Pyrolysis Of Plastic Waste Research Articles

Management of Plastic Wastes through Recent Advanced Pyrolysis Processes

Plastics are predominant in numerous sectors like packaging, agriculture, hardware, electronics, and many others. Annual plastic demand has been rapidly growing in the last few decades because of the increasing dependency on plastics. As a consequence, massive amounts of plastic waste are being generated every year. These plastic wastes are non-biodegradable, and hence their disposal poses a serious threat to the ecosystem and causes significant environmental problems such as endangering the safety of marine life, wildlife, air, water, and soil, etc. A large portion of plastic waste ends up in landfills, and only a small fraction is recycled. The continuous dependence on landfills as the main disposal method for plastic waste is costly and ineffective. Common solutions to plastic waste management are incineration and recycling; however, incineration emits harmful pollutants and greenhouse gases that contribute to ozone layer depletion and global warming; moreover, recycling is expensive and inefficient. As an alternative to recycling and incineration, the pyrolysis process can convert plastic wastes into more valuable fuel products. Pyrolysis is a thermal process that converts raw material into pyrolysis liquid, solid wax, and non-condensable gases in the absence of oxygen. This process is attractive because it is economical and energy-efficient, and it can be used to convert various types of plastic waste into valuable products. In recent years, there have been significant developments in pyrolysis applications in liquid fuel production from plastic wastes. This work reviews recent advances in and challenges for the pyrolysis process for converting plastic wastes into a valuable alternative fuel, focusing on studies of advanced pyrolysis processes published over the last five years. The paper also highlights the numerical modeling of pyrolysis of plastic wastes and the potential impact of pyrolysis on the future of sustainable waste-management practices of plastics.

Comparing carbon-saving potential of the pyrolysis of non-recycled municipal plastic waste: Influences of system scales and end products

Pyrolysis of non-recycled municipal plastic waste has the potential to mitigate the plastic waste crisis and to produce transport fuels (diesel or hydrogen), as compared with the conventional methods such as incineration or landfilling that have potential adverse environmental consequences. Transport fuel production from non-recycled municipal plastic waste contributes to the transition to more sustainable waste management. However, little is known about the influences of system scales and end product selection on the carbon footprints of the plastic waste treatment. Here, we applied the approach of life cycle assessment to compare the carbon-saving potential of centralized, large-scale and decentralized, small-scale pyrolysis systems producing diesel and hydrogen in the United Kingdom. It is shown that centralized systems had a lower global warming potential results than decentralized systems despite their greater transportation distances. The global warming potentials of diesel production for centralized and decentralized systems were 801 and 1345 kg CO2-eq. per tonne of non-recycled municipal plastic waste, respectively, whilst hydrogen production had much higher global warming potentials which are 7110 and 7990 kg CO2-eq per tonne of non-recycled municipal plastic waste, respectively. In hydrogen-producing systems, crude carbon nanotubes are also produced, and the purification process of carbon nanotubes requires significant material resource (hydrochloric acid and deionized water) inputs, resulting in high Scope 2 and 3 emissions. Also, it is worth noting that the global warming potential related to the Scope 1 emissions for the diesel-producing systems exceeds 80%, whereas the hydrogen-producing systems yield opposite results. The end use of diesel produced has a greater carbon footprint than the end use of hydrogen. The carbon saving from the displacement of fossil hydrogen was two times higher than that from diesel displacement. Decentralized, small-scale hydrogen production from plastic waste had the highest global warming potential among all as the conversion process of municipal plastic waste to hydrogen and carbon nanotubes for small-scale systems is more energy and resource intensive. Sensitivity analysis showed that various factors, such as feedstock composition and the heating energy consumption in the conversion process, had less influence on the global warming potential of centralized systems as compared to decentralized systems.

