Considering the inadequate integrity between boundary elements and wall connections in shear walls with PEC columns. A new type of PEC shear wall is proposed to enhance the connection between the PEC columns and the wall by introducing T-section connectors to improve the bearing capacity as well as the deformation capacity. In this study, the seismic behavior of composite shear walls was investigated in terms of the failure process, hysteresis, energy consumption, etc. The test results showed that the specimens had good stiffness and energy dissipation capacity. The combination of PEC columns with RC shear walls under the action of the T-section connector was effective. An increase in the width-to-thickness ratio can lead to shear bonding failure. In the PEC-RCSW structure with a shear-to-span ratio of 1.35, the bearing capacity and deformation capacity of the T-section connectors and PEC columns are slightly higher in the major axis direction than in the minor axis direction. Based on the test results, the finite element model was established and further research was conducted on the shear span ratio and T-section connector size. And provided engineering application suggestions for the innovative composite shear wall shear wall. Finally, flexural and shear capacity calculation formulae of the innovative composite shear wall were proposed.