Water-saturated Conditions Research Articles

1H NMR spectroscopy of degraded perfluorosulfonic acid membranes: A simple methodology for detecting onset of degradation

Perfluorosulfonic acid (PFSA) polymer electrolyte membranes (PEMs) used in fuel cells undergo chemical degradation when exposed to radicals formed during electrochemical reactions. One of the products or intermediates formed during the degradation was reported to be proton-exchangeable groups such as CF2OH and COOH. However, the 1H magic angle spinning nuclear magnetic resonance (MAS NMR) spectra of Nafion PEMs degraded chemically through the Fenton reaction revealed that CF2H was generated. Furthermore, the accompanying depletion of SO3H in the Nafion PEMs reduced the water contents of Nafion PEMs even under water saturation conditions. Our results are consistent with recent thermal degradation results of CF2H generation via SO3H substitution with H. While very simple, the 1H MAS NMR spectroscopic analysis was demonstrated to be a powerful technique for determining degradation of PFSA membrane such as Naion and Aquivion when other techniques, such as 19F MAS NMR spectroscopy, failed to show any degradation evidence. Hence, this method is potentially useful for investigating various PFSA PEMs for initial degradation evidence before analyzing their in-depth degradation mechanisms.

Finite element method-based resistivity simulation and water saturation calculation of irregular laminated shaly sandstone

Shaly sandstone reservoir is one of the most significant targets in petroleum and gas exploration. However, the influences of various factors on the resistivity of irregular laminated shaly sandstone are yet to be determined, and it is extremely challenging to accurately calculate the water saturation. By considering shaly sandstone in Zhujiang Formation of Neogene in Pearl River Mouth Basin as an example, this research extracts the shale distribution form and the pore structure by image processing, simulates the resistivity of rock by finite element method, analyzes the influence of shale parameters on resistivity, and deduces the water saturation equation of shaly sandstone. Results show that, in shaly sandstone, shale distributes in irregular laminated patterns on a millimeter scale. The other clean sandstone areas have high porosity and the capacity to reserve oil and gas. At high water saturation states, the shaly sandstone mainly conducts electricity in the clean sandstone area and various shale parameters have minor influences on the resistivity of shaly sandstone. At low water saturation states, the shaly sandstone mainly conducts electricity in the shale area, the resistivity of shaly sandstone is very close to the resistivity of the water layer, and the reservoir is the so-called low resistivity reservoir. The conductive form of clean sandstone area and shale laminae tends to parallel but remains a noticeable difference from total parallel. The simulation results deduced that the water saturation equation of shaly sandstone is more accurate than other equations, which provides an innovative mindset to calculate the water saturation of shaly sandstone.

Assessing the Effects of Different Fillers and Moisture on Asphalt Mixtures’ Mechanical Properties and Performance

This laboratory study was conducted to comparatively assess the effects of different fillers and moisture on the mechanical properties and performance of asphalt mixtures. In the study, a typical Pen70 base asphalt was modified with four different filler materials, namely limestone powder, cement, slaked (hydrated) lime, and brake pad powder, to produce different asphalt mortars that were subsequently used to prepare the asphalt mixtures. Thereafter, various laboratory tests, namely dynamic uniaxial repeated compressive loading, freeze-thaw splitting, and semicircular bending (SCB) were conducted to evaluate the moisture sensitivity, high-temperature stability, low-temperature cracking, and fatigue performance of the asphalt mixtures before and after being subjected to water saturation conditions. Overall, the study results indicated superior moisture tolerance, water damage resistance, and performance for slaked (hydrated) lime, consecutively followed by brake pad powder, cement, and limestone powder. That is, for the materials evaluated and the laboratory test conditions considered, limestone mineral powder was found to be the most moisture-sensitive filler material, whilst slaked (hydrated) lime was the most moisture-tolerant and water-damage resistant filler material.

