Textile Waste Research Articles

Synthesis of Bio-Oil via Catalytic Co-Pyrolysis of Cotton Fabric Waste and Polypropylene Plastic Waste

The growing energy demand and rising environmental concerns pose severe difficulties for future generations in maintaining energy sustainability. Therefore, it is critical to explore alternative green energy sources. Hence, this study synthesized renewable bio-oil by utilizing biomass of cotton fabric waste (CFW) and polypropylene plastic waste (PPW) as feedstocks. Titanium and alumina extracted from industrial solid waste (Ti-EA) were selected as catalysts due to their active sites promoting co-pyrolysis reaction towards bio-oil formation. The Ti-EA catalyst was prepared via the wet impregnation method at different calcination times. The bio-oil was synthesized via co-pyrolysis of CFW and PPW in a fixed bed reactor at the reaction temperature of 600 °C for 1 h. The effects of the catalyst calcination time were evaluated based on the bio-oil yield and product distribution. Moreover, the catalysts were characterized by BET and FTIR. The findings show that the Ti-EA catalyst calcined at 4 h (Ti-EA-4) obtained the highest bio-oil yield of 68% whereas calcination at 6 h (Ti-EA-6) gave the lowest yield of 28%. The BET shows that the Ti-EA-4 catalyst has a higher surface area of 121.6 m2/g than the Ti-EA-6 catalyst of 96.74 m2/g. This indicates that surface area is an important characteristic that promotes efficient catalytic activity for bio-oil production. Meanwhile, FTIR results show that the catalysts have similar surface functional groups mainly O-H stretching vibrations. Overall, Ti-EA catalyst calcined at 4 h has exhibited good performance in producing bio-oil via co-pyrolysis of CFW and PPW. Thus, Ti-EA catalyst has the potential to produce bio-oil as fuel, which contributes towards waste to energy conversion and environmental preservation.

Recovery of pure PET from wool/PET/elastane textile waste through step-wise enzymatic and chemical processing

Textile waste is mostly incinerated because few recycling processes are available to recover valuable materials. In this work, a feasible chemo-enzymatic recycling process of wool/polyethylene terephthalate (PET)/elastane blends to recover pure PET is for the first time successfully demonstrated. Two novel enzyme formulations were selected for wool hydrolysis, whereas the recovered amino acids were quantified using high-performance liquid chromatography and two assays (Ninhydrin and Folin–Ciocalteu). Kinetic studies on the amino acid formation alongside reaction observations by scanning electron microscopy proved sufficient removal of wool within 8 hours with the new enzyme formulation, marking an acceleration compared to previous studies. Finally, elastane was separated with a non-hazardous solvent to obtain pure PET. Tensile tests on the recovered PET fibres reveal only slight changes through the enzymatic treatment and no changes induced by the applied solvent. The enzyme formulation was successfully tested on five different post-consumer wool/PET textile waste samples. This valorization approach enhances the circular economy concept for textile waste recycling.

Microbiology of Industrial, Textile, Domestic and Fish Liquid Waste Treatment (Literature Review)

Microbiological research on waste treatment has been conducted to reduce the concentration of waste pollutants, such as ammonia, nitrites, and sulfide acids. Treatment of Fish Washing Waste with Microorganisms Rhodopseudomonas sp., Lactobacillus sp., Aspergillus sp., Penicilium sp., Sacharomyces sp., and Actinomycets sp. to reduce contaminants from cod fish washing waste. The addition of microorganisms can decrease the concentration of ammonia, nitrite, and sulfic acid. Research on the Identification of Organic Pollutant Decomposing Bacteria in Domestic Wastewater found Eschericia coli, Acinetobacter iwoffii, Acinetobacter haemolyticus, Proteus mirabilis, and Pseudomonas sp. The Role of Aerobic Microbes in Liquid Waste Treatment in textile waste treatment, especially in the process of activated sludge ponds found that microbes can reduce the concentration of BOD parameters in textile waste. Bioremediation methods that use microorganism agents can be used to degrade organic materials in waste. Microorganisms have been used to reduce the concentration of waste pollutants, such as ammonia, nitrite, and sulfide acid and microorganisms can be effective in reducing the concentration of waste pollutants.

Recycled Jute Non-Woven Material Coated with Polyaniline/TiO2 Nanocomposite for Removal of Heavy Metal Ions from Water.

