Volumes Of Wastewater Research Articles

Comparative Analysis of Locally Sourced Adsorbents for Iponda and Idominasi, Abandoned Gold Mine Wastewater Bioremediation in Osun State, Nigeria

This study investigates and compares the effects of Neem leaf (NL) and coconut husk (CCH) adsorbents in reducing the levels of heavy metal concentration and elemental content in wastewater from two specific abandoned gold mining sites, namely Iponda (Iponda wastewater- IPWW) (longitude 4°43'18''E, Latitude 7°43'57''N ) and Idominasi (Idominasi wastewater -IDWW) (longitude 4°42'0''E, Latitude 7°40'59''N). Preparation of locally sourced adsorbents, bioremediation process through adsorption and physico-chemical analysis of the treated wastewater samples were carried out. Adsorbents were prepared from washed, air-dried neem leaves, grinded to 40 microns size to facilitate penetration of the adsorbate. In addition, washed and airdried CCH was carbonized in an electric muffle furnace at between 300 0C and 350 0C over a period of 30 minutes, and then granulated and sieved with a mesh size of 40 µm to ensure uniform size. Measured dosages of adsorbent (0.5 g, 0.75 g, and 1 g) were added to a 50 ml volume of wastewater and the mixture was agitated at different speeds ranging from 30 rpm to 120 rpm. The treated wastewater samples were then subjected to various physico-chemical analytical tests to determine the effect of the adsorbents on the reduction of the heavy metal concentration and elemental content of the wasted water samples. The results of this study demonstrate that both NL and CCH adsorbents have a significant impact on the wastewater from the two abandoned gold mining sites, IPWW and IDWW. This impact is reflected in the reduction of heavy metal and other element concentrations in the wastewater. Furthermore, it can be concluded that the bioremediation process is more effective when utilizing NL compared to carbonized CCH. Locally sourced cheap non-edible biomass materials hitherto considered as wastes have proved to be highly effective and efficient when used as adsorbents in the treatment of wastewater from abandoned gold mining sites. This is evident from the results obtained from this study.

SUITABILITY OF THE HOSPITAL WASTEWATER TREATMENT SYSTEM IN BINH DUONG PROVINCE TO THE ENVIRONMENTAL CARRYING CAPACITY

As the number of healthcare facilities increases, stringent management of wastewater treatment systems becomes imperative. This study investigates a wastewater treatment system designed for a general clinic in Bình Dương Province, Vietnam, which complies with Vietnamese environmental standards. The clinic, located in Bến Cát City, serves approximately 200 patients per day and generates an average wastewater volume of 1.7m³/day. The treatment system, with a capacity of 10m³/day, employs a combination of biological and chemical methods, including anoxic and aerobic processes, to efficiently reduce pollutants. Results indicate that the treated wastewater meets the QCVN 28:2010/BTNMT, column A standards, ensuring minimal environmental impact when discharged into the Thi Tinh River. The study demonstrates the system's effectiveness in managing hospital wastewater, contributing to environmental protection and public health.

Application of Mill Scale Waste for Geoecological Protection of Aquatic Medium

The potential for use of mill scale (metallurgical production waste) as an affordable sorption-filtration material for aqueous medium protection from phosphates and heavy metals is considered. The results of X-ray phase studies of mill scale prototypes, as well as extraction of dissolved components from them into bidistilled water at long-term contact, which revealed insignificant emission of harmful substances indicating safety of the mill scale application as a sorbent, are given. It is proposed to use industrial cartridges (filter cartridges) loaded from rolled scale to purify large volumes of surface wastewater in real conditions.

Full-scale study on high-rate low-temperature anaerobic digestion of agro-food wastewater: process performances and microbial community.

