The low-order normal modes with small grazing angles (SGA) often control long-range sound field characteristics in shallow water. The SGA reflection loss from a half-space low-velocity bottom (LVB) is independent of the sound attenuation, except around the angle of complete transmission; the SGA bottom reflection loss (BRL) from a seafloor with a top low-velocity layer is very insensitive to the LVB attenuation also, except around a few selected frequencies. Thus, the "seafloor velocity-attenuation coupling" problem will be more fatal for LVB geo-acoustic inversions. The dispersion equation of the normal modes in the LVB layer is coincidentally the same as the singularity expression of the SGA reflection coefficient in the water column, resulting in a sound siphon effect that causes the abnormally high SGA BRL and transmission loss in the water at the siphon frequencies. The siphon effect is very sensitive to seafloor acoustic parameters, might offer a physical base for geo-acoustic inversion, and show a dim light in a "gray area" for inverting the LVB sound attenuation at low to mid frequencies. As an example, the acoustic siphon effect and related seafloor geophysical parameters forming it in the Yellow Sea are reported in this paper.