Optimization of plastic waste pyrolysis using carbon-metal oxide hybrid nanocomposite catalyst: Yield enhancement and energy resource potential

In this study, plastic waste was efficiently converted into valuable energy resources using a unique pyrolysis technique. A carbon-metal oxide hybrid nanocomposite was introduced as a catalyst, and analyses of structural and surface morphology were conducted. Pyrolysis process parameters such as temperature (PTemp), process time (PTime), and catalyst concentration (CC) were optimized through response surface methodology for a higher yield of energy resources. Char underwent proximate and ultimate analyses, oil underwent physicochemical and Fourier transform infrared analyses, and syngas composition was determined. Optimal conditions were found: PTemp 300 °C, PTime 60 min, CC 1 % for char; PTemp 465 °C, PTime 150 min, CC 1 % for oil; PTemp 550 °C, PTime 60 min, CC 4 % for syngas. Compared to the ZSM-5 catalyst, char, oil, and syngas yields increased by 7.9 %, 10.8 %, and 7.2 %, respectively, at optimum conditions. These findings suggest that waste plastic pyrolysis can effectively meet energy demands with enhanced energy outputs.

Performance and emission of a spark-ignition engine using gasoline-plastic pyrolysis oil blends

In response to the problem of plastic waste, this study investigates the conversion of PET waste plastics into Pyrolysis Plastic Oil (PPO) as an environmentally sustainable alternative energy source, aiming to tackle the pressing issue of plastic waste accumulation. Accordingly, the research comprehensively evaluates the physicochemical properties of PPO, examines its impact on engine performance, and determines the optimal concentrations for blending with gasoline. The investigation uncovers the potential of PPO through precise material preparation involving PET plastic waste pyrolysis, employing meticulous testing and analysis for comprehensive insights. Engine testing, conducted on a 125 cc, 4-stroke motorized vehicle, scrutinizes power, torque, and exhaust emissions under various PPO and gasoline blends. The findings reveal distinctive relationships between PPO ratios and engine behavior, emphasizing the need for nuanced fuel blending. The examination extends to fuel consumption and specific fuel consumption (SFC) testing, highlighting PPO's superior SFC. Exhaust emission testing demonstrates reduced emissions with heightened PPO concentration, showcasing its positive environmental impact. The results contribute valuable insights into PPO's viability as an alternative fuel source and its potential role in mitigating plastic waste. A comparative analysis with existing literature enriches our understanding of the field, emphasizing the need for careful consideration in fuel formulation. While PPO may not achieve performance parity with conventional gasoline, its environmental benefits and efficient waste utilization underscore its significance for a sustainable future. Further research is encouraged to optimize PPO properties and blending ratios, paving the way for an eco-friendlier energy landscape.

Gas-phase and liquid-phase purification of plastic waste derived carbon nanotubes: Effect of purification agent and operational parameters

The preparation of carbon nanotubes (CNTs) by catalytic pyrolysis of waste plastics is one of the most promising technologies to realize the harmless and high-value recycling of waste plastics. However, there are limited studies on the purification of waste-derived carbons, which is of significance for downstream applications. In this paper, the effects of different gas-phase purification conditions (temperature, gas type), liquid-phase purification (hydrochloric and nitric acid reflux), and combined gas-liquid purification on the properties of CNTs prepared from waste plastics were investigated. The as-obtained and purified CNTs were characterized using SEM, TEM, TPO, XRD, XPS, Raman spectroscopy, and FTIR spectroscopy. Results showed that operational temperatures have distinct impacts on the properties of CNTs during gas-phase purification. An appropriate temperature range for gas-phase purification was determined, with temperatures around 450 °C for air, 650 °C for CO2, and 700 °C for steam respectively, so that the amorphous carbon could be removed and the graphitization of CNTs was retained. Approximately 93 wt% of the metal catalyst particles could be removed with acid treatment for 4 h. In addition, carboxyl and hydroxyl functional groups were introduced to CNTs after acidic treatment. Furthermore, it was found that the approach combining CO2 treatment and nitric acid washing yielded CNTs with relatively higher quantities and lower defect levels. Results showed the properties of CNTs varied from the purification methods, which could meet different needs based on the downstream specific application requirements.

Hydrogen Production Came from Catalytic Reforming of Volatiles Generated by Waste-Plastic Pyrolysis Over Sepiolite-Based Catalysts

Hydrogen Production Came from Catalytic Reforming of Volatiles Generated by Waste-Plastic Pyrolysis Over Sepiolite-Based Catalysts

From Waste to Energy: Enhancing Fuel and Hydrogen Production through Pyrolysis and In-Line Reforming of Plastic Wastes

