Water Path Research Articles

Yield Impact of Data-Informed Surface Drainage: An On-Farm Case Study

Drainage is an important aspect of effective water management in row-crop agriculture. Drainage systems can be broadly categorized as either subsurface or surface drainage. A significant amount of design goes into subsurface drainage installations, such as tile networks, and permanent surface drainage installations, such as waterways and berms. However, many farmers also implement temporary surface drainage installations to drain localized areas within their fields each year. This practice involves creating shallow water paths, typically using spinner ditchers, and it is especially commonplace in areas with poor soil permeability. However, this practice is traditionally performed using only observations by farmers and without any data-based workflows. The objective of this study was to analyze the potential yield benefits from a more data-informed approach to surface drainage on a production row-crop farm by exploring corn and soybean yield data from 2008–2021 from two fields where a data-informed approach to surface drainage was implemented. Field topography and drainage information were combined with yield maps from prior years with traditional ad hoc drainage and the years following the incorporation of the data-informed approach to better understand the impact of the workflow. Geospatial distribution of the average normalized crop yields and elevation maps for the fields were analyzed to isolate the yield impacts of the areas affected by the data-informed on-farm surface drainage artifacts. In the years after implementation of the data-informed surface drainage approach, Field 1 and Field 2 showed respective increases of 18.3% and 13.9% in average corn yields. Further analysis isolating three areas affected by the surface drainage using topography and drainage layout showed that all three isolated areas improved more than the field averages, ranging from 15.9–26.5% for Field 1 and 21.4–40.2% for Field 2. Similarly, soybean yields were also higher in the isolated affected areas after the data-informed drainage ditch construction. The findings highlight the effectiveness of data-informed on-farm surface drainage, a relatively straightforward approach that proved beneficial for both soybean and corn production.

Weak liquid water path response in ship tracks

Abstract. The assessment of aerosol–cloud interactions remains a major source of uncertainty in understanding climate change, partly due to the difficulty in making accurate observations of aerosol impacts on clouds. Ships can release large numbers of aerosols that serve as cloud condensation nuclei, which can create artificially brightened clouds known as ship tracks. These aerosol emissions offer a “natural”, or “opportunistic”, experiment to explore aerosol effects on clouds, while also disentangling meteorological influences. Utilizing ship positions and reanalysis wind fields, we predict ship track locations, colocating them with satellite data to depict the temporal evolution of cloud properties after an aerosol perturbation. Repeating our analysis for a null experiment does not necessarily recover zero signal as expected; instead, it reveals subtleties between different null-experiment methodologies. This study uncovers a systematic bias in prior ship track research, due to the assumption that background gradients will, on average, be linear. We correct for this bias, which is linked to the correlation between wind fields and cloud properties, to reveal the true ship track response. We find that, once this bias is corrected for, the liquid water path (LWP) response after an aerosol perturbation is weak on average. This has important implications for estimates of radiative forcings due to LWP adjustments, as previous responses in unstable cases were overestimated. A noticeable LWP response is only recovered in specific cases, such as marine stratocumulus clouds, where a positive LWP response is found in precipitating or clean clouds. This work highlights subtleties in the analysis of isolated opportunistic experiments, reconciling differences in the LWP response to aerosols reported in previous studies.

The effect of obstructions above the flat- and circular-stepped spillway on energy dissipation

Stepped spillways are significant water structures that aerate rivers, disperse energy, and lower the cost of the downstream pool. Energy dissipators are means made to lower flow velocity to manageable levels, preventing erosion in downstream areas. A study was conducted to assess the effect of obstructions above the stepped spillway using a wooden physical model of 50 cm height, 100 cm length, 80 cm width. A total of 24 laboratory experiments were carried out using two shapes of steps (flat and circular), three cases of obstruction (no obstruction, an obstruction at the middle of the step, and an obstruction at the end of the step), and four discharges. The results showed that the energy dissipation using flat stepped spillway is higher than that for circular stepped spillway of about 3 %. The relation is inverse between ΔΕ/Eo (difference between upstream and downstream energy of stepped spillway/upstream energy) and E1/Eo (downstream energy/upstream energy), for all cases, whether flat or circular steeped spillway, with or without use of obstruction. In general, using a middle obstruction led to dissipate more energy than an end obstruction. For flat stepped spillway, the percentage of energy dissipation was 5 % when comparing a middle obstruction with no obstruction, while it was 4 % when comparing an end obstruction with no obstruction. For circular stepped spillway, the corresponding percentages of energy dissipation were 6 % and 5 %, respectively. The relation is direct between ΔΕ/Eo and l/Eo, and the largest water path is in the case of using the middle obstruction for flat and circular steeped spillway. One empirical relation was proposed to compute ΔΕ/Eo in terms of dimensionless variables using dimensional analysis.

