Sublimation Of Water Ice Research Articles

Experimental and theoretical simulations of ice sublimation with implications for the chemical, isotopic, and physical evolution of icy objects

Recent ground-based and spacecraft observations of comets in the inner solar system reveal two distinct features that provide important insight into their origin and evolution. The first of these is the observation that the D/H ratio of water vapor in cometary comae is significantly higher than that in Vienna Standard Mean Ocean Water (VSMOW). The second observation is that cometary jets are bursty (i.e, roughly steady state emissions that are punctuated with short-lived outbursts of water vapor and other materials) (Hughes, 1990; Soderblom et al., 2002; Soderblom et al., 2004a; Soderblom et al., 2004b). We present an experimental and theoretical study of ice sublimation in a vacuum that reveals several heretofore unknown and fundamental characteristics about the kinetics and mechanisms of ice sublimation that may explain both of these observed phenomena. In particular, we observe quasi-periodic sublimation cascades on time scales of hours to days, the D/H ratio in the vapor issuing from the sample is in general different from that of the sample, and in many cases, quasi-periodic changes in the D/H ratio of the vapor accompany the sublimation cascades. Changes are also observed in the infrared spectrum of the sample before, during and after a cascade that are consistent with our hypothesis that vacuum sublimation of water ice is a diffusive process that works to leave behind the most strongly bound molecules. Finally, we speculate as to whether the effects observed in the lab can be extrapolated to cometary-nucleus-scale phenomena.

THE DUST ENVIRONMENT OF MAIN-BELT COMET P/2010 R2 (LA SAGRA)

We present a model of the dust environment of Main-Belt Comet P/2010 R2 (La Sagra) from images acquired during the period 2010 October-2011 January. The tails are best simulated by anisotropic ejection models, with emission concentrated near the nucleus south pole, the spin axis having an obliquity near 90{sup 0}, indicative of a possible seasonally driven behavior. The dust mass loss rate increases rapidly shortly before perihelion, reaching a maximum value of {approx}4 kg s{sup -1}, and maintaining a sustained, cometary-like, activity of about 3-4 kg s{sup -1} up to at least 200 days after perihelion, the date of the latest observation. The size distribution function is characterized by particles in the 5 x 10{sup -4} cm to 1 cm radius range, assuming a time-constant power-law distribution with an index of -3.5. The ejection velocities are compatible with water-ice sublimation activity at the heliocentric distance of 2.7 AU, with values of 10-20 cm s{sup -1} for particle radius of 1 cm, and inverse square root dependence on particle size, typical of hydrodynamical gas drag.

NEAR-INFRARED OBSERVATIONS OF COMET-LIKE ASTEROID (596) SCHEILA

Asteroid (596) Scheila was reported to exhibit a cometary appearance and an increase in brightness on UT 2010 December 10.4. We used the IRCS spectrograph on the 8 m Subaru telescope to obtain medium-resolution spectra of Scheila in the HK band (1.4–2.5 μm) and low-resolution spectra in the KL band (2.0–4.0 μm) on UT 2010 December 13 and 14. In addition, we obtained low-resolution spectroscopy using the SpeX spectrograph on the 3 m NASA Infrared Telescope Facility on UT 2011 January 4 and 5. The spectrum of Scheila shows a consistent red slope from 0.8 to 4.0 μm with no apparent absorption features, resembling spectra of D-type asteroids. An intimate mixing model suggests that the amount of water ice that might be present on the surface of Scheila is no more than a few percent. The spectrum of the Tagish Lake chondrite matches the asteroid's spectrum at shorter wavelengths (λ < 2.5 μm), but no hydration features are observed at longer wavelengths on Scheila. Our analysis corroborates other studies suggesting that the comet-like activity of Scheila is likely not caused by the sublimation of water ice. The dust coma and tail may be results of a recent impact event.

