Wall Rocks Research Articles

Unveiling the Rheological Control of Magmatic Systems on Volcano Deformation: The Interplay of Poroviscoelastic Magma‐Mush and Thermo‐Viscoelastic Crust

AbstractUnderstanding the mechanical evolution of magmatic systems requires careful assessment of their rheological characteristics, particularly in light of the growing evidence that magma reservoirs are dominated by magma‐mush surrounded by thermally‐altered host‐rock. To address this complexity, we develop models for volcano deformation based on a poroviscoelastic source within a thermo‐viscoelastic host. We use Finite Element modeling to investigate the rheological and mechanical response to melt injection in a Maxwell poroviscoelastic reservoir hosted in a temperature‐dependent standard linear solid viscoelastic (“thermo‐viscoelastic”) crust. Our models consider the competing roles of poroelastic diffusion, and viscoelastic creep and relaxation. All cause time‐dependent post‐injection deformation. Post‐injection deformation of a poroviscoelastic reservoir in an elastic crust is dominated by poroelastic diffusion, a consequence of the short relaxation timescale of a hot and relatively low viscosity mush. For cooler, more viscous mush, the magnitude of viscoelastic deformation increases, supplementing the deformation caused by post‐injection poroelastic diffusion. Thermo‐viscoelasticity of the crust amplifies the poroelastic deformation response of the magma‐mush, leading to increased time‐dependent deformation both during and after melt injection. The rate of post‐injection surface deformation decreases at a rate proportional to the reservoir temperature. Crucially, our model sensitivity analysis demonstrates that the wall rock thermo‐viscoelastic response contributes more to surface deformation than the viscous effect of the magma‐mush. For this reason, neglecting the viscoelastic properties of the host rock and the poroelastic properties of the reservoir in interpretations of surface deformation data could produce errors in inferred processes (e.g., injection duration) and subsurface characteristics (e.g., reservoir compressibility, shape and depth).

Scheelite composition fingerprints pulsed flow of magmatic fluid in the Fujiashan W skarn deposit, eastern China

Abstract Scheelite (CaWO4) is an economically important W mineral in skarns that form when magmatic fluids exsolved from a granitic intrusion react with carbonate wall rocks. In the Fujiashan W skarn deposit, scheelite formed during four stages of the hydrothermal skarn development. We present cathodoluminescence (CL) images and in situ trace element and Sr-O isotope data of scheelite from these four stages, i.e., scheelite in prograde and retrograde skarn, quartz-sulfide veins, and late calcite replacements. Scheelite from prograde skarn and quartz sulfide veins are homogeneous and show oscillatory zoning textures in CL images, whereas scheelite from retrograde skarn and late carbonate stages display dissolution-reprecipitation and patchy textures. The brightness of CL textures decreases with a higher substitution of Mo. Molybdenum-rich scheelite (up to 2.1 wt%) is characterized by relatively high contents of Nb and Ta (up to 156 and 0.9 ppm, respectively), positive Eu anomalies, high-δ18O values (5.2 to 5.9‰), and relatively low-87Sr/86Sr values (0.70661 to 0.70727), and has grown in a system with a continuous supply of magmatic fluid. Molybdenum-poor scheelite (0.2 wt%) has low contents of Nb and Ta, negative Eu anomalies, low-δ18O values (4.2 to 4.3‰), and relatively high-87Sr/86Sr ratios (0.70748 to 0.70804). This type of scheelite formed in a system with a restricted flow of magmatic fluid during scheelite precipitation became increasingly depleted in elements that substitute into scheelite. The continued reaction of the magmatic fluid with the wall rocks and the precipitation of minerals from the fluid resulted in a systematic change of the δ18O and 87Sr/86Sr ratios. Chemical and isotopic variations in scheelite may reflect the pulsed flow of a magmatic fluid and do not require the involvement of different fluids or contrasting redox conditions.

Constraining the evolution of shear zones in the Himalayan mid crust in Central–Western Nepal: implications for the tectonic evolution of the Himalayan metamorphic core

AbstractStructural analysis, petrochronology and metamorphic petrology enable identification and bracketing of the timing of a newly mapped high-temperature ductile shear zone (Jagat Shear Zone (JSZ)) in the Himalayan metamorphic core in Central-Western Nepal. In situ U-Th-Pb monazite petrochronology constrains the timing of top-to-the-S/SW shearing between 28–27 Ma and 17 Ma. Burial and prograde metamorphisms in footwall rocks were linked to thrust-sense movement along the JSZ, while the hanging wall rocks were retrogressed and exhumed. The identification and age of the JSZ (as part of a regional system of shear zones: the High Himalayan Discontinuity (HHD)) coupled with the localization and timing of activity of the Main Central Thrust (MCT) (i) fills a gap in tracing the HHD along orogenic strike, (ii) supports the identification of the position and timing of the long-debated MCT and (iii) helps to place the boundaries of the Himalayan metamorphic core and its internal architecture. Thus, our study is a significant step towards a precise identification of the burial, assembly and exhumation mechanisms of the Himalayan metamorphic core.

