Water Ice Absorption Bands Research Articles

Detecting and characterizing the abundance and form of water-ice in permanently-shadowed regions of the moon using a three-band lidar system

We investigated the ability of a three-band lidar instrument (with wavelengths of 532, 1064, and 1560 nm) to detect and quantify different types of regolith ± water ice mixtures for both mare and highlands regions. A variety of samples were spectrally characterized, focusing on variables such as type of lunar regolith (simulant, lunar meteorite, highland vs mare), grain size (<45 μm, 45–1000 μm, <1 mm), water ice surface coverage and porosity of regolith (discontinuous, continuous, packed), and water ice percentages in intimate mixtures vs areal mixtures. Spectral metrics included absolute reflectance (532, 1064, 1560 nm) and reflectance ratios (1560/532, 1064/532, 1560/1064 nm). The ability to detect water ice in the presence of different types of regolith is critically dependent on the optical properties of end members, the selected wavelength, and the physical nature of the samples, such as grain size and areal vs intimate mixtures. Given the differences in the spectroscopic properties of the end members, both absolute reflectance and reflectance ratios have different predictive powers and both are required for robust analysis. The 1560 nm region is the most sensitive of the three wavelength regions to water ice content, as it falls well within a major water ice absorption band. Spectral contrast affects the ability to detect water ice. It is most sensitive for characterizing water ice + highland materials because the latter are brighter than water ice in this wavelength region. Powdered lunar materials are red-sloped across the 532 to 1064 to 1560 nm regions. By contrast, water ice shows a large downturn in reflectance between 1064 and 1560 nm. Detection limits for water ice in many situations can be as low as 2% and are lower for areal vs intimate mixtures. We found that porosity and angle of incidence with the surface have only minor effects on spectral reflectance properties of regolith. Further confirmation of water ice could be realized by comparing lidar data acquired by transects across permanently-shadowed regions and seeing how absolute reflectance and reflectance ratios vary between sunlit and adjacent shadowed regions. If it is known or assumed that regolith properties do not change as one enters a PSR, with the exception of the presence of surficial water ice, changes in reflectivity and reflectance ratios could provide compelling evidence for the presence of water ice.

Evaluation of the Capability of ExoMars-TGO NOMAD Infrared Nadir Channel for Water Ice Clouds Detection on Mars

As part of the payload of the 2016 ExoMars Trace Gas Orbiter (TGO) mission, the Nadir and Occultation for MArs Discovery (NOMAD) suite instrument has been observing the Martian atmosphere since March 2018. NOMAD is mainly dedicated to the study of trace atmospheric species taking advantage of a high-spectral resolution. We demonstrate that when NOMAD is observing in nadir mode, i.e., when the line-of-sight points to the centre of Mars, it can be also exploited to detect ice. In this study we present a method based on the investigation of nadir observations of the NOMAD infrared channel, acquired during Mars Years 34 and 35 (March 2018 to February 2021). We take advantage of the strong water ice absorption band at 2.7 µm by selecting the diffraction orders 167, 168, and 169. We derive the Frost and Clouds Index (FCI), which is a good proxy for ice mapping, and obtain latitudinal-seasonal maps for water ice clouds. FCI is sensitive to the Polar Hood clouds. Nevertheless, detections in the Aphelion Cloud Belt (ACB) are limited. This is consistent with previous observations showing different physical properties between the two main Martian atmospheric structures and making the ACB less detectable in the infrared. We hence derive the infrared nadir channel sensitivity limit for the detection of these clouds.

Nondetection of Water-ice Grains in the Coma of Comet 46P/Wirtanen and Implications for Hyperactivity