Distribution of Cu in agricultural soils with different land uses through stable isotope analysis

Conversion of paddy soil to abandoned land involves the change of the copper biogeochemical cycle. Both the excessive accumulation and deficit of this element can threaten soil sustainable development or food security. Copper (Cu) is one of the essential micronutrients for plants, yet little is known about how the conversion of paddy soil to abandoned land affects Cu isotope signature. This study investigated Cu isotope signatures in paddy land (PL) and abandoned paddy lands for 1, 3, and 5 years (NPL1, NPL3, NPL5) in the Mun River basin of a tropical zone. The results show higher [Cu] and positive δ65Cu values in profile PL, with a significant correlation between δ65Cu and the chemical index of alteration (CIA) value. The low [Cu] and positive δ65Cu values are in profile NPL1, while low [Cu] and negative δ65Cu values are in profiles NPL3 and NPL5. Owing to artificial and seasonal water saturation conditions in paddy soils (PL), the variation of δ65Cu values within the profile was controlled by the decomposition and rice uptake in the upper layer, and the transformation of Cu-bearing minerals with the long-term flooding (lower layer). After cropland abandonment, the distinct Cu isotope signatures among soil profiles might be due to the transformation of soil minerals. At the topmost of abandoned soils, rice harvest and the abandonment of paddy soil might result in 63Cu-deplete at the early abandonment times (1 ∼ 2 years), but the abandoned soil was restored with increased abandonment years and preferentially result in 65Cu-deplete. Our findings provide a comprehensive insight into Cu isotope signature in response to the conversion of land-use types, which will contribute to understanding the soil Cu geochemical cycle in terrestrial ecosystems.

Influence of Fiber Mixing Process on the Cracking Resistance of Cold Recycled Asphalt Mixture

Fiber reinforcement is often used to improve the road performance of cold recycled asphalt mixture (CRAM). The purpose of this research is to evaluate the impact of fiber mixing process on the cracking resistance of CRAM from multiple perspectives. Four kinds of fiber mixing processes, named A, B, C, and D, were designed by changing the order of fiber addition during the mixing process. Then, semicircle bending tests and indirect tensile tests were conducted to characterize the low-temperature cracking behavior of fiber CRAM. Freeze–thaw cycle tests under both dry and water-saturated conditions were performed to investigate the freeze–thaw damage behavior of fiber CRAM. Furthermore, the fiber dispersion in CRAM was observed using scanning electron microscopy (SEM). The results show that the fiber mixing process has a significant effect on the cracking resistance of CRAM. The CRAM specimens prepared by process C have the largest fracture energy, splitting strength, and fracture work, while the specimens made by process D have the smallest value. Specially, the fracture energy of the specimens prepared by process C is 77.23% larger than that of the specimens prepared by process A, while the fracture energy of the specimens prepared by process D is 5.6% smaller than that of the specimens prepared by process A. The reason for this phenomenon is that the fiber is well dispersed in the specimens prepared by process C, which contributes to obtain a better crack resistance. For all CRAM specimens, with the increase of freeze–thaw cycles, splitting strength and fracture work of fiber CRAM decrease. However, there is an obvious difference in the reduction rate of splitting strength and fracture work, especially for the specimens under the water saturation condition. The specimens made by process C have the smallest reduction rate, which indicates a better resistance to freezing and thawing damage. According to the analysis of fiber macro-distribution state in loose CRAM, the fiber dispersion is affected by the humidity conditions in the mixing environment. The best humidity conditions are obtained for fiber dispersion in process C. Based on the SEM observation, the overlapping bridging network structure can be observed in the microstructure of the specimens prepared by process C, allowing the mixture to better transfer and disperse stress.

