Passive daytime radiative cooling (PDRC) materials are beneficial to energy conservation and emission reduction of buildings. Currently, the design of PDRC coatings for exterior walls and roofs of buildings places excessive emphasis on improving the solar reflectance (Rs) and infrared emissivity (Ei) of the coating, while neglecting other important properties of building coatings, such as adhesion, waterproofness, corrosion resistance, and weather resistance. To address these deficiencies, this work developed a (calcined zeolite)/polyurea (CZ/PU) PDRC coating with excellent comprehensive performance for building exterior walls and roofs, using CZ and PU as raw materials. The CZ/PU coating is prepared using a method that is completely consistent with existing paint production and construction techniques, and can be applied to large-area building surfaces at scale. The Rs of the CZ/PU coating is 97.4 %, and the Ei is 94.4 %. Under direct sunlight in summer, the CZ/PU coating achieved significant PDRC effects under both adiabatic conditions (using test equipment to reduce heat conduction and convection) and natural conditions. The corresponding radiative cooling temperatures are 14.9 °C and 4.4 °C, respectively. In addition, the CZ/PU coating also exhibits excellent water resistance, reducing the capillary water absorption rate of a cement block by 78 %. In addition, the adhesion strength of the CZ/PU coating to the substrate reached the highest rating (rating 0). In particular, the optical properties, radiative cooling function, water absorption, and adhesion force of the CZ/PU coating showed ultra high stability in ultraviolet aging experiments. Energy consumption simulations show that the average energy saving efficiency of the CZ/PU coating on the annual total building energy consumption of ten typical Chinese cities is as high as 13.3 %. The CZ/PU-based coating developed in this work comprehensively considers various issues that may be faced in the practical application of radiative cooling architectural exterior wall coatings, providing an experimental foundation for promoting the application of radiative cooling coatings in buildings.