Stratigraphic and mineralization age, Sr–Nd isotope constraints on the source of fluids in the Yindonggou Ag–Au(–Pb–Zn) deposit, Qinling Orogen, China

The Yindonggou deposit, located in the northwestern margin of the Wudang Block, is the largest Ag–Au deposit (reserves: 2000 t Ag and 20 t Au) in the area. Quartz vein- and altered rock-type orebodies are hosted in the meta-volcanic rocks of the Wudang Group, and are controlled by the Yindongyan anticline and ductile shear zone along the anticlinal axis. The metamorphosed quartz keratophyre tuff from the Wudang Group yield LA-ICP-MS zircon concordant 206Pb/238U age of 738.30 ± 5.90 Ma, indicating a Neoproterozoic volcanic event. Four stages of mineralized quartz veins were found in the deposit. One hydrothermal sericite sample collected from the stage 2 smoke-gray quartz Ag–Au veins yield a well-defined 40Ar/39Ar isotopic plateau age of 234.65 ± 3.51 Ma, and 39Ar/36Ar-40Ar/36Ar normal isochron age of 220.11 ± 14.32 Ma, suggesting a Middle to Late Triassic (ca. 234 Ma) mineralization at Yindonggou. The difference between diagenetic and mineralization ages indicates that the Yindonggou deposit is not a volcanic eruption-related deposit, but a vein type epigenetic ore deposit. Five wall-rock samples from the Wudang Group of the Yindonggou deposit yield ISr(234 Ma) ratios of 0.714890–0.723704, averaging 0.719938; the (143Nd/144Nd)i values ranging from 0.512018 to 0.512078, averaging 0.512055, with the εNd(234 Ma) values of −6.22 to −5.05. Galena from stage 1 have ISr(234 Ma) values of 0.710801–0.718999, (143Nd/144Nd)i values of 0.511954–0.512234, and εNd(234 Ma) values of −7.47–2.01. Pyrite and sphalerite from stage 2 yield ISr(234 Ma) ratios of 0.704389–0.719884, (143Nd/144Nd)i values of 0.511920–0.512402 and εNd(234 Ma) values of −8.13 to 1.28. Both εNd(234 Ma) and ISr(234 Ma) values of the sulfides indicate that the ore-forming fluids were contaminated by wall rocks from the Wudang Group. The early stage sulfides are representative of the initial ore-forming fluids, which is similar to metamorphosed basic rocks and Mian-Lue ophiolite. This indicates that the deep-sourced initial ore-forming fluids with high εNd(234 Ma) and low ISr(234 Ma) were derived from the metamorphic devolatilization of the subducted oceanic crust. The Yindonggou is an orogenic-type deposit formed in Triassic oceanic subduction-related accretionary orogeny.

Mineralogy and Geochemistry of Nepheline Syenite From the Bang Phuc Massif of the Alkaline Cho Don Complex in North-Eastern Vietnam—Implications for Magma Evolution and Fluid–Rock Interactions

Abstract The alkaline Cho Don complex in NE Vietnam comprises several mafic-felsic suites related to the widespread magmatism developed during the early Permian–late Triassic. The contribution explores the petrogenesis of nepheline syenite from the Bang Phuc massif and its petrogenetic relationship with cogenetic scapolite-rich gabbro. The nepheline syenite formed through fractional crystallization of pristine mantle-derived basaltic melt modified by subduction-related components (chiefly sediment-derived melts), as shown by, e.g. low Ba/Th and high Th/Nb ratios of the rocks. The transition from gabbro to syenite follows a within-plate enrichment trend (e.g. increasing Ta/Yb, Nb/Yb, and Th/Yb ratios) that might reflect switch from post-orogenic to intra-plate regimes, accompanied by subduction–collision–extension events related to the Indosinian Orogeny. Furthermore, magma evolution involved the progressive contribution of asthenospheric-derived melts that resulted in the appearance of OIB-like signatures (e.g. high Nb/La ratios) in the nepheline syenite. Fractional crystallization of fluorapatite and mafic phases, as well as assimilation of carbonate wall rocks ultimately led to the decrease of LREE contents and/or modification of Zr/Hf ratios. Magmatic phases of the nepheline syenite include nepheline, sodalite, oligoclase, orthoclase, and annite, as well as accessory fluorapatite, fluorite, and minor amounts of zircon and metamict allanite-Ce. The nepheline equilibrated at temperatures ranging between 850°C and 700°C, which reflects protracted residence at a higher temperature. Later, it has been locally altered to cancrinite, dawsonite, and natrolite via CO2- and alkali-rich fluid influx. The fluid–rock interactions were also manifested by the presence of chessboard-twinned albite and coarsening of braid-perthite into patch-perthite, as well as recrystallization of primary orthoclase into microcline. The orthoclase→microcline conversion, albeit fairly indiscrete under a polarizing microscope and confirmed by Raman micro-spectroscopy, is followed by the change of cathodoluminescence colours, i.e. from light-blue (activated by Ti4+ and/or Al-O—Al centres) in orthoclase towards brownish and/or greenish (activated by Mn2+ and structural defects) in microcline.