Physical and Thermal Properties of Coarse-Fragment Soil in the Moraine-Talus Zone of the Qilian Mountains

Moraine-talus zone (hereafter referred to as MTZ) refers to the non-glacial area (including glacier mass supply area) above the upper boundary of alpine meadow in high mountains, where vegetation is sparsely distributed and coarse fragment (diameter > 2 mm) is widespread. The MTZ acts as the headwater region for many large river basins, and the freeze–thaw process of its coarse-fragment soil largely affects regional hydrological processes, carbon exchange, and ecosystem diversity. However, our knowledge of the physical and thermal properties of coarse-fragment soil in MTZs remains limited. Mainly distributed in the surroundings of Hala Lake, the area ratio of the MTZ in the Qilian Mountains is about 21%. On the basis of 170 samples collected from 22 soil profiles at a depth of 80 cm, coarse fragments dominated the compositions of soil textures in the MTZ, with relatively high volume proportion (about 63.3%) and mass proportion (about 75.0%). The mean volume and mass ratio of the coarse fragments tended to increase gradually from the surface to the deep soils and varied largely at different particle size ranges (i.e., 2–5, 5–10, 10–20, 20–40, 40–60, and >60 mm). Thermal conductivity measurements for the 24 samples collected from three soil profiles in dry (Kdry) and water-saturated (Ksat) conditions indicated that Kdry increased rapidly with temperatures from −20 °C to 25 °C (with a 5 °C interval), which appeared to be closely related with soil porosity. Ksat did not obviously change with temperature at the two designated temperature ranges (i.e., from −20 °C to −5 °C and from 5 °C to 25 °C), but fluctuated largely at 0 °C, possibly due to the drastic phase change. More detailed experimental designs combined with more influential elements should be considered in future research to fully understand the thermal properties of coarse-fragment soil in the MTZ.

Determination of Strength Characteristics of Rocks in Air-Dry and Water-Saturated State

Determination of Strength Characteristics of Rocks in Air-Dry and Water-Saturated State

A Two‐Martian Years Survey of the Water Vapor Saturation State on Mars Based on ACS NIR/TGO Occultations

AbstractOn Mars, condensation is the major factor constraining the vertical distribution of water vapor. Recent measurements of water and temperature profiles showed that water can be strongly supersaturated at and above the level where clouds form during the aphelion and perihelion seasons. Since 2018, the near‐infrared spectrometer (NIR) of the Atmospheric Chemistry Suite onboard the Trace Gas Orbiter has measured H2O and temperature profiles using solar occultation in the infrared from below 10 to 100 km of altitude. Here, we provide the first long‐term monitoring of the water saturation state. The survey spans 2 Martian years from Ls = 163° of MY34 to Ls = 170° of MY36. We found that water is often supersaturated above aerosol layers. In the aphelion season, the water mixing ratio above 40 km in the mid‐to‐high latitudes was below 3 ppmv and yet is found to be supersaturated. Around the perihelion, water is also supersaturated above 60 km with a mixing ratio of 30–50 ppmv. Stronger saturation is observed during the dusty season in MY35 compared to what was observed in MY34 during the Global Dust Storm and around the perihelion. Saturation varied between the evening and morning terminators in response to temperature modulation imparted by thermal tides. Although water vapor is more abundant in the evening, colder morning temperatures induce a daily peak of saturation. This data set establishes a new paradigm for water vapor on Mars, revealing that supersaturation is nearly ubiquitous, particularly during the dust season, thereby promoting water escape on an annual average.

Impact of salt deposition induced by water evaporation on petrophysical properties and pore structure in underground gas storage through dynamic and static experiments

During the production process of underground gas storage (UGS) with high-salinity formation water, salt deposition has been observed due to formation water evaporation. This work aims at understanding the effect of salt deposition on petrophysical properties and pore structure. Firstly, dynamic and static experiments are carried out to simulate the multi-cycle gas injection and production of the UGS based on the core plugs, rock debris and water from Wen23 gas field. Secondly, Nuclear magnetic resonance (NMR), scan electron microscope (SEM) and energy dispersive spectrum (EDS) are applied to investigate the change of pore structure and salt-crystal morphology. Results indicate that the core permeability and porosity after water evaporation are averagely increased by 39 % to 68 % and 42 % to 66 % respectively compared with the initial water saturation conditions under different water salinity. Salt crystals in the reservoir are mainly deposited in large pores. The dispersed and aggregated salt crystals are observed and most salt crystals are between 1 μm and 5 μm in size. Thus, formation water evaporation is beneficial to the improvement of reservoir petrophysical properties without formation water supplement. This work provides an effective method to understand the impact of salt deposition caused by formation water evaporation on the petrophysical properties, fluid flow ability, and gas storage capacity of the UGS and CO2 geological storage.