Abstract Hyperactive comets have high water production rates, with inferred sublimation areas of order the surface area of the nucleus. Comets 46P/Wirtanen and 103P/Hartley 2 are two examples of this cometary class. Based on observations of comet Hartley 2 by the Deep Impact spacecraft, hyperactivity appears to be caused by the ejection of water-ice grains and/or water-ice-rich chunks of nucleus into the coma. These materials increase the sublimating surface area and yield high water production rates. The historic close approach of comet Wirtanen to Earth in 2018 afforded an opportunity to test Hartley 2–style hyperactivity in a second Jupiter-family comet. We present high spatial resolution, near-infrared spectroscopy of the inner coma of Wirtanen. No evidence for the 1.5 or 2.0 μm water-ice absorption bands is found in six 0.8–2.5 μm spectra taken around perihelion and closest approach to Earth. In addition, the strong 3.0 μm water-ice absorption band is absent in a 2.0–5.3 μm spectrum taken near perihelion. Using spectroscopic and sublimation lifetime models, we set constraints on the physical properties of the ice grains in the coma, assuming they are responsible for the comet’s hyperactivity. We rule out pure water-ice grains of any size, given their long lifetime. Instead, the hyperactivity of the nucleus and lack of water-ice absorption features in our spectra can be explained either by icy grains on the order of 1 μm in size with a small amount of low-albedo dust (greater than 0.5% by volume) or by large chunks containing significant amounts of water ice.

Infrared Observations of Ganymede From the Jovian InfraRed Auroral Mapper on Juno

AbstractThe Jovian InfraRed Auroral Mapper (JIRAM) on board the NASA Juno spacecraft is a dual‐band imager and spectrometer in the 2–5 μm range with 9‐nm spectral sampling, primarily designed to study the Jovian atmosphere and aurorae. In addition to these goals, JIRAM is used to obtain images and spectra of the Galilean satellites, every time the spacecraft attitude is favorable. Here we present JIRAM images and spectra of Ganymede obtained during the first 4 years of the mission. In particular, on 26 December 2019, during a relatively close passage of Juno with the moon, a dedicated reorientation of the spacecraft was performed to achieve optimized observations of Ganymede by Juno's remote sensing instruments, including JIRAM. In the outbound phase of the flyby, observing the northern polar regions of Ganymede at a distance of roughly 100,000 km, JIRAM collected infrared images and spectra of the surface at a spatial resolution as high as 23 km per pixel, covering high northern latitudes that were scarcely mapped previously. A photometric model of Ganymede reflectance is produced, which diverges from the Lambert model. The spatial distribution of the obtained spectra complements the available coverage of the surface, with particular regard to the 2.0‐µm water ice absorption band and, to a lesser extent, to the 4.26‐µm spectral feature diagnostic of CO2 trapped in water ice. The water ice distribution is compatible with sputtered‐induced water ice grain enrichment at high latitude (&gt;45°). Several minor species (hydrated salts, trapped H2, CO2, and acids) are also identified in the measured spectra.

Spatially resolved near infrared observations of Enceladus’ tiger stripe eruptions from Cassini VIMS

Particle properties of individual fissure eruptions within Enceladus’ plume have been analyzed using high spatial resolution Visible and Infrared Mapping Spectrometer (VIMS) observations from the Cassini mission. To first order, the spectra of the materials emerging from Cairo, Baghdad and Damascus sulci are very similar, with a strong absorption band around 3µm due to water-ice. The band minimum position indicates that the ice grains emerging from all the fissures are predominantly crystalline, which implies that the water-ice particles’ formation temperatures are likely above 130K. However, there is also evidence for subtle variations in the material emerging from the different source fissures. Variations in the spectral slope between 1–2.5µm are observed and probably reflect differences in the size distributions of particles between 0.5 and 5µm in radius. We also note variations in the shape of the 3µm water-ice absorption band, which are consistent with differences in the relative abundance of > 5µm particles. These differences in the particle size distribution likely reflect variations in the particle formation conditions and/or their transport within the fissures. These observations therefore provide strong motivation for detailed modeling to help place important constraints on the diversity of the sub-surface environmental conditions at the geologically active south-pole of Enceladus.