Outgassing of icy bodies in the Solar System – I. The sublimation of hexagonal water ice through dust layers

Our knowledge about the physical processes determining the activity of comets were mainly influenced by several extremely successful space missions (Giotto, Deep Space I, Stardust, Deep Impact and EPOXI), the predictions of theoretical models and the results of laboratory experiments. However, novel computer models should not be treated in isolation but should be based on experimental results and should be verified and calibrated by experimental work. Therefore, a new experimental setup was constructed to investigate the temperature dependent sublimation properties of hexagonal water ice and the gas diffusion through a dry dust layer covering the ice surface. We show that this experimental setup is capable to reproduce known gas production rates of pure hexagonal water ice. The reduction of the gas production rate due to an additional dust layer on top of the ice surface was measured and compared to the results of another experimental setup in which the gas diffusion through dust layers at room temperature was investigated. We found that the relative permeability of the dust layer is inversely proportional to its thickness, which is also predicted by theoretical models. However, the measured absolute weakening of the gas flow was smaller than predicted by models. This lack of correspondence between model and experiment may be caused by an ill-determination of the boundary condition in the theoretical models, which further demonstrates the necessity of laboratory investigations. Furthermore, the impedance of the dust layer to the ice evaporation was found to be similar to the impedance at room temperature, which means that the temperature profile of the dust layer is not influencing the reduction of the gas production. Finally, we present the results of an extended investigation of the sublimation coefficient, which is an important factor for the description of the sublimation rate of water ice and, thus, an important value for thermophysical modeling of icy bodies in the Solar System. The achieved results of this laboratory investigations demonstrate that experimental works are essential for the understanding of the origin of cometary activity.

Thermal model of water and CO activity of Comet C/1995 O1 (Hale-Bopp)

An investigation of the activity of Comet C/1995 O1 (Hale-Bopp) with a thermophysical nucleus model that does not rely on the existence of amorphous ice is presented. Our approach incorporates recent observations allowing to constrain important parameters that control cometary activity. The model accounts for heat conduction, heat advection, gas diffusion, sublimation, and condensation in a porous ice–dust matrix with moving boundaries. Erosion due to surface sublimation of water ice leads to a moving boundary. The movement of the boundary is modeled by applying a temperature remapping technique which allows us to account for the loss in the internal energy of the eroded surface material. These kind of problems are commonly referred to as Stefan problems. The model takes into account the diurnal rotation of the nucleus and seasonal effects due to the strong obliquity of Hale-Bopp as reported by Jorda et al. (Jorda, L., Rembor, K., Lecacheux, J., Colom, P., Colas, F., Frappa, E., Lara, L.M. [1997]. Earth Moon Planets 77, 167–180). Only bulk sublimation of water and CO ice are considered without further assumptions such as amorphous ices with certain amount of occluded CO gas. Confined and localized activity patterns are investigated following the reports of Lederer and Campins (Lederer, S.M., Campins, H. [2002]. Earth Moon Planets 90, 381–389) about the chemical heterogeneity of Hale-Bopp and of Bockelée-Morvan et al. (Bockelée-Morvan, D., Henry, F., Biver, N., Boissier, J., Colom, P., Crovisier, J., Despois, D., Moreno, R., Wink, J. [2009]. Astron. Astrophys. 505, 825–843) about a strong CO source at a latitude of 20°. The best fit to the observations of Biver et al. (Biver, N. et al. [2002]. Earth Moon Planets 90, 5–14) is obtained with a low thermal conductivity of 0.01 W m −1 K −1. This is in agreement with recent results of the Deep Impact mission to 9P/Tempel 1 (Groussin, O., A’Hearn, M.F., Li, J.-Y., Thomas, P.C., Sunshine, J.M., Lisse, C.M., Meech, K.J., Farnham, T.L., Feaga, L.M., Delamere, W.A. [2007]. Icarus 187, 16–25) and with previous thermal simulations (Kührt, E. [1999]. Space Sci. Rev. 90, 75–82). The water production curve matches the production rates well from −4 AU pre-perihelion to the outgoing leg while the model does not reproduce so well the water production beyond 4 AU pre-perihelion. The CO production curve is a good fit to the measurements of Biver et al. (2002) over the whole measured heliocentric range from −7 AU pre- to 15 AU post-perihelion.