Growing volumes of textile waste and heavy metal pollution of water are emerging environmental challenges. In an attempt to tackle these issues, a non-woven sorbent based on jute fibers was fabricated by recycling the textile waste from the carpet industry. The influence of contact time, concentration, pH and temperature on the sorption of lead and copper ions from aqueous solutions was studied. In order to enhance the sorption capacity of the non-woven material, in situ synthesis of polyaniline (PANI) in the presence of TiO2 nanostructures was performed. The contribution of TiO2 nanoparticles and TiO2 nanotubes to the uniformity of PANI coating and overall sorption behavior was compared. Electrokinetic measurements indicated increased swelling of modified fibers. FTIR and Raman spectroscopy revealed the formation of the emeraldine base form of PANI. FESEM confirmed the creation of the uniform nanocomposite coating over jute fibers. The modification with PANI/TiO2 nanocomposite resulted in a more than 3-fold greater sorption capacity of the material for lead ions, and a 2-fold greater absorption capacity for copper ions independently of applied TiO2 nanostructure. The participation of both TiO2 nanostructures in PANI synthesis resulted in excellent cover of jute fibers, but the form of TiO2 had a negligible effect on metal ion uptake.

Modified Cellulose-Based Waste for Enhanced Adsorption of Selected Heavy Metals from Wastewater.

Due to industrial growth and its impact on the environment, the increasing amount of industrial waste requires a comprehensive approach aligned with the principles of sustainable development. The main goals are not only to preserve natural resources but also to encourage innovation in the reuse of waste materials. In an attempt to reduce the problems regarding waste disposal and wastewater treatment in the textile industry, fibrous textile waste was used as a starting material to obtain carbon adsorbents for the removal of pollutants from wastewater. Waste cotton and mixed yarns, mainly consisting of polysaccharide cellulose, were hydrothermally carbonized and activated with KOH to convert them into efficient carbon adsorbents for heavy metal removal from water. Characterization of carbonized material showed that after activation, an increase in specific surface area (up to 872 m2/g) and content of surface oxygen groups (6.04 mmol/g) leads to a higher affinity towards heavy metal ions, especially lead ions, and high adsorption capacity of 19.98 mg/g obtained for activated cotton yarns. The results of this research represent a contribution to the reduction of waste materials by modifying them into adsorbents, while the regeneration of adsorbents is an example of the practical application of polysaccharide-based materials in the purification of wastewater containing various heavy metal ions.

Pyrolysis-gas chromatography/mass spectrometry analysis as a useful tool in identifying fibre composition in mixed post-consumer textile waste

The progress of textile recycling is significantly impeded by the absence of adequate methodologies for determining the composition of fibres in textile blends. The examination of textile mixtures poses considerable difficulties, particularly due to the presence of elastane fibres, which in their limited quantities cannot be easily detected using conventional analytical techniques. Further, the undetected elastane fibres pose difficulty in separation during recycling of the textiles as they end up as impurities in cases where dissolution of the fibres is employed. Consequently, it is of utmost importance to explore new analytical tools that possess the capability to identify the primary fibres in post-consumer waste. In the current investigation, we conducted a study to assess the capabilities of Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Pyrolysis coupled with Gas Chromatography and Mass Spectrometry (Py-GC/MS) for the characterization of postconsumer textile fabrics. A comprehensive pyrolysis database was established encompassing prevalent pure fibres commonly employed in textile production. In addition, an examination was conducted on three textile blends with predetermined compositions, and the findings were subsequently compared with data obtained through the utilization of ATR-FTIR. The data derived from the original fibres was ultimately utilized for the examination of post-consumer fabric samples acquired from a waste landfill. The utilization of Py-GC/MS, scanning electron microscopy (SEM) and ATR-FTIR enabled to discern fibre compositions of mixtures even those that contained relatively low fibre content.

Establishment of circular economy by utilising textile industry waste as an adsorbent for textile dye removal

This study explored the use of waste from the textile industry (silkworm byproducts) as a promising raw feedstock for the production of carbon-based adsorbents (biochar). The silk excreta biochar generated at 600 and 700 °C (referred to as SEB-600 and SEB-700, respectively) were evaluated in terms of their efficacy in adsorbing cationic (methylene blue) and anionic (Congo red) textile dyes. Although the functional groups on the surfaces of SEB-600 and SEB-700 were not significantly different, the specific surface area of SEB-700 was greater than that of SEB-600. The dye adsorption capacity of SEB-700 was higher than that of SEB-600. The adsorption of methylene blue and Congo red on SEB-700 followed Freundlich isotherms (R2 ≥ 0.963) and pseudo-second-order kinetics (R2 = 0.999), indicating chemisorption with multilayer characteristics. The mechanism for the adsorption of methylene blue on SEB-700 may involve interactions with the negatively charged functional groups on the surface and the mesopores of SEB-700. For the adsorption of Congo red, the mesopores in the biochar and the electrostatic interaction between biochar (positively charged because of the dye solution pH < pHzpc) and the anionic dye could affect adsorption. The maximum adsorption capacities of SEB-700 for methylene blue and Congo red were determined to be 168.23 and 185.32 mg g−1, respectively. Utilising the waste generated from the textile industry to remove pollutants will build a sustainable loop in the industry by minimising waste generation and pollutant emissions.