Deciphering sub-micron ice particles on Enceladus surface

The surface of Saturn's moon Enceladus is composed primarily by pure water ice. The Cassini spacecraft has observed present-day geologic activity at the moon's South Polar Region, related with the formation and feeding of Saturn's E-ring. Plumes of micron-sized particles, composed of water ice and other non-ice contaminants (e.g., CO2, NH3, CH4), erupt from four terrain's fractures named Tiger Stripes. Some of this material falls back on Enceladus' surface to form deposits that extend to the North at ∼40°W and ∼220°W, with the highest concentration found at the South Pole. In this work we analyzed VIMS-IR data to identify plumes deposits across Enceladus' surface through the variation in band depth of the main water ice spectral features. To characterize the global variation of water ice band depths across Enceladus, the entire surface was sampled with an angular resolution of 1° in both latitude and longitude, and for each angular bin we averaged the value of all spectral indices as retrieved by VIMS. The position of the plumes’ deposits predicted by theoretical models display a good match with water ice band depths' maps on the trailing hemisphere, whereas they diverge significantly on the leading side. Space weathering processes acting on Enceladus' surface ionize and break up water ice molecules, resulting in the formation of particles smaller than one micron. We also mapped the spectral indices for sub-micron particles and we compared the results with the plumes deposits models. Again, a satisfactory match is observed on the trailing hemisphere only. Finally, we investigated the variation of the depth of the water ice absorption bands as a function of the phase angle. In the visible range, some terrains surrounding the Tiger Stripes show a decrease in albedo when the phase angle is smaller than 10°. This unusual effect cannot be confirmed by near infrared data, since observations with a phase angle lower than 10° are not available. For phase angle values greater than 10°, the depth of the water ice features remains quite constant within a broad range of phase angle values.

Near-infrared spatially resolved spectroscopy of (136108) Haumea’s multiple system

The transneptunian region of the solar system is populated by a wide variety of icy bodies showing great diversity. The dwarf planet (136108) Haumea is among the largest TNOs and displays a highly elongated shape and hosts two moons, covered with crystalline water ice like Hamuea. Haumea is also the largest member of the sole TNO family known to date. A catastrophic collision is likely responsible for its unique characteristics. We report here on the analysis of a new set of observations of Haumea obtained with SINFONI at the ESO VLT. Combined with previous data, and using light-curve measurements in the optical and far infrared, we carry out a rotationally resolved spectroscopic study of the surface of Haumea. We describe the physical characteristics of the crystalline water ice present on the surface of Haumea for both regions, in and out of the Dark Red Spot (DRS), and analyze the differences obtained for each individual spectrum. The presence of crystalline water ice is confirmed over more than half of the surface of Haumea. Our measurements of the average spectral slope confirm the redder characteristic of the spot region. Detailed analysis of the crystalline water-ice absorption bands do not show significant differences between the DRS and the remaining part of the surface. We also present the results of applying Hapke modeling to our data set. The best spectral fit is obtained with a mixture of crystalline water ice (grain sizes smaller than 60 micron) with a few percent of amorphous carbon. Improvements to the fit are obtained by adding ~10% of amorphous water ice. Additionally, we used the IFU-reconstructed images to measure the relative astrometric position of the largest satellite Hi`iaka and determine its orbital elements. An orbital solution was computed with our genetic-based algorithm GENOID and our results are in full agreement with recent results.

VLT/SINFONI OBSERVATIONS OF EUROPA: NEW INSIGHTS INTO THE SURFACE COMPOSITION

ABSTRACT We present new insights into Europa’s surface composition on the global scale from linear spectral modeling of a high spectral resolution data set acquired during a ground-based observation campaign using SINFONI4, an adaptive optics near-infrared instrument on the Very Large Telescope (ESO). The spectral modeling confirms the typical “bullseye” distribution of sulfuric acid hydrate on the trailing hemisphere, which is consistent with Iogenic sulfur ion implantation. However, the traditional hypothesis of the presence of sulfate salts on the surface of the satellite is challenged as Mg-bearing chlorinated species (chloride, chlorate, and perchlorate) are found to provide improved spectral fits. The derived global distribution of Mg-chlorinated salts (and particularly chloride) is correlated with large-scale geomorphologic units such as chaos and darker areas, thus suggesting an endogenous origin. Based on the 1.65 μm water-ice absorption band shape and position, the surface temperature is estimated to be in the range 110–130 K, and water ice is found to be predominantly in its crystalline state rather than amorphous. While amorphous water ice exhibits a strong correlation with the expected intensity of the Ionian plasma torus bombardment, crystalline water ice is instead more associated with distinct geomorphological units. Endogenous processes such as jets and ice heating due to active geology may explain this relationship. Otherwise, no evidence of a correlation between grain size for the water ice and the sputtering rate has been detected so far.

