Water Film Research Articles

Numerical Investigation of Air Natural Convection in the AP1000 Passive Containment Cooling System Following LBLOCA Using ANSYS FLUENT

The innovative design of the AP1000 power plant has various layers of passive safety systems aiming to enhance reactor safety during normal and transient conditions. The passive containment cooling system (PCCS) is a safety-related system capable of removing heat from the steel containment vessel (SCV) to the atmosphere and preventing the containment from exceeding the design pressure and temperature following a postulated design-basis accident. The PCCS heat removal mechanisms include condensation on the internal SCV surface, heat conduction, natural convection, evaporation of water film, and radiative heat transfer. In two basic postulated scenarios, the reactor decay heat can ultimately be removed from the SCV only by air natural convection. The first scenario occurs 72 h following a large-break loss-of-coolant accident (LBLOCA) when the passive containment cooling water storage tank becomes unavailable. The second scenario occurs following a postulated loss of shutdown decay heat removal event. Hence, investigating the thermal-hydraulic behavior of the containment under transient conditions is essential to ensure its safety and integrity. In this study, a simplified three-dimensional model using ANSYS FLUENT is developed to investigate the cooling capability of air natural convection outside the SCV during a LBLOCA event. Because of the lack of experimental data, code-to-code validation was performed using the actual results of AP1000 alongside other research findings. The results show good agreement with available data, which can be used for future research.

Experimental and Theoretical Investigation of the Bound Water Film Thickness in Porous Media

Experimental and Theoretical Investigation of the Bound Water Film Thickness in Porous Media

Erosion Induced Flow Changes in Pelton Bucket: A Numerical Approach

Abstract The hydro-turbines working in sediment-laden conditions often experience some material loss from their surface, which modifies the surface design. This material loss alters the mechanical strength of the turbine component as well as the corresponding flow phenomenon. These changes in the flow pattern can lead to efficiency losses, but they can also be exploited to determine the actual condition of the component in real time. In fact, if detected, they can be useful for developing maintenance strategies to predict the turbine conditions in real time. To compare the flow parameters, a numerical simulation has been performed for a 2D stationary Pelton bucket under both eroded and uneroded scenarios considering clean water as the working fluid. The 2D middle section of a reference Pelton bucket has been considered in two configurations: the uneroded bucket case and eroded, whose uneven surface patterns were created taking inspiration from real erosion patterns inside Pelton buckets observed in sediment-laden power plants. The CFD simulations have been carried out using OpenFOAM multiphase solver interFoam. The two cases were then compared based on several flow parameters such as water film thickness, velocity, and exit flow angle. The result analysis confirmed flow disturbances due to erosion causes the decrement in the overall flow velocity and the increment in water film thickness. The velocity reduction effect, as well as the water film thickness increment effect, strengthens approaching the outlet of the bucket. The results also showed a significant alteration of exit flow angle due to erosion. Specifically, for the erosion pattern considered in this study, the exit flow angle was observed to be larger compared to the uneroded bucket case.

Numerical and experimental investigation of the supercooled large droplets icing of rotating spinner

The icing of aero-engine rotating components is more complex than traditional aircraft icing. A three-dimensional numerical method was developed based on the Eulerian method to study the supercooled large droplets icing of a rotating spinner. Typical dynamic behaviours of supercooled large droplets, such as deformation, breakup, rebound, and splashing, were considered. An icing thermodynamic model applicable to a rotating spinner was established by considering the effects of pressure gradient, air shear force, and centrifugal force on the flow of the water film. Meanwhile, an ice wind tunnel experiment on supercooled large droplets icing of a rotating spinner was carried out. The results showed that the maximum relative deviation of the simulated icing thickness at the cone tip is no more than 15% compared with the experimental result, and the icing thickness on the surface of the rotating spinner is basically consistent with the experimental result. Based on the three-dimensional numerical method developed in this study, the effects of the rotational speed, inflow velocity, and inflow temperature on the supercooled large droplets icing of a rotating spinner were investigated. As the rotational speed increases, the rebound and splashing of supercooled large droplets becomes more obvious, leading to an increase in the mass loss coefficient and a decrease in the collected mass of water droplets on the surface of the rotating spinner. Consequently, the icing thickness at the tail of the rotating spinner decreases with an increase in the rotational speed. Since the liquid water content in the environment is relatively low, water droplets freeze immediately after impacting the surface of the rotating spinner and rime ice is usually formed. When the inflow temperature is relatively high, overflow water exists and glaze ice is formed near the tip of the rotating spinner. The findings of this study can provide valuable support for the design and verification of anti-icing systems for aero-engine rotating spinner.