The fast-growing global population has led to a substantial increase in food production, which generates large volumes of wastewater during the process. Despite most industrial wastewater being discharged at lower ambient temperatures (<20 °C), majority of the high-rate anaerobic reactors are operated at mesophilic temperatures (>30 °C). High-rate low-temperature anaerobic digestion (LtAD) has proven successful in treating industrial wastewater both at laboratory and pilot scales, boasting efficient organic removal and biogas production. In this study, we demonstrated the feasibility of two full-scale high-rate LtAD bioreactors treating meat processing and dairy wastewater, and the microbial communities in both reactors were examined. Both reactors exhibited rapid start-up, achieving considerable chemical oxygen demand (COD) removal efficiencies (total COD removal >80%) and generating high-quality biogas (CH4% in biogas >75%). Long-term operations (6-12 months) underscored the robustness of LtAD bioreactors even during winter periods (average temperature <12 °C), as evidenced by sustained high COD removal rates (total COD removal >80%). The stable performance was underpinned by a resilient microbial community comprising active acetoclastic methanogens, hydrolytic, and fermentative bacteria. These findings underscore the feasibility of high-rate low-temperature anaerobic wastewater treatment, offering promising solutions to the zero-emission wastewater treatment challenge.

Mitigating environmental pollution from tofu industry wastewater: Case of Suyanto Tofu Factory, Mojokerto

Background: This research investigates the impact of tofu industry wastewater on water environments at Suyanto Tofu Factory, Mojokerto. The tofu industry generates liquid waste containing high pH, Total Suspended Solids (TSS), Biochemical Oxygen Demand (BOD), and Chemical Oxygen Demand (COD), potentially polluting local rivers. Despite Suyanto Tofu Factory having wastewater treatment facilities, these are currently non-functional, underscoring the urgent need for designing new wastewater treatment installations. Methods: In this context, the study aims to determine the volume of wastewater produced, analyze the levels of BOD, COD, TSS, and pH in the wastewater, and design sustainable wastewater treatment facilities using a Constructed Wetland system. Findings: This method is expected to minimize the environmental impact of tofu wastewater, protect surrounding aquatic ecosystems, and comply with environmental regulations. By proposing sustainable solutions, the research aims to enhance awareness and management of wastewater in the tofu industry, offering technology solutions appropriate to local conditions. Conclusion: In conclusion, implementing effective and sustainable wastewater treatment installations is crucial to safeguard water quality and river ecosystems around Suyanto Tofu Factory. Novelty/Originality of this Study: By proposing a Constructed Wetland system for tofu industry wastewater treatment, this research introduces an innovative, sustainable solution tailored to local conditions, potentially revolutionizing waste management practices in small-scale food industries.

Biofilm Reactors: A Potential Alternative to Current Treatment Technology for Wastewater in Kathmandu Valley

Kathmandu Valley faces challenges managing its growing wastewater volume, compounded by the complex composition of unregulated industrial discharges. Releasing untreated wastewater poses a severe risk to public health and the environment. Existing wastewater treatment infrastructure, primarily reliant on conventional activated sludge processes (ASP) struggles to meet growing demands. These systems require substantial land area, are sensitive to influent variations, produce a high volume of sludge, and incur high operational and maintenance costs. Biofilms, naturally occurring assemblages of microorganisms adherent to surfaces and embedded within an extracellular polymeric matrix (EPS), present a compelling alternative for wastewater treatment due to their diverse pollutant removal capabilities. When implemented as biofilm reactors, they offer distinct advantages, including tolerance to fluctuations in wastewater composition, minimal land requirements, and reduced energy consumption. Notably, microbes residing within a biofilm are capable of biodegradation of persistent materials such as pharmaceuticals, metals, and plastics. Globally, biofilmmediated wastewater treatment has been implemented successfully, while a knowledge gap remains for the treatment of Kathmandu's wastewater. This review critically assesses biological wastewater treatment methods, providing insight into: a) suspended growth process with their configuration, application, and limitations, b) wastewater treatment infrastructures of Kathmandu Valley, and c) biofilm process with their configuration, factors influencing biofilm development and performance, application of specific microbial strains for enhanced treatment efficiency, and factors to be considered during implementation. Furthermore, the paper recommends: a) an extensive study of laboratory-scale biofilm reactors evaluating and optimizing their performance for local integration and b) investigating the role of diverse microbial communities to further enhance the treatment plant's operation. By prioritizing research and development towards biofilm technology, Kathmandu Valley can achieve efficient and environmentally friendly wastewater management.

