Hydrochemical Water Research Articles

Elucidating the hydrochemistry and REE evolution of surface water and groundwater affected by acid mine drainage.

The impact of pyrite mining on water quality is a global concern. This study investigates the impact of acid mine drainage (AMD) from an abandoned pyrite mine in the Qinling Mountains on surface and groundwater hydrochemistry and rare earth elements (REEs) evolution. A total of 54 water samples were collected in 2021, of which the Muzi River downstream of the mining area was repeated three times in three sampling periods. Hydrogeochemical methods and stable isotope techniques were used to analyze the impacts of AMD. Results showed that tailing water in comparison to groundwater and surface waters exhibits low pH with high concentrations of SO42-, potentially toxic elements (PTEs), and REEs, and is characterized by normalized middle REE (MREE) enrichment. Groundwater is less influenced by AMD and shows HCO3-Ca and HCO3-Ca·Na types. AMD contaminates surface water to different degrees. Surface water received SO42- input from AMD, exhibited SO4-Ca, SO4·HCO3-Ca, and HCO3·SO4-Ca types within the mining area, and evolved from HCO3·SO4-Ca to HCO3-Ca downstream as AMD influence diminishes. High concentrations of PTEs and REEs are presented in AMD and seepage near the slag heap, and decreased rapidly along the flow path, while SO42- migrated over longer distances. The water in the study area primarily originates from atmospheric precipitation, with close relation among surface water, groundwater, and tailing water. Water-rock interactions and pyrite oxidation governed the hydrochemical composition, with sulfide oxidation facilitated the carbonatite-water reaction, which alleviated sulfide oxidation-induced acidification. The concentrations of PTEs are regulated by adsorption and precipitation, carbonate buffering, and dilution along the flow path. REEs are mainly controlled by pH, inorganic complexation, and secondary mineral adsorption. As the pH changes from acidic to neutral or weakly alkaline, REEs shift from sulfate-complex dominated to carbonate-complex dominated. These insights contribute to a better understanding of AMD impacts on surface and groundwater, providing a basis for the rational management of AMD.

Irrigation suitability assessment of urban wastewater for sustainable agriculture: a case study of Musi river, India

In urban areas with dense populations and high water demands, effective management of water resources is crucial for sustainable development. It includes optimizing water usage and recycling wastewater to balance supply and demand. Urban rivers, which now carry sewage year-round due to increased urban water consumption, are increasingly used for irrigation in peri-urban regions. This study aims to assess the suitability of an urban stream for irrigation compared to catchment groundwater, using hydrochemical parameters to evaluate water quality indices. Analysis of major ion distribution from upstream to downstream reveals a significant increase of TDS (r2 = 0.65; p < 0.001) in the surface water and a decrease (r2 = 0.93; p < 0.001) in groundwater samples. The calculated Weighted Arithmetic-Water Quality Index (WA-WQI) indicates that around 85% and 75% of surface water and groundwater samples from the Musi river are classified as very poor to unsuitable for any use, highlighting critical pollution levels. Based on irrigation suitability indices, only 16% of the surface water samples and 60% of the groundwater samples are suitable for irrigation. The nitrate concentration increased from less than 10 mg l−1 in the upstream region to over 100 mg l−1 in the urban stretch. Nitrogen-Phosphate-Potassium (NPK) ratios across the basin are exceptionally higher, representing crops irrigated using the Musi river water might not require fertilizer applications. The adoption of fertilizer application concerning supplied water hydrochemistry, particularly the NPK ratio, might limit the excess usage of fertilizer and benefit farmers. Additionally, this practice may also limits the excess input of nitrate to the groundwater in the Musi river basin.