Study on the Support Effect of Energy-Absorbing Support Structure in the Coal Mine Roadway and the Synergic Effect with Wall Rock

This paper examines the effectiveness of energy absorption anti-impact support in protecting the coal mine roadway from rock burst and ensuring safe production. By establishing an ABAQUS numerical model of the support and wall rock, the mechanical behavior of the system under static and impact loads have been investigated. The analysis includes the deformation of the wall rock, plastic strain, plastic property, and damage range to evaluate the support effect and the synergistic effect with the wall rock. The findings indicate that compared to ordinary support, the energy absorption anti-impact support exhibits a 20.40% increase in maximum deformation, 4.74% increase in maximum stress, 66.67% decrease in maximum plastic strain, and 116.79% increase in maximum absorption energy. The wall rock also experiences a 2.91% increase in maximum deformation and 10.19% increase in maximum stress. These results suggest that energy absorption anti-impact support is effective in improving the anti-impact performance of the support and providing a certain level of protection to both the support and wall rock.

Coupled U–Pb and Lu–Hf zircon data of Late Devonian magmatism from Bajo de La Leona (Deseado Massif, Argentina): Tracking the southernmost exposure of the Devonian magmatic arc of Patagonia

In Bajo de La Leona, located in the eastern Deseado Massif, pre-Permian basement rocks of the Río Deseado Complex crop out. They consist of high- to medium-grade metamorphic rocks intruded by two Paleozoic granitoids, namely the Mina de La Leona Granite and the Laguna Larga Granite. The latter is the main goal of this work. It is a calc-alkaline to high-K calc-alkaline, ferroan, calcic to alkali-calcic, and mainly peraluminous monzoleucogranite which plots within the I&S-type and volcanic-arc fields of the tectonic discrimination diagrams. Its trace elements composition (e.g., Sr/Y, LaN/YbN, Sm/Yb, Eu/Eu*, Dy/Dy*, Dy/Yb) suggests plagioclase ± clinopyroxene fractionation in a shallow source at low pressures. Assimilation could have played a role in magma differentiation, thus the magmatic development of the Laguna Larga Granite is likely a consequence of assimilation-fractional crystallization (AFC) processes. Coupled LA-ICP-MS U–Pb and Lu–Hf zircon data for the studied granite, as well as Sm–Nd whole-rock data, are here presented for the first time. A Famennian U–Pb zircon crystallization age of 361.9 ± 1.7 Ma was obtained, together with εHf(t) zircon values from -15 to +6 with TDM-Hf model ages between 2.0 and 0.9 Ga. A thin crust, as suggested by low values of thickness proxies such as Sr/Y (1.06–1.83) and LaN/YbN (3.97–4.96), would allow emplacement of juvenile mantle-derived material, giving rise to the suprachondritic εHf(t) values. A mantle-derived source is also suggested by a suprachondritic εNd(t) whole-rock value of +2.34 (TDM-Nd = 0.93 Ga). On the other hand, the subchondritic εHf(t) values could be related to wall rock assimilation. In a regional context, the obtained results for the Laguna Larga Granite allow to correlate it with coeval rocks from northern Patagonia (e.g., San Martín de los Andes batholith, Paleozoic Central Patagonian igneous-metamorphic belt). Therefore, the Devonian magmatic arc might have extended from the North Patagonian Andes and the western North Patagonian Massif to the eastern Deseado Massif along a NNW-SSE-striking belt, confirming previous proposals.

Climate-vegetation-erosion interactions revealed by the sediments of Huguangyan Maar Lake, southern China

Soil erosion is a serious environmental problem in the red soil region of southern China, yet little is known about the factors responsible and their specific effects on long-term soil erosion dynamics in this region. We addressed this issue via a study of the sediments of Huguangyan Maar Lake (HML), a crater lake in southern China. Our results confirm that the sediments in HML are mainly derived from the erosional input of weathering products of wall rocks, via catchment runoff. Having established the provenance of the HML sediments, the sediment accumulation rate, mass accumulation rate, and geochemical element fluxes were used to reconstruct soil erosion processes in the HML catchment over the past ∼1400 years. The potential drivers of soil erosion were explored, and regional comparisons were made to evaluate the representativeness of this study. The results show that: 1) Higher precipitation before ∼830 CE, coupled with a lower level of human activity, promoted increased vegetation coverage which reduced the rate of soil erosion. 2) Lower precipitation during 830 CE–1390 CE reduced the rate of soil loss. 3) Abundant precipitation was the main cause of the more intense soil erosion during 1390 CE–1878 CE, which may have been exacerbated by the reduced vegetation cover caused by intensive human activity. 4) During 1878 CE–2019 CE, the vegetation cover gradually recovered under the combined effects of vegetation restoration and higher precipitation, which reduced the rate of soil erosion within the HML catchment. Compared to the Chinese Loess Plateau, the erosion level in the HML catchment was relatively low during the period of intensive human activities. Overall, our results contribute to an improving understanding of the driving mechanisms of soil erosion, and they provide a guide for soil conservation measures in southern China.

