Water Isotope Research Articles

Hydrochemical and Isotopic Characteristics and the Spatiotemporal Differences of Surface Water and Groundwater in the Qaidam Basin, China

In the context of climate change, precipitation and runoff in the arid inland basins of northwest China have undergone significant changes. The Qaidam Basin (QB) is a typical highland arid inland area. Understanding the spatial and temporal variations in surface water and groundwater chemistry and isotopes, as well as their causes, is crucial for future water resource management and ecological protection. Samples of river, lake, and groundwater, as well as others, were collected and tested in five typical watersheds in the summer and winter. The hydrochemistry and isotopic spatiotemporal differences in various water bodies were studied using the significant difference method, water vapor flux models, hydrochemistry, isotopes, and other methods for cause analyses. The results indicate the following: (1) There are differences in hydrochemistry between the southern and northern basins because the southern basin is more influenced by the dissolution of salt rocks and evaporation, whereas the northern basin is mainly affected by carbonate weathering. (2) The enrichment of δD and δ18O in the northern basin gradually increases from west to east, while in the southern basin, it is the opposite. This is because the southern basin receives a larger contribution of water vapor from the mid-latitude westerlies, while the northern basin primarily relies on local evaporation as its water vapor source. (3) Significant differences are observed in the total dissolved solids (TDS) and hydrochemical types of river water and groundwater between the summer and winter due to higher rates of rock weathering and evaporation in the summer. (4) The more pronounced seasonal differences in hydrogen and oxygen stable isotopes in the southern basin are due to higher rates of internal water vapor circulation in the summer. (5) The similarity in characteristics between river water and groundwater is the result of strong exchanges between river water and groundwater from piedmonts to terminals. The spatiotemporal heterogeneity of terminal lakes is attributed to the accumulation of salts and groundwater replenishment from other sources.

Topographic influence on ecohydrology in volcanic watersheds of the western Pacific monsoon area: evidence from water stable isotope composition of meteoric water, thermal water, and plants

ABSTRACT In Taiwanese volcanic watersheds, we investigated stable water isotopes in meteoric water, plants, and thermal water. Meteoric water exhibited a seasonal cycle, with heavier isotopes in winter and lighter ones in summer, especially in the southern region. The northern monsoon signal lagged the south by two weeks. In the Tatun mountains, young water fractions indicated prevalent old water sources. In the northern watershed, streamwater mainly came from the winter monsoon, while the southern one was influenced by alternating monsoons. Both indices indicated that winter plants depended on summer rainfall. Streamwater and plants had distinct sources in winter, supporting ecohydrological separation. Thermal spring water’s d-excess helped identify water–rock interactions, with low d value signaling such interactions. The topographic wetness index showed a higher summer monsoon contribution to southern streamwater but a lower one to plants. The mean linear channel direction significantly affected the monsoon contribution fraction, with northeast-oriented channels vulnerable to northeastward winter monsoons. Finally, we developed a model illustrating hydrological processes on short and long timescales. Our findings enhance our understanding of hydrological disturbances’ impact on water resources and ecosystems.

A Comprehensive Biogeochemical Assessment of Climate‐Threatened Glacial River Headwaters on the Eastern Slopes of the Canadian Rocky Mountains

