Volume Shrinkage Research Articles

Temperature-irrelevant superhydrophobic polyimide–SiO2 aerogels with a confined shrinkage strategy for high-temperature thermal protection (>400 °C)

Polyimide (PI) aerogels often experience substantial volume shrinkage when exposed to temperatures above 200 °C. Furthermore, research regarding the hydrophobic characteristics of PI aerogels under high-temperature conditions is limited. Herein, a confined shrinkage strategy was proposed, and the PI–SiO2 aerogels were prepared with ultralow thermal shrinkage and high-temperature superhydrophobic properties. Micrometer-sized silica aerogel powders were used in this strategy as shrinkage inhibitors during the production of PI aerogels. The silica aerogel powders were then pulled together using the PI chain and braced to each other, limiting the shrinkage of the PI aerogel matrix attached to the powders. Results indicated that the prepared aerogel experienced a shrinkage of only 6.2 % after heat treatment at 400 °C for 1 h in a muffle furnace. The surface area of the sample decreased from 669 m2/g to 649 m2/g after heat treatment, revealing a reduction of only 2.7 %. Previous studies have never reported this remarkable thermal stability. Furthermore, the aerogel exhibited superhydrophobic properties with a water contact angle of 157.4° and a water rolling angle of approximately 0° at 300 °C due to its high surface roughness.

Robust and Density Tunable Kevlar/Hexagonal Boron Nitride Microribbon Aerogels with Excellent Thermal, Mechanical, and Oil-Absorption Properties.

With rapid advancements in aerospace and supersonic aircraft technology, there is a growing demand for multifunctional thermal protective materials. Aerogels, known for their low density and high porosity, have garnered significant attention in this regard. However, developing a lightweight multifunctional aerogel that combines exceptional thermal and mechanical properties through a straightforward and time-efficient method remains a significant challenge. Herein, a facile and universal approach is developed for the preparation of Kevlar/hexagonal boron nitride (h-BN) aerogels, in which a spin-assisted method is applied to create robust microribbons and further accelerate solvent displacement. The resulting microribbon scaffold, with its entangled nanofiber-nanosheet morphologies, exhibits sufficient strength to prevent volume shrinkage during drying, thereby allowing precise control over aerogel density. The porous hybrid aerogels, featuring controllable geometric characteristics and tailored densities ranging from 6.9 to 100 mg cm-3, can be successfully fabricated. These aerogels exhibit excellent thermal insulation properties, and the thermal conductivities of the as-prepared KBX aerogels have a wide distribution in the range of 0.0269-0.0450 W m-1 k-1. The thermal stability of the hybrid aerogels is enhanced to 566 °C. Moreover, the resulting hybrid aerogels exhibit an ultrahigh bearing ratio, supporting more than 2000 times their own weight while maintaining stable structural integrity. These aerogels also demonstrate high compressive strength, hydrophobicity, and excellent sorption performance for various oils and solvents. Additionally, the oil-saturated aerogels can be easily recovered through heat treatment or combustion in air. The features endow hybrid Kevlar/h-BN aerogels with significant potential for applications in thermal management, environmental protection, and neutron protection.

Strategy for Simple Control of High Performance PQ/PMMA Holographic Media.

Holographic data storage technology is a cost-effective solution for long-term archival data storage. However, the development of suitable holographic recording materials remains a challenge. Among these materials, phenanthraquinone-doped poly(methyl methacrylate) (PQ/PMMA) stands out due to its low cost and controllable thickness. Nevertheless, its limited photosensitivity and diffraction efficiency hinder its widespread application. In order to solve these problems, we put forward a kind of convenient and simple, low cost strategy, by adding plasticizer N,N-dimethylformamide (DMF) for preparation of DMF-PQ/PMMA photopolymer, avoid the use of complex compounds. The addition of DMF not only influences the thermal polymerization stage but also forms weak interactions with PQ during the photoreaction process, thereby enhancing the holographic performance of DMF-PQ/PMMA. Consequently, we achieved a remarkable 9.1-fold increase in photosensitivity (from ∼0.35 to 3.18 cm J-1), improved diffraction efficiency by 20% (from 65% to 80%), and reduced volume shrinkage by a factor of 8 (from 0.4% to 0.05%). Furthermore, utilizing a collinear holographic storage system with multiplexing shift at a scale of 5 μm resulted in an impressively low minimum bit error rate (BER) of only 0.36% (with an average BER of 1.4%), highlighting the fast processing capability and potential for low BER applications in holographic information storage using DMF-PQ/PMMA.