Geochemical Characteristics and Metallogenic Significance of the X03 Vein Tourmaline in the Jiajika Rare Metal Deposit, West Sichuan

The Jiajika rare metal deposit contains the largest area of granitic pegmatite-type rare metal deposits in China. The X03 vein is an immense rare metal deposit dominated by lithium, which was found in the deposit in recent years. The contact metamorphic belt of tourmalinization and petrochemistry is widely developed in its wall rocks, and the altered rocks formed contain Li and other rare metal mineralization. In this paper, the tourmaline found in the different rocks of the Jiajika X03 vein is divided into four types: two-mica quartz schist (Tur-Ⅰ), tourmaline hornfels (Tur-Ⅱ), tourmaline-bearing granite pegmatite (Tur-Ⅲ) and spodumene-bearing granite pegmatite (Tur-Ⅳ); their in situ major element, trace element and boron isotope data are systematically studied. The results show that all tourmalines in the Jiajika X03 vein deposit belong to the alkali group, and are schorl–Oxy/Fluor–schorl, dravite–Hydroxy-dravite and foitite–Oxy foitite solid solutions, among which Tur-Ⅰ are dravite, Tur-Ⅱ are foitite of hydrothermal origin and Tur-Ⅲ and Tur-Ⅳ are schorl of magmatic origin. The boron isotope values show that the boron involved the formation process of tourmaline mainly originates from the Majingzi S-type granite, and the boron isotope variations in tourmaline are controlled by melt fluid and Rayleigh fractionation. Moreover, there is a clear correlation between the B isotope value of tourmaline and the Li, Mn, Zn, Mg, and V contents, showing that these contents in tourmaline are good indicators of the mineralization type of pegmatite.

Origin of chromitites in the Norilsk-1 intrusion (Siberian LIP) triggered by assimilation of argillaceous rocks by Cr-rich basic magma

Сhromite-rich rocks and monomineralic chromitites occur in mafic-ultramafic layered intrusions worldwide, and are economically important as they host major resources of chromium and platinum group elements. One of the acknowledged genetic concepts for such mineralization advocates bulk chromite crystallization in a response to hybridization of Cr-rich basic magma with felsic melts, derived from partial melting of the wall rocks. However, there has been lack of direct insights into this process and its details have been remaining largely obscured. In this study, we report data on chromite-rich assemblages of the Noril'sk-1 intrusion (Siberian LIP), with a particular focus on chromite-hosted multiphase inclusions. Composition of the latter is different from the rocks of the Noril'sk-1 intrusion and inherits geochemical fingerprints of the wall rock argillites and, therefore, represent snapshots of the heavily-contaminated medium of the magma-wall rock reaction front. Mineral relationships in chromite-rich breccias with fragments of the wall rocks also provide valuable insight into chromite mineralization mechanisms. Our results, along with geological evidence and data on other Noril'sk-type intrusions, indicate that bulk crystallization of chromite, aided by partial suppression of silicate crystallization, occurred in the hybrid medium during digestion of the wall rocks by ascending and emplacing basic magma. Continuous flow of the magma around outshoots of the wall rocks or through a “magmatic karst” in the wall rocks, allowed for a continuous precipitation of chromite. Concentration of chromite grains to form dense mineralization apparently occurred due to formation of chromite-rich blobs around the wall rock fragments, and selective collection and transport of chromite by fluid bubbles, which formed via degassing of wall rocks and then carried chromite and relics of the wall rocks (xenoliths) to the upper parts of the pluton. We propose that assimilation-driven formation of chromite-rich lithologies in intrusions requires: (1) sufficient Cr contents in magma, which allow for its oversaturation in Cr-spinel only by a sudden cooling and addition of SiO2, K2O or/and H2O; (2) efficient disintegration and digestion of the host rocks, releasing considerable amounts of these components to the magma, and (3) a mechanism ensuring accumulation of excess chromite within a small volume (e.g. continuous reaction of Cr-rich magma with the products of the host rocks' assimilation or/and mechanical concentration of chromite).