AbstractClimate change is driving the loss of alpine glaciers globally, yet investigations about the water quality of rivers stemming from them are few. Here we provide an overview assessment of a biogeochemical data set containing 200+ parameters that we collected between 2019 and 2021 from the headwaters of three such rivers (Sunwapta‐Athabasca, North Saskatchewan, and Bow) which originate from the glacierized eastern slopes of the Canadian Rocky Mountains. We used regional hydrometric data sets to accurately model discharge at our 14 sampling sites. We created a Local Meteoric Water Line (LMWL) using riverine water isotope signatures and compared it to collected regional rain, snow, and glacial ice signatures. Principal component analyses of river physicochemical measures revealed distance from glacier explained more data variability than other spatiotemporal factors (i.e., season, year, or river). Discharge, chemical concentrations, and watershed areas were then used to model site‐specific open water season yields for 25 parameters. Chemical yields followed what would generally be expected along river continuums from glacierized to montane altitudinal life zones, with landscape characteristics driving chemical sources and sinks. For instance, particulate chemical yields were generally highest near source glaciers with proglacial lakes acting as settling ponds, whereas most dissolved yields varied by parameter and site. As these headwaters continue to evolve with glacier mass loss, the data set and analyses presented here can be used as a contemporary baseline to mark future change against. Further, following this initial assessment of our data set, we encourage others to mine it for additional biogeochemical studies.

Application of gas chromatography-stable isotope mass spectrometry to determine the oxygen isotope ratio of water in concentrated fruit juice

In this study, we developed a method to determine the authenticity of concentrated fruit juice using the δ18O ratio of water. We utilized the gas chromatography-isotope ratio mass spectrometry (GC-IRMS) technique along with the offline isotope exchange equilibrium method to pretreat and measure the oxygen isotopes in water in concentrated apple juice. This innovative approach uses anhydrous ethanol as a solvent to dissolve concentrated juices, thereby facilitating a more comprehensive reaction between the water in the sample and the CO2 standard gas. Additionally, the reaction vessel exhibits excellent air tightness, ensuring rapid equilibrium time and enabling accurate determination of δ18O in the water content of concentrated juice. The reaction vessel had excellent air tightness and rapid equilibration time, enabling accurate measurement of δ18O of water in concentrated fruit juice. The reaction vessel used had excellent air tightness and rapid equilibration time, ensuring accurate measurement of the δ18O of water in concentrated fruit juice. We analyzed 40 samples of concentrated apple juice and found that the range of δ18O values in the water of concentrated apple juice was between 1.29 ‰ and 7.59 ‰. Additionally, we used prepared sucrose syrup as a simulated sample and found that the δ18O distribution range was between −10.43 ‰ and −10.53 ‰. Furthermore, we conducted adulteration simulation experiments on randomly selected real samples and discovered a linear negative correlation between the adulteration ratio and the δ18O value of water in the samples.

Seasonal distribution of water masses and their impacts on nutrient supply in the southern Beibu Gulf

Dual water isotopes were investigated to reveal the seasonal distribution of water masses and their impacts on nutrient supply in southern Beibu Gulf. In summer and winter, the South China Sea (SCS) water (61–69%) contributed the most to the seawater in the southern Beibu Gulf, followed by the diluted water (24–34%), and the west-Guangdong coastal current (WGCC) (5–7%) had the minimum contribution. However, the major nutrient source shifted from the diluted water in summer (39–73%) to the SCS water (57–90%) in winter. The WGCC's impact on nutrient loads was relatively small (2–10% in summer, 4–34% in winter). Our results highlight the control of nutrient supply was the SCS water (winter) and diluted water (summer), with limited influence from the WGCC, providing new insights into the impact of water mass transportation and its nutrient supply in the Beibu Gulf.

Surface occurrence of dawsonite and natural CO2 emanation in Covasna, in the Eastern Carpathians: A stable isotope study