Clouds and precipitation in the initial phase of marine cold-air outbreaks as observed by airborne remote sensing

Abstract. Marine cold-air outbreaks (MCAOs) strongly affect the Arctic water cycle and, thus, climate through large-scale air mass transformations. The description of air mass transformations is still challenging, partly because previous observations do not resolve fine scales, particularly for the initial development of an MCAO, and due to a lack of information about the thermodynamical evolution starting over sea ice and continuing over open ocean and associated cloud microphysical properties. Therefore, we focus on the crucial initial development within the first 200 km over open water for two case studies in April 2022 during the HALO-(AC)3 campaign (named after the High Altitude and Long Range Research Aircraft and Transregional Collaborative Research Centre ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes and Feedback Mechanisms (AC)3). The two events, just 3 d apart, belong to a particularly long-lasting MCAO and occurred under relatively similar thermodynamic conditions. Even though both events were stronger than the climatological 75th percentile of that period, the first event was characterized by colder air masses from the central Arctic which led to an MCAO index twice as high compared to that of the second event. The evolution and structure were assessed by flight legs crossing the Fram Strait multiple times at the same location, sampling perpendicularly to the cloud streets. Airborne remote sensing and in situ measurements were used to build statistical descriptions of the boundary layer, dynamics, clouds, and precipitation. For this purpose, we established a novel approach based solely on radar reflectivity measurements to detect roll circulation that forms cloud streets. The two cases exhibit different properties of clouds, riming, and roll circulations, though the width of the roll circulation is similar. For the stronger event, cloud tops are higher; more liquid-topped clouds exist; the liquid water path, mean radar reflectivity, precipitation rate, and precipitation occurrence have increased; and riming is active. The variability in rime mass has the same horizontal scale as the roll circulation, implying the importance of roll circulation on cloud microphysics and precipitation. Boundary layer and cloud properties evolve with distance over open water, as seen by, e.g., cloud top height rising. In general, cloud streets form after traveling 15 km over open water. After 20 km, this formation enhances cloud cover to just below 100 %. After around 30 km, precipitation forms, though for the weaker event, the development of precipitation is shifted to larger distances. Within our analysis, we developed statistical descriptions of various parameters (i) within the roll circulation and (ii) as a function of distance over open water. These detailed cloud metrics are particularly well suited for the evaluation of cloud-resolving models close to the sea ice edge to evaluate their representation of dynamics and microphysics.

Rotating evaporator for sustainable urban cooling and electricity generation

We have developed, for the first time, a rotating evaporator that synergistically performs sustainable urban cooling and electricity generation. Fabricated using 3D printing, it features a nature-inspired hierarchical water path that mimics tree transpiration. Under 1-sun illumination, the rotating evaporator achieved an evaporation rate of 2.08 kg/m2h, and in the presence of wind at a speed of 4 m/s, the evaporator began rotating, enhancing the evaporation rate to 19.58 kg/m2h. When the rotator was fixed to prevent rotation, the evaporation rate decreased by 24 %, highlighting the advantage of rotation in water evaporation by effectively preventing vapor accumulation near the evaporating surface and supplying environmental energy. Notably, the rotating evaporator provided evaporative cooling 12.2 times greater than the incident solar energy, cooling 25.6 m3 of air by 1 °C in one hour, highlighting its potential to mitigate the urban heat island effect. This rotation also generated electricity, achieving a voltage of 1.07 V and a power density of 4.73 W/m2, which was sufficient for practical applications such as lighting and water purification.