Chronolgy and Geochemistry of the Sijiaying Iron Deposit in Eastern Hebei Province, North China Craton: Implications for the Genesis of High-Grade Iron Ores

The Sijiaying iron deposit is located in the Eastern Hebei area of the southern section of the northern margin of the North China Craton (NCC) and is the largest single iron deposit in China. The deposit contains many banded iron formations (BIFs) and was proven to have more than 3 million tons of high-grade iron ore resources. This study carried out geochemistry and zircon U–Pb analysis of normal-grade iron ore, high-grade iron ore, and wall rock (biotite–leptynite, chlorite–sericite schist) in the Sijiaying deposit and discussed the genesis and metallogenic age of high-grade iron ore. BIFs have low concentrations of Al2O3 and TiO2 and high field strength element (HFSE) depletion, indicating almost no contamination via terrestrial debris. The standardized post-Archean Australian shale (PAAS) rare earth element (REE) distribution pattern indicates that the iron formation exhibits positive Eu, Y, and heavy rare earth element (HREE) anomalies and lacks negative Ce anomalies, indicating that the Sijiaying BIF was enriched with iron sources via high-temperature hydrothermal fluids from the seabed and deposited in an anoxic ancient marine environment. In addition, geological field work identified two types of high-grade iron ore in the mining area: primitive sedimentary and hydrothermally altered high-grade iron ore. Further ore geochemical research showed that the primitive sedimentary-type iron ore is similar in geochemistry to the BIF. In addition to low Eu/Eu* values, the hydrothermally altered high-grade iron ore shows geochemical characteristics similar to those of the BIF, suggesting that they share the same iron source but did not form at the same time. The total large ion lithophile element (LILE) (Sr, Ba, Pb) contents in primitive sedimentary-type high-grade iron ore are higher than those in hydrothermally altered high-grade iron ore, indicating that LILEs are carried away via fluids during the hydrothermal alteration process in normal-grade iron ore. The geochemical characteristics of biotite–leptynite and chlorite–sericite schist include high contents of SiO2 and Al2O3, light rare earth elements (LREEs), LILE enrichment (Rb, Ba, Sr, Zr), and HFSE depletion (Nb, Ta, P, Ti), characteristics that are similar to island arc volcanic rocks. The reconstruction of the original rock indicates that the wall rock is a product of volcanic sedimentary cycles in an island arc setting. Zircon cathodoluminescence images and LA–ICP–MS zircon U–Pb dating can be divided into four age groups (3283 Ma, 2547 Ma, 2500 Ma, and 2407 Ma), which correspond to the earliest volcanic activity in eastern Hebei, the main mineralization age of the Sijiaying BIF (the mineralization age of primitive sedimentary high-grade iron ore), a regional tectonic–metamorphic event, and the occurrence of migmatization (the mineralization age of hydrothermally altered high-grade iron ore), respectively. Therefore, the Sijiaying BIF and primitive sedimentary high-grade iron ores were deposited and mineralized at 2547 Ma, and the iron orebody was later altered via the hydrothermal solution at 2407 Ma, forming large-scale high-grade iron ores.

Tectono-metamorphic evolution of a post-variscan mid-crustal shear zone in relation to the Tethyan rifting (Ivrea-Verbano Zone, Southern Alps)

The Ivrea-Verbano Zone, in the Italian Southern Alps, samples a complete section of middle to lower continental crust, which records the transition between the Variscan and the Alpine Tethys rift-related tectonics. We present a structural-metamorphic characterization of one of the most important structures, the Forno-Rosarolo shear zone which drove the post-Variscan tectonic evolution of the Ivrea-Verbano Zone. The Forno-Rosarolo shear zone is a NE-SW-oriented, subvertical shear zone, mainly made of metapelites, amphibolites, calc-silicates and granulites involved in anastomosed proto- to ultra-mylonite layers enveloping weakly deformed lenses. Mylonitic deformation developed on an already folded and sheared metamorphic (Variscan) complex but predates brittle fracturing and faulting, locally associated with pseudotachylites.In present day orientation, the kinematic indicators point to a sinistral sense of shear. Removing the Alpine ∼90° tilt of the IVZ crustal section, this kinematic results in a former extensional shear zone. Investigations on the kinematic of the flow in the mylonites revealed a non-coaxial deformation with a major component of pure shear acting together with simple shear. Metamorphic conditions of the wall rocks vary from upper amphibolite (SE, footwall) to granulite facies (NW, hanging wall). Estimations from the mineral assemblages within the mylonites point to amphibolite facies conditions during deformation (∼650 °C and ∼5.5 kbar).In absence of precise geochronological constraints, we discuss the role of the Forno-Rosarolo shear zone within the Tethyan rifting system in comparison with recent reconstructions. Kinematic data and metamorphic conditions allow to constrain the development of the Forno-Rosarolo shear zone mylonitic deformation during the intermediate phase of the Tethyan rift known as “thinning mode”. This stage was characterized by general shear conditions (pure shear between 70% and 50%) suggesting a phase of transition from a symmetric to an asymmetric configuration of rift.