Plastics have become integral to modern life, playing crucial roles in diverse industries such as agriculture, electronics, automotive, packaging, and construction. However, their excessive use and inadequate management have had adverse environmental impacts, posing threats to terrestrial and marine ecosystems. Consequently, researchers are increasingly searching for more sustainable ways of managing plastic wastes. Pyrolysis, a chemical recycling method, holds promise for producing valuable fuel sustainably. This study explores the process of the pyrolysis of plastic and incorporates recent advancements. Additionally, the study investigates the integration of reforming into the pyrolysis process to improve hydrogen production. Hydrogen, a clean and eco-friendly fuel, holds significance in transport engines, power generation, fuel cells, and as a major commodity chemical. Key process parameters influencing the final products for pyrolysis and in-line reforming are evaluated. In light of fossil fuel depletion and climate change, the pyrolysis and in-line reforming strategy for hydrogen production is anticipated to gain prominence in the future. Amongst the various strategies studied, the pyrolysis and in-line steam reforming process is identified as the most effective method for optimising hydrogen production from plastic wastes.

Pilot Scale Pyrolysis and Simulation of Plastic Waste into a Value‐Added Product: An Integrated Approach

AbstractPlastic waste is utilized aggressively for food, product packaging, cosmetics, toys, clothes, and even furniture. As a result, discarded plastic as a waste has grown uncontrollably worldwide, most of it ending up as landfill. With increasing concern, researchers have made efforts to convert this plastic waste into a more useful product. Along these lines, this study focuses on producing 10 tons of diesel per day through fast pyrolysis at 450 °C in the fluidized bed reactor for a feed rate of 3000 kg of plastic waste per hour. The production was simulated in Aspen HYSYS V11 to ensure the desired yield. Further, a detailed economic analysis is carried out to estimate the return on investment and total cost per year, as well as the payback period and the profit for different scenarios.

Combustion and emission characteristics of distilled waste plastic pyrolysis oil-gasoline blends using single cylinder motorcycle petrol engine

ABSTRACT This study assessed the performance and emissions characteristics of a single cylinder, 2-stroke motorcycle spark ignition engine (Esoo 150 cc) utilising clay-catalytically produced distilled waste plastic pyrolysis oil (DWPPO) fuel. The clay catalyst and fuel properties were analysed using established standard testing procedures. The engine performance and exhaust gas emissions were determined for various fuel blends and compared with those of commercial gasoline at various parameters. Results showed that distilled pyrolysis fuel properties (kinematic-viscosity: 6.4 × 10–7 m2/s; caloric-value: 47.82 MJ/kg) were enhanced compared to kinematic viscosity of 1.92 × 10–6 m2/s and caloric value of 44.41 MJ/kg for Crude Waste Plastic Pyrolysis Oil. Notably, chemical composition of distilled fuel collected within a temperature range of 90°C-180°C closely resembled those of pure gasoline. It was also shown that 50% Distilled Waste Plastic Pyrolysis Oil (D50WPPO) significantly improved the brake power, brake thermal efficiency and reduction in brake specific fuel consumption while operating at full load conditions with various DWPPO-Gasoline blends and pure gasoline. Unburned hydrocarbon emissions reduced by 40% when the engine was fuelled with D50WPPO. The study concluded that DWPPO can potentially be employed as a substitute of conventional gasoline without any engine modifications.

Microwave‐Driven Pyrolysis of Plastic Waste into Carbon Nanotubes and Hydrogen Using Spinel Ferrites

Microwave‐Driven Pyrolysis of Plastic Waste into Carbon Nanotubes and Hydrogen Using Spinel Ferrites

Oxy-hydrogen, solar and wind assisted hydrogen ([formula omitted]) recovery from municipal plastic waste (MPW) and saltwater electrolysis for better environmental systems and ocean cleanup

The pyrolysis of plastic waste and the electrolysis of saltwater is a promising route to carbon neutrality in ocean cleanup and plastic waste management. Therefore, a solar and wind assisted H2-fuelled fast pyrolysis of MPW (municipal plastic waste) and electrolysis of desalinated saline were developed. The combined system uses an oxy-hydrogen furnace for thermal decomposition of MPW feed, CO2 as an inert reaction medium and both solar and wind energy systems to operate the electrical units. The deionised H2O feed to the electrolyser cell was produced from saltwater using the recovered heat from the fast pyrolyser unit. The process CO2 was captured and reused for soil improvement as current waste-to-energy routes of MPW recycling emit 695,850 tonnes of CO2. 2.65 kg/hrH2 fuel in an O2 environment was utilised to meet the decomposer operating temperature and heat duty which is approximately 29 % of the produced H2. Instability associated with bio-oil was prevented by using fast pyrolysis which release more volatiles. Compared to the related studies, this investigated work achieved the highest gas and carbon yields. Thermal NO < 0.1 ppm was recorded. The developed system is expected to reach ≥70 % energy efficiency and a sales price of < $3.89/kgH2.