Inversion of creep parameters and their application in underground salt cavern energy storage systems for enhancing wind power integration

While the development of wind energy presents great potential and opportunities, the high level of uncertainty inherent in wind farms also poses considerable challenges for operators, especially when it comes to participating in the energy market. The intermittent and unpredictable fluctuation characteristics of wind power generation may cause significant deviations in the frequency and voltage of the grid, which pose a certain threat to the stability of the grid and power quality and need to be mitigated by advanced energy storage solutions. Salt caverns, these geological structures deep in underground space, are widely used in oil and gas storage, compressed air energy storage(CAES), and other projects around the world. In the operation of underground salt caverns as storage, there is no effective technical means to monitor the deformation of deep caverns in real-time. Therefore, developing a high-precision real-time prediction method for cavern volume deformation is of great significance for the safety assessment during the underground salt cavern operation. In this context, this paper proposes a comprehensive technical approach to meet the needs of real-time monitoring of the cavern status, including volume changes, in the intelligent construction of underground salt cavern facilities in China. Firstly, through the shut-in pressure test of the brine well, the volume shrinkage of the cavern during the monitoring period is obtained, and the creep parameters of the salt rock strata in the regional salt mine are inversely derived. Secondly, for a typical cavern in operation in this region, the creep deformation is predicted using numerical simulation methods. By analyzing the cavern volume deformation under different pressures, an empirical equation for cavern volume deformation is established. Finally, by combining the volume changes obtained from sonar tests conducted during the operation of the cavern, the accuracy of the simulated results and the theoretical model derived from the inverted creep parameters is verified. The real-time analysis method for cavern volume deformation developed from this research will be applied to the intelligent construction of underground salt cavern facilities, ensuring safe and controllable operation management of the storage facilities.

A porous IPN-structured polyurethane/epoxy grouting material with low viscosity, high strength and low volume shrinkage

Epoxy based grouting materials should concern with low viscosity, high strength, rapid curing, and low shrinkage. A polyurethane/epoxy grouting material was prepared. Through formula design, its initial viscosity was reduced to below 200 mPa·s. The morphology observation confirmed its porous and IPN structure. Compared with pure EP, its tensile strength, compressive strength, and impact strength were increased by 87 %, 20 %, and 50 %, respectively, as well as the volume shrinkage was significantly reduced. The inherent strength of PU/epoxy resin grouting materials was significantly higher than that of concrete, even in humid environments, their bond strength was 3.26 MPa. The theoretical grout flow rate and diffusion radius at different stages of the grouting process were also determined, which achieved an excellent on-site grouting effect.

Layered Structure Modification of Sodium Vanadate through Ca/F Co‐Doping for Enhanced Energy Storage Performance

AbstractVanadate materials are promising for sodium‐ion batteries (SIBs) due to their low cost, high capacity, and high power characteristics enabled by vanadium's multiple oxidation states. However, their development is hindered by poor conductivity, suboptimal high‐rate performance, and limited cycle life. In this work, a layered structure modification strategy involving Ca/F co‐doping in sodium vanadate Na2CaV2O6F (CVF) is proposed to address these issues. Through a combination of experiments and density functional theory calculations, it is demonstrated that Ca/F synergies enhance the Na layer spacing in CVF, resulting in reduced crystal water content and volume shrinkage compared to Na2V2O6 (NVO). Additionally, Ca/F incorporation significantly mitigates the diffusion potential of Na+ within the material framework. The unmodified CVF sample exhibits a high reversible capacity of 220 mAh g−1 at 10 mA g−1 and an excellent rate capacity of 65.78 mAh g−1 at 400 mA g−1. Furthermore, the cathode material maintains a capacity of up to 138 mAh g−1 at 200 mA g−1 and retains 104.88 mAh g−1 after 100 cycles within the voltage range of 1.5−4.0 V. These findings enhance the understanding of the crystal structure of NVO cathode materials and pave the way for the rational design of high‐quality vanadate cathodes for SIBs.