The impact of cloud microphysics and ice nucleation on Southern Ocean clouds assessed with single-column modeling and instrument simulators

Abstract. Supercooled liquid clouds are common at higher latitudes (especially over the Southern Ocean) and are critical for constraining climate projections. We take advantage of the Macquarie Island Cloud and Radiation Experiment (MICRE) to perform an analysis of observed and simulated cloud processes over the Southern Ocean in a region and season dominated by supercooled liquid clouds. Using a single-column version of the European Centre for Medium-Range Weather Forecasts (ECMWF) Integrated Forecast System (IFS), we compare two different cloud microphysical schemes to ground-based observations of cloud, precipitation, and radiation over a 2.5-month period (1 January–17 March 2017). Both schemes are able to reproduce aspects of the cloud and radiation observations during MICRE to within the uncertainty of the data when the thermodynamic profile is prescribed with relaxation. There are differences in water mass and representation of reflectivity between the schemes. A sensitivity study of the cloud microphysics schemes, one a bulk one-moment scheme and the other a two-moment scheme with prediction of mass and number, indicates that several key processes create differences between the schemes. Surface radiative fluxes and total water path are highly sensitive to the formation and fall speed of precipitation. The prediction of hydrometeor number with the two-moment scheme yields a better comparison with observed reflectivity and radiative fluxes, despite predicting higher liquid water contents than observed. With the two-moment scheme, we are also able to test the sensitivity of the results to the input of liquid cloud condensation nuclei (CCN) and ice nuclei (IN). The cloud properties and resulting radiative effects are found to be sensitive to the CCN and IN concentrations. More CCN and IN increase liquid and ice water paths, respectively. Thus, both the dynamic environment and aerosols, integrated through the cloud microphysics, are important for properly representing Southern Ocean cloud radiative effects.

Systematic Upstream Large-Scale Control of Subtropical Low-Cloud Properties

Abstract It has recently been shown that the slow adjustment of the atmospheric boundary layer (ABL) to perturbations of the large-scale atmospheric conditions translate into an upstream control of the low-cloud cover (LCC) variability at climatological timescales in the subtropics. In this study we expand upon this recent study to investigate upstream control of the climatology of low-cloud radiative effect (CRE), as well as cloud properties relevant to their radiative effect: cloud liquid water path (LWP), and cloud optical depth (COD).We use machine-learning statistical models with feature selection capabilities (random-forests) to determine the influence of the local and upstream large-scale conditions in monthly data. These conditions are determined using back-trajectories in monthly-mean wind fields. Total CRE, dominated by the shortwave contribution, exhibits a dependence on upstream Estimated Inversion Strength (EIS), but not on upstream Sea-Surface Temperature (SST) as LCC does. Upstream control of COD was present but was not as consistent as LCC or CRE across different regions and cloud regimes, while LWP does not exhibit strong upstream control at all. This implies that the control of other boundary layer properties could explain the differences in response between LCC and CRE to SST and EIS. Looking at five subtropical eastern basins, it appears that key lead times are region-specific. The inclusion of upstream control provides significant improvements to the predictive skill of statistical models over local linear regression, with improvements in variance explained well over 20% in many cases.

Synergistic development path of conventional and unconventional water in China: From the perspectives of output and substitution elasticities

Exploring the synergistic relationship between conventional water (CW) and unconventional water (UW) is a better way to alleviate water scarcity. However, research remains lacking on the complex relationship between CW and UW from a water resources subdivision perspective. By constructing a heterogeneous trans-log stochastic frontier model, this study estimated the technical efficiency, output elasticity, and substitution elasticity; further, the study innovatively explored five development pathways for CW and UW. The results are as follows. First, China's overall technical efficiency demonstrated a fluctuating upward trend over the study period, which was significantly boosted by higher levels of research and development investment and an increased number of granted patents. Second, compared with UW, CW made a more substantial contribution to output. The output elasticity of CW demonstrated a “low in the center, high on the periphery” pattern, with the lowest elasticity areas clustered in the middle and lower reaches of the Yellow River. Conversely, the output elasticity of UW followed a “high in the east and low in the west” pattern, which was similar to that of capital. Third, with 2012 as the turning point, CW and UW shifted from a substitution to a complementary relationship. Fourth, this study proposes alternative structural optimization paths under various scenarios, namely balanced development of CW and UW, CW-driven, UW-driven, coordinated development of CW and UW, and aided development of CW and UW.