The study of electrochemical stabilization mechanism of Pt, GC, SS304, Ti and Cu as current collectors for aqueous lithium-ion batteries by electrochemical approaches

This paper employs electrochemical methods (linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS)) to investigate the electrochemical behavior of platinum, glassy carbon, 304 stainless steel, titanium, and copper in 21 and 1 M LiTFSI electrolytes. The LSV results indicate that the electrochemical stability window of the materials varies with the electrolyte concentration, and the stability window is wider in the high-concentration system. Through Tafel polarization curves and EIS analysis, the overpotential of the charge exchange process differs due to the type of material and the concentration of the electrolyte, mainly attributed to the influence of the proportion of free water, electrolyte viscosity, and SEI film formation on electrode process kinetics. After comparative analysis, glassy carbon exhibits a higher overpotential than other materials at both the cathode and anode, effectively suppressing water decomposition. These findings provide theoretical support for the development of high-performance aqueous lithium-ion battery current collector materials.

Water dynamics in calcium silicate hydrates probed by inelastic neutron scattering and molecular dynamics simulations

Calcium-silicate-hydrate (C-S-H) is a disordered, nanocrystalline material, acting as a primary binding phase in Portland cement. C-S-H and C-A-S-H (an Al-bearing substitute present in low-CO2 cement) contain thin films of water on solid surfaces and inside nanopores. Water controls multiple chemical and mechanical properties of C-S-H, including drying shrinkage, ion transport, creep, and thermal behavior. Therefore, obtaining a fundamental understanding of its properties is essential. We applied a combination of inelastic incoherent neutron scattering and molecular dynamics simulations to unravel water dynamics in synthetic C-(A)-S-H conditioned at five hydration states (from drier to more hydrated) and with three Ca/Si ratios (0.9, 1, and 1.3). Our results converge towards a picture where the evolution from thin layers of interfacial water to bulk-like capillary water is dampened by the structure of C-(A)-S-H. In particular, the hydrophilic Ca2+ sites organize the distribution of interfacial C-(A)-S-H water.

Sub6 GHz Non‐Line‐of‐Sight Effects in Mobile Communications: A New Perspective for Rainfall Monitoring?

AbstractSub6 GHz non‐line‐of‐sight signals are a potential opportunistic source of rainfall information that promises to improve the current urgent need regarding near‐surface rainfall detection, but the complex mechanisms in which these signals are impacted by rainfall have hindered further development in this area. In this study, we focus on four types of microwave propagation processes to explore the theoretical basis for Sub6 GHz signal sensitivity to rainfall. We also investigate how these signals change during rainy conditions using a cellphone signal recording experiment. The results demonstrate that the indirect effect of rainfall‐induced changes in the interfacial water film may significantly affect the Sub6 GHz signal, making it an opportunity to reflect rainfall information. Finally, we offer a comprehensive overview of the potential challenges, benefits, and drawbacks of low‐frequency non‐line‐of‐sight links in the context of rainfall inversion.