Using CO2 in pyrolysis to neutralise toxic aromatic compounds derived from blended textile waste

Blended textiles are favoured for their enhanced properties, combining the strengths of constituent fibres (typically synthetic fibres integrated with natural cellulosic fibres). However, the presence of aromatic components in blended textile waste (BTW) complicates its disposal and raises environmental concerns due to the release of toxic chemicals. To resolve this issue, this study suggests a pyrolysis system as a strategy to neutralise toxic aromatic compounds derived from BTW. Carbon dioxide (CO2) was used as the partial oxidative reagent. The characterisation of BTW revealed its composition, containing rayon and polyester. The complex composition of BTW, particularly the recalcitrant nature of polyester, leads to the massive generation of toxic aromatic chemicals, such as terephthalic acid and its analogues, during thermolysis. However, introducing CO2 to pyrolysis facilitates interacting with these toxic compounds, converting them into carbon monoxide (CO). The effectiveness of CO2 for the suppression of toxic aromatic formations was further enhanced when adopting a nickel-based catalyst. CO2-assisted catalytic pyrolysis achieved a 64.87 % reduction in toxic aromatic chemicals and an 11.36-fold increase in CO production compared with conventional pyrolysis. This study presents a promising approach for the sustainable disposal of BTW, emphasising the oxidative functionality of CO2 in neutralising toxic aromatic chemicals into detoxified products, especially CO.

Heterogeneous E‐Textiles: Materials, Manufacturing and Sustainability

AbstractElectronic textiles (e‐textiles) combine electronic functions (e.g., sensing, actuating, data processing) with textiles. E‐textiles are a platform technology with the potential for ubiquitous deployment in any application scenario where textiles can be found. E‐textiles have attracted significant research interests from materials and manufacturing process development to applications such as sports/fitness, healthcare, and workwear. While significant advances have been made in the research domain regarding the integration of electronic functionality, the technology is relatively immature and significant challenges remain in the manufacturing of commercialized e‐textile systems. This paper reviews the state of the art in e‐textile manufacturing including materials (e.g., yarns, inks), fabrication (e.g., weaving, knitting, printing), electronic integration and interconnections. This paper also reviews the key principles of textile sustainability and electronic waste (e‐wastemanagement, which provide useful guidance on e‐textile design and manufacturing to minimize their impact on the environment. Examples are given to demonstrate the early work toward sustainable e‐textiles. The remaining research challenges regarding scalable and sustainable manufacturing of e‐textiles are presented.

Properties of hydrogel for adsorbent textile dye waste based cellulose-carboxymethyl sago starch

Abstract The use of a single natural polymer in hydrogel preparations is considered insufficient to produce hydrogels that are more durable, more stable, and stronger. Blends of various natural polymers can improve each sago other’s lack of physicochemical characteristics and produce new properties. This research combines two natural polymers, cellulose and starch. Cellulose isolation from Gracilaria verrucosa seaweed using acid hydrolysis and alkaline autoclaving method produced 14.01% cellulose. This study combined the results of cellulose isolation with carboxymethyl sago starch at 0.09; 0.14 and 0.24 mol/mol AGU. The isolated cellulose-carboxymethyl sago starch has the potential as a hydrogel material with the addition of crosslinkers such as epichlorohydrin (ECH). This study aims to synthesize hydrogels from cellulose-carboxymethyl sago starch with application as a textile dye waste absorbent with a concentration of epichlorohydrin (ECH) at 7.5%. Analysis of carboxymethyl sago starch is degrees of substitution, water-soluble index (WSI), and swelling power (SP). The hydrogel properties are characterized by the degree of swelling, degree of polymerization, FTIR, and SEM, and the hydrogel adsorption ability is characterized by adsorption efficiency using a microplate reader. The research results show that hydrogel can be synthesized optimally by adding carboxymethyl sago starch (CMSS) at 0.24 mol/mol AGU. The results of FTIR analysis are also by chemical measurements (swelling and gel fraction). In contrast, for maximum colour absorption, the addition of carboxymethyl sago starch is 0.09 mol/mol AGU for purple, yellow, and black and 0.14 mol/mol AGU for green color absorption. In conclusion, the adsorption ability of hydrogel in commercial textile dyes is maximum when the carboxymethyl sago starch (CMSS) is added at 0.09 mol/mol AGU with the best adsorption efficiency at purple 86.22%, yellow 77.40%, black 73.70% and at the addition of CMSS 0.14 mol/mol AGU the best adsorption efficiency in green is 73.46%.