Dawsonite (NaAlCO3(OH)2) is widely known as a CO2 trapping mineral during the geological storage of CO2 (Carbon Capture and Storage). Dawsonite can occur naturally in various geological environments, however only few surface occurrences are known. The Covasna area (Eastern Carpathians) gives an excellent opportunity to study dawsonite in surface outcrop in the Hankó Valley and extend our knowledge about the possible precipitation environments of dawsonite. Based on the detailed petrographic and geochemical investigations of the rock and water samples from this area, formation environment of dawsonite and the concomitant mineral assemblage (e.g. alumohydrocalcite) were constrained. Based on our results, dawsonite and alumohydrocalcite formed at low temperature (7.6–20 °C). Utilizing the stable carbon, oxygen and hydrogen isotope composition of dawsonite separates (δ13CDaw: +8.0 − +10.1 ‰, δ18ODaw: +40.7 − +46.7 ‰, δ2HDaw: −55 - -42 ‰), the isotopic composition of the parental fluid was determined. Our results indicate that the dawsonite formed from a CO2 source, which has mantle origin. In addition, H2O which was present during the formation of dawsonite, had similar hydrogen isotope composition to recent spring waters, whereas the oxygen isotope composition is characterized by more positive values. This oxygen shifts relative to Global Meteoric Waterline might be related to water-rock interaction or contribution of metamorphic/magmatic water and oxygen isotope exchange between H2O and CO2.

Effects of urbanization on the water cycle in the Shiyang River basin: based on a stable isotope method

Abstract. In water-scarce arid areas, the water cycle is affected by urban development and natural river changes, and urbanization has a profound impact on the hydrological system of the basin. Through an ecohydrological observation system established in the Shiyang River basin in the inland arid zone, we studied the impact of urbanization on the water cycle of the basin using isotope methods. The results showed that urbanization significantly changed the water cycle process in the basin and accelerated the rainfall-runoff process due to the increase in urban land area, and the mean residence time (MRT) of river water showed a fluctuating downward trend from upstream to downstream and was shortest in the urban area in the middle reaches, and the MRT was mainly controlled by the landscape characteristics of the basin. In addition, our study showed that river water and groundwater isotope data were progressively enriched from upstream to downstream due to the construction of metropolitan landscape dams, which exacerbated evaporative losses of river water and also strengthened the hydraulic connection between groundwater and river water around the city. Our findings have important implications for local water resource management and urban planning and provide important insights into the hydrologic dynamics of urban areas.

Control of the temperature signal in Antarctic proxies by snowfall dynamics

Abstract. Antarctica, the coldest and driest continent, is home to the largest ice sheet, whose mass is predominantly recharged by snowfall. A common feature of polar regions is the warming associated with snowfall, as moist oceanic air and cloud cover increase the surface temperature. Consequently, snow that accumulates on the ice sheet is deposited under unusually warm conditions. Here we use a polar-oriented regional atmospheric model to study the statistical difference between average and snowfall-weighted temperatures. During snowfall, the warm anomaly scales with snowfall amount, with the strongest sensitivity occurring at low-accumulation sites. Heavier snowfall in winter helps to decrease the annual snowfall-weighted temperature, but this effect is overwritten by the event-scale warming associated with precipitating atmospheric systems, which particularly contrast with the extremely cold conditions that occur in winter. Consequently, the seasonal range of snowfall-weighted temperature is reduced by 20 %. On the other hand, the annual snowfall-weighted temperature shows 80 % more interannual variability than the annual temperature due to the irregularity of snowfall occurrence and its associated temperature anomaly. Disturbances of the apparent annual temperature cycle and interannual variability have important consequences for the interpretation of water isotopes in precipitation, which are deposited with snowfall and commonly used for paleotemperature reconstructions from ice cores.

Detection of dilution due to turbulent mixing vs. precipitation scavenging effects on biomass burning aerosol concentrations using stable water isotope ratios during ORACLES

