Recent advances in thermal localization-based passive solar desalination provide a great opportunity for the economical generation of freshwater, particularly in regions with insufficient energy and water infrastructure. Yet, the capillary-assisted passive desalination systems with a high-water productivity flux (measured in Lm−2 h−1) suffer from the issue of performance degradation due to salt accumulation and the inability to be scaled up. In this work, we propose siphon-based supply of saline water over the evaporator that enables scale up of the desalination system to a size significantly higher than the capillary rise height of the hydrophilic evaporator while preventing salt accumulation on the evaporator. The composite siphon comprises insulating fabric wick and a metallic grooved surface for localizing heat to evaporate a thin layer of saline liquid over the evaporator. We perform heat and mass transfer analysis to show that the thermal-to-vapor efficiency depends on the inlet mass flow rate and air gap between the evaporator and the condenser. We propose a methodology to passively control the mass flow rate to maximize the thermal to vapor efficiency at different input heat flux and initial concentration of the brine. A grooved condenser avoids mixing of brine and the freshwater, even at air gaps as low as 2 mm. A siphon-assisted 10-stage desalination system with a footprint area 15 cm × 15 cm and an air gap of 2 mm is shown to have a high water productivity flux of ∼5.73 Lm−2 h−1 from 3.5 wt% saline water at an applied heat flux 1000 W/m2, which increases to a record high distillate flux of ∼6.23 Lm−2 h−1 and thermal to water collection efficiency of ∼423 % for a 15-stage system. The ability of the desalination system to maintain a high-water productivity flux even when the evaporator area is increased by 4 times demonstrates its scalability to achieve higher desalinated water productivity rate.
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