Online Learning of Entrainment Closures in a Hybrid Machine Learning Parameterization

AbstractThis work integrates machine learning into an atmospheric parameterization to target uncertain mixing processes while maintaining interpretable, predictive, and well‐established physical equations. We adopt an eddy‐diffusivity mass‐flux (EDMF) parameterization for the unified modeling of various convective and turbulent regimes. To avoid drift and instability that plague offline‐trained machine learning parameterizations that are subsequently coupled with climate models, we frame learning as an inverse problem: Data‐driven models are embedded within the EDMF parameterization and trained online in a one‐dimensional vertical global climate model (GCM) column. Training is performed against output from large‐eddy simulations (LES) forced with GCM‐simulated large‐scale conditions in the Pacific. Rather than optimizing subgrid‐scale tendencies, our framework directly targets climate variables of interest, such as the vertical profiles of entropy and liquid water path. Specifically, we use ensemble Kalman inversion to simultaneously calibrate both the EDMF parameters and the parameters governing data‐driven lateral mixing rates. The calibrated parameterization outperforms existing EDMF schemes, particularly in tropical and subtropical locations of the present climate, and maintains high fidelity in simulating shallow cumulus and stratocumulus regimes under increased sea surface temperatures from AMIP4K experiments. The results showcase the advantage of physically constraining data‐driven models and directly targeting relevant variables through online learning to build robust and stable machine learning parameterizations.

Liquid Water Transport and Distribution in the Gas Diffusion Layer of a Proton Exchange Membrane Fuel Cell Considering Interfacial Cracks

The proton exchange membrane fuel cell (PEMFC), with a high energy conversion efficiency, has become an important means of hydrogen energy utilization. However, water condensation is unavoidable in the PEMFC because of low operating temperatures. The impact of liquid water on PEMFC performance and stability is significant. The gas diffusion layer (GDL) provides a critical transport path for liquid water in the PEMFC. Liquid water saturation and distribution in the GDL determine water flooding and mass transfer efficiency in the PEMFC. In this study, focusing on the effects of the water introduction method, osmotic pressure, and contact angle, the liquid water transport in the GDL was numerically investigated based on a pore-scale model using the volume of fluid (VOF) method. The results showed that compared with the conventional water introduction method without cracks, the saturation and spatial distribution of water inside the GDL obtained in the simulation were more consistent with the experimental results when the water was introduced through the microporous layer (MPL) crack. It was found that increasing the osmotic pressure resulted in a faster rate of water penetration, faster approaching the steady-state performance, and higher saturation. The ultra-high osmotic pressure contributed to the secondary breakthrough with a significant increase in saturation. Increasing the contact angle caused higher capillary resistance, especially in the region with small pore sizes. At a constant osmotic pressure, as the contact angle increased, the liquid water gradually failed to penetrate into the small pores around the transport path, causing saturation reduction and an ultimate failure to break through the GDL. Increasing the contact angle contributed to a higher breakthrough pressure and secondary breakthrough pressure.

Rapidly Screening the Correlation between the Rotational Mobility and the Hydrogen Bonding Strength of Confined Water.

Automated Deuterium Relaxation-Ordered SpectroscopY in solution (ADROSYS), an automated two-dimensional deuterium NMR methodology, discriminates between D2O populations (as well as deuterium-labeled alcohol groups) whose properties differ as a result of being confined inside nanoscale volumes. In this contribution, a proof-of-principle demonstration on reverse micelles (RMs) yields the insight that as the length scale of the confinement decreases from several nanometers down to less than a nanometer, the position of the signal peak migrates through the two-dimensional (2D) spectrum, tracing out a distinctive path in the 2D space (of relaxation time vs chemical shift). The signals typically follow a relatively gentle linear path for water confined on the scale of several nanometers, before curving once the surfactants confine the water molecules to length scales smaller than 1-2 nm. The qualitative shape of this path, especially in the regime of strong confinement, can change with different choices of surfactants, i.e., a different choice of chemistry at the edges of the confining environment. An important facet of this research was to demonstrate the relatively wide applicability of these techniques by showing that both: (1) Standard modern NMR instrumentation is capable of deploying an automated measurement, even though the choice of a deuterium nucleus is nonstandard and frequently requires companion proton spectra in order to reference the chemical shifts; and (2) well-established (though underutilized) modern techniques can process the resulting signal even though it involves the somewhat unusual combination of chemical shifts along one dimension and a distribution of relaxation times along another dimension. In addition to demonstrating that this technique can be deployed across many samples of interest, detailed facts pertaining to the broadening or shifting of resulting signals upon inclusion of various guest molecules are also discussed.