Geospatial insights into groundwater contamination from urban and industrial effluents in Faisalabad

Groundwater remains the most dependable resource for various essential uses such as drinking, cleansing, agricultural irrigation, and industrial applications. In urban areas, the dependency on groundwater to meet water demands is significant. However, this resource faces threats from overuse and poor management, leading to a degradation in quality primarily due to the unchecked release of industrial and household wastes. The escalation of industrial activities and rapid urban growth have amplified the volume of wastewater, adversely affecting the purity of freshwater sources within aquifers. This investigation focuses on evaluating the impact of industrial and urban effluents on groundwater quality in the city of Faisalabad. The main contributors to groundwater pollution include the indiscriminate disposal of industrial and urban effluents through unlined drains and the extensive application of chemical agents in agriculture, such as fertilizers, and pesticides. To understand the physiochemical properties of both, drain and groundwater, samples were collected at various distances 50 m, 100 m, and 150 m from drain outlets. This study utilized Geographic Information Systems (GIS) to accurately map and analyze the distribution and impact of contaminants. Parameters such as pH, electrical conductivity (EC), total dissolved solids (TDS), total hardness, bicarbonates, calcium and magnesium hardness, and chloride levels were examined. The findings indicated that contaminant levels were highest in drain water and increased in concentration the closer they were to the drainage sources, with the exception of pH levels. All samples exceeded the World Health Organization's (WHO) safe limits, deeming them unfit for use. This finding indicates widespread contamination, posing significant public health risks and highlighting the urgent need for improved waste management and water treatment practices in Faisalabad. It underscores the critical importance of implementing effective pollution control measures to safeguard public health and ensure water security in the region. However, a notable correlation was observed between the concentration of pollutants in drain water and key indicators such as EC, TDS, total hardness, and magnesium hardness, highlighting their role in deteriorating aquifer water quality. Moreover, groundwater samples collected 50 m from drains exhibited the highest pollutant concentrations compared to those taken further away, at 100 m and 150 m distances.

Моделирование системы очистки сточных вод животноводческих ферм

Among the sources of pollution of surface water bodies from agricultural activities, livestock, pig and poultry complexes can be prioritized, which are uncontrolled and diffuse sources of suspended solids, organic compounds, biogenic elements, heavy metals and pathogenic microflora, which causes biochemical pollution and has a particularly detrimental effect on the state of inland reservoirs. Wastewater from agricultural processing enterprises and household water from rural settlements with unpredictable pollutants play a significant role in pollution. The livestock sector is one of the largest consumers of water. The large number of animals in a confined space, the use of hydraulic harvesting systems when removing their waste products, leads to the formation of manure in significant quantities. Sanitary and hygienic standards in industrial premises are supported with the help of water – animals are washed with it, rooms are cleaned, and they are disinfected, food is prepared, dishes and equipment are washed, manure is washed off with water, and so on. Accordingly, as the demand for water in animal husbandry increases, the volume of wastewater discharge that contains manure into nearby water bodies increases. The effluents that are formed as a result of the activities of the livestock sector are classified as containing a large amount of harmful substances with a high concentration. Depending on the sources of pollution and the main pollutants, technical solutions should be developed to reduce the volume of wastewater and its treatment. The effectiveness of their functioning can be ensured with the help of modern information processing methods, using methods of system analysis of complex objects based on a mathematical description of the technological process. To analyze the state of the treatment system as a whole and predict the development of emergency situations, a software implementation of a wastewater treatment system for livestock farms was created.

Impacts of projected future changes in precipitation on wastewater treatment plant influent volumes connected by combined sewer collection systems

Climate change induced precipitation changes can impact wastewater influent volumes and, in turn, the design and operation of wastewater treatment plants (WWTPs). As influent volumes approach or exceeds the design capacity of the WWTP, the likelihood of poor treatment or untreated discharges that result in environmental damage, increases. To date, there has been a lack of research analysing the impact changes in precipitation may have on influent volumes of WWTPs with combined sewerage systems. This study leverages data driven models of observed precipitation and influent volumes for 14 Irish WWTPs with combined sewerage systems, to project monthly wastewater influent volumes in 2041 – 2060 using Ireland’s most up-to-date high resolution multi-model RCM projections under RCPs 4.5 and 8.5. With changing monthly average daily precipitation, influent volumes for all the WWTPs demonstrated maximum decreases during summer months for both RCP 4.5 and RCP 8.5. Winter months showed increasing trends in influent volumes, particularly under RCP 8.5. The results indicate that with projected increase in high and very high precipitation days in Ireland (under CMIP5), the return periods for influent volumes that exceed the hydraulic capacity of 5 of the WWTPs will reduce. This work also presents a framework by which newer high-resolution downscaled climate models can be used to developed updated impact analysis of changing rainfall patterns on wastewater. It likely that wastewater treatment infrastructure will need to adapt to more intense precipitation to minimise the occurrence of combined sewer overflows.