Domino-like water film manipulation with multifunctionality

Domino-like water film manipulation with multifunctionality

Study on the influence of tire polishing on surface texture durability and skid resistance deterioration of asphalt pavement

As an inherent attribute of asphalt pavement, texture durability is the essential reason for the change in skid resistance. However, different scale texture deterioration behavior remains unclear by tire wearing at present. To explore the influence of the durability of multi-scaled textures on skid resistance, nine pavement specimens were tested using the Harbin polishing and dynamic friction integrated experimental machine (HPFM). The pavement anti-skid texture tester (PATT-II) was used for high-precision texture scanning and reconstruction. The results show that the texture richness and skid resistance of the three types of pavements in 300 min polishing are ranked as Open-graded Friction Coarse (OGFC) > Stone Mastic Asphalt (SMA) > Asphalt Concrete (AC), while SMA presents the best durability, determined by the material skeleton structure of asphalt mixture. The macro-texture deterioration occurs slightly at first and then tends to stabilize in 300 min polishing. The micro-texture deterioration behavior is the same as the μHPFM, increasing rapidly at the beginning, then slowly decreasing, and finally remaining constant. This deterioration is caused by the asphalt damage and continuously wearing aggregate surface. The 2D-PSD deterioration behavior is more significant with a smaller texture scale in 300min polishing, and the most considerable contribution wavelength in the microscopic scale range is 0.15 mm–0.3 mm, which is determined by the adhesion characteristics and molecular mechanism between a mineral mixture and asphalt material. The influence of pavement texture on the dynamic friction coefficient is significantly different under different water film thicknesses, the micro-texture and macro-texture play the main roles in boundary and mixed lubrication, respectively.

Effect of liquid properties on film behavior on the surface of an airfoil in a high-speed flow and subsequent atomization from the trailing edge

This study examines the behavior of ethanol or water films on the surface of a NACA 0012 airfoil placed in a high-speed air flow. New water film results complement previous measurements of time averaged ligament lengths and droplet sizes generated with the same airfoil. In addition, new data are obtained for ethanol. Air velocities up to 175 m/s are used with liquid flow rates between 1.4 cm2/s and 2.6 cm2/s. The liquid was introduced onto one side of the airfoil via 26 holes, each measuring 0.5 mm in diameter and spaced 1 mm apart. These holes are positioned 35 mm downstream from the leading edge and 65 mm upstream from the trailing edge. Film behavior on the vane is captured with front-lit high-speed video. The accumulation of liquid and breakup of ligaments are captured with backlit highspeed video. Phase Doppler interferometry is used to measure droplet size and simultaneous axial and pitch wise velocity 70 mm downstream of the trailing edge. Finally, laser diffraction is used to measure line averaged droplet sizes. The results indicate notable differences between ethanol and water films. The ethanol film spreads more extensively across the width of airfoil which is attributed due to its lower surface tension. The maximum ligament length for both liquids decrease with higher air velocity and increase with the liquid flow rate. A correlation for maximum ligament length is developed and captures the effect of liquid properties, flow rate, and air velocity. Furthermore, the variation in liquid volume flow rate did not impact droplet size. However, for a given air velocity, the Sauter Mean Diameter is found to depend on surface tension. On the dependency of droplet size on the Weber number, ethanol produced smaller droplet sizes at low values of Weber number. However, at relatively high Weber numbers, the droplet sizes for both water and ethanol were similar. This suggests that droplet size is influenced by factors besides surface tension at low Weber numbers but not at higher Weber numbers. In addition, the Nukiyama-Tanasawa model to fit the volume distribution curves is simplified by fixing p and q terms. Simplification makes the model easier to understand and implement.

