Water Electrolysis System Research Articles

Operation strategy optimization of an integrated proton exchange membrane water electrolyzer and batch reverse osmosis desalination system powered by offgrid wind energy

Operation strategy of the integrated wind-hydrogen system is the key to ameliorate the negative impacts of the fluctuated wind power on the hydrogen production capacity and durability ofelectrolyzer. However,the desalination system supplying pure water to electrolyzers was neglectedpreviously, with which the practical operation strategy of the hybrid wind-hydrogen-desalination system has yet to be investigated. In this work, we proposed a novel control strategy named step-by-step start for wind-hydrogen-desalination system consisting of wind turbine, proton exchange membrane water electrolyzer (PEMWE), battery and batch reverse osmosis (BRO) desalination system, which can produce hydrogen andfresh water. Real-time wind data from Shenzhen, Chinawere used as input to the integrated system. The results demonstratethe wind-hydrogen-desalination system with the proposed strategy can improve the hydrogen production by 17.55 %, the energy efficiency by 17.68 % in August, and increase hydrogen production by 10.29 %, the energy utilization efficiency by 10.44 % in December compared with traditional strategies. At low wind speeds, the switching times of PEMWE for this strategy is higher than the other strategies, while at high wind speeds, the switching times of PEMWE is significantly decreased. This work provides insights into the practical operation strategy for wind-hydrogen-desalination system depending on the real-time wind speed.

Ultra-fast green hydrogen production from municipal wastewater by an integrated forward osmosis-alkaline water electrolysis system

Recent advancements in membrane-assisted seawater electrolysis powered by renewable energy offer a sustainable path to green hydrogen production. However, its large-scale implementation faces challenges due to slow power-to-hydrogen (P2H) conversion rates. Here we report a modular forward osmosis-water splitting (FOWS) system that integrates a thin-film composite FO membrane for water extraction with alkaline water electrolysis (AWE), denoted as FOWSAWE. This system generates high-purity hydrogen directly from wastewater at a rate of 448 Nm3 day−1 m−2 of membrane area, over 14 times faster than the state-of-the-art practice, with specific energy consumption as low as 3.96 kWh Nm−3. The rapid hydrogen production rate results from the utilisation of 1 M potassium hydroxide as a draw solution to extract water from wastewater, and as the electrolyte of AWE to split water and produce hydrogen. The current system enables this through the use of a potassium hydroxide-tolerant and hydrophilic FO membrane. The established water-hydrogen balance model can be applied to design modular FO and AWE units to meet demands at various scales, from households to cities, and from different water sources. The FOWSAWE system is a sustainable and an economical approach for producing hydrogen at a record-high rate directly from wastewater, marking a significant leap in P2H practice.

A hybrid electrochemical system for spontaneous green‑hydrogen production with simultaneous desalination using catechol oxidation

Green hydrogen, commonly produced through water electrolysis, has attracted considerable attention owing to its energy-efficient and eco-friendly properties. However, since conventional water electrolysis system has fatal drawbacks owing to the high process cost and energy requirements, various approaches are being adopted to increase its energy efficiency. In this study, a novel hybrid system for green hydrogen production was designed by replacing the oxygen evolution reaction (OER) with electrochemical oxidation of catechol (CAT). CAT is an environmental pollutant generated by diverse industries and needs to be further treated because of its toxicity to humans and nature. Accordingly, to facilitate the degradation of CAT and increase the energy efficiency, the pH values of the anolyte (containing CAT) and catholyte were adjusted to alkali and acid, respectively. Two types of ion-exchange membranes (IEMs; anion-/cation-exchange membranes) were coupled to divide the hybrid cell into three compartments, and a buffer solution (NaCl solution) was injected between the IEMs. As a result, the hybrid system output 3.75 mW/cm2 of electricity, spontaneously produced hydrogen with 4.2 mL/h of hydrogen production rate and removed ions from the buffer solution with 0.46 mg/cm2∙min of high desalination rate.