Effect of grain dissolution on sloping ground

The static and dynamic stability of natural or constructed slopes can be affected by dissolution or dissolution-like phenomena. Their underlying mechanisms, however, remain unclear. New experimental results and discrete element simulations provide particle-level and macroscale information on the consequences of mineral dissolution on slope behavior. At the microscale, load-carrying grain arches develop around dissolving particles, the porosity increases, and contact force chains evolve to form a honeycomb topology. At the macroscale, while vertical settlements are the prevailing deformation pattern, lateral granular movements that create mass wasting are prominent in sloping ground, even under the quasi-static granular loss. Horizontal grain displacement is maximum at the surface and decreases linearly with the distance from the slope surface to become zero at the bottom boundaries, much like vertical granular displacement along the depth. Sediments with smaller friction angles and steeper slopes experience greater displacement, both vertically and horizontally. Slopes become flatter after dissolution, with the reduction in slope angle directly related to the loss in ground elevation, ΔH/Ho. Yet, because of the porous fabric that results from dissolution, vertical shortening is less than the upper bound, estimated from the loss in the solid mass fraction, ΔH/Ho≈SF. Under water-saturated conditions, the post-dissolution fabric may lead to sudden undrained shear and slope slide.

Logan Medallist 7. Appinite Complexes, Granitoid Batholiths and Crustal Growth: A Conceptual Model

Appinite bodies are a suite of plutonic rocks, ranging from ultramafic to felsic in composition, that are characterized by idiomorphic hornblende as the dominant mafic mineral in all lithologies and by spectacularly diverse textures, including planar and linear magmatic fabrics, mafic pegmatites and widespread evidence of mingling between coeval mafic and felsic compositions. These features suggest crystallization from anomalously water-rich magma which, according to limited isotopic studies, has both mantle and meteoric components. Appinite bodies typically occur as small (~2 km diameter) complexes emplaced along the periphery of granitoid plutons and commonly adjacent to major deep crustal faults, which they preferentially exploit during their ascent. Several studies emphasize the relationship between intrusion of appinite, granitoid plutonism and termination of subduction. However, recent geochronological data suggest a more long-lived genetic relationship between appinite and granitoid magma generation and subduction.Appinite may represent aliquots of hydrous basaltic magma derived from variably fractionated mafic underplates that were originally emplaced during protracted subduction adjacent to the Moho, triggering generation of voluminous granitoid magma by partial melting in the overlying MASH zone. Hydrous mafic magma from this underplate may have ascended, accumulated, and differentiated at mid-to-upper crustal levels (ca. 3–6 kbar, 15 km depth) and crystallized under water-saturated conditions. The granitoid magma was emplaced in pulses when transient stresses activated favourably oriented structures which became conduits for magma transport. The ascent of late mafic magma, however, is impeded by the rheological barriers created by the structurally overlying granitoid magma bodies. Magma that forms appinite complexes evaded those rheological barriers because it preferentially exploited the deep crustal faults that bounded the plutonic system. In this scenario, appinite complexes may be a direct connection to the mafic underplate and so its most mafic components may provide insights into processes that generate granitoid batholiths and, more generally, into crustal growth in arc systems.

Mechanical Properties and Failure Behavior of Dry and Water-Saturated Foliated Phyllite under Uniaxial Compression.