Combination effects of laser heating and water cooling on the repair performance of Hastelloy C-276 by underwater laser direct metal deposition

The Ni-based Hastelloy C-276 was repaired by in-air and underwater laser direct metal deposition (in-air DMD and UDMD) with four gradient cooling rates (in-air DMD, in-air DMD with interlayer cooling, UDMD and UDMD with each layer re-covered by water). The microstructure and mechanical properties of repaired samples were systematically characterized with respect to the cooling rates. All samples presented good metallurgical bonding and columnar dendrites with epitaxial growth. The underwater environment had a more pronounced acceleration effect on the cooling rate compared to interlayer cooling. The rapid cooling induced intense thermal cycling, resulting in increased dislocation density and grain refinement with primary dendrite arm spacing (PDAS) diminishing from 5.30 to 3.21 μm. Accelerated cooling rate contributed to precipitation of massive M6C carbides. Carbides coarsened (sizes from 257 to 354 nm) and exhibited a reduced content as cooling rate slowed down due to intrinsic heat treatment (IHT). The residual water film in UDMD repair promoted oxide formation. Samples with increased cooling rates exhibited superior mechanical performance. The improved microhardness, tensile and impact properties were primarily attributed to the enhanced fine grain strengthening and Orowan strengthening facilitated via reduced grain size, increased dislocation density and carbide content. Quantities of large-size carbides were detrimental to tensile and impact properties as displayed in the in-air DMD sample with interlayer cooling (carbide size of 341 μm). The study could serve as a reference for in-situ restoration in deep-water environments.

Robust and repairable PET superwicking surfaces: A simple two-step fabrication approach for enhanced liquid transport

Superwicking surfaces stand out for their superior wicking abilities that expedite liquid flow across their structural form. The surface has attracted significant attention due to its promising applications in water harvesting, thermal management, biomedical fields, and more. However, minimizing manufacturing costs while ensuring long-term stability remains a challenge in the production of superwicking surfaces and enhancing their applications. This study presents the development of polyethylene terephthalate (PET) superwicking surfaces using a straightforward two-step technique with sandpaper abrasion and nanocomposite coating of TiO2-SiO2. Superwicking performance was evaluated through droplet spread analysis, contact angle measurements, and water drying tests. Results exhibited a more than 100% rise in absorbed water film thickness on the 180-grit abraded superwicking surface versus the coating on raw PET. Additionally, a 10μl droplet displayed more than triple the spreading diameter. Sandpaper abrasion, high-pressure water impact, and outdoor stability tests appraised surface durability. The PET superwicking surface showed enhanced mechanical durability and outdoor stability, attributed to protective microgrooves and photocatalytic self-cleaning capacity. The findings of this study clearly address the high cost, instability, and extreme lack of durability associated with conventional superwicking surface preparation. More importantly, the developed self-repairing capability of the surface allows it to be restored by reapplying the spray coating after the nanoparticles have been worn away due to heavy use. This advancement will significantly promote the use of such surfaces in heat transfer and self-cleaning applications.

Improved wet skid resistance of NR/SBR composites induced by irradiation vulcanised styrene-butadiene rubber particles

Improving the wet skid resistance of tire tread is very important for the safety of vehicle driving. Using a novel ultrafine full-vulcanised powdered styrene-butadiene rubber (UFPSBR), this work prepared an advanced UFPSBR/nature rubber (NR)/styrene-butadiene rubber (SBR) composites used for the tire tread. On one hand, the UFPSBR improves the loss factor (tanδ) values of the UFPSBR/NR/SBR composites in temperature range from 0 °C to 10 °C, indicating that the UFPSBR modified tire tread has better wet skid resistance. On the other hand, the UFPSBR increases the surface roughness and complex modulus of the UFPSBR/NR/SBR composites while decreasing the water contact angle of the UFPSBR/NR/SBR composites, which is conducive to increasing the wet skid resistance of tire tread by puncturing the water film or leading a thinner water film between tire tread surface and road surface. Above researches are more comprehensive and benefit for studying the advanced green tire with high wet skid resistance.

