Voltage Coefficient Research Articles

One-step high-speed thermal-electric aerosol printing of piezoelectric bio-organic films for wirelessly powering bioelectronics.

Piezoelectric biomaterials hold a pivotal role in the progression of bioelectronics and biomedicine, owing to their remarkable electromechanical properties, biocompatibility, and bioresorbability. However, their technological potential is restrained by certain challenges, including precise manipulation of nanobiomolecules, controlling their growth across nano-to-macro hierarchy, and tuning desirable mechanical properties. We report a high-speed thermal-electric driven aerosol (TEA) printing method capable of fabricating piezoelectric biofilms in a singular step. Electrohydrodynamic aerosolizing and in situ electrical poling allow instantaneous tuning of the spatial organization of biomolecular inks. We demonstrate TEA printing of β-glycine/polyvinylpyrrolidone films, and such films exhibit the piezoelectric voltage coefficient of 190 × 10-3 volt-meters per newton, surpassing that of industry-standard lead zirconate titanate by approximately 10-fold. Furthermore, these films demonstrate nearly two orders of magnitude improvement in mechanical flexibility compared to glycine crystals. We also demonstrate the ultrasonic energy harvesters based on the biofilms, providing the possibility of wirelessly powering bioelectronics.

Effect of epoxy resin addition on the acoustic impedance, microstructure, dielectric and piezoelectric properties of 1–3 connectivity lead-free barium zirconate titanate ceramic cement-based composites

In this work, 1–3 connectivity barium zirconate titanate ceramic cement-based composites were fabricated using Portland cement and epoxy resin as the matrix. Barium zirconate titanate (BZT) of 40–60 % by volume was used while epoxy was used with cement at 0–7% by volume. Dielectric and piezoelectric properties, and other properties such as acoustic impedance, density and microstructure were investigated. It was found that epoxy resin can be used in combination with BZT to achieve a suitable acoustic impedance value (9–11 × 106 kg/m·s2) matching that of concrete for structural health monitoring application. Thus, when epoxy resin was used at 7 %, BZT volume can be increased to 60 % where the highest d33 value of 93 pC/N was found and remain within the acoustic matching range. In addition, when epoxy resin was increased, both piezoelectric charge coefficient (d33) and piezoelectric voltage coefficient (g33) were also found to increase. This is likely due to the lower porosity thus denser matrix when epoxy resin was used in addition to cement.

Role of Pb(Zr0.52Ti0.48)O3 on Electric, Dielectric, Electromagnetic Wave Absorption Characteristics of Multiferroic Nanocomposites for Magnetoelectric Devices

Multiferroic composites of ferrite and ferroelcectric phases with systematically varying concentration (100-x)Mg0.48Cu0.12Zn0.4Fe2O4 + x Pb(Zr0.52Ti0.48)O3 (MCZPZT) ( where, x mol% = 0, 20, 40, 50, 60, 80, 100) were prepared by mechanical alloying and sintering methods. The dc resistivity and dielectric constant of the samples as a function of temperature were studied in detail and obtained results are reported. The magnetoelectric effect was investigated for the composites. The sample with 80% ferroelectric phase (MP5), shows largest magnetoelectric output voltage coefficient (dE/dH) H value of 880 μVcm.Oe at 2000 Oe magnetic field. Electromagnetic interference shielding properties of transmission loss and attenuation constant were determined for the composites. Skin depth decreases with frequency from 0.29 to 0.2 cm in the range 8–12 GHz for all composites. The composite MP5 with 80% PZT shows lowest α value between 282 dB m−1 and 414 dB m−1 throughout X-band frequencies. The present results proved that the current magnetoelectric materials of all concentrations exhibit strong magnetoelectric coupling with excellent microwave absorbing performance in X-band region and are appropriate for EMI shielding and novel device applications.

Capacitance-Voltage Fluctuation of SixNy-Based Metal-Insulator-Metal Capacitor Due to Silane Surface Treatment.