Phyllite is widely distributed in nature, and it deserves to be studied considering rock engineering applications. In this study, uniaxial compression tests were conducted on foliated phyllite with different foliation angles under dry and water-saturated conditions. The impacts of water content and foliation angle on the stress-strain curves and basic mechanical properties of the Phyllite were analyzed. The experimental results indicate that the peak stress and peak strain decrease first and then increase with increasing foliation angle as a U-shape or V-shape, and the phyllite specimens are weakened significantly by the presence of water. Moreover, an approach with acoustic emission, digital image correlation, and scanning electron microscopic is employed to observe and analyze the macroscopic and mesoscopic failure process. The results show that tensile microcracks dominate during the progressive failure of phyllite, and their initiation, propagation, and coalescence are the main reasons for the failure of the phyllite specimens. The water acts on biotite and clay minerals that are main components of phyllite, and it contributes to the initiation, propagation, and coalescence of numerous microcracks. Finally, four failure modes are classified as followed: (a) for the specimens with small foliation angles α = 0° or 30° (Saturated), both shear sliding and tensile-split across the foliation planes; (b) for the specimens with low to medium foliation angles α = 30° (Dry) or 45°(Saturated), shear sliding dominates the foliation planes; (c) for the specimens with medium to high foliation angles α = 45° (Dry) or 60°, shear sliding dominates the foliation planes; (d) for the specimens with high foliation angles α = 90°, tensile-split dominates the foliation planes.

Use of wood and cork in biofilters for the simultaneous removal of nitrates and pesticides from groundwater

About 13% and 7% of monitored groundwater stations in Europe exceed the permitted levels of nitrates (50 mg NO3− L−1) or pesticides (0.1 μg L−1), respectively. Although slow sand filtration can remove nitrates via denitrification when oxygen is limited, it requires an organic carbon source. The present study evaluates the performance of the use of wood pellets and granulated cork as carbon sources in bench-scale biofilters operated under water-saturated and water-unsaturated conditions for more than 400 days. The biofilters were monitored for nitrate (200 mg L−1) and pesticide (mecoprop, diuron, atrazine, and bromacil, each at a concentration of 5 μg L−1) attenuation, as well as for the formation of nitrite and pesticide transformation products. Microbiological characterization of each biofilter was also performed. The water-saturated wood biofilter achieved the best nitrate removal (>99%), while the cork biofilters lost all denitrification power over time (from 38% to no removal). The unsaturated biofilter columns were not effective for removing nitrates (20–30% removal). As for pesticides, all the biofilters achieved high removal rates of mecoprop and diuron (>99% and >75%, respectively). Atrazine removal was better in the wood-pellet biofilters than the cork ones (68–96% vs. 31–38%). Bromacil was only removed in the water-unsaturated cork biofilter (67%). However, a bromacil transformation product was formed there. The water-saturated wood biofilter contained the highest number of denitrifying microorganisms, with Methyloversatilis as the characteristic genus. Microbial composition could explain the high removal of pesticides and nitrates achieved in the wood-pellet biofilter. Overall, the results indicate that wood-pellet biofilters operated under water-saturated conditions are a good solution for treating groundwater contaminated with nitrates and pesticides.

Effects of void content on the moisture uptake and mechanical strength of a glass/epoxy composite

The effect of voids on the moisture uptake and transverse modulus and strength of a unidirectional glass/epoxy composite has been examined. To create voids, a foaming agent was mixed with the liquid epoxy resin prior to infusion. Micrographs of polished cross-sections indicate that voids are close to spherical in shape appearing in the matrix and at the fiber/matrix interface. The fiber, matrix, and void contents were analyzed by micrograph, burn-off, and density (Archimedes) methods. The void contents in the void-free and void-containing composites were respectively close to zero and 21%. Specimens were immersed in distilled water at 40°C until saturation. The weight gain was monitored periodically. For the void-free specimens, saturation moisture contents of about 0.60%. The void-containing specimens absorbed much more water, about 5%. The Fickian diffusion model provided good fits to experimental data although the transport mechanism for the void-containing composite appeared non-Fickian. Young’s modulus of the void-free composite was slightly affected by water absorption, although, the transverse tensile strength dropped significantly. Voids were found to substantially reduce transverse modulus and strength about 70%, for both dry and water saturated specimens. Moisture content analysis was in good agreement with experiments for the void-free composite but over-predicted the moisture content for the voidcontaining composite. Micromechanics predictions of the transverse modulus were within 21% of the experimental results for void-free and void containing composites at dry and water saturated conditions.