Enhanced Extraction of Low-Molecular Weight DNA from Wastewater for Comprehensive Assessment of Antimicrobial Resistance.

Environmental surveillance is recognized as an important tool for assessing public health in the post-pandemic era. Water, in particular wastewater, has emerged as the source of choice to sample pathogen burdens in the environment. Wastewater from open drains and community water treatment plants is a reservoir of both pathogens and antimicrobial resistance (AMR) genes, and frequently comes in contact with humans. While there are many methods of tracking AMR from water,isolating good-quality DNA at high yields from heterogeneous samples remains a challenge. To compensate, sample volumes often need to be high, creating practical constraints. Additionally, environmental DNA is frequently fragmented, and the sources of AMR (plasmids, phages, linear DNA) consist of low-molecular-weight DNA. Yet, few extraction processes have focused on methods for high-yield extraction of linear and low-molecular-weight DNA. Here, a simple method for high-yield linear DNA extraction from small volumes of wastewater using the precipitation properties of polyethylene glycol (PEG) is reported. This study makes a case for increasing overall DNA yields from water samples collected for metagenomic analyses by enriching the proportion of linear DNA. In addition, enhancing low-molecular-weight DNA overcomes the current problem of under-sampling environmental AMR due to a focus on high-molecular-weight and intracellular DNA. This method is expected to be particularly useful when extracellular DNA exists but at low concentrations, such as with effluents from treatment plants. It should also enhance the environmental sampling of AMR gene fragments that spread through horizontal gene transfer.

Electrochemical treatment of azo dye wastewater by dynamic flow diaphragm system: Response surface methodology optimization and energy consumption analysis

In this experiment, the degradation process of azo dye wastewater was studied based on the diaphragm double chamber electrochemical reactor, taking the mono azo dye amaranth as an example. Through the circulation flow of appropriate volume of wastewater in the cathode and anode chamber, the simultaneous action of cathode and anode was realized, and the degradation and decolorization efficiency of azo wastewater was improved while reducing energy waste. The optimal reaction conditions optimized by response surface methodology were as follows: the voltage was 20.74 V, the plate spacing was 4.89 cm, and the cycle speed was 60.66 rad / min. The optimal decolorization rate was 99.66 %. The energy consumption analysis of the dynamic flow diaphragm system electrochemical method and the static flow diaphragm system electrochemical method for the treatment of azo dye wastewater was compared and analyzed. In addition, the possible degradation process of azo dye wastewater by dynamic flow electrochemistry was inferred by ultraviolet spectroscopy and mechanism prediction analysis. The experimental results show the great potential of the dynamic flow membrane system process in the treatment of azo dyes.

Investigations of nanomaterial-based membranes for efficient removal of contaminants from wastewater via membrane distillation: a critical review

The requirement for wastewater treatment is paramount in ensuring environmental sustainability and safeguarding public health. As industrialization and urbanization accelerate, the volume of wastewater generated continues to increase, containing a diverse range of pollutants and contaminants. Untreated wastewater poses serious threats to ecosystems, water bodies, and human communities, leading to pollution, waterborne diseases, and ecological imbalances. Effective wastewater treatment becomes essential to mitigate these adverse effects by removing or reducing pollutants before discharge into natural water sources. This process helps to preserve water quality, protect aquatic life, and maintain the overall health of ecosystems. Membrane distillation (MD) has emerged as a promising technology for wastewater treatment, offering an innovative approach to address the challenges associated with conventional treatment methods. In MD, a hydrophobic membrane serves as a selective barrier, allowing water vapor to pass through while preventing the passage of contaminants. This paper offers an extensive overview of the latest advancements in nanotechnology and membrane distillation applied in wastewater treatment. We will delve into different types of nanomaterials that have been used to enhance the properties of MD membranes, such as nanocomposites, nanoparticles, and nanofiber membranes. We also explore the mechanisms by which these nanomaterials improve the separation efficiency, anti-fouling properties, and durability of MD membranes. Additionally, we highlight the potential of hybrid membranes that combine different types of nanomaterials for further improving the performance of MD in wastewater treatment. We provide examples of recent studies that have investigated the use of hybrid membranes, including carbon nanotube-graphene oxide hybrid membranes, nanocomposite nanofiber membranes, and silver nanoparticle-embedded membranes. We also identify some areas for future research and development, such as the scale-up and commercialization of nanotechnology-based MD systems. In summary, this review paper highlights the potential of nanotechnology to enhance the performance of MD in wastewater treatment, leading to improved water quality and a cleaner environment.