Major Ion Chemistry of Surface Water and Its Controlling Factors in Ebinur Lake Basin

The sustainable development of arid regions is significantly constrained by the availability of water resources, which play a crucial role in this context. It is necessary to deeply investigate and analyze the hydrochemical characteristics and major ion sources. This study, which was based on data from 183 water samples collected from the Jinghe River Basin, provided a comprehensive analysis of the river water hydrochemistry. The results show that the average TDSs (total dissolved solids) was measured at 49.8 mg·L−1. HCO3− (82.4%) and Ca2+ (77.1%) were the ions present in the highest abundances. The river water was classified as the HCO3−-Ca2+ hydrochemical type. The Gibbs diagrams indicated that the ion composition was primarily influenced by rock weathering. Additionally, the Na-normalized molar ratio diagrams suggested that the chemical composition was primarily governed by the weathering and dissolution of silicate rocks, while the carbonate rock dissolution played a lesser role. This study demonstrates a critical aspect of water resources quality evaluation, which is of great significance for the sustainable development, utilization and environmental protection of regional water resources.

Baseline survey of environmental parameters, radiation, and drip water hydrochemistry in Niah Caves (Sarawak, Malaysia)

Relict caves in fenglin karst may typically have numerous entrances and openings. Hence, they host a variety of environments in which parameters such as light, airflow, humidity, and temperature may vary significantly over short distances. Similarly, drip water hydrochemistry, including isotopic values, may vary due to different contributions of various sources and residence time in the karst. This study investigated environmental parameters, including radiation, using hand-held instruments, along a transect within several major caves in the Niah karst of Sarawak (Malaysia). This has led to a baseline data set which showed an inverse relationship between humidity and temperature, gamma radiation levels that are about 25% of that in surrounding non-karst region, and high percentages of twilight zones in the studied caves. Airflow was found to be variable, with high values of 530 m3/s in Painted Cave and 122 m2/s in parts of Gan Kira passage, with flow towards the southeast at the time of the study. The hydrochemistry of the drip water and surface water was also analyzed and found to be dominantly Ca–Mg–Cl water type which indicates dissolution of minerals through water–rock interaction. In addition, the cave environment, particularly air temperature, humidity, and ventilation, also influences the drip water composition and isotopic values. Three different origins (precipitation, evaporation, and paleo-recharge) of drip water have been identified through the δ18O-δ2H diagram. Enriched isotopic values were observed in the cave entrance due to increased evaporation caused by lower humidity and higher air temperature. Factor analysis identifies the key geochemical processes responsible for the drip water chemistry. The outcome of this study provides the first baseline environmental data for the Niah caves, which could support future initiatives for sustainable management of this famous archeological site in southeast Asia.

Spatial and Seasonal Variation of Doline Water Hydrochemistry in West Gunungsewu Karst Area, Yogyakarta Special Region, Indonesia

Spatial and Seasonal Variation of Doline Water Hydrochemistry in West Gunungsewu Karst Area, Yogyakarta Special Region, Indonesia

Monitoring air fluxes in caves using digital flow metres

Precise measurements of airflow within caves are increasingly demanded to assess heat and mass transfers and their impacts on the karst environment, including subsurface ecosystems, hydrochemistry of karst water and secondary mineral precipitates. In this study, we introduce a new, low-cost and lightweight device adapted to monitoring air fluxes in caves which addresses the need for reliable measurements, low power consumption, durability and affordability. The device was calibrated in a wind tunnel, showing the high accuracy and precision of the device. Field-related uncertainties were further investigated in a ventilated cave to determine the effect of local airflow conditions on the inferred mass flux. Comparing measured values with a 3-D air velocity distribution modelled on a surveyed cave section suggests that most of the uncertainties in estimating the airflow result from the relative position of the instrument in the streamlines rather than from the accuracy of the device.

Dissolved organic matter quality in thermokarst lake water and sediments across a permafrost gradient, Western Siberia