Enhanced radiation damage tolerance in Zr-doped UO2

This study explores the effect of tetravalent Zr doping on the radiation behaviour of UO2 through a combination of experimental and theoretical approaches. The intrinsic changes that Zr introduces in UO2 were quantified using X-ray diffraction and Raman spectroscopy, which reveal a shrinkage of the lattice volume and the formation of ZrO8-type clusters. Heavy-ion irradiation was carried out on both undoped and doped UO2 under conditions similar to the ballistic regime of fission products in nuclear fuels. Empirical data, together with DTF+U simulations, found that Zr doping modifies the irradiation-induced defect mechanisms by enabling recombination pathways, allowing a rapid recovery of the UO2 lattice. The fundamental mechanisms involving the role of dopant in modifying the radiation damage kinetics are discussed in this paper, as well as the subsequent evolution in fluorite-structured materials relevant to nuclear fuels.

Research of interlayer dip angle effect on stability of salt cavern energy and carbon storages in bedded salt rock

In order to clean and decarbonize energy, large-scale underground energy storage in salt caverns can be utilized. The construction and safety evaluations for these caverns are crucial, especially for salt caverns with significant interlayer dip angles. Aimed at the bedded salt rocks for energy and carbon storage, this study focuses on the impact of different interlayer dip angles on the stability of underground energy and carbon storage caverns in bedded salt rock formations in China. Four salt caverns with varying interlayer dip angles of 0–30° were established for stability comparison. Numerical simulations reveal that caverns with high interlayer dip angles demonstrate low volume shrinkage, general deformation resistance and small equivalent strain, while exhibiting a larger volume of plastic zones compared to caverns with lower interlayer dip angles. It is important to consider the deformation of the cavern wall rock in the down-dip direction for caverns with high interlayer dip angles. The presence of inclined interlayers affects the symmetry of the contour distribution of deformation, safety factor and equivalent strain. Furthermore, recommendations are provided for the construction of salt caverns in salt rock formations with high interlayer dip angles.

Surface weathering process of earthen heritage under dry-wet cycles: A case study of Suoyang City, China

Dry-wet cycle is a key factor in surface weathering of earthen heritage, which remains insufficiently explained. It involves the interaction of humidity, stress, and damage. Using the RFPA (realistic failure process analysis) numerical method, this study reproduced the processes of humidity diffusion, deformation, stress, and damage evolution under dry-wet cycles in the soil site of Suoyang City, China. The numerical results indicate that the drying phase following rainfall has the most significant deteriorative impact on the earthen heritage. The evaporation of surface moisture during this phase causes volume shrinkage, which in turn generates tensile stress and leads to the formation of numerous desiccation cracks. Desiccation cracks provide channels for moisture diffusion, which further exacerbates generation of the cracks, leading to a mutual promotion between the two phenomena. Furthermore, during the wetting phase, the model elements undergo hygroscopic expansion, resulting in a slight increase in strain and displacement. Previously formed cracks may exhibit temporary narrowing or closure, but will revert during the subsequent drying phase. Ultimately, the overall displacement increases with the number of dry-wet cycles. The findings provide a theoretical foundation for protection against surface weathering and other damage in earthen heritage in arid regions.

Accelerated warming of High Mountain Asia predicted at multiple years ahead

High-Mountain Asia (HMA) is an important source of freshwater since it holds the largest reservoir of frozen water outside the polar regions. HMA feeds ten great rivers, ultimately supporting more than 2 billion people. However, the threat of accelerated glacier melt, which is a consequence of unprecedented global warming since the early 1950s, threatens water resources in the surrounding countries. Accurate predictions of the near-term temperature change and synergistic mass loss of glaciers are essential but challenging to implement because of the impacts of internal climate variability. Here, based on large ensembles of state-of-the-art decadal climate prediction experiments, we provide evidence that the internally generated surface air temperature variations in HMA can be predicted multiple years in advance, and the model initialization has robust added value to the decadal prediction skill. Real-time decadal forecasts suggest that the HMA will experience accelerated warming in 2025–2032, where the surface warming will increase by 0.98 °C (0.67 to 1.33 °C; 5 % to 95 % range) relative to the reference period 1991–2020, which is equivalent to 1.75 times the observed warming during 2016–2023. The decadal predictability originates from extratropical Pacific decadal variability modes, which modulate the convective heating in the tropical Pacific and influence HMA via the eastward-propagating atmospheric Kelvin waves. Accelerated warming in the coming decade will likely increase the shrinkage of the glacier volume over the HMA by 1.4 %. This change poses unprecedented challenges, including potential water scarcity, ecosystem disruption, and increased risk of natural disasters, to HMA and surrounding regions.