Optimalisasi Produksi Bersih dengan Pendekatan Neraca Air di Pabrik Tahu ABC

Tofu is a food product derived from soybeans. The production process generates waste that can pollute the environment. This study aims to examine clean production methods through direct observation and interviews. The growth of food industry centers, particularly in Wagir, Malang, has intensified competition, often neglecting environmental impacts. Conducted at ABC tofu factory in December 2022, this research investigates the tofu production stages: soaking, washing, grinding, boiling, filtering, coagulating, pressing, molding, and cutting. Notably, ABC factory’s washing process involves flowing water over soybeans soaked for 3 minutes. Water is essential for all stages except molding and is sourced from a well. The factory’s water storage system fills the tank unless manually stopped. At ABC tofu industry, 4350 liters of water are used for 75 kg of soybeans, producing 3813.3 liters of wastewater. Soaking lasts 4-5 hours in a 42 cm diameter and 50 cm height bucket, causing soybeans to swell and soften. Wastewater volume is measured by filtering water from soaked soybeans in a 7-liter bucket; not all soak water is captured during filtration

Global publication trend in the field of resource recovery from wastewater: A bibliometric analysis

ABSTRACT In the 19th century, wastewater was not given the proper attention, leading to its mismanagement and neglect. The increase in wastewater volume over time led to the adoption of treatment methods. Technological advancements have enabled a shift from wastewater treatment to resource recovery. Recently, resource recovery from wastewater has gained global attention, generating a wealth of information. Therefore, it is critical to evaluate that information as it could shed light on unexplored areas. A bibliometric analysis was conducted over 20 years, from 2002 to 2021. The study revealed that publication productivity was initially low, but there was a significant increase in productivity starting in 2013. A 5-fold increase in contributions was observed from 2013 to 2021, specifically in the number of countries. Among these countries, China and the USA were the major contributors, accounting for 50% of the publication productivity. Further, the importance of international collaboration in this field is evident, as it accounted for 40% of the publication. Wastewater is now recognized as a valuable renewable resource, rather than a liability, and continued exploration is necessary to find solutions to freshwater scarcity challenges.

Selective Adsorption of Hazardous Substances from Wastewater by Hierarchical Oxide Composites: A Review.

Large volumes of wastewater containing toxic contaminants (e.g., heavy metal ions, organic dyes, etc.) are produced from industrial processes including electroplating, mining, petroleum exploitation, metal smelting, etc., and proper treatment prior to their discharge is mandatory in order to alleviate the impacts on aquatic ecosystems. Adsorption is one of the most effective and practical methods for removing toxic substances from wastewater due to its simplicity, flexibility, and economics. Recently, hierarchical oxide composites with diverse morphologies at the micro/nanometer scale, and the combination advantages of oxides and composite components have been received wide concern in the field of adsorption due to their multi-level structures, easy functionalization characteristic resulting in their large transport passages, high surface areas, full exposure of active sites, and good stability. This review summarizes the recent progress on their typical preparation methods, mainly including the hydrothermal/solvothermal method, coprecipitation method, template method, polymerization method, etc., in the field of selective adsorption and competitive adsorption of hazardous substances from wastewater. Their formation processes and different selective adsorption mechanisms, mainly including molecular/ion imprinting technology, surface charge effect, hard-soft acid-base theory, synergistic effect, and special functionalization, were critically reviewed. The key to hierarchical oxide composites research in the future is the development of facile, repeatable, efficient, and scale preparation methods and their dynamic adsorption with excellent cyclic regeneration adsorption performance instead of static adsorption for actual wastewater. This review is beneficial to broaden a new horizon for rational design and preparation of hierarchical oxide materials with selective adsorption of hazardous substances for wastewater treatment.