Metal‐Organic Framework‐Based Electrocatalysts for Acidic Water Splitting

AbstractThe proton exchange membrane water electrolysis system has long been considered a promising technique for the generation of hydrogen owing to its high electrolytic efficiency, reliability, and quick response to renewable energy sources. At present, noble metals and their oxides (e.g., Pt, IrO2, and RuO2) are widely used as high active electrocatalysts for accelerating the conversion efficiency of the water electrolysis process, especially in acidic media. Nevertheless, the scarcity and instability seriously impede their large‐scale application in practice. In the past years, metal‐organic frameworks (MOFs) have proven to be an ideal platform for designing efficient and cost‐effective electrodes due to their unique physicochemical properties. In this review, the fundamental catalytic mechanisms of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in acidic media are discussed first. Then, design strategies and advanced characterizations for MOF‐based water‐splitting catalysts are summarized. Finally, the recent research advances of MOF‐based electrocatalysts for HER and OER in acidic electrolytes, along with current challenges and future opportunities, are provided.

Reverse‐Current Tolerance for Hydrogen Evolution Reaction Activity of Lead‐Decorated Nickel Catalysts in Zero‐Gap Alkaline Water Electrolysis Systems

AbstractAlkaline water electrolysis (AWE) systems offer a cost‐effective and scalable approach for large‐scale hydrogen production using renewable energy sources. However, their susceptibility to load fluctuations, particularly the reverse‐current (RC) phenomenon during shutdown events, poses a significant challenge to the long‐term stability and scalability of these systems. Herein, a catalytic approach for enhancing the RC tolerance in AWE systems by using Pb‐decorated Ni cathode catalysts (Pb/Ni) is introduced. The oxidation of Pb/Ni by repeated RC lowers the electromotive force for the reverse current operation, and consequently, imparts RC tolerance. Intriguingly, contrary to the expectation that the decoration with lead, an inert material for the hydrogen evolution reaction (HER), will interfere with the hydrogen generation of the Ni catalyst, the presence of Pb on the Ni cathode after the RC flow promotes both the proton desorption and water‐dissociation steps, improving the HER activity. Furthermore, the AWE stack testing with Pb/Ni catalysts is perfectly operated, demonstrating remarkably enhanced RC tolerance during startup/shut‐down (SU/SD) testing protocol. This paper presents a new strategy for mitigating the AWE performance degradation induced by RC flow and for achieving Pb/Ni catalysts with improved operational durability against RC flow in AWE systems.

Improved control-oriented polarization characteristic modeling for proton exchange membrane water electrolyzer with adaptive hunting game based metaheuristic optimization

The proton exchange membrane water electrolyzer has garnered increasing attention for the large-scale consumption of intermittent renewable energy to produce high purity “green hydrogen”, contributing to the realization of futural carbon neutrality goals. The necessity of control-oriented polarization characteristic modeling with accurate parameter identification remains a significant challenge for the performance evaluation of this type of water electrolyzer. In this paper, an improved control-oriented polarization characteristic modeling for proton exchange membrane water electrolyzer with adaptive hunting game based metaheuristic optimization is proposed to foster collaborative performance enhancement between model improvement and optimizer investigation. The inspiration behind model improvement lies in the nonlinear mechanism linkage between partial pressures of liquid water supplying and anode gas separator. Then, an adaptive hunting game based metaheuristic optimizer is proposed to address the inherent local multi-extremum distribution problem in the established model. Experimental data from a commercial water electrolyzer system is used to validate the effectiveness and practicability of the proposed model-optimizer pair. Detailed comparisons reveal that the improved model development, with its consideration of critical mechanisms, ensures enhanced metaheuristic efficiency in the designed optimizer, both in terms of robust intensity evaluation and efficient quasi-Newton based local search. Statistically, the collaboration performance enhancement reaches up to 7.33% when compared with the other model-optimizer.

Robust poly(p‐phenylene oxide) anion exchange membranes reinforced with pore‐filling technique for water electrolysis

AbstractMechanical robustness and durability are crucial for anion exchange membranes to guarantee the longevity and consistent performance of AEM water electrolysis (AEMWE) systems. In this study, a composite membrane based on the quaternized poly(p‐phenylene oxide) (QPPO)/polytetrafluoroethylene (PTFE) was developed. This membrane was fabricated by enhancing the QPPO‐based AEM through a pore‐filling technique within a porous PTFE structure. The tensile strength of the composite membrane was increased significantly from 16.5 to 31 MPa. The conductivity of the composite membrane was 6.25 mScm−1 lower than 30 mScm−1 of the QPPO‐based membrane at 20°C, resulting from the low volume fraction of QPPO in the composite membrane. At 40% RH, the net change mass of the composite membrane is 1.59%, much lower than that of QPPO‐based membrane (10.98%) at 40°C. The composite membrane demonstrated a significantly increased lifetime in the working electrolyzer (>200 h) compared with an otherwise identical electrolyzer assembled with a QPPO‐based membrane (50 h).