Herschelobservations of EXtra-Ordinary Sources (HEXOS): Observations of H2O and its isotopologues towards Orion KL

We report the detection of more than 48 velocity-resolved ground rotational state transitions of H2(16)O, H2(18)O, and H2(17)O - most for the first time - in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H2(18)O line fluxes, which are less affected by line opacity than their H2(16)O counterparts, and an escape probability method, the column densities of H2(18)O associated with each emission component are derived. We infer total water abundances of 7.4E-5, 1.0E-5, and 1.6E-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources.

Dust tail of the active distant Comet C/2003 WT42 (LINEAR) studied with photometric and spectroscopic observations

We present the study of dust environment of dynamically new Comet C/2003 WT42 (LINEAR) based on spectroscopic and photometric observations. The comet was observed before and after the perihelion passage at heliocentric distances from 5.2 to 9.5 AU. Although the comet moved beyond the zone where water ice sublimation could be significant, its bright coma and extended dust tail evidenced the high level of physical activity. Afρ values exceeded 3000 cm likely reaching its maximum before the perihelion passage. At the same time, the spectrum of the comet did not reveal molecular emission features above the reflected continuum. Reddening of the continuum derived from the cometary spectrum is nonlinear along the dispersion with the steeper slop in the blue region. The pair of the blue and red continuum images was analyzed to estimate a color of the comet. The mean normalized reflectivity gradient derived from the innermost part of the cometary coma equals to 8% per 1000 Å that is typical for Oort cloud objects. However, the color map shows that the reddening of the cometary dust varies over the coma increasing to 15% per 1000 Å along the tail axis. The photometric images were fitted with a Monte Carlo model to construct the theoretical brightness distribution of the cometary coma and tail and to investigate the development of the cometary activity along the orbit. As the dust particles of distant comets are expected to be icy, we propose here the model, which describes the tail formation taking into account sublimation of grains along their orbits. The chemical composition and structure of these particles are assumed to correspond with Greenberg’s interstellar dust model of comet dust. All images were fitted with the close values of the model parameters. According to the results of the modeling, the physical activity of the comet is mainly determined by two active areas with outflows into the wide cones. The obliquity of the rotation axis of the nucleus equals to 20° relative to the comet’s orbital plane. The grains occupying the coma and tail are rather large amounting to 1 mm in size, with the exponential size distribution of a −4.5. The outflow velocities of the dust particles vary from a few centimeters to tens of meters per second depending on their sizes. Our observations and the model findings evidence that the activity of the nucleus decreased sharply to a low-level phase at the end of April–beginning of May 2007. About 190 days later, in the first half of November 2007 the nucleus stopped any activity, however, the remnant tail did not disappear for more than 1.5 years at least.

MGS TES observations of the water vapor above the seasonal and perennial ice caps during northern spring and summer

We report on new retrievals of water vapor column abundances from the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) data. The new retrievals are from the TES nadir data taken above the ‘cold’ surface areas in the North polar region ( T surf < 220 K, including seasonal frost and permanent ice cap) during spring and summer seasons, where retrievals were not performed initially. Retrievals are possible (with some modifications to the original algorithm) over cold surfaces overlaid by sufficiently warm atmosphere. The retrieved water vapor column abundances are compared to the column abundances observed by other spacecrafts in the Northern polar region during spring and summer and good agreement is found. We detect an annulus of water vapor growing above the edge of the retreating seasonal cap during spring. The formation of the vapor annulus is consistent with the previously proposed mechanism for water cycling in the polar region, according to which vapor released by frost sublimation during spring re-condenses on the retreating seasonal CO 2 cap. The source of the vapor in the vapor annulus, according to this model, is the water frost on the surface of the CO 2 at the retreating edge of the cap and the frost on the ground that is exposed by the retreating cap. Small contribution from regolith sources is possible too, but cannot be quantified based on the TES vapor data alone. Water vapor annulus exhibits interannual variability, which we attribute to variations in the atmospheric temperature. We propose that during spring and summer the water ice sublimation is retarded by high relative humidity of the local atmosphere, and that higher atmospheric temperatures lead to higher vapor column abundances by increasing the water holding capacity of the atmosphere. Since the atmospheric temperatures are strongly influenced by the atmospheric dust content, local dust storms may be controlling the release of vapor into the polar atmosphere. Water vapor abundances above the residual polar cap also exhibit noticeable interannual variability. In some years abundances above the cap are lower than the abundances outside of the cap, consistent with previous observations, while in the other years the abundances above the cap are higher or similar to abundances outside of the cap. We speculate that the differences may be due to weaker off-cap transport in the latter case, keeping more vapor closer to the source at the surface of the residual cap. Despite the large observed variability in water vapor column abundances in the Northern polar region during spring and summer, the latitudinal distribution of the vapor mass in the atmosphere is very similar during the summer season. If the variability in vapor abundances is caused by the variability of vapor sources across the residual cap then this would mean that they annually contribute relatively little vapor mass to significantly affect the vapor mass budget. Alternatively this may suggest that the vapor variability is caused by the variability of the polar atmospheric circulation. The new water vapor retrievals should be useful in tuning the Global Circulation Models of the martian water cycle.

