doi: 10.28991/CEJ-2024-010-02-020 Full Text: PDF

Review of nanotechnology in water treatment: Adoption in the USA and Prospects for Africa

This research paper explores the adoption of nanotechnology in water treatment, focusing on the advanced perspective of the United States and the potential prospects across diverse landscapes in Africa. Investigating current trends, challenges, and ethical considerations, the USA is a model for cutting-edge research, robust regulatory frameworks, and innovative applications of nanotechnology. Meanwhile, Africa, grappling with water scarcity, presents an opportunity for leapfrogging with context-specific strategies and international collaboration. Environmental and ethical considerations are paramount, emphasizing the need for responsible practices, equitable distribution of benefits, and global justice. Future trends anticipate innovative nanomaterials, decentralized solutions, and green nanotechnology shaping water treatment practices. The conclusion underscores this journey's dynamic and collaborative nature, advocating for interdisciplinary efforts, international collaboration, and ethical governance to realize a sustainable future with nanotechnology as a critical catalyst for water security.

A retrospective study on cholera understanding and WASH (water, sanitation, and hygiene) behavior among adolescents in three regions of La Gonâve, Haiti

BackgroundsThis study assesses the impact of Water, Sanitation, and Hygiene (WASH) interventions on cholera understanding and hygiene practices in La Gonâve Island, Haiti. It examines the changes after implementing interventions in seven villages across the Downtown, Mountain, and Seaside regions. MethodsA retrospective investigation surveyed 210 school students from each region using a validated questionnaire. It assessed knowledge, attitudes, practices (KAP), and environmental aspects related to cholera and hygiene. Data analysis involved descriptive statistics and chi-square tests. ResultsThe study highlights significant disparities in education levels, toilet ownership, and healthcare access. Challenges in finding public toilets (86.67%) and accessing water sources (67.78%) are consistent across regions, with Seaside facing financial constraints (85.00%) and water cost concerns (91.67%). Attitudes toward hygiene vary, with the Mountain region having the highest ‘Never’ responses for handwashing (38.89%), and Downtown leading in water treatment practices (11.67%). There is a strong willingness to share health knowledge, particularly in Downtown (100.00%). Seaside (83.33%) and Downtown (73.33%) revealed a higher cholera awareness, while nearly half of Mountain students lacked knowledge (54.44%). ConclusionsThis study highlights significant disparities in WASH practices among La Gonâve's adolescents in Downtown, Mountain, and Seaside regions. Urgent interventions are crucial for improving sanitation, ensuring clean water access, and implementing targeted hygiene education, especially in the resource-constrained Mountain and Seaside areas. The findings underscore the vital roles of adolescents and schools in disseminating knowledge, with further research needed to explore intervention differences.

Household Water Treatment Practice and Associated Factors in Sub-Saharan Africa: A Systematic Review and Meta-Analysis.

Household water treatment practices, also known as point-of-use water management, offer means to enhance the overall drinking water quality and reduce the prevalence of diarrheal diseases. Nevertheless, there is a scarcity of information on household water treatment practices and related factors in sub-Saharan Africa. This study aimed to determine the pooled prevalence of water treatment practices and associated factors in sub-Saharan Africa. We conducted a search of eligible primary studies in PubMed, Google Scholar, and Hinari, as well as gray literature available in online repositories. The Stata v.17 software was utilized to extract and analyze the data obtained from these studies. To determine the overall pooled prevalence of water treatment practices and their predictors, a weighted inverse-variance random-effects model was employed. We assessed variations across the included studies using forest plots, funnel plots, I 2 statistics, and Egger's tests. In this study, we reviewed a total of 927 articles, 28 of which were eligible for inclusion. The overall pooled prevalence of water treatment practices in sub-Saharan Africa was 36.31(95% CI: 27.64, 44.98). The factors associated with water treatment practices included having formal education (AOR: 2.38, 95% CI: 1.70, 3.34), being male (AOR: 1.78, 95% CI: 1.39, 2.29), having a higher income (AOR: 2.12, 95% CI: 1.39, 3.25), and having received training in water treatment (AOR: 2.25, 95% CI: 1.59, 3.18). In this review, the pooled prevalence of water treatment practices in sub-Saharan Africa was found to be considerably low. Therefore, we recommend that household heads receive enhanced information on water treatment practices through strengthened health education and intensive training in small-scale water treatment practices.

Identifying predictors of E. coli in rural household water in sub-Saharan Africa using elimination regression.

