Supported Pt catalysts are often subjected to severe deactivation under the conditions of high temperature and water vapor in catalytic oxidation; thus, the superior stability and water-resistant ability of catalysts have great significance for the effective degradation of volatile organic compounds (VOCs). Herein, we constructed a Pt/CeO2-N catalyst with an active interfacial perimeter, in which Pt species were partially embedded in the defective CeO2-N support to prevent the sintering. A significant charge transfer between Pt species and ceria in the embedding structure occurred via the Pt-CeO2 interface, which induced the formation of a Pt4+-Ov-Ce3+ interfacial structure. Experimental research and theoretical calculations demonstrated that the active Pt4+-Ov-Ce3+ interface promoted the activation and migration of lattice oxygen, thus facilitating the participation of oxygen species in toluene oxidation. Consequently, Pt/CeO2-N showed excellent catalytic performance for toluene degradation. In situ DRIFTS and DFT calculation proved that the Pt4+-Ov-Ce3+ interfacial sites served as the intrinsic active center in the dissociation of H2O to generate ·OH, which contributed to the formation of benzaldehyde, thus remarkably improving the water-resistant property. This study provided a facile strategy for fabricating the interfacial embedding structure to enhance the catalytic activity and water tolerance for eliminating VOCs in practical application.
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