2007 OUTBURST OF 17P/HOLMES: THE ALBEDO AND THE TEMPERATURE OF THE DUST GRAINS

Based on optical and infrared observations, we study the albedo and the temperature of the dust grains associated with the spectacular 2007 outburst of Jupiter-family comet 17P/Holmes. We found that the albedo at the solar phase angle ~16° was 0.03-0.12. While the color temperature around 3-4 μm was 360 ± 40 K, the color temperature at 12.4 μm and 24.5 μm was ~200 K, which is consistent with that of a blackbody. We studied the equilibrium temperature of the dust grains at 2.44 AU and found that the big discrepancy in the temperature was caused by the heterogeneity in particle size, that is, hotter components consist of submicron absorbing grains whereas colder components consist of large (1 μm) grains. The contemporaneous optical and mid-infrared observations suggest that the albedo and the temperature could decrease within ~ 3 days after the outburst and stabilized at typical values of the other comets. We estimated the total mass injected into the coma by the outburst on the basis of the derived albedo and the optical magnitude for the entire dust cloud, and found that at least 4 × 1010 kg (equivalent to a few meter surface layer) was removed by the initial outburst event. The derived mass suggests that the outburst is explainable by neither the exogenetic asteroidal impact nor water ice sublimation driven by solar irradiation, but by an endogenic energy source. We conclude that the outburst was triggered by the energy sources several meters or more below the nuclear surface.

Photometric investigations of distant comets C/2002 VQ94 (LINEAR) and 29P/Schwassmann-Wachmann-1

We present an analysis of the results of photometric investigations of two distant comets, C/2002 VQ94 (LINEAR) and 29P/Schwassmann-Wachmann 1, obtained with the 6m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences. The comets under study demonstrate sufficient activity out of the zone of water ice sublimation (at heliocentric distances longer than 5 AU). In the spectra of the investigated comets, we found the CO+ and N2+ emission. The presence of this emission may say that the comets were formed in the outer parts of the Solar System, in a protoplanetary cloud at a temperature <=25 K. We found that the photometric maximum of the ionosphere (in the CO+ filter) of the comet C/2002 VQ94 (LINEAR) is shifted relative to the photometric center of the dust coma by 1.4 arcsec (7.44*10^3 km) in the direction deflected by 63 deg from the direction to the Sun. Using special filters to process the images, we picked out active structures (jets) in the dust coma of the 29P/Schwassmann-Wachmann 1 comet.

THE ACTIVE CENTAURS

The are recent escapees from the Kuiper belt that are destined either to meet fiery oblivion in the hot inner regions of the Solar system or to be ejected to the interstellar medium by gravitational scattering from the giant planets. Dynamically evolved Centaurs, when captured by Jupiter and close enough to the Sun for near-surface water ice to sublimate, are conventionally labeled as short-period (specifically, Jupiter-family) comets. Remarkably, some show comet-like activity even when far beyond the orbit of Jupiter, suggesting mass-loss driven by a process other than the sublimation of water ice. We observed a sample of 23 and found nine to be active, with mass-loss rates measured from several kg/s to several tonnes/s. Considered as a group, we find that the Centaurs in our sample have perihelia smaller than the inactive (median 5.9 AU vs. 8.7 AU), and smaller than the median perihelion distance computed for all known (12.4 AU). This suggests that their activity is thermally driven. There are several possibilities for the origin of the mass-loss from the active Centaurs. We consider the possibility that activity in the is triggered by the conversion of amorphous ice into the crystalline form accompanied by the release of trapped gases, including carbon monoxide. By imposing the condition that crystallization should occur when the crystallization time is shorter than the orbital period we find a qualitative match to the perihelion distribution of the active and conclude that the data are consistent with the hypothesis that the contain amorphous ice.