Thermokarst (thaw) lakes of permafrost peatlands are among the most important sentinels of climate change and sizable contributors of greenhouse gas emissions (GHG) in high latitudes. These lakes are humic, often acidic and exhibit fast growing/drainage depending on the local environmental and permafrost thaw. In contrast to good knowledge of the thermokarst lake water hydrochemistry and GHG fluxes, the sediments pore waters remain virtually unknown, despite the fact that these are hot spots of biogeochemical processes including GHG generation. Towards better understating of dissolved organic matter (DOM) quality at the lake water – sediment interface and in the sediments pore waters, here we studied concentration and optical (UV, visual) properties of DOM of 11 thermokarst lakes located in four permafrost zones of Western Siberia Lowland. We found systematic evaluation of DOM concentration, SUVA and various optical parameters along the vertical profile of lake sediments. The lake size and hence, the stage of lake development, had generally weak control on DOM quality.The permafrost zone exhibited clear impact on DOM porewater concentration, optical characteristics, aromaticity and weight average molecular weight (WAMW). The lowest quality of DOM, reflected in highest SUVA and WAMW, corresponding to the dominance of terrestrial sources, was observed at the southern boundary of the permafrost, in the sporadic/discontinuous zone. This suggests active mobilization of organic matter leachates from the interstitial peat and soil porewaters to the lake, presumably via subsurface or suprapermafrost influx. Applying a substitute space for time scenario for future evolution of OM characteristics in thermokarst lake sediments of Western Siberia, we foresee a decrease of DOM quality, molecular weight and potential bioavailability in lakes of continuous permafrost zone, and an increase in these parameters in the sporadic/discontinuous permafrost zone.

Hydrochemistry and isotope hydrology of groundwater and surface water in the Sor and Gebba watershed, southwestern Ethiopia

The Sor and Gebba watershed plays a crucial role in the water resources of the Baro-Akobo River Basin. However, various factors have had a detrimental effect on the watershed. Unplanned groundwater extraction, wetland drainage, surface water pollution, and land use changes have all intensified due to population growth, urbanization, commercial farms, industrial development, poor water resources management, and improvements in living standards. This research utilized major hydrochemical ions and environmentally stable isotopes to elucidate the interaction between groundwater and surface water in the watershed, which are reliable tracers in various hydrologic processes. During the 2020 wet season and 2022 dry season, over 25 meteoric water samples were collected from different locations for hydrochemical and isotopic analysis. The hydrochemical analysis revealed that the dominant water type is Ca–Mg–HCO3−. Among the anions, HCO3− was the most dominant, followed by NO3−, Cl−, and SO42−, and those of cations Ca2+, followed by Na+, Mg2+, and K+. The spatial analysis of environmentally stable isotopes confirmed the interaction between groundwater and surface water in the watershed. The quality of groundwater is primarily influenced by rock-water interaction (Gibb's diagram) and, to some extent, by evaporation (Isotope study). A graph of the water samples closely aligned with the Addis Ababa-local meteoric water line indicates their meteoric origin. However, there was a slight deviation to the left due to the effects of distance and altitude. The isotopic correlation further supported the interaction between different water sources.

Assessment of Some Trace Elements in Surface Water and Soil near Al-Ahdab Oil Field, Wasit Governorate, Iraq

The main objective of this munscript is to spot light on the negative consequences of oil emissions from Al-Ahdab oil field on the water and soil surrounding the oil field at Wasit Governorate. To obtain this objective, seven sediment samples were collected from the surfacre soil, in addition to five water samples from the Tigris River near Al-Ahdab oil field within Al-Kut Wasit governorate. The more effective eight trace elements were chosen to detect the limitations of their occurrence in the soil and water of the study area, these are Fe, Cd, Cu, Cr, Ni, Pb, Zn, and Zr. The Zr is used as a background for the specific equations applied. Samples of sediments and water were collected in October 2022. The standardization of the Enrichment Factor (EF), geo-accumulation index (I-geo), and contamination factor (CF) in addition to the pollution load index (PLI) were applied to detect the extent of soil pollution. In contrast, the hydrochemistry of water samples was determined by comparing the results of the analysis with the standards of WHO, 2018, and IQS, 2009. The enrichment factor value (EF) Cadmium value (Cd) in soil samples is 6.6, which reflects a significant impact of air emissions, the cobalt (Co) value is 1.77m this value reflects minimum Enrichment factor while the EF has a rather moderate enrichment factor. By applying the I-geo equation, the oitput results indicate unpolluted soil for Co, and Ni metals, while it is moderately polluted for Cu, Cr, Zn, and Pb metals. According to the PLI index, the soil of the study area is ordered as moderately contaminated for these metals. As for the hydrochemistry of surface water of the Tigris River near the study area, the water samples are classified as not contaminated by (Ni, Cd, Pb, Zn, Cr, and Cu).