Abstract. The interaction between biomass burning aerosols and clouds remains challenging to accurately determine, in part because of difficulties using direct observations to account for influences on aerosol concentrations from precipitation scavenging and dilution due to air mass mixing and separating those signals from source contributions. The prevalence of mixing versus precipitation processes in air laden with biomass burning aerosol (BBA) in the southeast Atlantic lower free troposphere (FT) and marine boundary layer (MBL) is assessed during three observation periods (September 2016, August 2017, and October 2018) during the NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) campaign. Significant sources of BBAs over the African continent combined with regional circulation patterns result in BBA-laden air flowing from the continent over the southeast Atlantic in the lower FT, then subsiding onto the semi-permanent stratocumulus cloud deck, and entraining into the MBL. This study is broken into two parts, first analyzing hydrologic histories of the BBA air in the lower FT and then carrying out a similar assessment in the underlying MBL. Both analyses leverage joint measurements of water concentration and its heavy isotope ratio, interpreted in the previously established (q, δD) phase space framework. For the lower-FT analysis, in situ observations (water concentration, water isotope ratios) in the lower FT are combined with satellite and Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2), global reanalysis data into simple analytical models to constrain hydrologic histories. We find that even simple models are capable of detecting and constraining the primary processes at play, e.g., distinguishing air masses that experienced moist convection and precipitation (likely over the continent) from those that underwent dry convection and turbulent mixing. Regression of the aircraft data onto a simple model of convective detrainment is used to develop a metric of total precipitation for the in situ measurements and then compared to an aerosol metric of black carbon scavenging also derived from the in situ measurements (the ratio of black carbon to carbon monoxide, BC/CO). There is a strong correlation between the two, suggesting black carbon scavenging has been detected and partially quantified, if only in a relative manner. In comparison, weak correlation is found between BC/CO and the total water concentration itself. The above method is expanded to test for entrainment and precipitation influences on BBA concentrations in the MBL. This is more difficult than the FT analysis since signals are subtle and limited by imperfect knowledge of the water and isotope ratios of the entrained air mass at cloud top. For some of the MBLs observed during 2016 and 2018, lower cloud condensation nuclei (CCN) concentrations occur in the sub-cloud layer coincident with isotopic evidence of precipitation, indicating aerosol scavenging, but more complex models are needed to produce definitive conclusions. For the 2017 observation period, with the highest sub-cloud CCN concentrations, there is no connection between precipitation signals and CCN concentrations, likely indicating the importance of different geographic sampling and air mass history in that year. Nonetheless, these findings along with the FT analysis suggest that utilizing isotope ratio signals may be an aid in addressing cloud–aerosol challenges. Especially for the FT case, these findings support the pursuit of more complex models combined with targeted in situ data to constrain BC scavenging coefficients in a manner which can guide model parameterizations, leading to improvements in the accuracy of simulated BC concentrations and lifetimes in climate models.

Investigating the Seasonal Variations of Event, Recent, and Pre-Recent Runoff Components in a Pre-Alpine Catchment using Stable Isotopes and an Iterative Hydrograph Separation Approach

An analysis of the runoff generation processes in terms of event, recent, and pre-recent runoff components is demonstrated for the Swiss pre-Alpine Alp catchment (46.4 km2) and two smaller tributaries (Erlenbach, 0.7 km2, and Vogelbach, 1.6 km2), whereas, recent water is understood as the contribution of the respective three prior rainfall-runoff events. A four-years time series of daily stable water isotope data in stream water and precipitation is used for the analysis of seasonal variations. In addition, high-frequency data (10 minutely intervals) are used for a detailed visualization of the rapid mobilization of recent water for single events. An iterative extension of the standard two-component hydrograph separation method is applied; this approach can be interpreted as a discretization of the catchment water and tracer mass balance along the event and pre-event time axis. Furthermore, the calculated event, recent, and pre-recent runoff components can be used to estimate time-varying backward travel time distributions.

Use of the nitrogen/ oxygen isotope fractionation technique for tracing nitrogen removal from activated sludge in municipal wastewater treatment plants