Novel renewable seawater desalination system using hydrogen as energy carrier for self-sustaining community

This study proposes a novel renewable seawater desalination system in which hydrogen is utilized as an energy carrier to balance the fluctuating electricity supply and demand and provide heat to the desalination system. The proposed system employs a water‑hydrogen nexus framework to achieve an efficient operation for providing electricity, potable water, and green hydrogen. The optimal system configuration that considers seasonal variations in renewable energy production is determined by using a heuristic algorithm. It can sustain flexible and standalone operations with less curtailment. The results demonstrate that the system has an average efficiency of 38.9 %, which is higher than the results reported in previous studies. The daily differences in system efficiency are primarily caused by the solar and water electrolysis systems. Curtailment rates of 5 % to 14 % during the operation are owing to the energy storage capacity and supply-demand balance. A higher utilization rate of water electrolysis and fuel cell systems is beneficial for profitability. However, the present utilization rate ranges from 40 %–60 % for water electrolysis systems and <20% for fuel cell systems. Thus, an integrated net-zero system of water electrolysis and fuel cells is proposed, which can be used as a substitute for traditional fossil-based desalination plants.

Increased Readiness for Water Splitting: NiO-Induced Weakening of Bonds in Water Molecules as Possible Cause of Ultra-Low Oxygen Evolution Potential.

The development of non-precious metal-based electrodes that actively and stably support the oxygen evolution reaction (OER) in water electrolysis systems remains a challenge, especially at low pH levels. The recently published study has conclusively shown that the addition of haematite to H2SO4 is a highly effective method of significantly reducing oxygen evolution overpotential and extending anode life. The far superior result is achieved by concentrating oxygen evolution centres on the oxide particles rather than on the electrode. However, unsatisfactory Faradaic efficiencies of the OER and hydrogen evolution reaction (HER) parts as well as the required high haematite load impede applicability and upscaling of this process. Here it is shown that the same performance is achieved with three times less metal oxide powder if NiO/H2SO4 suspensions are used along with stainless steel anodes. The reason for the enormous improvement in OER performance by adding NiO to the electrolyte is the weakening of the intramolecular O─H bond in the water molecules, which is under the direct influence of the nickel oxide suspended in the electrolyte. The manipulation of bonds in water molecules to increase the tendency of the water to split is a ground-breaking development, as shown in this first example.

Electrochemical Water Splitting for Scale Hydrogen Production: From the Laboratory to Industrial Applications

AbstractHydrogen energy is an important carrier for global energy transformation and development due to its advantages of rich sources, green and carbon‐free, and wide application. The generation of clean hydrogen can be achieved through electrochemical water splitting driven by renewable energy, which has gained wide attention, but its large‐scale industrial application still faces challenges. This review summarizes the research status and bottleneck of industrial hydrogen production via electrolysis in developing electrocatalysts and optimizing electrolytic systems. It highlights that the deviation of electrocatalysts developed in the laboratory and their industrial application in the working environment and evaluation indicators should be corrected. Combining material recycling from solid waste with the recyclable design of electrocatalysts is necessary to achieve low‐cost and sustainable production of high‐performance electrocatalysts. In addition, the future design of hybrid water electrolysis with low energy consumption and the ecological cycle issues that should be addressed in the industrial water electrolysis system are discussed.

Organic Catalysis Promotor for Advanced Water Electrolysis

AbstractAchieving carbon neutrality necessitates large‐scale water electrolyzers for green hydrogen production. Accordingly, it is emphasized to develop promising catalyst candidates, which can simultaneously achieve high catalysis efficiency, environmental friendliness, and sustainability. Recently, 3d‐transition‐metal–based catalysts are proposed to replace noble‐metal–based catalysts, which have limited reserves and emit CO2 during their production; however, the limited catalytic performance of 3d‐transition‐metal–based catalysts introduces a tradeoff. Therefore, in this work, the authors focus on suggesting a breakthrough that can intrinsically enhance the catalysis efficiency by adopting a new component in water electrolysis system. Here, a novel concept of organic catalysis promotor (OCP), dissolved in the electrolyte as an additive, which accelerates the sluggish oxygen evolution reaction in alkaline‐based water electrolysis, currently the most mature technology, is proposed. OCP acts as a liquid‐phase cocatalyst, decreasing the activation energy of oxygen evolution reaction by spontaneous chemical reduction to extract an electron from the reaction intermediates. This innovative approach of adopting the OCP of the 2,2,6,6‐tetramethylpiperidine‐1‐oxyl series significantly decreases the overpotential and shows successful general applicability, offering a new rudder in shifting the energy paradigm toward carbon neutrality.