Experimental investigation on the effect of high-pressure water on tensile strength and microstructure of cementitious materials

The strength of cementitious materials is strongly related to their microstructures. This paper aims to investigate the effect of high-pressure water on the static and dynamic tensile strength of cementitious materials and interpret the influence through the view of microstructure. Specimens were first put in different water pressure (0 MPa, 1 MPa, 3 MPa, and 5 MPa) then their strength and microstructures were measured through splitting tensile tests, SEM tests, and MIP tests. Results showed that as water pressure increased, the strength of mortar decreased with a maximum loss of 32.54 %, while strain rate sensitivity increased. The static strength of saturated specimens was higher than the dried ones under the same water pressure, whereas the opposite results were obtained for dynamic strength. The observed microstructure morphology indicated that higher water pressure would induce more microcracks around pores and around aggregate-matrix interfaces, which led to the loss of strength. The water content and total porosity increased with increasing water pressure. Predictive static and dynamic tensile strength models concerning water pressure, porosity, and saturation states are proposed. The predicted values are in good agreement with the test values.

Gas content prediction model of water-sensitive shale based on gas–water miscible competitive adsorption

The evaluation of gas content plays a key role in determining the efficient development of shale reservoirs. To better understand the gas–water miscible competitive adsorption mechanism in the pore-fracture system of water-bearing shale, the water vapor adsorption experiment of dry shale and the methane gas adsorption experiment of water-bearing shale were carried out to compare and analyze the competitive adsorption laws of formation water and methane gas on the shale surface under different temperatures, pressures, and water saturation conditions. Moreover, based on the molecular layer adsorption theory, the gas–liquid–solid interface competitive adsorption model considering the coupling of temperature, pressure, and water saturation was established to predict the actual gas content of water-bearing shale reservoirs. The results show that the main controlling factors affecting the adsorbed gas content of water-bearing shale are specific surface area, temperature, and water content in turn according to weight coefficients; Compared with the gas–solid adsorption model, the gas–liquid–solid competitive adsorption model has higher accuracy in calculation results, which are much closer to the desorption data of shale cores in Jiaoshiba area, Fuling, China. Hence, the competitive adsorption model provides a theoretical foundation for reasonably evaluating the exploitation potential of shale gas reservoirs.

Assessing water-induced changes in tensile behaviour of porous limestones by means of uniaxial direct pull test and indirect methods

Understanding the uniaxial tensile behaviour of rocks and its water-induced variation are key issues for designing effective mining and civil engineering structures and for assessing numerous geotechnical hazards. However, these aspects remain poorly analysed because conducting uniaxial direct pull tests is a difficult and time-consuming laboratory task that requires the use of sophisticated equipment and complex rock sample preparation and processing. This work attempts to expand knowledge by determining several tensile properties of three porous limestone lithotypes under dry and water-saturated conditions through two different approaches: by conducting direct tensile tests and by means of indirect methods (i.e. Brazilian and point load tests). The results revealed that water saturation generated important reductions in their uniaxial tensile strength (UTS), tensile elastic modulus (Et), Brazilian tensile strength (BTS) and point load strength index (Is(50)). In addition, their petrological characteristics and mineralogical composition are used to discuss the main causes of the observed tensile softening. Furthermore, highly accurate correlation functions were established between the direct tensile strength parameters (UTS and Et) and the indirect ones (BTS and Is(50)) for the whole set of tested rocks. The proposed relationships are a novel and useful contribution to geomechanics because they enable the estimation of pure tensile parameters using alternative, cheap, rapid and versatile tests.

