European regulations require that by 2030 waste suitable for recycling, material recovery, or energy recovery will no longer be allowed in landfills. MSW composition in non-recyclable containers affects what measures for recovery could be implemented. This study is a screening examination of 32 non-recyclable MSW samples in the Getafe municipality (Spain). In addition to non-combustible elements, MSW is separated into 15 waste materials. Merely 18.1 % of the non-recyclable component is placed in appropriate containers. Composition of all materials is analyzed. MSW samples are grouped into six clusters with similar properties using the K-nearest neighbor methodology. Representative sample from each cluster is pyrolyzed at 520 °C. The main product of pyrolysis is liquid, which makes up 57.9 wt%, while solid and gas fractions are 16.4 and 16.5 wt%, respectively. Liquid fraction is a blend of aromatic, aliphatic, oxygenated, and nitrogenated compounds, while gas fraction is mainly CO2.