Influence of Natural Water Hydrochemistry in the Vakhsh River Basin on the Water–Salt Regime of the Irrigated Agricultural Land

Influence of Natural Water Hydrochemistry in the Vakhsh River Basin on the Water–Salt Regime of the Irrigated Agricultural Land

Изотопный состав и условия образования фаменских карбонатолитов Центрально-Хорейверского вала (Хорейверская впадина, Печорская плита)

The article presents results of the distribution of the isotopic composition of 13C and 18O (119 samples) across four facies zones to substantiate the conditions of Famennian carbonation accumulation. The Lower Famennian carbonates of the shoal zone showed values of 13C (1.5 ± 0.15 %), 18O (25.01 ± 0.29 %) reflecting evaporative processes in a shallow basin in a warm and dry climate. For the rocks of the microbial mounds zone, the values of 13C (2.47 ± 1.12 %) and 18O (23.51 ± 1.12 %) reflect an increase in bioproductivity and some fluctuation in water salinity. In the limestones of the zone of transition to depression, the variations of isotopic composition are more distinct in the section. Thus, the Early Famennian is characterized by the average values of 13C (0.94 ± 0.59 %) and 18O (23.73 ± 2.18 %) for marine carbonates. The transition to the Middle Famennian is accompanied by isotopic weighting of 13C (1.30 ± 0.47%) and 18O (24.52 ± 1.45%), which shows an increase in evaporation processes under aridization conditions. In the Late Famennian, the isotopic composition abruptly lightens by 13C (–1.05 ± 0.66 %), which is associated with desalination under conditions of climate humidification. At the same time, the value of 18O (25.75 ± 0.31 %) corresponds to the average values for carbonates of the Devonian. The values of 13C (1.04 ± 0.89 %) and 18O (26.01 ± 0.99 %) in the carbonates of the zone slope of the carbonate bank towards the shallow shelf reflect the conditions of the normal sea basin with a slight increase in the evaporation regime during climate aridization. The obtained results indicate that the Famennian sedimentation basin characterized by fluctuations in sea level, facies, water hydrochemistry and climate.

Identification of Hydrochemical Characteristics, Spatial Evolution, and Driving Forces of River Water in Jinjiang Watershed, China

Rivers are an important source of water in humid regions, but their availability is greatly limited by water chemistry. In order to accurately identify the changes in river water chemical composition, the compositional analysis method (CoDA) is proposed from the perspective of compositional data analysis theory, which considers the geochemical riverine system as a whole and detects the compositional changes of the entire watershed. The basic data analysis is carried out by traditional analysis methods, and the results show that the hydrochemical characteristics of different sections of the basin have significant features. The water chemistry of Dongxi River is of the HCO3− Ca type. The water of the Xixi River shows a gradual evolution from the HCO3-Ca type and high SO42− content in the upper reaches to the Cl-Ca type in the lower reaches. The hydrochemistry of river water in the watershed is mainly affected by rock weathering leaching (PC1) and agricultural and domestic pollutant discharge (PC2), with a contribution rate of 48.4% and 19.7%, respectively. Rock weathering, mining, and agricultural pollution are the main factors affecting the chemical composition of river water in different regions. The spatial composition of a single sample at different scales is monitored by the Mahalanobis distance approach in an iterative manner to minimize the influence of a single anomaly on the composition center. The results show that the main reasons for the change in river water chemical composition along the Xixi River are attributed to mine pollution, domestic pollution, and tea plantation and that along the Dongxi River is caused by domestic pollution. The hydrochemical composition changes after the confluence of the Xixi River and Dongxi River are mainly affected by human activities and seawater in urban areas. This research could provide new perspectives and methods for detecting the influences of human and natural factors on the hydrochemistry of river water in humid regions worldwide.