Experimental Study on the Properties of Basalt Fiber–Cement-Stabilized Expansive Soil

Expansive soil is prone to rapid strength degradation caused by repeated volume swelling and shrinkage under alternating dry–wet conditions. Basalt fiber (BF) and cement are utilized to stabilize expansive soil, aiming to curb its swelling and shrinkage, enhance its strength, and ensure its durability in dry–wet cycles. This study examines the impact of varying content (0–1%) of BF on the physical and mechanical characteristics of expansive soil stabilized with a 6% cement content. We investigated these effects through a series of experiments including compaction, swelling and shrinkage, unconfined compressive strength (UCS), undrained and consolidation shear, dry–wet cycles, and scanning electron microscope (SEM) analyses. The experiments yielded the following conclusions: Combining cement and BF to stabilize expansive soil leverages cement’s chemical curing ability and BF’s reinforcing effect. Incorporating 0.4% BFs significantly improves the swelling and shrinkage characteristics of cement-stabilized expansive soils, reducing expansion by 36.17% and contraction by 28.4%. Furthermore, it enhances both the initial strength and durability of these soils under dry–wet cycles. Without dry–wet cycles, the addition of 0.4% BFs increased UCS by 24.8% and shear strength by 24.6% to 40%. After 16 dry–wet cycles, the UCS improved by 38.87% compared to cement-stabilized expansive soil alone. Both the content of BF and the number of dry–wet cycles significantly influenced the UCS of cement-stabilized expansive soils. Multivariate nonlinear equations were used to model the UCS, offering a predictive framework for assessing the strength of these soils under varying BF contents and dry–wet cycles. The cement hydrate adheres to the fiber surface, increasing adhesion and friction between the fibers and soil particles. Additionally, the fibers form a network structure within the soil. These factors collectively enhance the strength, deformation resistance, and durability of cement-stabilized expansive soils. These findings offer valuable insights into combining traditional cementitious materials with basalt fiber to manage expansive soil hazards, reduce resource consumption, and mitigate environmental impacts, thereby contributing to sustainable development.

Phase-field-based lattice Boltzmann method for containerless freezing.

In this paper we first propose a phase-field model for the containerless freezing problems, in which the volume expansion or shrinkage of the liquid caused by the density change during the phase change process is considered by adding a mass source term to the continuum equation. Then a phase-field-based lattice Boltzmann (LB) method is further developed to simulate solid-liquid phase change phenomena in multiphase systems. We test the developed LB method by the problem of conduction-induced freezing in a semi-infinite space, the three-phase Stefan problem, and the droplet solidification on a cold surface, and the numerical results are in agreement with the analytical and experimental solutions. In addition, the LB method is also used to study the rising bubbles with solidification. The results of the present method not only accurately capture the effect of bubbles on the solidification process, but also are in agreement with the previous work. Finally, a parametric study is carried out to examine the influences of some physical parameters on the sessile droplet solidification, and it is found that the time of droplet solidification increases with the increase of droplet volume and contact angle.

Recycle of steel slag as cementitious material and fine aggregate in concrete: mechanical, durability property and environmental impact.

Using steel slag (SS) as cementitious material and fine aggregate in concrete is an effective and environmental method for SS consumption and cost reduction. In this paper, SS was recycled in large volumes in concrete as partial cementitious material and fine aggregate. The compressive strength and reaction mechanism of cementitious material with different SS powder contents including 20%, 25%, 30%, and 35% were presented. The results indicated that 20% of SS powder improved the compressive strength by 34.57% and the hydration products were ettringite (AFt) and calcium silica hydrate(C-(A)-S-H). Furthermore, the mechanical and durability performance of concrete with SS as fine aggregate were investigated. When the SS substitution rate was 75%, the compressive strength was increased by 37.83%. The volume shrinkage rate and 28d-carbonation depth were reduced nearly by 64% for 90days and 2.33mm, respectively. The chloride ion penetration resistance reached the optimal grade Q-V and abrasion resistance was improved by nearly 24%. Along with the reduced CO2 by 210-294kg/m3 and the decreased cost by 12.61 USD/m3, it is regarded as an effective method to consume steel slag. As such, this research provided a scientific and systematic basis for the large-scale disposal and utilization of industrial waste residues as well as recycled materials preparation.