Novel Staged Free-Fall Reactor for the (Catalytic) Pyrolysis of Lignocellulosic Biomass and Waste Plastics.

Pyrolysis of lignocellulosic biomass and waste plastics has been intensely studied in the last few decades to obtain renewable fuels and chemicals. Various pyrolysis devices have been developed for use in a laboratory setting, operated either in batch or continuously at scales ranging from milligrams per hour to tenths of g per hour. We report here the design and operation of a novel staged free-fall (catalytic) pyrolysis unit and demonstrate that the concept works very well for the (catalytic) pyrolysis of pinewood sawdust, paper sludge, and polypropylene as representative feeds. The unit consists of a vertical tube with a pretreatment section, a pyrolysis section, a solid residue collection section, a gas-liquid separation/collection section, and a catalytic reaction section to optionally perform ex situ catalytic upgrading of the pyrolysis vapor. The sample is placed in a tube, which is transported by gravity through various sections of the unit. It allows for rapid testing with semicontinuous feeding (e.g., 50 g h-1) and the opportunity to perform reactions under an (inert) gas (e.g., N2) at atmospheric as well as elevated pressure (e.g., 50 bar). Liquid yields for noncatalytic sawdust pyrolysis at optimized conditions (475 °C and atmospheric pressure) were 63 wt % on biomass intake. A lower yield of 51 wt % (on a biomass basis) was obtained for the noncatalytic pyrolysis of paper sludge, likely due to the presence of minerals (e.g., CaCO3) in the feed. The possibility of using the unit for ex situ catalytic pyrolysis (pyrolysis at 475 °C and catalytic upgrading at 550 °C) was also successfully demonstrated using paper sludge as the feed and H-ZSM-5 as the catalyst (21 wt % catalyst on biomass). This resulted in a biphasic liquid product with 25.6 wt % of an aqueous phase and 11 wt % of an oil phase. The yield of benzene, toluene, and xylenes was 1.9 wt % (on a biomass basis). Finally, the concept was also proven for a representative polyolefin (polypropylene), both noncatalytic as well as in situ catalytic pyrolysis using H-ZSM-5 as the catalyst at 500 °C. The liquid yield of thermal, noncatalytic plastic pyrolysis was as high as 77 wt % on plastic intake, while in situ catalytic pyrolysis gave a combined 7.8 wt % yield of benzene, toluene, and xylenes on plastic intake.

Low-temperature hydrogen production from waste polyethylene by nonthermal plasma (NTP)-assisted catalytic pyrolysis using NiCeOx/β catalyst

Conventional catalytic pyrolysis of waste plastics for H2 production faces challenges due to excessively high reaction temperatures. This study introduced a NiCeOx/β catalyst for low-temperature H2 production from polyethylene (PE), aiming to enhance H2 yield through nonthermal plasma (NTP) and catalytic active sites. Experimental results confirmed the efficacy of NTP in promoting collision between high-potential-energies active species and plasma-catalyst interactions, identifying acidic sites as primary catalytic active sites. Both experiments and density functional theory (DFT) calculations confirmed NiO and CeO2 particles as metallic active sites, exhibiting thermodynamic and kinetic benefits for primary products from PE pyrolysis. Under optimal conditions, the highest H2 yield and selectivity respectively reached 32.71 mmol/g and 82.10 % at a PE/(NiCeOx/β) ratio of 1:4, reaction temperature of 400 °C, and NTP discharge power of 210 W. The NiCeOx/β catalyst facilitated low-temperature pyrolysis of waste plastics, enhancing H2 selectivity and yield.