The dual isotope fractionation technique of nitrogen and oxygen has been successfully applied to analyze microbially-driven nitrogen transformations and partitioning in aquatic ecosystems, but not in municipal water treatment facilities. Nitrogen removal efficiency in wastewater treatment plants using activated sludge is critical and difficult to monitor. Here, we tested the nitrogen and oxygen isotope fractionation technique for capacity to trace nitrogen removal from municipal wastewater. Long-term monitoring of Anaerobic/anoxic/aerobic (A2/O) process municipal wastewater treatment plants revealed that nitrogen removal performance gradually improved with increasing seasonal temperatures. The δ15N value of activated sludge increased from 5.18‰ (January) to 6.37‰ (June). An increase in temperature promoted the increase in NO3--N from 1.23 mg/L (January) to 6.06–7.02 mg/L (June to August) in the aerobic reaction. The δ15NNO3 decreased from 17.82‰ to 37.37‰ to 4.09–17.68‰, and variability in utilization of light and heavy isotopes gradually decreased. The slope of the ratio δ15NNO3:δ18ONO3 gradually decreased from 21.58 ± 12.15 (January) to 0.57 ± 0.51 (August). The dynamic response of δ15N values in sludge and isotopes in water revealed the migration transformation of nitrogen and realized the differential analysis to denitrification performance with seasonality. It also provided a technical basis for long-term stable nitrogen removal system.

Isotopic and Remote Sensing-Based Characterisation of a Rainfall Event over Western Sierra de Gádor (Spain): Implications for Carbonate Aquifer Recharge

Stable water isotopes are widely recognised as essential tools to trace processes within the hydrological cycle and to disentangle complex phenomena, such as regional–local atmospheric patterns, infer water balances or characterise the aquifer recharge. In this work, we characterised two post-summer precipitation events over the western sector of Sierra de Gádor through the analysis of the rainwater δ18O and δ2H ratios, ionic composition and, complementarily, remote sensing products to define the atmospheric circulation during the rainfall episodes. This information enabled us to discern the moisture source, formation conditions and orographic influence on the rain episodes, and to better define the origin of the groundwater recharge and its dynamics in the study area. Although the samples share a common moisture source (W Mediterranean), they display substantial differences in their isotopic compositions. Such differences are attributable to sub-cloud evaporation processes that mask their Mediterranean origin, and to the strong influence of the orography on the hydrochemical and isotopic characteristics of the rainfall at the local level. The groundwater presents a very stable isotopic content and is strongly depleted in heavy isotopes, evidencing that most of the aquifer recharge takes place at very high altitudes and primarily during winter, when the influence of evaporation is attenuated.

Quantitative delineation of water sources in the river Ganga using stable water isotopes

AbstractQuantitative delineation of water sources in a large river system is essential for the sustainable use of water. In the present study, we have tested two different methodologies to estimate the contribution from different water sources in the river Ganga. The first model uses stable isotopes and physicochemical parameters of water to delineate the contribution of glacier‐melt, groundwater, and surface runoff in different stretches of the river Ganga. The end member‐based mixing model provides glacier‐melt contribution of ~31.2%, ~5.5%, and ~0.5% in the upper, middle, and lower stretch of the river Ganga. The model showed maximum contribution from groundwater (~66.3%) in the middle stretch and surface runoff (~57.2%) in the lower stretch of the river Ganga. However, the uncertainties in the estimates from the three‐component mixing model were significantly high due to temporal variability in the end member values. To provide estimates with lower uncertainty, an alternate method (discharge dependent budget estimation [DDBE]) has been proposed which delineates the contribution of groundwater and surface runoff in small segments of the river. The DDBE model confines the calculation for budget estimates to smaller segments of the river and hence leads to lower uncertainties in the results, providing improved systematic estimation of water budget for large river systems. In the present study, estimates from the DDBE model suggest that groundwater contributes ~79% of the additional water whereas the contribution from surface runoff is ~21% in the middle and lower stretch of the river Ganga. The DDBE model was successfully applied in 5 small segments along the stretch of the river Ganga and the methodology used shows great potential for systematic delineation of water sources in large river system.