Flexible-rigid hybrid siloxane network for stone heritage conservation

Siloxane oligomers produced through the hydrolysis of tri-alkoxysilanes or tetra-alkoxysilanes have been widely used as consolidants for stone heritage. However, the resulting xerogels tend to crack due to the volume shrinkage after curing. In this study, a novel flexible-rigid hybrid siloxane oligomer material is designed by the self-catalyzed copolymerization of di-alkoxysilane (3-Aminopropyl) dimethoxymethylsilane with tetra-alkoxysilane tetraethyl orthosilicate. The flexible linear SiOSi segments produced by di-alkoxysilane are inserted into the tetra-alkoxysilane derived rigid three-dimensional silicon-oxygen domains, as confirmed by spectroscopic characterizations. This unique structure alleviates the shrinkage stress during curing and enables the formation of crack-free xerogels. Therefore, the hybrid siloxane oligomer can invade into the interior of weathered stone to form one three-dimensional continuous network to strengthen its fragile structure. As a result, the flexible-rigid hybrid siloxane oligomer outperforms both as-made polysiloxane consolidant and commercial consolidant for the consolidation of the weathered Tianlong Mountain Grottoes stone samples. The consolidation treatment was evaluated in terms of effectiveness (Leeb hardness, ultrasonic velocity and compressive strength) and compatibility (pore size distribution, water vapor transmission rate and color variation). Following the treatment, the consolidated samples demonstrate remarkable improvements in mechanical properties, reaching a Leeb hardness of 410 HL and a compressive strength of 8.98 Mpa. Additionally, permeability and color variation of the stone after consolidation are all within acceptable ranges. The results confirm the positive consolidation performance of the flexible-rigid hybrid siloxane oligomer on weathered Tianlong Mountain Grottoes stone, indicating promising practical applications.

Research on the Thermal Aging Mechanism of Polyvinyl Alcohol Hydrogel.

Polyvinyl alcohol (PVA) hydrogels find applications in various fields, including machinery and tissue engineering, owing to their exceptional mechanical properties. However, the mechanical properties of PVA hydrogels are subject to alteration due to environmental factors such as temperature, affecting their prolonged utilization. To enhance their lifespan, it is crucial to investigate their aging mechanisms. Using physically cross-linked PVA hydrogels, this study involved high-temperature accelerated aging tests at 60 °C for 80 d and their performance was analyzed through macroscopic mechanics, microscopic morphology, and microanalysis tests. The findings revealed three aging stages, namely, a reduction in free water, a reduction in bound water, and the depletion of bound water, corresponding to volume shrinkage, decreased elongation, and a "tough-brittle" transition. The microscopic aging mechanism was influenced by intermolecular chain spacing, intermolecular hydrogen bonds, and the plasticizing effect of water. In particular, the loss of bound water predominantly affected the lifespan of PVA hydrogel structural components. These findings provide a reference for assessing and improving the lifespan of PVA hydrogels.

Warpage evaluation and mechanical characterisation of modified polyamide-6 specimens produced by Arburg plastic freeformer

AbstractIn injection moulding and additive manufacturing processes, it is common for the final product to exhibit warpage induced by a non-uniform cooling rate after material deposition. Residual stresses can be generated in the built parts, with a volume shrinkage that leads to dimensional inaccuracy and reduced usability. This phenomenon is even amplified in the presence of semi-crystalline polymers, which still need to be more widespread among additive manufacturing processes despite their capacity to show better mechanical properties when compared to amorphous ones. This study evaluates the degree of deformation and subsequently characterises the mechanical properties of a novel modified Polyamide 6 formulation (i.e., RADILON® S X21351 NT) printed through the Arburg Plastic Freeforming process. This new proprietary formulation modified the crystallisation behaviour during cooling. The whole exothermic crystallisation peak was shifted to lower temperatures, allowing the processing envelope of the modified formulation to widen. More specifically, after preliminary polymer characterisation analyses and after evaluating the warpage, a mechanical characterisation was performed using tensile tests on specimens (dry-as-moulded and conditioned) printed with different filling strategies on the build platform (XY-0°; XY- ± 45°; XY-90°; ZX-0°). Measured mechanical properties were ultimately compared to those achieved by applying the injection moulding technique on the same non-modified material. The specimens produced through the Arburg Plastic Freeforming process showed brittle behaviour that was more marked than those obtained by injection moulding. Moreover, the infill direction and water content significantly influenced the mechanical properties of specimens.

