Diamond-like carbon (DLC) coatings are celebrated for their exceptional mechanical properties, including high hardness, low friction and excellent wear resistance, making them indispensable in industrial applications. This study explores the influence of applied voltage on the structural evolution and properties of DLC films deposited on stainless steel 316L using micro-plasma at atmospheric pressure. Ethanol, in an argon environment, served as the carbon precursor, and five samples were processed for 5 min under varying voltage potentials ranging from 2.5 to 4.5 kV. The results reveal a clear correlation between increasing voltage and enhanced DLC deposition. X-ray diffraction (XRD) analysis confirmed the emergence of crystalline structures at higher voltages while scanning electron microscopy (SEM) highlighted the gradual transformation of DLC from an amorphous to a crystalline phase. Samples processed at 4.0–4.5 kV exhibited well-defined crystal growth along the peripheries. Mechanical characterization demonstrated a remarkable increase in hardness, exceeding 50 GPa at 4.5 kV, accompanied by a significant improvement in electrical conductivity as resistivity decreased consistently with voltage. These findings demonstrate that higher deposition voltages significantly enhance the structural and functional attributes of DLC coatings, unlocking new possibilities for their application in demanding industrial and biomedical environments.
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