Produksi Bahan Bakar dari Limbah Plastik HDPE dan LDPE Menggunakan Metode Pirolisis

The purpose of this study is to calculate the volume and composition of fuel produced from the production of fuel from polyethylene plastic waste per liter. Method: research using pyrolysis method with temperature 450-621°C without using catalyst, and quantitative analysis. Quantitative analysis using the GC-MS method. Result: Pyrolysis of 5 Kg HDPE waste produces 3.25 liters of naphtha, 0.85 liters of gasoline; diesel 0.325 liters; and activated carbon 18.06 grams. 5 Kg LDPE waste produces 500 mL naphtha, 2.9 liters of gasoline; diesel 0.1 liters; and 19 grams of activated carbon. Conclusion: Pyrolysis of 5 Kg HDPE waste produces 3.25 liters of naphtha; gasoline 0.85 liters; diesel 0.325 liters (88.86% total fuel), and activated carbon 18.06 grams; and 5 Kg LDPE waste produces 2.9 liters of gasoline; 0.1 liters of diesel (70.38% of total fuel), and 19 grams of activated carbon. The composition of fuel produced in pyrolysis of polyethylene plastic waste (HDPE and LDPE) in the form of naphtha, gasoline, and diesel and produces residues in the form of activated carbon.

Design of sustainable supply chains for managing plastic waste: The case of low density polyethylene

Plastic waste management presents a significant challenge that requires the integration of supply chain and sustainability principles. This study proposes a comprehensive supply chain model for plastic waste and management, specifically low-density polyethylene (LDPE), focusing on economic and environmental considerations. A model based on Mixed Integer Linear Programming (MILP) is developed to address the type of plastic waste management technology, their location through the United States East Coast and the effect of transitioning to an electrified transportation. The model determines plastic waste pyrolysis as the preferred technology to maximize profitability, and mechanical recycling combined with hydrogenolysis and hydrocracking to minimize the global warming potential (GWP). The mix of technologies for minimizing the GWP is highly correlated with the type of transportation, being desired to remove hydrogenolysis when electric trucks are introduced. This electrification of the transportation reduces the emissions by 23 %, but with an increase in the costs by 4 %.

A comparative study of aromatic content in pyrolysis oils from waste plastics and tires: Assessing common refinery methods

The conversion of waste plastics and tires via pyrolysis to pyrolysis oil represents one of the most promising ways of chemical recycling. Determining aromatics in pyrolysis oils from these feedstocks is crucial for their utilization as both petrochemicals and fuels. In this study, we compared three standard methods commonly available in refinery laboratories (ASTM D1319 − FIA, EN12916 − HPLC-RI, ASTM D8396 − GC × GC-FID) for analyzing aromatic content across a wide range of waste plastic pyrolysis oils, their middle distillate fractions, and hydrotreated products. Using model compounds, we explained most of the observed differences in aromatic content determined by these methods. HPLC-RI and FIA resulted in significant errors. For instance, the FIA reports some dienes and heterocompounds as aromatics. The results from HPLC-RI showed that monoaromatics are overestimated, while polyaromatics are underestimated. Among the tested methods, GC × GC-FID provided the most reliable results.

Recent Progresses in Pyrolysis of Plastic Packaging Wastes and Biomass Materials for Conversion of High-Value Carbons: A Review.

The recycling of plastic packaging wastes helps to alleviate the problems of white pollution and resource shortage. It is very necessary to develop high-value conversion technologies for plastic packaging wastes. To our knowledge, carbon materials with excellent properties have been widely used in energy storage, adsorption, water treatment, aerospace and functional packaging, and so on. Waste plastic packaging and biomass materials are excellent precursor materials of carbon materials due to their rich sources and high carbon content. Thus, the conversion from waste plastic packaging and biomass materials to carbon materials attracts much attention. However, closely related reviews are lacking up to now. In this work, the pyrolysis routes of the pyrolysis of plastic packaging wastes and biomass materials for conversion to high-value carbons and the influence factors were analyzed. Additionally, the applications of these obtained carbons were summarized. Furthermore, the limitations of the current pyrolysis technology are put forward and the research prospects are forecasted. Therefore, this review can provide a useful reference and guide for the research on the pyrolysis of plastic packaging wastes and biomass materials and the conversion to high-value carbon.