Substrate engagement by the intramembrane metalloprotease SpoIVFB

S2P intramembrane metalloproteases regulate diverse signaling pathways across all three domains of life. However, the mechanism by which S2P metalloproteases engage substrates and catalyze peptide hydrolysis within lipid membranes has remained elusive. Here we determine the cryo-EM structure of the S2P family intramembrane metalloprotease SpoIVFB from Bacillus subtilis bound to its native substrate Pro-σK. The structure and accompanying biochemical data demonstrate that SpoIVFB positions Pro-σK at the enzyme active site through a β-sheet augmentation mechanism, and reveal key interactions between Pro-σK and the interdomain linker connecting SpoIVFB transmembrane and CBS domains. The cryo-EM structure and molecular dynamics simulation reveal a plausible path for water to access the membrane-buried active site of SpoIVFB, and suggest a possible role of membrane lipids in facilitating substrate capture. These results provide key insight into how S2P intramembrane metalloproteases capture and position substrates for hydrolytic proteolysis within the hydrophobic interior of a lipid membrane.

The Non-Monotonic Response of Cumulus Congestus to the Concentration of Cloud Condensation Nuclei

This study uses idealized simulations to investigate the impact of cloud condensation nuclei (CCN) on a cumulus congestus. Thirteen cases with the initial CCN_C, which is the CCN concentration at 1% supersaturation with respect to water, from 10 to 10,000 cm−3 are simulated. The analysis focuses on the liquid phase due to the negligible ice phase in this study. A non-monotonic response of cloud properties and precipitation to CCN concentration is observed. When CCN_C is increased from 10 to 50 cm−3, the enhanced condensation due to the more numerous droplets invigorates the cumulus congestus. The delayed precipitation formation due to the smaller droplets also facilitates the cloud development. The two processes together lead to a higher liquid water path (LWP), higher cloud top, and heavier precipitation. The cumulus congestus has the highest cloud top, the strongest updraft, and the most accumulated precipitation and at CCN_C = 50 cm−3. When CCN_C is increased from 50 to 500 cm−3, the condensation near the cloud base is further enhanced and the precipitation is further delayed, both of which lead to more liquid water remaining in the cloud, and thus an even higher LWP and heavier precipitation rate in the later stage. However, the significantly enhanced evaporation near the cloud top limits the vertical development of the cumulus congestus, leading to a lower cloud top. When CCN_C is further increased to be higher than 1000 cm−3, the cumulus congestus is strongly suppressed, and no precipitation forms. The ratio of the precipitation production rate to vertical cloud water flux in the updraft is not a constant, as is generally assumed in cumulus parameterization schemes, but decreases significantly with increasing CCN concentration. It is also found that the CCN effect on the cumulus congestus relies on which parameters are used to describe the cloud strength. In this study, as CCN_C increases, the LWP and the maximum precipitation rate peak at CCN_C = 500 cm−3, while the cloud top height, maximum updraft, and accumulated precipitation amount peak at CCN_C = 50 cm−3.

Analysis of the Meteorological Conditions and Atmospheric Numerical Simulation of an Aircraft Icing Accident

With the rapid development of the general aviation industry in China, the influence of high-impact aeronautical weather events, such as aircraft icing, on flight safety has become more and more prominent. On 1 March 2021, an aircraft conducting weather modification operations crashed over Ji’an City, due to severe icing. Using multi-source meteorological observations and atmospheric numerical simulations, we analyzed the meteorological causes of this icing accident. The results indicate that a cold front formed in northwestern China and then moved southward, which is the main weather system in the icing area. Based on the icing index, we conducted an analysis of the temperature, relative humidity, cloud liquid water path, effective particle radius, and vertical flow field, it was found that aircraft icing occurred behind the ground front, where warm-moist airflows rose along the front to result in a rapid increase of water vapor in 600–500 hPa. The increase of water vapor, in conjunction with low temperature, led to the formation of a cold stratiform cloud system. In this cloud system, there were a large number of large cloud droplets. In addition, the frontal inversion increased the atmospheric stability, allowing cloud droplets to accumulate in the low-temperature region and forming meteorological conditions conducive to icing. The Weather Research and Forecasting model was employed to provide a detailed description of the formation process of the atmospheric conditions conducive to icing, such as the uplifting motion along the front and supercooled water. Based on a real case, we investigated the formation process of icing-inducing meteorological conditions under the influence of a front in detail in this study and verified the capability of a numerical model to simulate the meteorological environment of frontal icing, in order to provide a valuable reference for meteorological early warnings and forecasts for general aviation.