Spatial and Temporal Variations of the Hydrochemical Parameters in the Gravelly Aquifer of the Lower Course of Vjosa River, Albania

Vjosa is the main river of South Albania. Currently, the confined Quaternary gravelly aquifer in its lower course supplies drinking water for roughly 300,000 local residents. In the past years, extracted groundwater quantity has increased, whereas the groundwater quality has been affected by seawater intrusion. This paper aims to assess the groundwater quality and to discuss the dominant hydrochemical processes in the aquifer. To fulfil this goal, the study discusses the groundwater quality’s spatial and temporal variations on the basis of the hydrochemical parameters and ratios for 2010–2021 period, during which data are collected from three monitoring wells, located 6, 14 and 17 km, from the sea. While for 1961–2009 period, hydro-chemical water types and TDS maps are prepared using roughly 100 chemical analyses. The hydro-chemical parameters are discussed related to the factors controlling the groundwater’s chemical constituents and the groundwater extraction. Heavy metals and nitrates’ contents indicate that the aquifer is not affected by anthropogenic pollution. The main conclusion is that the groundwater quality is affected by seawater intrusion due to overexploitation. The study reveals its gaps, mentions its possible usefulness, and underlines the discrepancy between the policy makers and the hydrogeologists approaches concerning groundwater extraction.

Roman water management impacted the hydrological functioning of wetlands during drought periods

During the Roman domain of the Iberian Peninsula (from 201 BCE to 460 CE) water management infrastructures were built to satisfy high water demand. However, whether the Roman activities affected the hydrological balance of Iberian wetlands remains unclear. Here, we investigate the paleo-hydrology of Lake Zóñar (southern Iberia) by using the stable isotopes (16O, 17O, 18O, 1H and 2H) of its gypsum (CaSO4·2H2O) sediments and reconstruct the isotopic composition of the lake water during Roman times. A period of recurrent lake low stand occurred between 2120 and 1890 cal. yr BP (ca. 170 BCE to 60 CE), coinciding with a relatively dry climate stage recorded by most regional paleoclimate archives. The stable isotopes and hydrochemistry of the lake water during gypsum precipitation are consistent with a shallow saline lake that evaporated under relative humidity ~ 10% lower than the present annual mean and at least 20% less rainfall amount. Our analytical and archeological findings support lake level lowering during the Roman period was probably caused by combined arid climate conditions and diversion of the inlets feeding the lake. Spring capturing was likely necessary to satisfy the high water demand of nearby Roman settlements, in the framework of a period of persistent droughts.

GEOCHEMICAL CONDITIONS OF SULLAR SPRING: FORMATION OF AUTHIGENIC MINERALS AND METHANE FLUXES

Link for citation: Soldatova E.A., Sidkina E.S., Kiriukhin B.A., Maximov P.N., Krivenok L.A., Ivanov V., Tananaev N.I. Geochemical conditions of Sullar spring: formation of authigenic minerals and methane fluxes. Bulletin of the Tomsk Polytechnic University. Geo Аssets Engineering, 2023, vol. 334, no. 10, рр. 16-33. In Rus. Relevance and the research object. Interpermafrost aquifers and areas of their discharge with seasonal ice covers are special permafrost-hydrogeological and hydrochemical systems that are not typical for the thick continuous permafrost zone of Central Yakutia. Differences in chlorofluorocarbon content indicate the anaerobic conditions of some springs suggesting microbial degradation of these compounds by methanogenic bacteria. In the discharge area of such springs, a sharp change in the geochemical conditions takes place leading to a transformation in the water chemical composition and boosting the processes of authigenic mineral formation in this buffer area. In current work we considered the geochemical system of the Sullar spring – the most northern and the least studied among interpermafrost groundwater discharge zones of the Lena River right bank. Intensive accumulation of authigenic minerals was found in the Sullar discharge area during field research. It was Fe compounds with bacterial mats as an opalescent film. Some researchers state the connection between the transformation of Fe compounds during permafrost melting and the migration and transformation of organic matter, including its consumption by microorganisms with further methane emission. We assumed that there is a relationship between the authigenic mineral formation and the content and emission of methane in the discharge area of the spring. This research is the first comprehensive description of the hydrochemistry of the interpermafrost water of the Sullar spring. The aim of the research was to explore influence of geochemical conditions and microbial communities on formation of authigenic minerals and methane fluxes, in particular the effect of the change of geochemical conditions due to groundwater discharge on Fe precipitation and to analyze the relation of that process with methane fluxes. For this purpose, we study water chemical composition of the Sullar spring, measure methane fluxes from water surface and analyze mineral and microbial composition of secondary mineral crusts and bottom eluvium collected near water sampling points. Methods. The main element content was determined by ion chromatography. The concentrations of the bicarbonate ion and dissolved carbon dioxide were calculated by the equilibrium modeling method based on the pH and Eh values of the system. The content of trace elements was measured by mass spectrometry with inductively coupled plasma. To identify seasonal and annual variability, a retrospective analysis of the water chemical composition of the Sullar spring for the period from 1962 to 2020 was carried out. Methane fluxes were measured using the chamber method. The methane concentration was determined by gas chromatography with a flame ionization detector. The features of the secondary mineral crusts and bottom eluvium were determined using a petrographic microscope. The chemical composition of individual mineral phases was evaluated using a scanning electron microscope equipped with a detector for energy dispersive X-ray spectral microanalysis. The DNA concentration was measured on a fluorimeter. Amplicon libraries were generated by polymer chain reaction with universal primers for the V4 region. Equilibrium modeling was carried out using the HCh software.