Martian north polar cap summer water cycle

A key outstanding question in Martian science is “are the polar caps gaining or losing mass and what are the implications for past, current and future climate?” To address this question, we use observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) of the north polar cap during late summer for multiple Martian years, to monitor the summertime water cycle in order to place quantitative limits on the amount of water ice deposited and sublimed in late summer.We establish here for the first time the summer cycle of water ice absorption band signatures on the north polar cap. We show that in a key region in the interior of the north polar cap, the absorption band depths grow until Ls = 120, when they begin to shrink, until they are obscured at the end of summer by the north polar hood. This behavior is transferable over the entire north polar cap, where in late summer regions 'flip' from being net sublimating into net condensation mode. This transition or 'mode flip' happens earlier for regions closer to the pole, and later for regions close to the periphery of the cap.The observations and calculations presented herein estimate that on average a water ice layer ∼70 microns thick is deposited during the Ls = 135–164 period. This is far larger than the results of deposition on the south pole during summer, where an average layer 0.6–6 microns deep has been estimated by Brown et al. (2014) Earth Planet. Sci. Lett., 406, 102–109.

Spectroscopic classification of icy satellites of Saturn II: Identification of terrain units on Rhea

Rhea is the second largest icy satellites of Saturn and it is mainly composed of water ice. Its surface is characterized by a leading hemisphere slightly brighter than the trailing side. The main goal of this work is to identify homogeneous compositional units on Rhea by applying the Spectral Angle Mapper (SAM) classification technique to Rhea’s hyperspectral images acquired by the Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini Orbiter in the infrared range (0.88–5.12μm). The first step of the classification is dedicated to the identification of Rhea’s spectral endmembers by applying the k-means unsupervised clustering technique to four hyperspectral images representative of a limited portion of the surface, imaged at relatively high spatial resolution. We then identified eight spectral endmembers, corresponding to as many terrain units, which mostly distinguish for water ice abundance and ice grain size. In the second step, endmembers are used as reference spectra in SAM classification method to achieve a comprehensive classification of the entire surface. From our analysis of the infrared spectra returned by VIMS, it clearly emerges that Rhea’ surface units shows differences in terms of water ice bands depths, average ice grain size, and concentration of contaminants, particularly CO2 and hydrocarbons. The spectral units that classify optically dark terrains are those showing suppressed water ice bands, a finer ice grain size and a higher concentration of carbon dioxide. Conversely, spectral units labeling brighter regions have deeper water ice absorption bands, higher albedo and a smaller concentration of contaminants. All these variations reflect surface’s morphological and geological structures. Finally, we performed a comparison between Rhea and Dione, to highlight different magnitudes of space weathering effects in the icy satellites as a function of the distance from Saturn.

Spectroscopic classification of icy satellites of Saturn I: Identification of terrain units on Dione

Dione is one of the largest and densest icy satellites of Saturn. Its surface shows a marked asymmetry between its leading and trailing hemispheres, the leading side being brighter than the trailing side, which shows regions mantled by a dark veneer whose origin is likely exogenic. In order to identify different terrain units we applied the Spectral Angle Mapper (SAM) classification technique to Dione’s hyperspectral images acquired by the Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini Orbiter in the infrared range (0.88–5.12μm). On a relatively limited portion of the surface of Dione we first identified nine spectral endmembers, corresponding to as many terrain units, which mostly distinguish for water ice abundance and ice grain size. We then used these endmembers in SAM to achieve a comprehensive classification of the entire surface. The analysis of the infrared spectra returned by VIMS shows that different regions of Dione have variations in water ice bands depths, in average ice grain size, and in the concentration of contaminants, such as CO2 and hydrocarbons, which are clearly connected to morphological and geological structures. Generally, the spectral units that classify optically dark terrains are those showing suppressed water ice bands, a finer ice grain size and a higher concentration of carbon dioxide. Conversely, spectral units labeling brighter regions have deeper water ice absorption bands, higher albedo and a smaller concentration of contaminants. We also considered VIMS cubes of the small satellite Helene (one of the two Dione’s trojan moons) and we compared its infrared spectra to those of the spectral units found on Dione. We observe that the closest match between the spectra of the two satellites occurs for one of the youngest and freshest terrain units on Dione: the Creusa crater region.

