This paper investigates the complex relationship between apparent resistivity and electrode separation, revealing key underlying features. The research uses a range of field curve types to quantitatively and qualitatively analyse data from Vertical Electrical Sounding (VES). The study is divided into two sections: a qualitative interpretation section and a quantitative interpretation section, the latter of which focuses on the dynamics of aquifer potential in the Warri South region. Understanding the link between apparent resistivity and electrode separation is essential for hydro-geoelectric research. To increase the reliability of the results, curve matching, sophisticated modelling, and geological knowledge are used. Particularly, the predominance of HH curve types, followed by AH, HQ, KH, and KK configurations, provides a complete description of the hydrogeological terrain and a thorough description of subsurface features. To comprehend groundwater flow, distribution, and management, aquifer resistivity, thickness, depth, transverse resistance, longitudinal conductance, hydraulic conductance, and transmissivity are all researched. The complex interaction between resistivity levels and different rock types emphasises the dynamic nature of aquifer resistivity and disproves the idea that it has a set range. The patterns in the regional distribution of aquifer resistivity reflect the complexity of subsurface water supply. Aquifer thickness, depth, and transverse resistance, which highlight the complex interaction of geology and aquifer characteristics, are additional factors that aid in understanding hydrogeological processes. The hydrological potential of aquifers is discovered through variables like transmissivity and hydraulic conductivity, indicating the balance between geological characteristics and hydraulic gradients. These discoveries open the door to responsible water resource management and sustainable use by providing insights into the dynamics of hidden aquifers under the Earth’s surface.