Thermo-mechanical response of sand-silt mixtures

The thermo-mechanical response under undrained conditions is crucial in evaluating the mechanical behaviors of sand-silt mixtures. A series of consolidated undrained triaxial shear tests were conducted to investigate the mechanical response of sand-silt mixtures with different fines contents, temperatures, and initial mean effective stresses. The results showed that the volume shrinkage was observed in all specimens during heating. The amplitudes of volume shrinkage were dependent on the fines content and initial mean effective stress. Moreover, the fines content and temperature significantly influence the peak strength, flow behavior, stress ratio at the undrained instability state, and collapsibility index. Furthermore, a unified critical state line has been established in the compression plane for both clean sand and binary mixture under different temperatures and fines contents. It is reliable and suitable to use the equivalent skeleton void ratio to illustrate the thermo-mechanical response of sand-silt mixtures under undrained conditions.

Performance enhancement of cement mortar with superabsorbent polymer composite internally embedded with porous ceramsite sand

Superabsorbent polymer (SAP), which can act as water reservoir, was an internal curing (IC) agent with great potential to reduce the shrinkage and cracking of cement-based materials. However, the volume shrinkage of SAP after water release will lead to the formation of additional voids, which will lead to a clear reduction of mechanical properties. In present work, a novel SAP composite with a rigid skeleton (IP-PS) was synthesized by embedding in-situ polymerized SAP hydrogel into the pores of porous ceramic (PS). The results demonstrated that the compressive strength of IP-PS0.054 was above 10 % higher than that of SAP0.054 in the early and late stages, the compressive strength of IP-PS0.054 at 28 days reached 97.71 % of that of the control group, which was predominantly ascribed to the support provided by the embedded skeleton. The development of self-desiccation was also notably delayed by the incorporation of IP-PS, as evidenced by the approximately 12 % reduction compared to SAP0.054 and 47 % reduction compared to Control group in 7-day autogenous shrinkage, which was on account of the enhanced water storage and durable IC capacity of IP-PS. Furthermore, the impermeability of cement-based materials was also improved by the in-situ polymerized hydrogel modification.

Performance and Microstructure of Grouting Materials Made from Shield Muck.

In response to the environmental pollution caused by transportation and accumulation of large-scale shield muck, the on-site reutilization of shield muck is an effective approach. This study explored the feasibility of silty clay muck to prepare muck grout. Through orthogonal experiments, the effects of cement, fly ash, shield muck, admixture, and the water-solid ratio on the fresh properties and mechanical properties of muck grout were studied. The performance prediction model was established Additionally, the intrinsic relationships between the compressive strength and microstructure of shield muck grouting materials were explored through multi-technology microstructural characterization. The results indicate that the content of muck and the water-solid ratio have a greater significant influence on the bleeding ratio, flowability, setting time, and volume shrinkage rate of muck grout compared to other factors. Cement has a greater significant influence on the compressive strength of muck grout than other factors. An optimal mix proportion (12% for cement, 18% for fly ash, 50% for muck, 0.465 for water-solid ratio, 19.5% for river sand, and 0.5% for bentonite) can produce grouting materials that meet performance requirements. The filling effect of cementitious substances and the particle agglomeration effect reduce the internal pores of grouting materials, improving their internal structure and significantly enhancing their compressive strength. Utilizing shield muck as a raw material for shield synchronous grouting is feasible.

Bionic light-responsive hydrogel actuators with multiple-freedom motions in water environments

Soft actuators with biomimetic behavior have widely been utilized in intelligent robotics and artificial muscles. Herein, tannic acid (TA) non-covalently modified and γ-methacrylic trimethoxysilane (MPS) covalently modified MXene (MPS-TA-MXene) are incorporated into a poly(n-isopropylacrylamide-polyacrylamide) (PNIPAM-PAM) copolymer hydrogel to yield a light-responsive hydrogel nanocomposite, denoted as MNA. TA effectively preserves the surface characteristics of MXene while the double bonds in MPS form covalent bonding between MXene and PNIPAM-PAM copolymer, ensuring uniform dispersion of MPS-TA-MXene in MNA hydrogel. Under exposure to ultraviolet light, the resulting MNA hydrogel actuators with nematode- or starfish-shaped exhibit not only bending capabilities in various directions and angles but also demonstrate remarkable multiple-freedom rolling behavior in water environments due to their volume shrinkage induced by the phase transition of MNA hydrogel. Overall, the proposed simply assembled MNA hydrogel actuators with multiple and continuous bionic motions, distinguishing them from conventional single soft actuators limited to bending in one specific direction or performing a simple singular action of rolling, look promising for use in underwater exploration.