Recovery of Metal Ions (Cd2+, Co2+, and Ni2+) from Nitrate and Sulfate on Laser-Induced Graphene Film Using Applied Voltage and Its Application.

The urgent removal of Cd, Co, and Ni from nitrate and sulfate is essential to mitigate the potential risk of chemical pollution from large volumes of industrial wastewater. In this study, these metal ions were rapidly recovered through applying voltage on nitrate and sulfate, utilizing laser-induced graphene/polyimide (LIG/PI) film as the electrode. Following the application of external voltage, both the pH value and conductivity of the solution undergo changes. Compared to Co2+ and Ni2+, Cd2+ exhibits a lower standard electrode potential and stronger reducibility. Consequently, in both nitrate and sulfate solutions, the reaction sequence follows the order of Cd2+ > Co2+ > Ni2+, with the corresponding electrode adsorption quantities in the order of Cd2+ > Co2+ ~ Ni2+. Additionally, using the recovered Co(OH)2 as the raw material, a LiCoO2 composite was prepared. The assembled battery with this composite exhibited a specific capacity of 122.8 mAh g-1, meeting practical application requirements. This research has significance for fostering green development.

Recovery of Lithium from Industrial Li-Containing Wastewater Using Fluidized-Bed Homogeneous Granulation Technology

In this study, a novel fluidized-bed homogeneous granulation (FBHo-G) process was developed to recover lithium (Li) from industrial Li-impacted wastewater. Five important operational variables (i.e., temperatures, pH, [P]0/[Li]0 molar ratios, surface loadings, and up-flow velocities (Umf)) were selected to optimize the Li recovery (TR%) and granulation ratio (GR%) efficiencies of the process. The optimal operational conditions were determined as the following: a temperature of 75 °C, pH of 11.5, [P]0/[Li]0 of 0.5, surface loading of 2.5 kg/m2·h, and Umf of 35.7 m/h). The TR% and GR% at optimal condition could be as much as 90%. The material characterization of the recovery pellet products showed that they were highly crystallized Li3PO4 (purity ~88.2%). The pellets had a round shape and smooth surface with an average size of 0.65 mm, so could easily be stored and transported. The high purity enables them to be further directly reused as raw materials for a wide range of industrial applications (e.g., in the synthesis of cathode materials). Our calculation shows that the FBHo-G process could recover up to 0.1845 kg of lithium per cubic meter of Li-containing wastewater, at a recovery rate of ~90%. A brief technoeconomic analysis shows that FBHG process had economic viability, with an estimate production cost of USD 26/kg Li removed, while the potential gained profit for selling lithium phosphate pellets could be up to USD 48 per the same volume of wastewater and the net profit up to USD 22/m3 Li treated. In all, fluidized-bed homogeneous granulation, a seedless one-step recovery process, opens a promising pathway toward a green and sustainable recycling industry for the recovery and application of the resource-limited lithium element from nonconventional water sources.

Sewage Water Use in Crop Production and Its Effect on Physico-Chemical and Biological Properties of Soil: A Review

The availability of freshwater for irrigation is dwindling, prompting the need for innovative solutions to tackle this critical issue. This research delves into comparing sewage water with fresh water, recognizing the immense volume of wastewater generated daily due to rapid population growth and industrial expansion. The current state of sewage water in India presents a formidable challenge, highlighting the imperative for proactive management strategies moving forward. The study explores methods to harness sewage water for agricultural use, aiming to enhance productivity while acknowledging the global significance of wastewater management. Sewage water composition varies depending on local industrial activities, often containing higher levels of nutrients like nitrogen, phosphorus, potassium, organic carbon, micronutrients, and soil microbial content compared to regular water sources. Utilizing sewage water for irrigation can positively impact soil chemistry and fertility, although it may increase electrical conductivity, albeit usually within acceptable limits to mitigate soil salinity risks. However, sewage water typically contains elevated concentrations of heavy metals such as Cadmium, Chromium, Lead, and Nickel, posing potential hazards to soil and plant health if surpassing safety thresholds. Continuous use of sewage water may exacerbate the accumulation of these hazardous metals, posing risks to both soil quality and human health. Nonetheless, during periods of water scarcity crucial for crop growth, sewage water emerges as a vital resource, potentially saving agricultural productivity. In this context, sewage farming emerges as a promising approach to alleviate the demand for freshwater while addressing wastewater challenges. Embracing sewage water for irrigation holds the promise of significant advancements in curbing wastewater proliferation, underscoring its role as a sustainable solution for agricultural water requirements.