Assessment of groundwater recharge and connectivity with surface water in a mountainous watershed using natural tracers in Daejeon, Korea

The water supply from headwater streams in mountainous regions is considered an important source for sustaining both water quality and quantity in lowland areas. The Korean terrain is characterized by mountainous regions, the hydrological environment is significantly impacted by seasonal weather conditions. This study focused on investigating the hydrochemistry and isotopic composition of groundwater and surface water to identify hydrological connectivity within a mountainous watershed area in Daejeon, Korea. The estimated recharge rate using water budget methods suggests that approximately 20% of the total precipitation contributes to groundwater recharge in this site. The δ18O–δ2H values of the water samples indicate a meteoric water source for groundwater recharge, while the isotope composition of surface water reveals altitude effects, implying that groundwater recharges at a higher altitude region. Additionally, water revealed altitude effects suggesting that the groundwater was inferred to recharge at a higher altitude region. The hydrochemical conservative components (87Sr/86Sr ratio and Cl−) indicate that this watershed undergoes temporary similar water–rock interactions along its flow path, but it is also impacted by anthropogenic contaminants from the surrounding public area. The results of the three-component endmember mixing analysis demonstrate that groundwater is predominantly influenced by surface water, indicating a close interrelationship among various water bodies in mountain hydrology. These findings provide a comprehensive approach to water resource management by combining recharge rate estimation and the assessment of water body connectivity using natural tracers.

Geological and hydrochemical controls on water chemistry and stable isotopes of hot springs in the Three Parallel Rivers Region, southeast Tibetan Plateau: The genesis of geothermal waters

The Three Parallel Rivers Region (TPRR) is a tectonically active area in the middle segment of the Sanjiang Tethys Orogen, southeast Tibetan Plateau, characterized by many hot springs. This area is up-and-coming for producing geothermal energy, a CO2-free energy source, which will help China in reducing the effects of climate change. We report here the results of 37 geothermal springs that have been sampled to investigate the physical and chemical characteristics of the thermal water and evolution patterns. These springs are drained along three major N-S faults zones (the Lujiang Fault, the Lancangjiang Fault and the Jinshajiang-Red River Fault) to the interior of the Lanping Basin. Five hydrochemical water facies were recognized with Na-HCO3 being the primary type. Fluorine and boron that are produced through water-rock interactions are commonly enriched in these waters, and their concentrations are further controlled by secondary hydrochemical processes during water migration. The water's stable isotopes (δ18O and δD) suggest the meteoric origin of all thermal waters in the TPRR. The estimated reservoir temperatures range between 61 °C and 118 °C with the relatively hot reservoirs (> 100 °C) generally developed in major shear zones. These results indicate variable water circulation depth exceeding 3000 m, implying that the large-scale shearing displacement plays a vital role in heat acquisition. Conductive cooling and possible mixing of the thermal water with near-surface cold water occurred as the thermal water ascended along the fault systems and was ejected along the outlets of the springs. This study adds insights into hydrogeochemical constrains on evolution of water solutes over a large-scale hydrological cycle in the TPRR.