Activity of comets at large heliocentric distances pre-perihelion

We present observational data for two long-period and three dynamically new comets observed at heliocentric distances between 5.8 to 14.0 AU. All of the comets exhibited activity beyond the distance at which water ice sublimation can be significant. We have conducted experiments on gas-laden amorphous ice samples and show that considerable gas emission occurs when the ice is heated below the temperature of the amorphous–crystalline ice phase transition ( T ∼ 137 K ). We propose that annealing of amorphous water ice is the driver of activity in comets as they first enter the inner Solar System. Experimental data show that large grains can be ejected at low velocity during annealing and that the rate of brightening of the comet should decrease as the heliocentric distance decreases. These results are consistent with both historical observations of distant comet activity and with the data presented here. If observations of the onset of activity in a dynamically new comet are ever made, the distance at which this occurs would be a sensitive indicator of the temperature at which the comet had formed or represents the maximum temperature that it has experienced. New surveys such as Pan STARRS, may be able to detect these comets while they are still inactive.

Drilling Systems for Extraterrestrial Subsurface Exploration

Drilling consists of 2 processes: breaking the formation with a bit and removing the drilled cuttings. In rotary drilling, rotational speed and weight on bit are used to control drilling, and the optimization of these parameters can markedly improve drilling performance. Although fluids are used for cuttings removal in terrestrial drilling, most planetary drilling systems conduct dry drilling with an auger. Chip removal via water-ice sublimation (when excavating water-ice-bound formations at pressure below the triple point of water) and pneumatic systems are also possible. Pneumatic systems use the gas or vaporization products of a high-density liquid brought from Earth, gas provided by an in situ compressor, or combustion products of a monopropellant. Drill bits can be divided into coring bits, which excavate an annular shaped hole, and full-faced bits. While cylindrical cores are generally superior as scientific samples, and coring drills have better performance characteristics, full-faced bits are simpler systems because the handling of a core requires a very complex robotic mechanism. The greatest constraints to extraterrestrial drilling are (1) the extreme environmental conditions, such as temperature, dust, and pressure; (2) the light-time communications delay, which necessitates highly autonomous systems; and (3) the mission and science constraints, such as mass and power budgets and the types of drilled samples needed for scientific analysis. A classification scheme based on drilling depth is proposed. Each of the 4 depth categories (surface drills, 1-meter class drills, 10-meter class drills, and deep drills) has distinct technological profiles and scientific ramifications.

Secular light curve of Comet 9P/Tempel 1

In support of the Deep Impact Mission, we have updated the secular light curve of 9P/Tempel 1 presented in Paper I [Ferrín, I., 2005. Icarus 178, 493–516], with new data sets. The secular light curves (SLC) of the comet are presented in the log and time plots (Figs. 1 and 2) and provide a clear profile of the overall shape of the envelope. We arrive at the following conclusions: (1) Improved values of 18 photometric parameters are derived including the turn on and turn off points, R ON = − 3.47 ± 0.05 AU , R OFF = + 4.20 ± 0.05 AU , and T ON = − 410 ± 25 d , T OFF = + 555 ± 25 d . (2) The improved SLC shows a most interesting and peculiar shape, with a linear power law of slope n = 7.7 ± 0.1 from R ON = − 3.47 AU to R BP = − 2.08 ± 0.05 AU , and then converts to a law with curvature. The break point of the power law at R BP = − 2.08 AU , m V ( 1 , R ) = 14.0 ± 0.1 mag , is interpreted as a change in sublimating something more volatile than water ice (most probably CO 2), to water ice sublimation. In other words, the comet's sublimation is controlled by two different substances. (3) The photometric-age (defined in Paper I) and the time-age of the comet [Ferrín, I., 2006. Icarus. In press] are recomputed, and results in a value P-AGE = 21 ± 2 and T-AGE = 11 ± 2 comet years. Thus 9P is a young comet. (4) The comet is active almost up to aphelion since the turn off point has been determined at R OFF = + 4.20 ± 0.05 AU while aphelion takes place at Q = + 4.74 AU . (5) The comet exhibits activity post-aphelion which is not understood. Two hypothesis are advanced to explain this behavior.