Investigation of tribological performance of the ultra-dispersive TBC-CNTs as additives for aqueous lubrication

Carbon nanotubes (CNTs), as water-based additives, are potential candidates for reducing friction and wear whereas the weak dispersion stability impedes their application in aqueous lubrication. Therefore, CNTs were functionally modified by 4-tert-butylcatechol (TBC) nucleophilic for synthesizing the ultra-dispersive TBC-CNTs. The particle sizes and dispersibility of TBC-CNTs in water were investigated. It was found that particle sizes of the most of CNTs were reduced after modification and 0.035 wt% TBC-CNTs remained uniformly dispersed in water for 2 months. The lubrication behavior of TBC-CNTs as water-based additives for ceramic/steel tribo-pairs was investigated by using a ball-on-disc apparatus. Notably, the optimum concentration of TBC-CNTs was determined 0.2 wt% that contributed to 30.6 % of friction reduction and 28.3 % of wear resistance, respectively, at 0.6 m/s and 8 N. The tiny structure of TBC-CNTs contributed to their entrance into the contact interface and playing lubricating roles. Furtherly, the increase of water film thickness within contacts and formation of lubrication film on rubbing surfaces caused by TBC-CNTs addition resulted in the friction and wear reduction.

Effect of aqueous layer thickness on nano-scratching of single-crystal γ-TiAl alloys

ABSTRACT The study of nano-scratching under water lubrication is helpful to understand the role of lubrication mechanism in the machining of single crystal γ-TiAl alloy. In this paper, through the comparative analysis of nano-scratching under different thicknesses of water layers, it was found that under a water layer thickness of 1 nm, nano-scratching not only improves the surface quality but also achieves multiple reductions in scratch force, stress, temperature and subsurface structural damage. In order to deeply reveal the internal mechanism of workpiece temperature variation under different thicknesses of water layer lubrication, a fitting formula was innovatively adopted to conduct quantitative analysis. In addition, with the increase of the thickness of the water layer, it was observed that the water film effect was continuously enhanced, and this change caused the matrix stress to gradually increase, which hindered the forward motion of the nanoscratch, ultimately resulting in an increase in the friction coefficient. These findings provide valuable insights into the nanoscratching mechanism of monocrystalline γ-TiAl alloy in the presence of water film, and provide a new perspective for understanding the complex mechanism of nanoscratch behaviour under water lubrication, thus promoting the understanding of nanoscale lubrication effects.

Characterization of Composite Film Containing Polyvinyl Alcohol Cross‐Linked With Dialdehyde Cellulose Using Citric Acid as a Catalyst for Sustainable Packaging

ABSTRACTThis study is aimed at fabricating composite films by cross‐linking polyvinyl alcohol (PVA) and dialdehyde cellulose (DAC) in varying ratios using citric acid as a catalyst. The acetal formation between the two components was studied using FTIR. Characterizations of the physiochemical properties revealed that increasing the DAC ratio of the composite film improved the hydrophobicity, tensile strength and barrier properties (water vapour, UV and oxygen) of the films while reducing elongation at break (flexibility), swelling and solubility of the film in water. When the DAC ratio was elevated to 50%, the tensile strength was enhanced to 98 MPa. In comparison, flexibility diminished to 29%, the solubility of the film reduced to 10% and water vapour permeability was lower by two orders of magnitude than that of the control PVA film. The peroxide value of linoleic acid decreased from 21.2% ± 7.6 (packed with PVA film) to 9.9% ± 0.9 (packed with 50% DAC composite film) after 15 days. Furthermore, the composite films demonstrated effective absorption of UV radiation, with the order of effectiveness being UV‐C > UV‐B > UV‐A radiation. No significant difference in biodegradability was detected in the composite films with an increase in DAC ratio during indoor soil burial tests for 30 days. This study implies that the composite film could serve as an alternative sustainable packaging option, especially when transparency and high oxygen barrier properties are desired.