Study on the High-quality Development of Water Sports Tourism in Hainan

With the deepening of establishing a national sports tourism demonstration area, water sports tourism, as an important part of Hainan tourism, is facing unprecedented opportunities for development. This paper aims to analyze the resource advantages, development status and existing problems of Hainan water sports tourism, and put forward the strategies and suggestions for high-quality development. Through literature review, field research and case analysis, this paper discusses the high-quality development path of water sports tourism in Hainan, in order to provide theoretical support and practical guidance for the construction of Hainan free trade port and international tourism consumption center.

Can agricultural water rights trading promote intensive and economical utilization of water resources in China based on the difference-in-differences model?

IntroductionImproving the level of intensive and economical utilization of water resources is an important step towards water and food security.MethodsBased on China’s provincial panel data from 2015 to 2021, this study uses a difference-in-differences (DID) model to examine the effect of agricultural water rights trading on intensive and economical utilization of water resources.ResultsThe results show that agricultural water rights trading can significantly promote an intensive and economical utilization of water resources at the 1% level, and the results remain valid even after a series of robustness tests. Further analysis indicates that agricultural water rights trading can promote better utilization of water resources by significantly reducing agricultural water consumption at the 1% level and reducing the proportion of agricultural water consumption at the 5% level to optimize water use structure. Moreover, in regions with scarce water resources, strong water resource constraints, more farmland water conservancy projects, and greater economic development, the promoting effect of agricultural water rights trading on the intensive and economical use of water resources is more significant.DiscussionThis study provides evidence of the impact of China’s agricultural water rights trading policy and offers new ideas and experiences to improve China’s water resource utilization efficiency. The contributions of this work are mainly threefold. First, this paper clearly distinguishes the intensive conservation of water resources, presents an evaluation index system, and complements the existing literature on measuring the intensive and economical utilization of water resources. Second, the path of agricultural water rights trading is analyzed to improve the level of intensive and economical utilization of water resources, thus enriching related research on transmission mechanisms. Third, the heterogeneity of the influence of different regional conditions on the level of intensive and economical utilization of water resources is discussed to improve relevant policies.

The Ice Cloud Imager: retrieval of frozen water column properties

Abstract. The Ice Cloud Imager (ICI) aboard the second generation of the EUMETSAT Polar System (EPS-SG) will provide novel measurements of ice hydrometeors. ICI is a passive conically scanning radiometer that will operate within a frequency range of 183 to 664 GHz, helping to cover the present wavelength gap between microwave and infrared observations. Reliable global data will be produced on a daily basis. This paper presents the retrieval database to be used operationally and performs a final pre-launch assessment of ICI retrievals. Simulations are performed within atmospheric states that are consistent with radar reflectivities and represent the three-dimensional (3D) variability of clouds. The radiative transfer calculations use empirically based hydrometeor models. Azimuthal orientation of particles is mimicked, allowing for the consideration of polarisation. The degrees of freedom (DoFs) of the ICI retrieval database are shown to vary according to cloud type. The simulations are considered to be the most detailed performed to this date. Simulated radiances are shown to be statistically consistent with real observations. Machine learning is applied to perform inversions of the simulated ICI observations. The method used allows for the estimation of non-Gaussian uncertainties for each retrieved case. Retrievals of ice water path (IWP), mean mass height (Zm), and mean mass diameter (Dm) are presented. Distributions and zonal means of both database and retrieved IWP show agreement with DARDAR. Retrieval tests indicate that ICI will be sensitive to IWP between 10−2 and 101 kg m−2. Retrieval performance is shown to vary with climatic region and surface type, with the best performance achieved over tropical regions and over ocean. As a consequence of this study, retrievals from real observations will be possible from day one of the ICI operational phase.

Fabrication of Low-Cost Porous Carbon Polypropylene Composite Sheets with High Photothermal Conversion Performance for Solar Steam Generation.