From atmospheric water isotopes measurement to firn core interpretation in Adélie Land: a case study for isotope-enabled atmospheric models in Antarctica

Abstract. In a context of global warming and sea level rise acceleration, it is key to estimate the evolution of the atmospheric hydrological cycle and temperature in polar regions, which directly influence the surface mass balance of the Arctic and Antarctic ice sheets. Direct observations are available from satellite data for the last 40 years and a few weather data since the 1950s in Antarctica. One of the best ways to access longer records is to use climate proxies in firn or ice cores. The water isotopic composition in these cores is widely used to reconstruct past temperature variations. We need to progress in our understanding of the influence of the atmospheric hydrological cycle on the water isotopic composition of ice cores. First, we present a 2-year-long time series of vapor and precipitation isotopic composition measurement at Dumont d’Urville Station, in Adélie Land. We characterize diurnal variations of meteorological parameters (temperature, atmospheric water mixing ratio (hereafter humidity) and δ18O) for the different seasons and determine the evolution of key relationships (δ18O versus temperature or humidity) throughout the year: we find that the temperature vs. δ18O relationship is dependent on synoptic events dynamics in winter contrary to summer. Then, this data set is used to evaluate the atmospheric general circulation model ECHAM6-wiso (model version with embedded water stable isotopes) in a coastal region of Adélie Land where local conditions are controlled by strong katabatic winds which directly impact the isotopic signal. We show that a combination of continental (79 %) and oceanic (21 %) grid cells leads model outputs (temperature, humidity and δ18O) to nicely fit the observations, at different timescales (i.e., seasonal to synoptic). Therefore we demonstrate the added value of long-term water vapor isotopic composition records for model evaluation. Then, as a clear link is found between the isotopic composition of water vapor and precipitation, we assess how isotopic models can help interpret short firn cores. In fact, a virtual firn core built from ECHAM-wiso outputs explains much more of the variability observed in S1C1 isotopic record than a virtual firn core built from temperature only. Yet, deposition and post-deposition effects strongly affect the firn isotopic signal and probably account for most of the remaining misfits between archived firn signal and virtual firn core based on atmospheric modeling.

Effects of global and climate change on the freshwater-seawater interface movement in a Mediterranean karst aquifer of Mallorca Island

Karst aquifers are globally prized freshwater sources, posing a significant preservation challenge. These aquifers typically exhibit dual or even triple porosities, encompassing matrix, fractures-fissures and conduits, rendering them highly responsive to variations in chemical characteristics and hydraulic head. In coastal regions, these aquifers often possess extensive subsurface conduit networks intricately linked to the rock matrix, facilitating groundwater discharge into the sea. Therefore, they display acute sensitivity to seawater intrusion, swiftly reacting to changes in precipitation and pumping regimes. This makes them exceptionally vulnerable to short-term meteorological fluctuations and long-term climate change. Their high heterogeneity leads to uneven penetration of the freshwater-seawater interface, causing rapid seawater intrusion inland over significant distances. The Mediterranean region, characterized by water deficit and water stress, faces strong impacts from climate change, featuring a warming atmospheric trend exceeding the global average, along with diminished rainfall exacerbating water scarcity. Increasing water demands for agriculture, urban development, and the growing tourism industry, because of global change, are worsening water stress. Our primary research objectives were analyzing the environmental consequences of global and climate change on seawater intrusion in Mediterranean coastal karst aquifers, with a focus on the role of the double-flow model, thus contributing to the understanding of the processes involved. To achieve this, we selected a study region on Mallorca Island in the western Mediterranean, where a karst aquifer system discharges into the sea. We employed various study methods, notably hydrochemical techniques and multi-isotopic analysis, encompassing the examination of 2H and 18O isotopes in water, 87Sr/86Sr ratio, Sr and B concentrations, and δ11B in water. A key finding is the rebound effect, wherein aquifers recontaminate due to solute molecular back-diffusion following cessation of extractions and the retreat of marine intrusion, providing insight into the impact of climate and global change on Mediterranean karst aquifers.