Analysis of self-organizing maps and explainable artificial intelligence to identify hydrochemical factors that drive drinking water quality in Haor region

Water contamination undermines human survival and economic growth. Water resource protection and management require knowledge of water hydrochemistry and drinking water quality characteristics, mechanisms, and factors. Self-organizing maps (SOM) have been developed using quantization and topographic error approaches to cluster hydrochemistry datasets. The Piper diagram, saturation index (SI), and cation exchange method were used to determine the driving mechanism of hydrochemistry in both surface and groundwater, while the Gibbs diagram was used for surface water. In addition, redundancy analysis (RDA) and a generalized linear model (GLM) were used to determine the key drinking water quality parameters in the study area. Additionally, the study aimed to utilize Explainable Artificial Intelligence (XAI) techniques to gain insights into the relative importance and impact of different parameters on the entropy water quality index (EWQI). The SOM results showed that thirty neurons generated the hydrochemical properties of water and were organized into four clusters. The Piper diagram showed that the primary hydrochemical facies were HCO3−-Ca2+ (cluster 4), Cl---Na+ (all clusters), and mixed (clusters 1 and 4). Results from SI and cation exchange show that demineralization and ion exchange are the driving mechanisms of water hydrochemistry. About 45 % of the studied samples are classified as “medium quality”,” that could be suitable as drinking water with further refinement. Cl− may pose increased non-carcinogenic risk to adults, with children at double risk. Cluster 4 water is low-risk, supporting EWQI findings. The RDA and GLM observations agree in that Ca2+, Mg2+, Na+, Cl− and HCO3− all have a positive and significant effect on EWQI, with the exception of K+. TDS, EC, Na+, and Ca2+ have been identified as influencing factors based on bagging-based XAI analysis at global and local levels. The analysis also addressed the importance of SO4, HCO3, Cl, Mg2+, K+, and pH at specific locations.

Investigation of Water Dynamics Nearby Hydroelectric Power Plant of the Gorky Reservoir on Water Environment: Case Study of 2022

Regulated water bodies like lakes and reservoirs are increasingly becoming an object of attention due to the problems of greenhouse gas emissions, regional ecology, and the necessity to ensure safe environmental management. However, for some local tasks, it is important to assess the contribution of a hydroelectric power plant (HPP) to various parameters of the nearest water environment, for example, mortality of zooplankton, transfer of suspended matter and phytoplankton, formation of secondary deposits, methane emissions, spatial features of stratification, etc. An example of such studies is the present paper. It is based on unique data of complex measurements of hydrophysical, hydrooptical, hydrobiological, and hydrochemical water parameters, as well as methane fluxes, that were collected at the Gorky Reservoir nearby a HPP in the spring, summer, and autumn of 2022. Preliminary correlations between these parameters were obtained. The results are useful for the correct interpretation of satellite images of inland waters, quantitative description of HPPs’ influence on the water environment, knowledge of the main patterns of transformation of aquatic organism communities under conditions of runoff regulation, determination of water quality by hydrobiological parameters, development of mechanisms for improving the ecological state of water bodies, and accounting spatial heterogeneity of methane flows from the surface of the reservoir.

Definition of Circulation Conditions and Groundwater Genesis of the Complex Krupaja Hydrogeological Karst System (Eastern Serbia)

The complex Krupaja karst system, located in Serbia, which consists of a strong karst spring, a thermal karst spring, and a borehole that captures sub-thermal waters, has been studied. A phenomenon which gives rise to the occurrence of karst waters of three different temperatures within a relatively short distance (about 200 m) led us to assume that these karst waters are formed within the same karst aquifer and circulate through different levels of karst channels that are zonally distributed within a vertical profile; this was confirmed by assessing the groundwater ages. Based on the development of karstification, as presented in this paper, as well as on previous investigations, explanations of four types of circulation within same karst system are provided. The results of measurements of stable isotopes (H, 18O, and 13C) and radioactive isotopes of tritium and T+He and 14C, as well as hydrochemical water analyses, speleogenetic spatial modeling, speleodiving research, etc., confirmed the assumption that these groundwaters belong to the same karst system. However, these karst waters have different residence times, i.e., from only a few days to over several decades and even up to approximately 4000 years, circulating through channels with various distributions along the depth of the karst aquifer.