The development of absorber materials with strong light absorption properties and low-cost fabrication processes is highly significant for the application of photothermal conversion technology. In this work, a mixed powder consisting of NaCl, polypropylene (PP), and scale-like carbon flakes was ultrasonically pressed into sheets, and the NaCl was then removed by salt dissolution to obtain porous carbon polypropylene composite sheets (P-CPCS). This process is simple, green, and suitable for the low-cost, large-area fabrication of P-CPCS. P-CPCS has a well-distributed porous structure containing internal and external connected water paths. Under the dual effects of the carbon flakes and porous structure, P-CPCS shows excellent photothermal conversion performance in a broad wavelength range. P-CPCS-40 achieves a high temperature of 128 °C and a rapid heating rate of 12.4 °C/s under laser irradiation (808 nm wavelength, 1.2 W/cm2 power). When utilized for solar steam generation under 1 sun irradiation, P-CPCS-40 achieves 98.2% evaporation efficiency and a 1.81 kg m-2 h-1 evaporation rate. This performance means that P-CPCS-40 outperforms most other previously reported absorbers in terms of evaporation efficiency. The combination of carbon flakes, which provide a photothermal effect, and a porous polymer structure, which provides light-capturing properties, opens up a new strategy for desalination, sewage treatment, and other related fields.

Microphysical Evolution in Mixed-Phase Midlatitude Marine Cold-Air Outbreaks

Abstract Five cold-air outbreaks are investigated with aircraft offshore of continental northeast America. Flight paths aligned with the cloud-layer flow from January through March span cloud-top temperatures from −5° to −12°C, in situ liquid water paths of up to 500 g m−2, while in situ cloud droplet number concentrations exceeding 500 cm−3 maintain effective radii below 10 μm. Rimed ice is detected in the four colder cases within the first cloud pass. After further fetch, ice particle number concentrations reaching 2.5 L−1 support an interpretation that secondary ice production is occurring. Rime splintering is clearly evident, with dendritic growth increasing ice water contents within deeper clouds with colder cloud-top temperatures. Buoyancy fluxes reach 400–600 W m−2 near the Gulf Stream’s western edge, with 1-s updrafts reaching 5 m s−1 supporting closely spaced convective cells. Near-surface rainfall rates of the three more intense cold-air outbreaks are a maximum near the Gulf Stream’s eastern edge, just before the clouds transition to more open-celled structures. The milder two cold-air outbreaks transition to lower-albedo cumulus with little or no precipitation. The clouds thin through cloud-top entrainment. Significance Statement Cold-air outbreaks off of the eastern U.S. seaboard are visually spectacular in satellite imagery, with overcast, high-albedo clouds transitioning to more broken cloud fields. We use data from the recent NASA Aerosol Cloud Meteorology Interactions over the Western Atlantic Experiment (ACTIVATE) aircraft campaign to examine the microphysics and environmental context of five such outbreaks. We find the clouds are not ice-deprived, but updrafts still supply significant liquid water. Cloud transitions are encouraged through near-surface rain for the deeper clouds, and otherwise, clouds thin and break through mixing in drier air from above. These observations support understanding and further modeling examining how mixed-phase cloud microphysics affect cloud reflectivity and surface rainfall rates, important for both weather and climate forecasting.

Do Subsampling Strategies Reduce the Confounding Effect of Errors in Bispectral Retrievals on Estimates of Aerosol Cloud Interactions?

AbstractBi‐spectral retrievals of droplet effective radius and cloud optical depth are widely utilized to estimate aerosol cloud interactions (ACI) in warm clouds in the marine boundary layer. Here, we assess the effect of retrieval errors due to the neglect of 3D radiative transfer during the retrieval process on this analysis of ACI. We use an ensemble of stochastically‐modeled cloud fields and 3D radiative transfer simulations to study the retrieval errors at a solar zenith angle of 30°. Simulated retrieval biases in droplet number concentration (Nd) for all three MODIS channels vary systematically from +35% to −80% as cloud heterogeneity increases. Pixel‐level errors can be much larger. Commonly utilized subsampling strategies do not reduce the systematic variation in retrieval error. Negative error correlations between optical depth and droplet effective radius produce spuriously negative slopes between the logarithm of liquid water path and Nd (−1.0 to −0.3). Pixels at the center of (8 km)2 patches that are not overcast have a relative bias in Nd of −50%. The relative frequency of these biased pixels varies linearly with the clear fraction in MODIS data and form the basis for a simple parameterization of Nd bias that varies with cloud fraction (CF). Using this parameterization, synthetic data experiments indicate that estimates of the first indirect effect in the tropical ocean can be overestimated by up to 30%, and the effect of aerosol on CF is overestimated by 50%, due to neglecting the correlation between retrieval errors and cloud microphysics.