Isotopic evolutionary track of water due to interaction with rocks and its use for tracing water cycle through the lithosphere

Hydrogen and oxygen isotopic compositions of natural spa waters from hot and/or mineral-rich springs (including flowing/pumping wells) potentially provide important clues about water cycle in Earth's interior, because some of the waters are deep-seated and non-meteoric. However, the isotopic compositions of these waters are typically altered by contamination with meteoric water and are thus poorly known. To reconstruct their original (i.e., before these waters mix with meteoric water) isotope compositions, here we develop an isotopic evolution model of the lithosphere-enclosed waters and derive the “ocean-origin lithospheric water curve” (OLWC; δ2H = 60 / (δ18O – 11)) as a typical evolutionary track starting from ocean water. Then we apply them to spa waters from central Japan, a globally unique geotectonic region where double subduction of slabs occurs. The OLWC explains well observed isotope data of subseafloor pore waters, submarine mud volcano pore waters, coastal oil-field brines, and subduction zone volcanic steam. Mixing analysis indicates that lithospheric water accounts for 19–95 % of each spa water we investigated. The nonlinear relationships of the reconstructed water δ18O and Cl or Li concentrations justify our hypothesis that the lithospheric waters are undergoing evolution from ocean water to magmatic water by rock-water isotopic exchange and that they are not simply mixtures of the two. A comparison of the reconstruction results with model predictions under slab subduction settings suggests that most spa waters in the southern to central part of the study region contain progressively evolving lithospheric waters released from the subducting Philippine Sea slab, and that a few at western edge of the region contain waters released from the Pacific slab. The others in the northern and eastern part of the region contain waters at the early-to-mid evolutionary stage, which are discharged from Tertiary marine sedimentary rocks (including tuffs). All these waters were enclosed in the lithosphere for more than 1–5 Ma. Our approach provides useful tools for tracing sources of non-meteoric water and highlights water cycle through lithosphere for more than one million years.

Preservation of chemical and isotopic signatures within the Weißseespitze millennial old ice cap (Eastern Alps), despite the ongoing ice loss

Alpine ice core research has long focused on a few suitable drilling sites at high elevation in the Western European Alps, assuming that the counterparts at lower elevation in the eastern sector are unsuitable for paleoenvironmental studies, due to the presence of melting and temperate basal conditions. However, it has been demonstrated that even in the Eastern Alpine range, below 4,000 m a.s.l., cold ice frozen to bedrock can exist. In fact, millennial-old ice has been found at some locations, such as at the Weißseespitze (WSS) summit ice cap (Ӧtztal Alps, 3,499 m a.s.l.), where about 6 kyrs appear locked into 10 m of ice. In this work, we present a full profile of the stable water isotopes (δ18O, δ2H), major ions (Na+, K+, Mg2+, Ca2+, NH4+, Cl−, NO3−, SO42−), levoglucosan, and microcharcoal for two parallel ice cores drilled at the Weißseespitze cap. We find that, despite the ongoing ice loss, the chemical and isotopic signatures appear preserved, and may potentially offer an untapped climatic record. This is especially noteworthy considering that chemical signals of other archives at similar locations have been partially or full corrupted by meltwater (i.e., Silvretta glacier, Grand Combin glacier, Ortles glacier). In addition, the impurity concentration near the surface shows no signs of anthropogenic contamination at WSS, which constrains the age at the surface to fall within the pre-industrial age.

Modeling Water Isotopes Using a Global Non‐Hydrostatic Model With an Explicit Convection: Comparison With Gridded Data Sets and Site Observations