Syn-Bushveld “granite sheets” associated with the Molopo Farms Complex intruding into Transvaal Supergroup strata in southern Botswana

Abstract LA-ICPMS U-Pb isotope analyses are presented for zircons from a thin granite sheet intersected in a borehole drilled into the upper Transvaal Supergroup wall rocks to the Molopo Farms Complex in southern Botswana. Many of the zircons have irregular or angular grain margins, and some have rounded cores. Approximately half of the analysed grains yielded concordant 207Pb/206Pb ages ranging between 2 282 ± 29 and 2 113 ± 16 Ma. Assuming that these grains were inherited from the surrounding upper Transvaal Supergroup sedimentary strata, the youngest zircon age provides a maximum depositional age for these sediments. Importantly, these zircon ages coincide with dates from detrital zircons in upper Transvaal Supergroup strata in the eastern Kaapvaal Craton and in the Magondi Supergroup in western Zimbabwe. Hf isotope analyses of the rounded zircons suggest that these grains were sourced from a variable mixture of an old basement and more juvenile material. A younger age of 2 060 ± 12 Ma was obtained from a single subhedral zircon grain from the granite sheet. This is interpreted as the granite’s emplacement age, making it coeval with the adjacent Molopo Farms Complex that forms part of the Bushveld Large Igneous Province.

Neogene and Quaternary dikes and related joints as conduits for recent juvenile degassing: case studies from the seismically active region of NW-Bohemia, Czech Republic

The contemporary occurrence of juvenile gas emissions at springs or mofettes in active volcanic areas can be observed worldwide. This correlation is less frequent in areas with dormant or post-volcanic activity. The NW-Bohemia/Vogtland region located at the Eger rift zone (Czech Republic) provides an intriguing example of this correlation between numerous Neogene-aged post-volcanism locations and juvenile fluid emission sites. Newly discovered dikes and diatremes are located close to vents with the highest helium isotope ratios (3He/4He) of about 6 Ra. Our results lend support to the hypothesis that feeder dikes and their fractured wall rocks should be considered the predominant conduits for the continuous upwelling of juvenile fluids. Moreover, 77% of the CO2 gas emission sites are located close to dikes or diatremes, i.e., within a distance of 4 km. Our studies reveal a spatial dependence of the Ra values at the spring sites with the estimated distances to the basaltic bodies. The results confirm the negative trend known from the literature. That is, Ra values decrease with increasing distance from the feeder dikes.

Influence of Low-Temperature Hydrothermal Events and Basement Fault System on Low-Resistivity Shale Reservoirs: A Case Study from the Upper Ordovician to Lower Silurian in the Sichuan Basin, SW China

High graphitization is responsible for low-resistivity shale development with poor reservoir quality. This paper provides an explanation of organic matter graphitization and determines the impact of high graphite content on low-resistivity shale reservoir quality at the Wufeng-Longmaxi Formation in the Southern Sichuan Basin. Fine veins are frequently developed at shale samples with Ro > 3.5%, graphitized organic matter > 25%, and resistivity < 5 Ω•m, which are dominated by three mineral assemblages: brunsvigite, barite-hyalophane-barium feldspar-potassium feldspar-anhydrite, and calcite-ankerite. These filling minerals are characterized by an Eu positive anomaly and high Ba, Fe, and Mn contents, suggesting that low-resistivity shale was modified by magmatic-related low-temperature hydrothermal fluid. Temperature measurements of brine inclusions and a semi-empirical geothermometer of chlorite show that low-temperature hydrothermal fluid experienced the chlorite stage (150–180 °C), the low-sulfidation stage (120–150 °C), and the low-temperature calcitization stage. Paleozoic fault systems and late Permian hydrothermal activities associated with the Emeishan mantle plume control the graphitization of low-resistivity shale. The water formation and seawater infiltrated into the deep crust along the Paleozoic basement faults under gravity, developing alkaline hot brine through mantle plume heating and then causing a water-rock reaction with basement rocks. They migrated upward along deep and large Paleozoic faults through convective thermal circulation in the Tiangongtang area, the Shuanglong-Luochang area, and the Xuyong area. Cation exchange and redox reactions occurred during the interaction between high-temperature hydrothermal fluid and cool wall rocks. The migration of alkaline hot brine via the Wufeng-Longmaxi shale introduced a subsequent water-rock reaction, resulting in the development of hydrothermal mineral assemblages that intricately filled fractures. It increased formation temperature and enhanced thermal maturity and graphitization of organic matter at the Wufeng-Longmaxi low-resistivity shale, resulting in a wide distribution of low-resistivity shale at the Changning Block.

Ore-forming material sources of the Pb–Zn–(Ag–Fe–Cu) deposits in the northern Gangdese belt, Lhasa terrane: Constraints from geology, geochronology and S–Pb isotopes