DATA ANALYSIS FOR THE PREDICTION OF TEXTILE WASTE RECYCLING IN UKRAINE

The textile and sewing industry is known to be the second most environmentally harmful industry for the environment. To maintain a circular economy, textile sources should be recycled, repaired, and used as much as possible while retaining their value. This research provides primary information about the database of post-production textile waste. The data suggests that 30 garment companies produce 778.11 tons of postproduction textile waste per year, with cotton accounting for 42.14% and polyester for 32.45%. It is important to consider processing waste using different technologies according to the certification of textile waste to determine its raw material composition and purity. For an effective waste management policy, it is essential to implement it systematically, continually assess outcomes and challenges, and involve all stakeholders and activities that generate and manage waste. This is crucial in formulating an effective waste management policy.

Histology of skin, gill, liver, and kidney of tilapia Oreochromis niloticus exposed by azo dyes acid red 88.

Abstract Coloring is one of the main process in textile production. Using azo dyes type are the first pick of textile industries. Therefore, the disposal of dye waste containing high levels of azo can increase the toxicity level also impact the fish. Acid Red 88 is an azo type dye which provides a red color as the basic color for coloring textile products. Acid Red 88 are left behind as much as 60% of textile waste. the textile factories wastewater in Indonesia contains an average of 750 mg/L suspended solids. The aim of this study was to determine the effect of azo dye Acid Red 88 exposure to tilapia by the histology of its skin, gills, liver and kidneys. The method used was experimental method with 4 different exposure concentrations of Acid Red 88 P0 (0 mg/L), P1 (75 mg/L), P2 (150 mg/L), P3 (225 mg/L), and P4 (300 mg/L). The damage is identified on the histology of the organs and then measured using a scoring method. The results showed that several damages were found such as epithelial erosion, edema, hyperplasia, telangectasis, hemorage, fatty degeneration, congestion and necrosis.

TG-FTIR-Py-GCMS analysis and catalytic pyrolysis mechanism of textile waste by red mud catalyst for liquid fuel production

The substantial generation of textile waste (TW) and red mud (RM) has resulted in significant resource wastage and environmental challenges. Co-utilization technology of solid waste is an effective approach to improve waste utilization efficiency. In this study, RM catalytic pyrolysis experiments of TW were conducted using TG-FTIR and Py-GC–MS for liquid fuel production, and TW and RM were recycled simultaneously. At the optimal experimental conditions (temperature of 600 °C and feed catalyst ratio of 2:1), the tar yield and higher heating value (HHV) of TW pyrolysis catalyzed by RM were 73.43 wt% and 32.34 kJ/g, respectively. Additionally, experiments on the pyrolysis of various TW types revealed that LDPE and PP are suitable for tar production, while cotton, nylon, and PET are more suitable as feedstock for syngas production. The RM catalytic pyrolysis mechanism of textile waste is that Fe2O3 in RM exhibits significant catalytic activity in enhancing tar and syngas yields. However, during the catalytic process, Fe2O3 undergoes reduction to Fe3O4, resulting in diminished catalytic performance of the RM. After five cycles of use, the RM essentially lost its catalytic activity due to the accumulation of char and tar. All experimental findings of this study could offer an effective guideline for TW recycle and promoting RM utilization toward the waste-to-energy circular economy.

Improving textile waste biodegradation through fungal inoculation

Textile waste currently contributes about 780,000 tonnes of waste to landfill in Australia alone. Within landfill, biodegradable textiles take multiple years to decompose and most synthetic textiles are effectively not biodegradable. Blends of these fiber types are currently too costly to separate and recycle. Decomposition depends on the presence of suitable microorganisms already present in the landfill. This study aimed to investigate which fungi could best be used to pre-inoculate textile waste entering landfill (to reduce volume) or in a composting system (to recover non-biodegradable materials for re-use). Ten textiles were inoculated with 14 fungi well known for their degradative ability and incubated at 25–30°C for 1–2 months. Greatest weight losses (100 %) were achieved by Chaetomium globosum (Ascomycota), Trametes versicolor and Ganoderma species (Basidiomycota). In textiles with mixtures of cellulose with polyester or elastane, only the cellulose fibers were degraded and the other fiber types were left available for recycling. These results suggest that pre-inoculation with the most effective fungi could increase the rate of decay in cellulosic portions of textiles discarded into landfill, at the least reducing textile volumes quickly. Alternatively, aerobic fermentation of textile waste could recover non-biodegradable synthetic fibers for re-processing and re-use in a low-cost and environmentally benign manner, reducing the need for its manufacture de novo from petroleum derivatives.