Secular light curve of Comet 9P/Tempel 1

In support of the Deep Impact Mission, we have updated the secular light curve of 9P/Tempel 1 presented in Paper I [Ferrín, I., 2005. Icarus 178, 493–516], with new data sets. The secular light curves (SLC) of the comet are presented in the log and time plots (Figs. 1 and 2) and provide a clear profile of the overall shape of the envelope. We arrive at the following conclusions: (1) Improved values of 18 photometric parameters are derived including the turn on and turn off points, R ON = − 3.47 ± 0.05 AU , R OFF = + 4.20 ± 0.05 AU , and T ON = − 410 ± 25 d , T OFF = + 555 ± 25 d . (2) The improved SLC shows a most interesting and peculiar shape, with a linear power law of slope n = 7.7 ± 0.1 from R ON = − 3.47 AU to R BP = − 2.08 ± 0.05 AU , and then converts to a law with curvature. The break point of the power law at R BP = − 2.08 AU , m V ( 1 , R ) = 14.0 ± 0.1 mag , is interpreted as a change in sublimating something more volatile than water ice (most probably CO 2), to water ice sublimation. In other words, the comet's sublimation is controlled by two different substances. (3) The photometric-age (defined in Paper I) and the time-age of the comet [Ferrín, I., 2006. Icarus. In press] are recomputed, and results in a value P-AGE = 21 ± 2 and T-AGE = 11 ± 2 comet years. Thus 9P is a young comet. (4) The comet is active almost up to aphelion since the turn off point has been determined at R OFF = + 4.20 ± 0.05 AU while aphelion takes place at Q = + 4.74 AU . (5) The comet exhibits activity post-aphelion which is not understood. Two hypothesis are advanced to explain this behavior.

Hubble Space TelescopeACS Multiband Coronagraphic Imaging of the Debris Disk around β Pictoris

We present F435W (B), F606W (broad V), and F814W (broad I) coronagraphic images of the debris disk around β Pictoris obtained with the Hubble Space Telescope's Advanced Camera for Surveys. These images provide the most photometrically accurate and morphologically detailed views of the disk between 30 and 300 AU from the star ever recorded in scattered light. We confirm that the previously reported warp in the inner disk is a distinct secondary disk inclined by ∼5° from the main disk. The projected spine of the secondary disk coincides with the isophotal inflections, or "butterfly asymmetry," previously seen at large distances from the star. We also confirm that the opposing extensions of the main disk have different position angles, but we find that this "wing-tilt asymmetry" is centered on the star rather than offset from it, as previously reported. The main disk's northeast extension is linear from 80 to 250 AU, but the southwest extension is distinctly bowed with an amplitude of ∼1 AU over the same region. Both extensions of the secondary disk appear linear, but not collinear, from 80 to 150 AU. Within ∼120 AU of the star, the main disk is ∼50% thinner than previously reported. The surface brightness profiles along the spine of the main disk are fitted with four distinct radial power laws between 40 and 250 AU, while those of the secondary disk between 80 and 150 AU are fitted with single power laws. These discrepancies suggest that the two disks have different grain compositions or size distributions. The F606W/F435W and F814W/F435W flux ratios of the composite disk are nonuniform and asymmetric about both projected axes of the disk. The disk's northwest region appears 20%-30% redder than its southeast region, which is inconsistent with the notion that forward scattering from the nearer northwest side of the disk should diminish with increasing wavelength. Within ∼120 AU, the mF435W - mF606W and mF435W - mF814W colors along the spine of the main disk are ∼10% and ∼20% redder, respectively, than those of β Pic. These colors increasingly redden beyond ∼120 AU, becoming 25% and 40% redder, respectively, than the star at 250 AU. These measurements overrule previous determinations that the disk is composed of neutrally scattering grains. The change in color gradient at ∼120 AU nearly coincides with the prominent inflection in the surface brightness profile at ∼115 AU and the expected water-ice sublimation boundary. We compare the observed red colors within ∼120 AU with the simulated colors of nonicy grains having a radial number density ∝r-3 and different compositions, porosities, and minimum grain sizes. The observed colors are consistent with those of compact or moderately porous grains of astronomical silicate and/or graphite with sizes ≳0.15-0.20 μm, but the colors are inconsistent with the blue colors expected from grains with porosities ≳90%. The increasingly red colors beyond the ice sublimation zone may indicate the condensation of icy mantles on the refractory grains, or they may reflect an increasing minimum grain size caused by the cessation of cometary activity.