Many new skarn Pb–Zn–(Ag–Fe–Cu) deposits have been identified in the northern Gangdese polymetallic belt (NGPB). The NGPB comprises skarn deposits with different metal associations: Pb–Zn–(Ag), Pb–Zn–Fe–Cu, and Fe–Cu. The sources of ore-forming materials and whether intrusions contribute materials to these deposits, remain debated subjects. This study focused on zircon U–Pb dating and S–Pb isotopes of metal sulfides, ore-forming rocks, and wall rocks from the typical deposits in the three systems. Zircon U–Pb dating indicates that the biotite granite in the Longmala deposit was emplaced at 54.6 ± 0.6 Ma, which is consistent with its metallogenic age. The δ34S values of sulfides from the Pb–Zn–(Ag) deposits (Yaguila: −2.1‰ to + 6.0‰, Mengya’a: −0.8 ‰ to + 4.6 ‰) are similar to those from Pb–Zn–Fe–Cu deposits (Longmala: +1.6‰ to + 3.6‰, Lietinggang–Leqingla: −8.3 ‰ to + 2.0 ‰), suggesting a magmatic source of sulfur. The Pb isotopes of sulfides in Pb–Zn–(Ag) deposits (206Pb/204Pb = 18.4804–18.6935, 207Pb/204Pb = 15.6637–15.7331, and 208Pb/204Pb = 38. 0164–39.2612) are similar to those of the contemporaneous intrusions, as are those of Pb–Zn–Fe–Cu and Fe–Cu deposits, suggesting that the intrusions provided metals for the three systems. In comparison, the sulfides from the Pb–Zn–(Ag) deposits have higher 207Pb/204Pb values (15.6637 to 15.7331, mostly > 15.70) than the Fe–(Cu) deposits (15.6186 to 15.6848) and the Pb–Zn–Fe–Cu deposits (15.6163 to 15.7197), indicating that the metals of Pb–Zn–(Ag) deposits were derived from the upper-crust magma, whereas the metals of Fe–(Cu) and Pb–Zn–Fe–Cu deposits originated from the deep magma that required the involvement of mantle-derived components. Combined with previous research, we propose that the metals of Pb–Zn–(Ag) deposits originated from S-type granites, whereas those of Pb–Zn–Fe–Cu and Fe–(Cu) deposits were derived from I-type granites in the NGPB.

Genesis of Fibrous Calcite in the Chang 7 Member of the Yanchang Formation, Ordos Basin

AbstractTo explore the genesis of the laminated calcite veins developed in the black shale of Chang 73 submember of the Ordos Basin, the petrology, microstructure and geochemistry of calcite veins are studied using thin sections, fluid inclusions, trace elements and isotopic geochemistry. The source, the time of formation, the mechanism of formation, and the dynamic background of the veins are discussed. The veins are mostly made up of calcite, mixed with lenticular or spindle‐shape solid wall rock inclusions. Three structures are identified in the calcite minerals: fibrous, rhombic cleavage, and wedge‐like structure. Trace elements and isotopes of carbon and oxygen confirm that the calcite veins were formed from a high density hydrothermal fluid. It is assumed that calcite veins formed prior to wall rock consolidation during the formation of the Qinling Orogenic Belt in the Middle and Late Triassic. The results show that the sedimentary sources of Chang 73 submember were influenced by hydrothermal materials besides terrigenous detritus. The fibrous calcite is different from the fibrous calcite reported in the morphology and mechanism of formation. In this way, the research complements and improves the morphology and the mechanism of formation of fibrous calcite.

Apatite texture and composition in the Tonglushan porphyry-related skarn system, eastern China: Implications for mineral exploration

The composition of ‘indicator’ minerals is thought to provide a guide to the potential of magmatic arc systems to form porphyry Cu deposits, but whether this is also the case for endoskarn- and exoskarn-dominated systems remains unclear, despite their importance as a source of Cu, Fe and Au. In a first step to address this, we compare the texture, cathodoluminescence (CL) colour and composition of apatite between relatively fresh quartz monzodiorite (QMD) and porphyry-type-, endoskarn- and Fe-(Cu)-mineralised exoskarn components of the Tonglushan porphyry-skarn system of the Daye ore district, China. In the relatively fresh QMD, apatite luminesces yellow-green due to elevated Mn contents. However, where affected by potassic-sodic alteration, it shows green–blue CL thought to reflect partial removal of Mn and an associated increase in REE. Apatite in the endoskarn is more pervasively replaced and veined, and shows mid-blue luminescence due to relatively low Mn, Mg and Cl. The exoskarns contain apatite with variable grain shapes and navy blue-violet or bright to dark blue CL colours, caused by low Mn and elevated Ce, and with only small patches of pale yellow-green CL. Apatite is near absent in the limestone wall rocks and xenoliths and, therefore, where present in the exoskarns is interpreted to have precipitated from the same fluids as the Fe-(Cu) mineralization.Apatite CL colour and chemistry is indicative of the different styles of alteration and mineralisation in the Tonglushan system and provides insights into the composition of skarn-forming fluids. Our results offer a potentially effective method for utilising apatite as a porphyry and skarn deposit indicator mineral in a range of exploration materials including regolith and stream sediments.