A Mapping of Textile Waste Recycling Technologies in Europe and Spain

A Mapping of Textile Waste Recycling Technologies in Europe and Spain

Hydrogen-Rich Syngas Production from Waste Textile Gasification Coupling with Catalytic Reforming under Steam Atmosphere

Hydrogen-Rich Syngas Production from Waste Textile Gasification Coupling with Catalytic Reforming under Steam Atmosphere

Post-Consumer Textile Waste Management Practices and Challenges in India: A Systematic Literature Review

Post-Consumer Textile Waste Management Practices and Challenges in India: A Systematic Literature Review

Sustainable removal of pigment dye from traditional batik textile wastewater using ZnO photocatalysis

Wastewater management in the textile industry poses significant challenges, especially for small-scale facilities lacking proper treatment systems. As an alternative solution, in-situ wastewater treatment has gained prominence. Presently, solar-driven photocatalytic materials offer a promising avenue for effective wastewater remediation. This study employed a one-step probe ultrasonication method to synthesize ZnO nanoparticles with exceptional photocatalytic properties. Comprehensive optimization was undertaken to achieve ZnO particles with superior photocatalytic performance. The effects of various parameters, including wave amplitude (ranging from 0 to 80 %), ultrasonication time (from 0 to 45 min), and precursor zinc acetate concentration (between 0.1 to 0.3 M), were thoroughly investigated. By carefully controlling these conditions, non-agglomerated ZnO particles significantly improved photocatalytic activity, especially under visible-light conditions, when treating wastewater from the textile industry. The produce particle at 0.1 M in conjunction with maximum ultrasonication time and amplitude, provide more dispersed particle with smaller particle sizes. The photocatalytic process exhibited remarkable efficiency, with up to 98 % of the textile waste degraded within 60 min of reaction time using the ZnO particle produced under this condition. Moreover, this higher photocatalytic activity was supported by the rate of kinetic constant of 0.0365 min⁻¹, representing the pseudo-first-order kinetic. Furthermore, this research highlights the robust reusability of ZnO as a photocatalytic material, which remained stable even after three consecutive cycles. These findings affirm that ZnO particles synthesized through the probe ultrasonication method hold great potential for treating dye-containing textile effluents, providing a sustainable and effective solution for addressing this environmental concern.

Textile waste pretreatment for anaerobic digestion: a review and technology feasibility study

AbstractThe increasing volume of textile waste in landfills and incineration poses severe environmental challenges. Waste valorisation of textile waste via anaerobic digestion (AD) is preferable, as it offers economic and environmental benefits, but it is hindered by textile complexity, necessitating effective pretreatment technologies to improve biogas production. This study aims to evaluate various pretreatment technologies for biogas production from textile fibres via AD. A weighted‐scoring analysis (WSA) assessed pretreatment methods based on technical, economic, environmental and operational criteria. Hydrothermal pretreatment emerged as the most technically effective method, scoring 140 owing to its substantial methane enhancement. Economically, shredding was the most viable option, scoring 125, as a consequence of low capital and O&amp;M cost. Environmentally, hydrothermal and deep eutectic solvent (DES) pretreatments were top performers with 100 points owing to low environmental impact and positive heat reactions. In a case study conducted in the Auckland region, the potential environmental impact (PEI) obtained from hydrothermal and DES were 169 and 92 per year, respectively, resulting in minimal environmental impact. Operationally, ultrasonic and biological pretreatments scored highest owing to their ease of operation, and minimal health and safety requirements. Overall, hydrothermal pretreatment achieved the highest WSA score of 340, reflecting its balanced performance across all criteria. Hydrothermal pretreatment is the most promising technology for enhancing biogas production from textile waste. Its technical efficiency, economic feasibility and environmental benefits regarding the WSA score make it suitable for upscaling and providing a viable solution for managing textile waste in the AD plant. © 2024 The Author(s). Journal of Chemical Technology and Biotechnology published by John Wiley &amp; Sons Ltd on behalf of Society of Chemical Industry (SCI).

Development of nonwoven mulch mats from textile waste and its performance assessment on for chilli crop

Development of nonwoven mulch mats from textile waste and its performance assessment on for chilli crop