Complete removal of organophosphate pesticides from wastewaters with sustainable ionic liquid-based aqueous two-phase strategy

Due to extensive food production, organophosphate pesticides (OPs) are widely utilized for crop protection, leading to their presence in the environment. The focus of this study was the design of an efficient aqueous biphasic system (ABS) strategy for OP removal, namely, malathion (MAL), azinphos-methyl (AZM), and chlorpyrifos (CHP) from water. Different ionic liquids (ILs) with symmetrical cations were selected as ABS phase-formers (tetrabutylphosphonium salicylate, tetrabutylammonium salicylate, 1,3-dibutylimidazolium dicyanamide, 1,3-dibutylimidazolium salicylate and 1,3-dibutylimidazolium bromide) with citrate salt as a salting-out agent. Initially, phase diagrams were determined, followed by partition studies revealing that the partition of MAL and CHP aligns with the IL- ABS formation trend, while the AZM partition is governed by specific interactions with ILs. For optimization studies, tetrabutylphosphonium-salicylate i.e. [TBP][Sal]-based ABS was chosen, due to obtained high extraction efficiencies of over 99.3 %. After establishing the effects of pH, temperature, tie-line length, and phase ratio on extraction performance, extraction of OPs from a real wastewater sample further confirmed the effectiveness of the designed method achieving complete removal of each pesticide. Furthermore, recovery of IL was achieved using an antisolvent method to precipitate CHP followed by IL-reuse in three consecutive cycles without efficiency decreased. Finally, it was demonstrated that [TBP][Sal] exhibits low cytotoxic potential, indicating that the presence of low amounts of this IL in aqueous media could be acceptable from ecotoxicological standpoint. This study showcased the exceptional potential of the proposed technology for the efficient and sustainable treatment of wastewater contaminated with OPs, affirming its capability to treat significant wastewater volumes.

CURRENT STATE AND DEVELOPMENT PROSPECTS FOR THE RENEWAL OF SEWERAGE NETWORKS IN KHARKIV CITY

Ensuring the reliable operation of sewerage systems is one of the essential tasks of municipal services in Ukrainian cities. As the research shows, in most cases, their construction involved concrete and reinforced concrete, which are prone to destruction under the influence of many factors, particularly microbiological corrosion. The destruction of sewage collectors is often the reason for wastewater leaking into groundwater and soil, resulting in pollution. The article provides statistical data on the ‘Kharkivvodovidvedennia’ Complex of the ME ‘Kharkivvodokanal’ as of 01.01.2024, which operates the city’s external water drainage networks. The article outlines the most common factors that lead to emergencies in sewage networks, such as aging and wear of infrastructure, insufficient maintenance and repair, mechanical damage, pollution and clogging, increased volume of wastewater, planning problems, chemical reactions, biological corrosion, and connection defects. The relationship between these causes may be that corrosion can weaken pipeline materials, making them more vulnerable to mechanical damage and leakage. According to preliminary calculations, it is necessary to relay or rehabilitate (trenchless pipeline laying) at least 22–25 km of city networks annually to ensure the reliability of sewage networks. The article analyses the work cycles performed on the tunnel collectors’ objects and large-diameter collectors over five years. Major repair and reconstruction work that deserves attention includes work on the repair of mine No. 12 of the tunnel collector of the 761 micro-district (mine depth H = 6.75 m, diameter – 5 m); restoration work of the Oleksiivskyi collector Ø 2000 mm near the viewing chamber No. 33 on the street Lopanska; restoration of the collector of the Northern group of factories Ø 900 mm at Danylivskyi Uzviz. As a result, we carried out an analysis of the current state of the sewage network of the city of Kharkiv. The main factor in the wear and tear of sewerage networks is corrosion, which, in turn, can weaken pipeline materials, making them more vulnerable to mechanical damage and leaks. Despite the difficult economic conditions, work on the repair and operation of networks is carried out. Also worthy of special attention for future research is the survey of mines where restoration work took place over the past ten years using modern methods. Keywords: underground construction, sewerage, renewal, repair, reconstruction, bearing capacity, wear, corrosion.