Connections between spectra and structure in Saturn’s main rings based on Cassini VIMS data

Saturn’s main rings exhibit variations in both their opacity and their spectral properties on a broad range of spatial scales, and the correlations between these parameters can provide insights into the processes that shape the composition and dynamics of the rings. The Visual and Infrared Mapping Spectrometer (VIMS) instrument onboard the Cassini Spacecraft has obtained spectra of the rings between 0.35 and 5.2μm with sufficient spatial resolution to discern variations on scales below 200km. These relatively high-resolution spectral data reveal that both the depths of the near-infrared water–ice absorption bands and the visible spectral slopes are often correlated with structural parameters such as the rings’ optical depth. Using a simplified model for the ring-particles’ regolith properties, we have begun to disentangle the trends due to changes in the gross composition of the ring particles from those that may be due to shifts in the texture of the ring particles’ regolith. Consistent with previous studies, this analysis finds that the C ring and the Cassini Division possess enhanced concentrations of a contaminant that absorbs light over a broad range of wavelengths. On the other hand, a second contaminant that preferentially absorbs at short visible and near-ultraviolet wavelengths is found to be more evenly distributed throughout the rings. The optical activity of this short-wavelength absorber increases inwards of 100,000km from Saturn center, which may provide clues to the origin of this contaminant. The spectral variations identified as shifts in the regolith texture are in some places clearly correlated with the ring’s optical depth, and in other locations they appear to be associated with the disturbances generated by strong mean-motion resonances with Saturn’s various moons. These variations therefore seem to be controlled by the ring particles’ dynamical environment, and may even provide a new avenue for constraining the structure and mass density of Saturn’s most opaque ring regions.

Characterisation of candidate members of (136108) Haumea’s family

From a dynamical analysis of the orbital elements of transneptunian objects (TNOs), Ragozzine & Brown reported a list of candidate members of the first collisional family found among this population, associated with (136108) Haumea (a.k.a. 2003 EL61). We aim to distinguish the true members of the Haumea collisional family from interlopers. We search for water ice on their surfaces, which is a common characteristic of the known family members. The properties of the confirmed family are used to constrain the formation mechanism of Haumea, its satellites, and its family. Optical and near-infrared photometry is used to identify water ice. We use in particular the CH4 filter of the Hawk-I instrument at the European Southern Observatory Very Large Telescope as a short H-band (Hs), the (J-Hs) colour being a sensitive measure of the water ice absorption band at 1.6 {\mu}m. Continuing our previous study headed by Snodgrass, we report colours for 8 candidate family members, including near-infrared colours for 5. We confirm one object as a genuine member of the collisional family (2003 UZ117), and reject 5 others. The lack of infrared data for the two remaining objects prevent any conclusion from being drawn. The total number of rejected members is therefore 17. The 11 confirmed members represent only a third of the 36 candidates. The origin of Haumea's family is likely to be related to an impact event. However, a scenario explaining all the peculiarities of Haumea itself and its family remains elusive.

Brightness and polarization opposition effects at low phase angles of the Saturnian satellites Tethys, Dione, and Rhea

The photometric and polarization phase dependences of the Saturnian moons Tethys, Dione, and Rhea are studied in a narrow domain of solar phase angles around opposition by using observations obtained with the 2-m RCC telescope of the National Astronomical Observatory at Rozhen, Bulgaria. The observations were made in the solar phase angle range from 5.7° to 0.01° and in three different wavelength regions, that is, the blue, red, and infrared color bands. After applying corrections for longitude variation of the brightness, the disk-integrated photometric phase curves revealed a steep non-linear intensity growth in the narrow backscatter domain of phase angles less than 2°. The measured polarization state was found to be negative all over the investigated region of the phase angles. The profiles of polarization-phase dependences are most probably irregular with a steep descent and minima at phase angles approximately equal to the angular width of the corresponding intensity peaks. Both the profiles of backscatter peak intensities and the observed polarization phase dependences provided evidence in favor of the “coherent backscatter mechanism” as being the main contributor to the opposition effect of all three Saturnian moons. Surprisingly, the polarization phase dependences demonstrated deep minima of negative polarization at small phase angles with the exception of Tethys’ leading hemisphere and the brightest area of Rhea’s leading side (100°W<θ<180°W), which were assumed to be due to high albedos and low contaminant abundances. Finally, the longitude dependences of the water–ice absorption bands, which are deduced from the Cassini VIMS observations of Rhea and Dione, were compared with the measured polarization in a narrow range of phase angles around 5°. This comparison suggested that the larger negative polarizations (in absolute values) correspond to areas with surface materials which most likely are strongly contaminated and composed of smaller regolith grains.