AbstractIn this study, we developed a global cloud system‐resolving model (GCSRM) incorporating stable water isotopes (NICAM‐WISO). Using a single‐moment cloud microphysics scheme, we applied the new model to conduct a current climate simulation at a horizontal resolution of 56 km. NICAM‐WISO simulated the seasonal means of the atmospheric hydrological cycle, as well as water isotopic ratios of precipitation and vapor. The model captured the general features of precipitation isotope effects and its spatial correlations were comparable to those of other isotope‐incorporated global atmospheric models. The model showed better spatial correlation between simulated and observed values for a fine‐horizontal‐resolution (14 km) simulation compared to coarse‐horizontal‐resolution (56 km) simulation. However, the model had isotopic biases in tropical mid‐troposphere, ocean, and cold continental regions. A comparison of stable water isotopes between the simulation and observations offered clues for improving the model. For example, in the tropical mid‐troposphere, we found a negative bias in the mixing ratio and isotopic ratio of water vapor. Our analysis using satellite retrievals revealed that these underestimations were caused by weak mixing with the boundary layer vapor and low raindrop evaporation with a small evaporation fraction. The underestimations indicated weak shallow convective mixing in the model, inducing negative bias in the mixing ratio and isotopic ratio of the mid‐tropospheric vapor. These biases were also seen in the fine horizontal‐resolution simulation. Furthermore, we conducted several km‐scale atmospheric isotope circulation simulations using NICAM‐WISO. We expect that global‐scale fine‐horizontal‐resolution simulations using isotope‐incorporated GCSRMs will improve our understanding of the atmospheric hydrological cycle.

Global diagnosis of land–atmosphere coupling based on water isotopes

Land–atmosphere coupling (LAC) plays a significant role in weather and climate and is related to droughts and heatwaves. We propose a simple and efficient LAC diagnosis method based on the analysis of water isotopes in atmospheric water vapour and precipitation. Using the method, we identify the primary LAC hotspot regions of the globe and reveal the seasonality of LAC strength. We find that LAC strength exhibits a relationship with latitude. Low latitudes present stronger LAC strength and contribute more significantly to the overall LAC area compared to boreal middle and high latitudes. It's important to note that LAC primarily manifests in the troposphere and is detected in the lower stratosphere of low latitudes, with limited influence observed in the stratosphere. However, the impact of LAC is noticeable in the upper stratosphere in boreal middle and high latitudes. Moreover, the seasonality of LAC strength is pronounced. On a global scale, the season with the strongest LAC is boreal autumn in the Northern Hemisphere but boreal summer in the Southern Hemisphere. Notably, this pattern does not exhibit a seesaw effect between the two hemispheres. Our isotope-based LAC diagnosis method captures the major LAC hotspots found in previous work and validates the seasonality of LAC within these hotspots. This substantiates the reliability and effectiveness of our isotope-based approach.

Radium Isotopes as Tracers of Shelf‐Basin Exchange Processes in the Eastern Arctic Ocean

AbstractRadium isotopes, which are sourced from sediments, are useful tools for studying potential climate‐driven changes in the transfer of shelf‐derived elements to the open Arctic Ocean. Here we present observations of radium‐228 and radium‐226 from the Siberian Arctic, focusing on the shelf‐basin boundary north of the Laptev and East Siberian Seas. Water isotopes and nutrients are used to deconvolve the contributions from different water masses in the study region, and modeled currents and water parcel back‐trajectories provide insights on water pathways and residence times. High radium levels and fractions of meteoric water, along with modeled water parcel back‐trajectories, indicate that shelf‐ and river‐influenced water left the East Siberian Shelf around 170°E in 2021; this is likely where the Transpolar Drift was entering the central Arctic. A transect extending from the East Siberian Slope into the basin is used to estimate a radium‐228 flux of 2.67 × 107 atoms m−2 d−1 (possible range of 1.23 × 107–1.04 × 108 atoms m−2 d−1) from slope sediments, which is comparable to slope fluxes in other regions of the world. A box model is used to determine that the flux of radium‐228 from the Laptev and East Siberian Shelves is 9.03 × 107 atoms m−2 d−1 (possible range of 3.87 × 107–1.56 × 108 atoms m−2 d−1), similar to previously estimated fluxes from the Chukchi Shelf. These three shelves contribute a disproportionately high amount of radium to the Arctic, highlighting their importance in regulating the chemistry of Arctic surface waters.