Quest for optimal nanoconfinement for hydrate-based CO2 capture

CO2 capture is a viable solution for mitigating the global CO2 emission in the atmosphere. Hydrate-based CO2 capture is a promising technology. In this study, the CO2 hydrate formation thermodynamics and kinetics, along with the factors that influence CO2 capture in nanoporous silica gels (named S9, S26, and S77 with an average pore size of 9, 26 and 77 nm, respectively), with different degrees of nanoconfinement were investigated. The CO2 hydrate phase equilibrium and dissociation heat were determined by heat flow analysis. The heat flow curves revealed the formation of both confined- and bulk-phase hydrates in S9 and only bulk-phase hydrate in S26 and S77. The phase equilibrium temperature of the confined-phase hydrate was about 10 K lower than that of the bulk-phase hydrate and the dissociation heat of confined phase hydrate is 285.81 J/g in S9. According to the pressure curves, the CO2 hydrate formation time in S9 was 2–3.5 times longer than that in S26 and S77. Compared with dry silica gel, the supersaturated one was more conducive to CO2 capture. Under the same water saturation condition, the CO2 capture ability of S26 and S77 was stronger than that of S9, and the effect of water saturation was dominant over that of pressure. Thus, nanoconfinement in S9 has an adverse effect on hydrate-based CO2 capture whereas that in S26 and S77 is advantageous to it. This study provides an important fundamental basis for enhancing the hydrate-based CO2 capture ability via nanoconfinement in silica gel.

Identification of fluid types and their implications for petroleum exploration in the shale oil reservoir: A case study of the Fengcheng Formation in the Mahu Sag, Junggar Basin, Northwest China

The Fengcheng Formation in the Junggar Basin is a typical shale oil reservoir. Fluid type identification and controlling factors on fluid combination types are significant challenges in shale oil exploration and development. By using two-dimensional (2D) nuclear magnetic resonance (NMR) technology, the accurate boundary values of each fluid type can be determined. Combined with thin sections, scanning electron microscopy (SEM), cathode-luminescence (CL), X-ray diffraction (XRD) and NMR, the effect of lithologies on fluid combination types has been evaluated. The results show that a total of six fluid types can be identified in the Fengcheng Formation, including free oil, adsorbed oil, kerogen, hydroxyls, adsorbed water and free water. Their boundary values on the NMR T1-T2 map can be determined by comparing fluid signals under the original state and water-saturated state after oil washing. In this study, different fluid types eliminated kerogen and hydroxyls can be combined into four fluid combination types defined as Type 1 (free oil, adsorbed oil and adsorbed water), 2 (free oil, adsorbed oil, free water and adsorbed water), 3 (adsorbed oil, free oil and free water) and 4 (movable fluids), existing in the dolomitic shale, mixed shale, felsic shale and sandstone, respectively. Meanwhile, the geometric means of T2 (T2gm) and T2 curves indicate that the pore size can effectively distinguish different lithologies and can be considered as an essential factor influencing the occurrence state of fluids. As the average pore size increases, free water emerges in the mixed shale, and adsorbed water disappears in the felsic shale. Furthermore, after the lithology transforms into sandstone, the fluid type is simple, and only movable fluids exist. Finally, the oil test results imply that the reservoirs with fluid combination Type 4 and Type 3 have relatively high oil production. Therefore, the subsequent orientation for petroleum exploration in shale oil reservoirs targets the sandstone and felsic shale interlayers in the Fengcheng Formation.

Thermal stability of limestone calcined clay cement (LC3) at moderate temperatures 100–400 °C

The mechanical properties, phase evolution, microstructure development and (re)hydration properties of limestone calcined clay cement (LC3) paste and mortar were investigated to understand their thermal stability under moderate temperatures (100–400 °C). The residual compressive strengths of LC3 and Portland cement (PC) mortars kept constant or slightly increased from ambient to 300 °C, and sharply dropped at 400 °C. At 100 °C, monocarboaluminate (Mc) and ettringite (AFt) converted into hemicarboaluminate (Hc) and monosulfate (Ms), and caused partial dehydroxylation of C-(A)-S-H. As the temperature increased, at 200–300 °C, due to the decomposition of large fraction of hydration products, macroscopic cracks and microstructure damage occurred. At 400 °C, the mean chain length (MCL) of C-(A)-S-H gel decreased, accompanied by the shift of Si and Al-coordination number and the formation of active sites. Under water saturation conditions, the microstructure showed self-repairing performance.