In this study, we analyze metal-insulator-metal (MIM) capacitors with different thicknesses of SixNy film (650 Å, 500 Å, and 400 Å) and varying levels of film quality to improve their capacitance density. SixNy thicknesses of 650 Å, 500 Å, and 400 Å are used with four different conditions, designated as MIM (N content 1.49), NEWMIM (N content 28.1), DAMANIT (N content 1.43), and NIT (N content 0.30). We divide the C-V characteristics into two categories: voltage coefficient of capacitance (VCC) and temperature coefficient of capacitance (TCC). There was an overall increase in the VCC as the thickness of the SixNy film decreased, with some variation depending on the condition. However, the TCC did not vary significantly with thickness, only with condition. At the same thickness, the NIT condition yielded the highest capacitance density, while the MIM condition showed the lowest capacitance density. This difference was due to the actual thickness of the film and the variation in its k-value depending on the condition. The most influential factor for capacitance uniformity was the thickness uniformity of the SixNy film.

Impact of Ca2+ and Zr4+ substitution on mechanical energy harvesting response of lead-free BaTiO3 piezoceramics with thermally stable storage density and efficiency

The Ba1-xCaxZryTi1-yO3 (BCZT; x = 0.18, y = 0.08; x = 0.15, y = 0.10; x = 0.12, y = 0.12; x = 0.09, y = 0.14; both x and y are in mol. %) piezoceramics were prepared by solid-state reaction method and investigated their energy storage and harvesting responses. The composition x = 0.15, y = 0.10 ( i.e. BCZT-2) reveals the morphotropic phase boundary (MPB) near room temperature with enhanced piezoelectric properties such as piezoelectric charge coefficient (d33) ∼ 380 pC/N, piezoelectric strain coefficient (d33*) ∼ 583.71 pm/V, piezoelectric voltage coefficient (g33) ∼ 14.09 ×10−3Vm/N, figure of merits (d33×g33) ∼ 5.35 ×10−12m2/N and the electromechanical coupling coefficient (kp) ∼ 0.291. The harvested peak-to-peak open circuit AC voltage is 30 V and the calculated current is in the range of 0.02–0.14 mA with varied load resistance and the maximum obtained power density is 13.38 μW/mm3 for BCZT-2 ceramics. The DC output signal of BCZT-2 ceramics successfully lit up the 'FCLNT' panel consisting of 53 red LEDs. At room temperature, BCZT ceramics have a recoverable energy storage density (Wrec) and storage efficiency (η) in the range between 506.46 and 257.49 mJ/cm3 and 50.53 – 64.93 % respectively. The composition x = 0.12, y = 0.12 (i.e. BCZT-3) revealed the highest energy storage efficiency (η) ∼ 64.93 % at room temperature. Nonetheless, the temperature-dependent (till its Curie temperature) maximum obtained Wrec of all BCZT ceramics is found in the range between 238.41 and 446.49 mJ/cm3 with an η of 66.98–79.67 %. Thus, compositionally tuned BCZT ceramics exhibit considerable piezoelectric properties, including energy storage and harvesting capabilities.

Enhanced piezoelectric properties of additively manufactured BCZT with an oriented ceramic lamellar structure formed via vat photopolymerization

Advances in additive manufacturing have enabled the creation of piezoceramic materials with complex architectures. However, the lack of a clear structural design strategy limits their performance and application in high-performance piezoelectric transducer devices. This work outlines the additive manufacture of a novel sandwich architecture based on a porous (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 (BCZT) layer containing oriented ceramic lamellae. The d33 charge coefficients and g33 voltage coefficients of the optimized porous ceramic were 1.16 times and 2.11 times higher than those of the dense counterparts respectively. After electroding the aligned lamellar ceramic with an indium tine oxide film a piezoelectric sensor was obtained which, when subject to a pressure of 7.5 MPa, produced a open circuit voltage of 173 V. This paper provides a new structural design strategy to effectively improve the performance of piezoelectric ceramics, and provides new opportunites for the design and production of additive manufactured piezoelectric sensors and energy harvesting devices.

Flexible DC transmission line fault type identification scheme based on Pearson correlation coefficient

Abstract Faults occurring on the DC side of the line are very harmful to the MMC-MTDC system, and with the popularization of flexible DC transmission technology based on overhead lines, how to discriminate the type of fault is the difficulty of MTDC DC line protection. This paper gives a fault kind identification approach based totally on the Pearson correlation coefficient, which discriminates the fault kind with the aid of calculating the Pearson correlation coefficient of the line voltage at each pole after the fault.