Electrodeposited Large-Area Nickel-Alloy Electrocatalysts for Alkaline Hydrogen Evolution under Industrially Relevant Conditions

Developing efficient water splitting electrocatalysts plays a critical role in lowering the energy cost for hydrogen production, which requires accurate evaluation of the catalytic performance especially under industrially relevant conditions. In this work, we design a two-chamber electrolyzer testing system simulating practical water electrolyzer system to enable catalytic performance evaluation under industrially relevant conditions. A one-step electrodeposition method is used to synthesize binary and ternary Ni alloy HER catalysts and the catalytic electrodes are screened and optimized with the two-chamber electrolyzer testing system. A voltage of 1.64V without iR compensation at a current density of 200mA/cm2 is obtained with continuous operation for 70h. Different HER activity trend is observed from conventional three-electrode experiments with low-concentration alkaline electrolytes at room temperature and the two-chamber electrolyzer measurements, further supporting the importance of catalytic performance evaluation under industrially relevant conditions. The electrodeposition synthesis method is further used to prepare large-area catalytic electrodes over 400 cm2 with good uniformity.

Transition metal nitride/sulfide nanoparticles attached to nitrogen-doped carbon nanotubes synthesized by modified black powder detonation for efficient overall water splitting

To overcome the energy crisis, the rational construction of efficient electrolytic water catalysts is urgently required. Herein, an innovative proposal was presented for the preparation of self-supported electrolytic water catalysts on nickel foam (NF) substrates using modified black powder (BP) detonation method. The transient high temperature of the controlled detonation can obtain a variety of highly active catalytic components. First, carbon nanotubes (CNTs) were immobilized on NF by electroplating nickel to improve the pore utilization and electrical conductivity of NF. The unique hollow channel structure and extensive surface area of CNTs facilitated the attachment of the active catalysts. The introduction of Co metal salt not only controlled the reaction degreed effectively but also served as an effective transition metal source. With sulfur (S) source in BP and the additional nitrogen (N) source, the detonation successfully produced nano Co5.47N and Ni3S2. Nanocrystals Co5.47N and Ni3S2 along with N-doped CNTs, acquired via transient high-temperature reaction, were abound in defects. Consequently, the obtained sample exhibited excellent catalytic activities for both hydrogen evolution and oxygen evolution reactions. A remarkable overall water-splitting was achieved at a voltage of 1.52 V at 10 mA cm−2 in a two-electrode water electrolysis system.

Capacitance Determination for the Evaluation of Electrochemically Active Surface Area in a Catalyst Layer of NiFe-Layered Double Hydroxides for Anion Exchange Membrane Water Electrolyser.

The determination of the electrochemically active surface area (ECSA) of a catalyst layer (CL) of a non-precious metal catalyst is of fundamental importance in optimizing the design of a durable CL for anion exchange membrane (AEM) water electrolysis, but has yet to be developed. Traditional double layer capacitance (Cdl), measured by cyclic voltammetry (CV), is not suitable for the estimation of the ECSA due to the nonconductive nature of Ni-based oxides and hydroxides in the non-Faradaic region. This paper analyses the applicability of electrochemical impedance spectroscopy (EIS) compared to CV in determining capacitances for the estimation of the ECSA of AEM-based CLs in an aqueous KOH electrolyte solution. A porous electrode transmission line (TML) model was employed to obtain the capacitance-voltage dependence from 1.0 V to 1.5 V at 20 mV intervals, covering both non-Faradic and Faradic regions. This allows for the identification of the contribution of a NiFe-layered double hydroxide (LDH) catalyst and supports in a CL, to capacitances in both non-Faradic and Faradic regions. A nearly constant double layer capacitance (Qdl) observed in the non-Faradic region represents the interfaces between catalyst supports and electrolytes. The capacitance determined in the Faradic region by EIS experiences a peak capacitance (QF), which represents the maximum achievable ECSA in an AEMCL during reactions. The EIS method was additionally validated in durability testing. An approximate 30% loss of QF was noted while Qdl remained unchanged following an eight-week test at 1 A/cm2 constant current density, implying that QF, determined by EIS, is sensitive to and therefore suitable for assessing the loss of ECSA. This universal method can provide a reasonable estimate of catalyst utilization and enable the monitoring of catalyst degradation in CLs, in particular in liquid alkaline electrolyte water electrolysis systems.