Carbonatitic Magma Fractionation and Contamination Generate Rare Earth Element Enrichment and Mineralization in the Maoniuping Giant REE Deposit, SW China

Abstract Carbonatite intrusions host the world’s most important light rare earth element (LREE) deposits, and their formation generally requires extraordinary fertile sources, magmatic evolution, and hydrothermal events. However, carbonatitic magma evolution, particularly the role of fractional crystallization and contamination from silicate rocks in REE enrichment, remains enigmatic. The Maoniuping world-class REE deposit in southwestern China, is an ideal target to decipher magmatic evolution and related REE enrichment as it shows continuous textual evolution from medium- to coarse-grained calcite carbonatite (carbonatite I) at depth, to progressively pegmatoidal calcite carbonatite (carbonatite II) at shallow levels. In both types of calcite carbonatites, four generations of calcite can be classified according to petrographic and geochemical characteristics. Early-crystalizing calcite (Cal-I and Cal-II) are found in carbonatite I and exhibit equigranular and a polygonal mosaic textures, while late calcites (Cal-III and Cal-IV) in carbonatite II are large-size oikocrysts (>0.5 mm in length) with strain-induced undulatory extinction and bent twinning lamellae. All these generations of calcite yield similar, near-chondritic, Y/Ho ratios (26.6–28.1) and are inferred to be of magmatic origin. Remarkably, gradual enrichment of MgO, FeO and MnO from Cal-I to Cal-IV is coupled with a significant increase in REE contents (~800 to 2000 ppm), with LREE-rich and gentle-to-steep chondrite-normalized REE patterns ((La/Yb)N = 3.1–26.8 and (La/Sm)N = 0.9–3.9, respectively). Such significant REE enrichment is ascribed to protracted magma fractional crystallization with initial low degree of fractional crystallization (fraction of melt remining (F) = ~0.95) evolving to late stage (F = 0.5–0.6) by formation of abundant calcite cumulates. Differential LREE and HREE behavior during magma evolution largely depend on separation of phlogopite, amphibole, and clinopyroxene from the carbonatitic melt, which is indicated by progressively elevated (La/Yb)N ratios ranging from 3.1 to 26.8. The four generations of calcite have significantly different C and Sr isotopic compositions with δ13CV-PDB decreasing from −3.28 to −9.97‰ and 87Sr/86Sr increasing from 0.70613 to 0.70670. According to spatial relations and petrographic observations, the relative enrichment of δ13C and depletion in 87Sr/86Sr ratios of Cal-I and Cal-II show primary isotopic characteristics inherited from initial carbonatitic magma. By contrast, the variable Sr and C isotopic compositions of Cal-III and Cal-IV are interpreted as the results of contamination by components derived from silicate wall rocks and loss of CO2 by decarbonation reactions. To model such contamination processes, Raleigh volatilization and Monte Carlo simulation have been invoked and the model results reveal that carbonatitic melt-wall rock interaction requires 40% radiogenic Sr contamination from silicate rocks and 35% CO2 degassing from carbonatitic melt. Moreover, positive correlations between decreasing δ13C values and increasing REE contents, together with bastnäsite-(Ce) precipitation, indicate further REE accumulation during the contamination processes. In summary, alongside REE-rich magma sources, the extent of fractional crystallization and contamination during carbonatitic magma evolution are inferred to be important mechanisms in terms of REE enrichment and mineralization in carbonatite-related REE deposits worldwide.

Transcrustal and source processes affecting the chemical characteristics of magmas in a hyperactive volcanic zone

Arc magma generation and evolution are affected by transcrustal processes, such as assimilation and fractional crystallisation, and source processes like slab influx into the mantle wedge. However, the relative contribution of these mechanisms remains contentious. The Pleistocene to Holocene Taupo Volcanic Zone (TVZ) is unusually dominated by felsic volcanism with more than 95% of the total eruptive volume corresponding to rhyolitic magmas. Despite the relatively thin crustal basement (∼16–30 km), combined wall rock assimilation and fractional crystallization (AFC) of primary basalt has previously been presented as a necessary means to generate the chemical characteristics of these magmas. This petrogenetic model is here assessed using a new, internally consistent set of major and trace element concentrations, and Sr-Pb isotope data from a suite of basaltic to rhyolitic samples that are representative of the entire TVZ with respect to geographical distribution and age. The dataset was modelled for AFC using the energy- and mass-constrained Magma Chamber Simulator (MCS) and the local Permian to Early Jurassic Torlesse composite terrane basement used as the principal assimilant. Regardless of the intensive parameters employed, the energy- and mass-constrained models presented here fail to realistically reproduce the combined major oxide, trace element, and isotope systematics of the sample set. The Pb isotope ratios of TVZ basalts to rhyolites reveal a broadly linear trend ranging from an unradiogenic (206Pb/204Pb: 18.77) to a more radiogenic crustal endmember (206Pb/204Pb: 18.84). This trend can be reproduced by a composite mélange dominated by the Torlesse terrane (representative of tectonically eroded forearc crust), with some contribution of subducting sediments (GLOSS-II), interacting with the sub-arc mantle to generate the source of the magmas observed in the TVZ. This model is also consistent with Sr-Pb isotope systematics. At New Zealand’s active margin, tectonic erosion has been reported based on geophysical data. Therefore, it is proposed that slab input can have a stronger relevance in the magma generation of the TVZ than previously thought. The broad compositional variations in the TVZ may result from source contamination by a subduction mélange, with differentiation processes within the overriding crust being subordinate.