Cassini Encounters Enceladus: Background and the Discovery of a South Polar Hot Spot

The Cassini spacecraft completed three close flybys of Saturn's enigmatic moon Enceladus between February and July 2005. On the third and closest flyby, on 14 July 2005, multiple Cassini instruments detected evidence for ongoing endogenic activity in a region centered on Enceladus' south pole. The polar region is the source of a plume of gas and dust, which probably emanates from prominent warm troughs seen on the surface. Cassini's Composite Infrared Spectrometer (CIRS) detected 3 to 7 gigawatts of thermal emission from the south polar troughs at temperatures up to 145 kelvin or higher, making Enceladus only the third known solid planetary body-after Earth and Io-that is sufficiently geologically active for its internal heat to be detected by remote sensing. If the plume is generated by the sublimation of water ice and if the sublimation source is visible to CIRS, then sublimation temperatures of at least 180 kelvin are required.

Viscous relaxation of craters within the martian south polar layered deposits

The South Polar Layered Deposits (PLD) are of fundamental importance to martian climatology, as they may comprise the largest reservoir of near-surface water on Mars. The South PLD exhibit relatively young crater retention surface ages, which are widely attributed to recent resurfacing. However, we show that both constructional and destructional resurfacing mechanisms (such as dust deposition and water ice sublimation, respectively) are inconsistent with the size, depth, and spatial distributions of South PLD craters. We demonstrate that another process—viscous creep relaxation of dusty water ice—is more compatible with the observed cratering of South PLD surfaces. The results of our finite element relaxation simulations suggest that, despite their apparent youthfulness, the PLD have been stable for at least several hundred million and perhaps even over a billion years. Consequently, our modeling implies that the time scales for the formation and preservation of the layers characteristic of the South (and possibly North) PLD are much longer than generally assumed.

The Coma of Comet 9P/Tempel 1

As comet 9P/Tempel 1 approaches the Sun in 2004–2005, a temporary atmosphere, or “coma,” will form, composed of molecules and dust expelled from the nucleus as its component icy volatiles sublimate. Driven mainly by water ice sublimation at surface temperatures T > 200 K, this coma is a gravitationally unbound atmosphere in free adiabatic expansion. Near the nucleus (≤102 km), it is in collisional equilibrium, at larger distances (≥104 km) it is in free molecular flow. Ultimately the coma components are swept into the comet’s plasma and dust tails or simply dissipate into interplanetary space. Clues to the nature of the cometary nucleus are contained in the chemistry and physics of the coma, as well as with its variability with time, orbital position, and heliocentric distance.

Water in the upper martian surface at mid- and low-latitudes: presence, state, and consequences

Sublimation of water ice is more effective than evaporation of sorption water at the same temperature. Therefore, water in the form of ice must, over geologic time-scales, have left the upper martian surface ( m-scale) at mid- and low-latitudes, leaving sorption water as a possible physical form of stable subsurface water. Adsorption water is “liquid-like” at these temperatures (in the sense of a 2D-liquid). This property is the reason for the specific importance of physisorbed water under martian conditions. It is shown that unfrozen adsorption water can cause numerous physical, chemical, and possibly also biological processes in the upper martian surface and may be responsible for a number of its properties.