Electrochemical behavior of Pt nano-particles dispersed on Cu/Ni electrode in alkaline environment

The development of a low-cost Pt-based electrocatalyst for industrial water splitting is important. In this study, to prepare cost-efficient Pt-based electrocatalyst for hydrogen evolution, Cu electrode is deposited with nickel (Cu/Ni) and this surface is modified with Pt nanoparticles by electrodeposition method (Cu/Ni–Pt). The surface properties of the produced electrocatalysts are studied via X-ray diffraction (XRD), scanning electron spectroscopy (SEM), energy dispersive X-ray analysis (EDX), transmission electron microscopy (TEM) and atomic force microscopy (AFM). Characterizations demonstrated that the coating is homogeneous and compact. Hydrogen evolution and corrosion behaviors of prepared electrode (Cu/Ni–Pt) are examined in 1.0 M KOH solution using cyclic voltammetry (CV) and cathodic and anodic current-potential curves, electrochemical impedance spectroscopy (EIS). Tafel slope is determined to be 133 mV dec−1 on Cu/Ni–Pt. Very high exchange current density (5.65 mA cm−2) and very low charge transfer resistance (0.91 Ω cm2 at 1.05 V vs RHE) are measured again on this electrocatalyst. High activity is due to intrinsic activity of Pt and synergistic interaction of Pt and Ni. Besides, Cu/Ni–Pt exhibits so stable structure over 4 h without any current densities decay as well as showing good corrosion performance after long-term immersion times and these properties make it possible electrocatalyst with high corrosion resistant and activity in the water electrolysis systems.

Design of polybenzimidazolium membranes for use in vanadium redox flow batteries.

In recent years, polybenzimidazole (PBI) membranes have been proposed for vanadium redox flow batteries (VRFBs) as an alternative to perfluoroalkylsulfonic acid membranes such as Nafion™. Despite their excellent capacity retention, PBI membranes tend to suffer from a low ionic conductivity. The formation of a polybenzimidazolium through an N-alkylation of the benzimidazole core is shown to improve the ionic conductivity of the membrane, with this class of materials having found uses in alkaline fuel cell and water electrolysis systems. However, much less is known about their incorporation into a VRFB. This article describes the use of hexamethyl-p-terphenyl polybenzimidazolium (HMT-PMBI) membranes for a vanadium redox flow battery, with the membrane characteristics in acidic media being related to their performance in a single-cell VRFB setup. A change of the degree of methylation from 56 to 65, 75, and 89% leads to an increase in ionic conductivity, correlated with an increased fraction of free water in the ionomer. The corresponding increase in cell performance is, however, accompanied by a drop in capacity retention. The membrane with a degree of methylation of 65% shows balanced properties, with a 5% higher efficiency and a two times improved capacity retention compared to Nafion™ NR212 over 200 charge-discharge cycles at 200 mA cm-2.

Feasibility analysis and Atlas for green hydrogen project in MENA region: Production, cost, and environmental maps

Renewable energy markets in the Middle East and North Africa (MENA) countries are growing quickly. Therefore, the objective of the current study is to investigate the feasibility of green hydrogen production based on the meteorological conditions within each MENAcountry utilizing a water electrolysis system powered by available solar and wind energies. In addition, it shows the opportunities for constructing hydrogen projects in MENA countries based on the available power, system performance, cost, and CO2 emission mitigation. The simulation is conducted using MATLAB/Simulink software. In addition, five degradation rates are examined in economic analysis in the context of hydrogen production from photovoltaic panels and wind turbines due to the unpredictability of the future value of money. The results revealed that the highest hydrogen production density for WT/H2 is 1.29 kg/m2 in Morocco, 1.26 kg/m2 in Egypt, 5.7 kg/m2 in Saudi Arabia, and 5.58 kg/m2 in Egypt for PV/H2. The WT/H2 system is more efficient than the PV/H2 system, with a maximum value of 31.54 %. The minimal production cost is 2.12 $/kg in Morocco and 2.17 $/kg in Egypt for the WT/H2. In the case of PV/H2, it is 3.28 $/kg in Saudi Arabia and 3.35 $/kg in Egypt. MENA countries have significant potential in hydrogen production and hydrogen investment. The range of CO2 mitigation lies between 11.47 and 87.4 kgCO2/m2. Finally, the current investigation revealed that the MENA region has an excellent opportunity to construct green hydrogen production projects based on wind/solar energies.