Methanol ice on the surface of minor bodies in the solar system

Aims. Spectral analyses of trans-Neptunan objects (TNOs) and of the linked Centaurs, which are supposed to be among the most primitive minor bodies in the solar system, reveal some chemical and physical properties of their surface. To determine the surface composition of these objects and their surface evolution is essential for gaining clues on the conditions under which the solar system has been formed. Methods. Chemical composition and physical properties of the surface of three objects have been constrained by computing the depth of the absorption features of the spectra in the near-infrared, running spectral models based on radiative transfer theory in the [0.4-2.3] μm range, and analyzing new laboratory measurements of the spectral behavior of thin samples of H 2 O-CH 3 OH mixtures. Results. Our investigations allow us to confirm the presence of CH 3 OH ice on the surface of the Centaur (5145) Pholus and the resonant (55638) TNO 2002 VE 95 . It may also possibly be found on the classical TNO (120348) 2004 TY 364 . Our laboratory experiments indicate that the behavior of the methanol and water ice absorption bands is dependent on the ambient temperature and the dilution level of the mixture. These results also suggest that methanol may be diluted in water ice on the surface of the Centaur Pholus. Conclusions. Formation and destruction processes of methanol suggest that a part (at least) of the surface of these objects is younger than the solar system age. If confirmed, this shows that primordial ices could still be detected on the surface of objects that are submitted to irradiation and rejuvenation processes.

DISCOVERY OF CRYSTALLIZED WATER ICE IN A SILHOUETTE DISK IN THE M43 REGION

We present the 1.9--4.2um spectra of the five bright (L<11.2) young stars associated with silhouette disks with moderate to high inclination angle of 39--80deg in the M42 and M43 regions. The water ice absorption is seen toward d121-1925 and d216-0939, while the spectra of d182-316, d183-405, and d218-354 show no water ice feature around 3.1um within the detection limits. By comparing the water ice features toward nearby stars, we find that the water ice absorption toward d121-1925 and d216-0939 most likely originates from the foreground material and the surrounding disk, respectively. The angle of the disk inclination is found to be mainly responsible for the difference of the optical depth of the water ice among the five young stars. Our results suggest that there is a critical inclination angle between 65deg and 75deg for the circumstellar disk where the water ice absorption becomes strong. The average density at the disk surface of d216-0939 was found to be 6.38x10^(-18) g cm^(-3). The water ice absorption band in the d216-0939 disk is remarkable in that the maximum optical depth of the water ice band is at a longer wavelength than detected before. It indicates that the primary carrier of the feature is purely crystallized water ice at the surface of the d216-0939 disk with characteristic size of ~0.8um, which suggests grain growth. This is the first direct detection of purely crystallized water ice in a silhouette disk.

Europa's icy bright plains and dark linea: Exogenic and endogenic contributions to composition and surface properties

We compare linear spectral modeling solutions yielding surface abundance estimates and water ice grain size information from low‐noise Galileo Near‐Infrared Mapping Spectrometer (NIMS) observations for three widely spaced locations on Europa. Bright equatorial plains on the orbital leading side are dominated by fine‐grained (∼50–75 μm) water ice (&gt;80 wt%). This area shows a low abundance of hydrated salts and statistically insignificant amounts of hydrated sulfuric acid. A midlatitude northern hemisphere location on the trailing side exhibits strikingly different surface composition and properties for similar terrain. The modeled abundance of hydrated sulfuric acid exceeds 40% here; large‐grained water ice (∼250 μm diameter) dominates the ice grain size distribution. A third location at high southern latitudes on the leading side exhibits high abundances of water ice (&gt;67%) and no detectable sulfuric acid hydrate. Water ice grain sizes here are intermediate between those of the other locations, at 75–100 μm. We resolve compositional differences between the darkest materials (at visible wavelengths) and the most hydrated materials (as evidenced by the distortion of water ice absorption bands) on Europa's leading side. Distinctive water ice grain size distributions are associated with visibly dark materials in all three locations. Our results help distinguish between exogenic and endogenic influences on Europa's present‐day surface composition. The results are consistent with migration and redeposition of sputtered water ice molecules from trailing to leading side locations.