Exposure to fecally contaminated drinking water contributes to the global disease burden, especially in sub-Saharan Africa (SSA). We used cross-sectional data and elimination regression analysis to examine factors influencing E. coli contamination in household drinking water samples from 4,499 rural households in nine countries in SSA (Malawi, Mozambique, and Zambia in Southern Africa; Ghana, Mali, and Niger in Western Africa; and Kenya, Rwanda, and Tanzania in Eastern Africa). The proportion of household water samples containing E. coli was 71%, ranging from 45% (Malawi) to 89% (Tanzania). Pooled and multi-country predictive logistic regression models showed that using an unimproved-type water source, the absence of a community water committee, and domestic animal ownership were significantly associated with household drinking water contamination. Household water treatment and storage practices, sanitation and hygiene practices, and payment for drinking water were not significantly associated with E. coli contamination in any model. The season was a significant predictor of E. coli in the pooled model; samples collected in the rainy season were 2.3 [2.0, 2.7] times as likely to be contaminated with E. coli. Practitioners and policymakers should prioritize implementing piped on-plot water services, establishing effective local water source management structures, and incorporating animal husbandry practices into water, sanitation, and hygiene interventions.

Biosorption as Technique for Remediation of Heavy Metals from Wastewater using Microbial Biosorbent

Biosorption, a sustainable technology, utilizes living or non-living organism and their derivative as sorbents for the removal of heavy metals from wastewater. This review explores the mechanisms and applications of biosorption in addressing environmental challenges posed by heavy metal contaminants. Pretreatment methods enhance biosorbent performance by modifying cell wall structures through physical and chemical alterations, increasing metal binding capacity. Immobilization techniques like cell entrapment and cross-linking improve biosorbent stability and reusability in continuous systems, offering controlled particle size and ease of biomass separation. Differential Scanning Calorimetry assesses biosorbent thermal stability, providing insights into performance under varying conditions. Non-living microorganisms present advantages for biosorption, including resilience to toxic wastes and extended storage capabilities. Economic considerations are crucial when evaluating biosorbent modifications for enhanced performance. The review show that biosorption using microbial biosorbents is a versatile and efficient method for heavy metal removal from wastewater, with applications in environmental remediation and sustainable water treatment practices. Future research should focus on novel biosorption strategies and optimization of existing techniques to effectively combat heavy metal pollution.

Effect of copper doping on the photocatalytic performance of Ni2O3@PC membrane composites in norfloxacin degradation.

In this study, copper (Cu) and nickel oxide (Ni2O3) microtubes (MTs) were synthesized using an electroless template deposition technique within porous polycarbonate (PC) track-etched membranes (TeMs) to obtain Cu@PC and Ni2O3@PC composite membranes, respectively. The pristine PC TeMs featured nanochannels with a pore density of 4 × 107 pores per cm2 and an average pore diameter of 400 ± 13 nm. The synthesis of a mixed composite, combining Cu and Ni2O3 within the PC matrix, was achieved through a two-step deposition process using a Ni2O3@PC template. An analysis of the resultant composite structure (Cu/Ni2O3@PC) confirmed the existence of CuNi (97.3%) and CuO (2.7%) crystalline phases. The synthesized catalysts were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) analysis, and atomic force microscopy (AFM). In photodegradation assessments, the Cu/Ni2O3@PC mixed composite demonstrated higher photocatalytic activity, achieving a substantial 59% degradation of norfloxacin (NOR) under UV light irradiation. This performance surpassed that of both Ni2O3@PC and Cu@PC composites. The optimal pH for maximum NOR removal from the aqueous solution was determined to be pH 5, with a reaction time of 180 min. The degradation of NOR in the presence of these composites adhered to the Langmuir-Hinshelwood mechanism and a pseudo-first order kinetic model. The reusability of the catalysts was also investigated for 10 consecutive runs, without any activation or regeneration treatments. The Cu@PC membrane catalyst demonstrated a marked decline in degradation efficiency after the 2nd test cycle, ultimately catalyzing only 10% of NOR after the 10th cycle. In contrast, the Ni2O3@PC based catalyst demonstrated a more stable NOR degradation efficiency throughout all 10 runs, with 27% NOR removal observed during the final test. Remarkably, the catalytic performance of the Cu/Ni2O3@PC mixed composite remained highly active even after being recycled 4 times. The degradation efficiency exhibited a gradual reduction, with a 17% decrease after the 6th run and a cumulative 35% removal of NOR achieved by the 10th cycle. Overall, the findings indicate that Cu/Ni2O3@PC mixed composite membranes may represent an advancement in the quest to mitigate the adverse effects of antibiotic pollution in aquatic environments and hold significant promise for sustainable water treatment practices.