Enhanced H2 production assisted by anodic iodide oxidation using transparent tin oxide-based electrodes.

In this work, the direct use of transparent conducting oxides (TCOs) as cost-efficient anodes for the iodide oxidation reaction (IOR) is explored. Energy-saving hydrogen production assisted by the IOR is demonstrated using a hybrid water electrolysis system with FTO as the anode and Pt-wire as the cathode. The hybrid system delivers 10 mA cm-2 at a cell voltage as low as 1.15 V with the faradaic efficiency for H2 found to be ∼91%. This study may open avenues for developing novel systems that integrate the IOR with other high-value reduction reactions.

Investigation into the hydrogen production performance of a novel 5-kW hybrid-system composed of a solar steam generator directly connected with conventional solid oxide electrolysis cells

Coupling solar energy with solid oxide electrolysis cell has the potential to reduce electricity consumption and improve energy conversion efficiency. This study introduces a pioneering 5 kW direct-connected hybrid system that couples a solar steam generator with solid oxide electrolysis cells utilizing conventional electrical energy for the electrolysis process. The successful demonstration of hydrogen production showcases promising results. When the solar irradiation power is 2.26 kW, the inlet water flow rate is 1.23 kg/h under operations at 700 °C, the hydrogen production efficiency of the system reaches 95.2 %, and the steam conversion ratio approaches 92 %, giving a cumulative hydrogen production yield of 5,840 NL in 6.3 h. The solid oxide electrolysis system is further tested under different operating conditions of the stack and solar irradiation. The experimental results show that a greater operating temperature is conducive to more efficient hydrogen production, while more water vapor at the cathode leads to a larger steam conversion ratio. The results indicate that increasing the irradiation power is beneficial to hydrogen production while decreasing the irradiation power will lead to fluctuations of hydrogen yield. In addition, the system efficiency (45.3 %) is higher than that of a photovoltaic alkaline water electrolysis (12.6 %) or photovoltaic proton exchange membrane electrolysis (14.76 %) system at the same irradiation power. Under the same electrolysis power and cathode inlet temperature, the total power consumption of a traditional solid oxide electrolysis system is significantly greater than that of the proposed hybrid system. The comparison shows that the saved electricity of the proposed hybrid system can account for about 30 %. Therefore, the proposed hybrid system has significant efficiency and power savings advantages.

(Digital Presentation) Dynamic Thermal Detection of Water Electrolyzer with Dual-Layer Characteristic Temperature Based on IR

As the prevalence of water electrolysis systems continues to expand, increased attention has been placed on the dynamic thermal detection of the electrolyzer. Presently, the scope of dynamic thermal detection for water electrolysis systems is limited to solely the temperatures at the inlet and outlet. This study propounds a novel dual-layer characteristics temperature (DLCT) model for the purpose of water electrolyzer temperature monitoring. The DLCT model addresses two significant issues of the dynamic thermal detection of the WEE: characteristic temperature extraction difficulty and signal perturbation caused by auxiliary factors. The first layer of multi-gaussian distribution (MGD) regression in the DLCT model quantifies the sectional temperature of the electrolyzer surface and produces numerous potential characteristic temperatures (CT). These temperatures are subsequently assigned to each section and are then conveyed to the second layer of linear regression, which provides an incisive quantized temperature variation pattern for the electrolyzer surface temperature distribution. Importantly, the DLCT model requires no supplementary modifications to the water electrolysis system or the installation of temperature sensors within or on the surface. By employing the DLCT model during dynamic operation, the ability to monitor the temperature of the electrolyzer comprehensively is improved, the temperature distribution of the electrolyzer can be quantized and richer insights regarding the surface temperature distribution can be gained, promoting better thermal uniformity, as well as pin-pointing the potential hot spot. Hence this method can also be used for structure design to produce better uniformity. The dynamic temperature detection results under different operating conditions are analyzed, and it can be concluded that the operating parameters, especially the lye circulation flow, can greatly influence the temperature distribution uniformity of the electrolyzer significantly. In conclusion, the DLCT model effectively handles the two primary challenges in dynamic thermal detection of water electrolysis systems by providing global and sectional characteristic temperature readings, enabling electrolyzer to be monitored holistically. So that future improvement regarding both structural and operational optimization can be conducted in improving the thermal uniformity. Figure 1