The librational band of water ice in AFGL 961: revisited

Of all the water ice absorption bands seen in the laboratory, the librational band near 12–13 μ m has proven the most difficult to conclusively identify in observational spectra. Cox reported the detection of this band in the IRAS spectrum of the massive protostar AFGL 961 near 13.6 μ m; however, the details of the structure of the band were limited by the quality of the IRAS spectrum and the accuracy of the subtracted silicate absorption. AFGL 961 is also a double system comprising two point-like components separated by ∼6 arcsec (AFGL 961E and AFGL 961W) so the IRAS aperture included both components – it is unclear how the combination of the intrinsic spectra of these two sources may have affected the resultant IRAS spectrum. In this paper we report Spitzer and European Southern Observatory (ESO) 3.6-m mid-infrared spectroscopic observations of each component of AFGL 961. We find a broad absorption feature near 13.1 μ m common to both AFGL 961E and W. The profile and peak wavelength of this feature are well matched by the laboratory spectrum of the librational band of amorphous H2O ice in the temperature range 10–30 K, in agreement with the Cox result. Both AFGL 961E and W also have strong CO2 ice absorption near 15.2 μ m, indistinguishable in profile between the two. However, AFGL 961E shows silicates in absorption near 9.7 μ m, while AFGL 961W shows polycyclic aromatic hydrocarbons in emission and, in a small aperture, also silicates in emission. Uncertainty in where the true continuum lies in the 8–13 μ m spectral region for both AFGL 961E and W means we cannot rule out the possibility that a combination of silicate emission and absorption could be responsible for at least some of the features we see in this region. In this case, a much weaker librational band could still be present, but not as a distinct feature. In either case, the ice must be located in a cool, outer envelope surrounding both stars or a cool foreground cloud, far enough away that the ice is not appreciably modified by the local environment of either one.

Modeling variations in near-infrared spectra caused by the coherent backscattering effect

We study a new optical effect, a spectral manifestation of coherent backscattering, which reveals itself as systematic variations in the depth of absorption bands with changing phase angle. We used Cassini VIMS near-infrared spectra of Saturn's icy satellite Rhea in order to identify and characterize the spectral change with phase angle, focusing on the change in the depth of water–ice absorption bands. To model realistic characteristics of the surfaces of icy satellites, which are most likely covered by micron-sized densely packed particles, we perform simulations using a theoretical approach based on direct computer solutions of the macroscopic Maxwell equations. Our results show that this approach can reproduce the observed phase-angle variations in the depth of the absorption bands. The modeled changes in the absorption bands are strongly affected by physical properties of the regolith, especially by the size and packing density of the ice particles. Thus, the phase-angle spectral variations demonstrate a promising remote-sensing capability for studying properties of the surfaces of icy bodies and other objects that exhibit a strong coherent backscattering effect.

Near-infrared spectroscopy of 133P/Elst-Pizarro

Comet 133P/Elst-Pizarro, known to be a main-belt asteroid with a cometary activity, was observed with the near-infrared integral field spectrograph SINFONI at the 8.2-m Very Large Telescope in J, H, and K bands during its 2007 perihelion passage. The goal of these observations was to attempt detection of water ice absorption bands. We present here the details of the data processing, the results of these observations, and our compositional modeling of the final spectrum. No water ice absorptions were detected within the noise of the spectrum but we show that this spectrum is compatible with a reasonable near-infrared albedo value of 7–10% and a mixture of water ice, black carbon, Tholin and silicates. This interpretation, nevertheless, is not unique.