Piezoelectric polymeric flexible plates can be placed in the wake of bluff bodies to harvest the fluid flow energy. The undulating motion of such plates generated by the vorticity in the wake has been described by previous researchers; the influence of different aspect ratios of the plate on the strain energy has also been investigated. Less information is given on the fluid-structure interaction mechanism and on the mode shapes contribution to strain energy. Moreover, the optimum thickness and aspect ratios of the plates are still to be determined. As a reason, different polyethylene thin plates were clamped to a square cylinder and placed in a water tunnel. We used a high speed camera to capture the plate deflection and the flow pattern. From the deflection, we proceeded to modal decomposition into cantilever beam mode shapes and to strain energy calculation. The flow pattern for several characteristic plate deflection shapes were computed using the software PIVlab. Two way fluid-structure interaction modelling was carried out using ANSYS. We observed that the plate deflection evolves from splitter plate oscillation type into travelling wave type where strain energy is maximized. Strain energy is proportional to the thickness until an optimum thickness after which any further increase renders the plate too stiff to undergo significant bending. The particle image velocimetry analysis and the fluid structure-interaction modelling showed that there is no deflection when the flow is symmetrical or when there is no perpendicular flow impinging on the plate. Deflection occurs when the flow impinges in a different fashion on the two sides of the plate. The motion of the plate drastically influences the wake flow by increasing the drag and generating vorticity.