A genetic algorithm-based optimal selection and blending ratio of plastic waste for maximizing economic potential

Pyrolysis of plastic waste presents an innovative solution to convert plastics into valuable fuels like oil and gas, thereby contributing to circular economy and sustainability. The efficiency of this process highly depends on the types and compositions of plastics utilized, as each type reacts uniquely during pyrolysis, affecting fuel yield and quality. However, previous studies have not thoroughly examined the impact of plastic selection and blending ratios on the pyrolysis outcome, as this requires extensive experimentation due to the numerous possible combinations. Optimizing these factors, along with operational conditions, is essential for enhancing the economic viability of plastic recycling via pyrolysis. This study introduces an optimal selection and blending ratio for plastic waste in pyrolysis fuel production to enhance economic viability using the surrogate model-based genetic algorithm (GA). The optimization process involves (1) generating data via a process model of the plastic waste pyrolysis reactor, (2) preprocessing data, (3) developing a surrogate model based on deep neural networks (DNNs), and (4) deriving the optimal solution using GA. The results reveal an optimal blending ratio: 4 wt% LDPE, 30 wt% HDPE, 43 wt% PP, and 24 wt% PS. Additionally, the optimal pyrolysis temperature is 607 ℃. By adopting this optimal solution, the net profit could increase by 20% compared to the conventional scenario, resulting in an additional annual net profit of US$ 407,811, thus highlighting the potential this approach offers to attain maximum economic feasibility in industrial applications.

Dechlorination of a real plastic waste pyrolysis oil by adsorption with zeolites

The adsorptive dechlorination of a pyrolysis oil coming from real plastic waste was investigated using different Na-zeolites (4A, 13X, and Y) as adsorbents. The dechlorination experiments were performed in a fixed bed trap under inert atmosphere operating at moderate temperatures (< 180 °C). The dechlorination efficiency of the adsorbents was significantly improved by performing a dehydration pre-treatment due to the removal of water molecules physisorbed on the zeolite surface. Among the zeolitic materials tested, 13X zeolite showed the best dechlorination efficiency, which was related to its high content of Lewis acid sites (attributed to the presence of Na+ cations ionically interacting with the zeolite framework), acting as chemisorption sites, as well as the high accessibility of the FAU-zeolitic topology to the Cl-containing compounds. For that sample, a detailed study of the adsorption temperature (from 30 to 180 °C) and time on stream (1–6 h) was further carried out. The maximum chlorine removal efficiency was achieved, reducing the chlorine content of the pyrolysis oil from 421 to 45 ppm, at temperatures of about 150 – 180 °C. Interestingly, under these conditions, thermal or catalytic cracking effects of the zeolite on the feedstock were not observed. However, the study of the time on stream showed that, after 3 h, the chlorine removal efficiency of the zeolite started to decrease. Thus, different regeneration treatments were evaluated proving that, after a combustion at 600 °C, the zeolite recovered its initial dechlorination efficiency. This research reveals the potential of the adsorptive dechlorination process with Na-zeolites to reduce the chlorine content in plastic pyrolysis oils under mild operating conditions.

Catalytic pyrolysis of FeAlOx and medical plastic waste: Kinetic, slag conversion, and gas emission patterns

The globally substantial increase in medical waste stream and types renders efficient disposal and circularity strategies imperative. Currently, most medical waste disposed of is predominantly plastic materials. A promising approach for its recycling efficiency involves using catalytic pyrolysis to transform plastic waste into reusable pyrolysis oil. This study aimed to characterize gas products and bottom slag of the catalytic pyrolysis of medical waste infusion tubes (PVC) via thermogravimetric (TG) and pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS) analyses. As s bimetallic catalyst known for its exceptional ability as a carbon carrier that can turn carbon into CO at high pyrolysis temperatures, FeAlOx was synthesized and characterized. The addition of 50% (wt) FeAlOx yielded the lowest activation energy (Eα = 108.11 kJ/mol). The catalyst facilitated the breaking of the C-Cl bond in PVC, increasing HCl and light hydrocarbon gases, such as CH4. Prolonged pyrolysis residence times reduced chlorine remnants in the bottom slag, increased its alumina content, and achieved a stable slag composition. The reaction model with varying catalyst additions was dynamically evolved as follows: F1.6→F2→F2.2→F1.5 in the first stage and F2.3→F2.8→F4.8→F2 in the second stage, thus achieving an optimal kinetic and thermodynamic ratio of 5:5. The addition of the catalyst reduced not only the energy consumption and complexity of the two pyrolysis stages of PVC but also the production of pollutants, thus improving the circularity. This study provides actionable insights into the potential of the catalyst-assisted pyrolysis as an effective method for the circular management of medical waste.