Intelligent films based on dual-modified starch and microencapsulated Aronia melanocarpa anthocyanins: Functionality, stability and application

This study aims to enhance the physical properties and color stability of anthocyanin-based intelligent starch films. Three dual-modified starches, namely crosslinked-oxidized starch (COS), acetylated distarch phosphate (ADSP), and hydroxypropyl distarch phosphate (HDSP), were utilized as film matrices. Aronia melanocarpa anthocyanins were incorporated through three different pre-treatments (free, spray-drying microencapsulation, and freeze-drying microencapsulation) to assess the prepared films' functionality, stability, and applicability. The results indicate that the ADSP film exhibited an approximately two-fold increase in elongation at break (EAB) compared to native starch film. Specifically, the ADSP film's water contact angle (WCA) reached 90°, demonstrating excellent flexibility and hydrophobicity. Scanning electron microscopy (SEM) revealed stronger interactions between anthocyanins and the film matrix after microencapsulation. Furthermore, after 30 days of exposure to 37 °C heat and light radiation, the freeze-dried anthocyanin-based intelligent film (FDA film) exhibited minimal fading, displaying the highest stability among the tested films. Notably, during beef freshness monitoring, the intelligent films underwent significant color changes as the beef deteriorated. In conclusion, the developed FDA film, with its outstanding stability and responsive pH characteristics, holds immense potential as a novel packaging material for food applications.

Rheology and microstructure of lithium slag/metakaolin geopolymer pastes: Insights from particle packing and water dynamic evolution

The high viscosity of alkali activator and physicochemical characteristics of metakaolin particles impair the rheological properties of fresh geopolymer pastes, becoming one of the urgent problems. To better understand and control the rheological properties of geopolymer pastes, this study investigates the particle packing of fluid suspensions and water dynamic evolution in pastes. The incorporation of lithium slag (LS) reduces the water required for the geopolymerization reaction, contributing to the increase of water film thickness between particles and the free water in pastes. Consequently, the internal friction between particles is reduced and the workability is improved. The results obtained identify the relevance of water film thickness and water occurrence state to qualitatively estimate the rheological properties, and confirm the applicability of LS for geopolymer manufacture. This work presents a theoretical approach towards assessing rheology and proposes an efficient method to develop more workable metakaolin-based geopolymer concrete.

Effects of nanoactive fluids on water wettability reversal of shale: Implications for CO2 geo-sequestration

CO2 geo-sequestration (CGS) is crucial in tackling global climate change, and the safety of CO2 storage within the reservoir is intricately linked to wettability. The utilization of nanofluids-surfactants for adjusting reservoirs’ wettability has emerged as a promising approach to enhance the security of CGS. However, the mechanism underlying their impact on reservoir wettability and carbon sequestration remains elusive. Regarding nanoactive fluid (ASNF) compounded with nano-SiO2 and AOS, to explore its potential for wettability reversal of CO2-exposed shale under in situ conditions, comparative experiments were conducted with Longmaxi Formation shale as the subject. The chemical structures and microstructures of shale before and after the experiments were comprehensively characterized. The results showed that a maximum of 67.93 % enhanced the water wettability of samples co-treated with ASNF and ScCO2. The primary reason for shale wettability reversal was increased hydrophilic chemical groups and enhanced interaction energy between organic matter and water molecules, stemming from nanoactive particle retention on the shale surface. The alteration in wettability decreased the mobility of CO2 and increased the distribution of surface water films, enhancing the carbon sequestration capabilities of the trapping mechanism. These findings provided an important foundation for improving the effectiveness and safety of CGS in shale reservoirs.

Dynamic antifouling strategies of soft corals: Disrupting the flow field by tentacles

As permanently attached organism, soft corals can prevent fouling organisms from attaching to them through its anti-fouling mechanisms. In this paper, the antifouling mechanism of soft coral tentacles was revealed through the combination of numerical simulation and laboratory experiment. The results indicated that the interaction between tentacle structures and fluid medium affects the distribution and adhesion of bacteria. At the microscopic level, the boundary layer of low normal flow velocity forms a "water film" near the tentacles, preventing bacteria from approaching the tentacle surface. From the macro perspective, coral tentacles can disrupt the flow field through vortex streets, disrupt water flow stability, and make it difficult for bacteria to attach. The new discovery of bacterial movement and attachment behavior in the flow around a circular cylinder provides theoretical guidance for the design of antifouling surfaces.