Piezoelectric Properties of As-Spun Poly(vinylidene Fluoride)/Multi-Walled Carbon Nanotube/Zinc Oxide Nanoparticle (PVDF/MWCNT/ZnO) Nanofibrous Films.

Conductive multi-walled carbon nanotubes (MWCNTs) as well as piezoelectric zinc oxide (ZnO) nanoparticles are frequently used as a single additive and dispersed in polyvinylidene fluoride (PVDF) solutions for the fabrication of piezoelectric composite films. In this study, MWCNT/ZnO binary dispersions are used as spinning liquids to fabricate composite nanofibrous films by electrospinning. Binary additives are conducive to increasing the crystallinity, piezoelectric voltage coefficient, and consequent piezoelectricity of as-spun films owing to the stretch-enhanced polarization of the electrospinning process under an applied electric field. PCZ-1.5 film (10 wt. % PVDF/0.1 wt. % MWCNTs/1.5 wt. % ZnO nanoparticles) contains the maximum β-phase content of 79.0% and the highest crystallinity of 87.9% in nanofibers. A sensor using a PCZ-1.5 film as a functional layer generates an open-circuit voltage of 10 V as it is subjected to impact loads with an amplitude of 6 mm at 10 Hz. The piezoelectric sensor reaches a power density of 0.33 μW/cm2 and a force sensitivity of 582 mV/N. In addition, the sensor is successfully applied to test irregular motions of a bending finger and stepping foot. The result indicates that electrospun PVDF/MWCNT/ZnO nanofibrous films are suitable for wearable devices.

Porous Structure Enhances the Longitudinal Piezoelectric Coefficient and Electromechanical Coupling Coefficient of Lead-Free (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3.

The introduction of porosity into ferroelectric ceramics can decrease the effective permittivity, thereby enhancing the open circuit voltage and electrical energy generated by the direct piezoelectric effect. However, the decrease in the longitudinal piezoelectric coefficient (d33) with increasing porosity levels currently limiting the range of pore fractions that can be employed. By introducing aligned lamellar pores into (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3, this paper demonstrates an unusual 22-41% enhancement in the d33 compared to its dense counterpart. This unique combination of high d33 and a low permittivity leads to a significantly improved voltage coefficient (g33), energy harvesting figure of merit (FoM33) and electromechanical coupling coefficient ( ). The underlying mechanism for the improved properties is demonstrated to be a synergy between the low defect concentration and high internal polarizing field within the porous lamellar structure. This work provides insights into the design of porous ferroelectrics for applications related to sensors, energy harvesters, and actuators.

A gas sensing neural circuit for an olfactory neuron

A gas sensor can convert external gas concentration or species into electric voltage or current signals by physical adsorption or chemical changes. As a result, a gas sensor in a nonlinear circuit can be used as a sensitive sensor for detecting external gas signals from the olfactory system. In this paper, a gas sensor and a field-effect transistor are incorporated into a simple FithzHugh–Nagumo neural circuit for capturing and encoding external gas signals. An improved functional neural circuit is obtained, and the effect of gas concentration, gas species and neuronal activity can be discerned as the gate voltage, threshold voltage and activation coefficient of the field-effect transistor, respectively. The gas concentration can affect the neural activities from quiescent to normal working and, finally, to saturation state in bursting, spiking, periodic and chaotic firings with different frequencies. The effects of gas species and neuronal activity on the firing state can also be achieved in this functional neural circuit. In addition, variations in the gate voltage, threshold voltage and activation coefficient can cause switching between different firing modes. These results can be helpful in designing artificial olfactory devices for bionic gas recognition and other coupled systems arising in applied sciences.

Arbitrary low-frequency power-splitting strategy in ferrite/piezoelectric magnetoelectric heterostructures: theory and experimental validation

Exploring low-frequency (LF) arbitrary power-splitting technologies to address the independent excitation issues of LF/VLF mechanical antennas (MA) with random distributions is challenging due to unidentified device construction and operation mechanism. In light of this, a device construction strategy for three-port magnetoelectric (ME) arbitrary power splitter in composite of ferrite/piezoelectric heterostructure, as well as theoretical model was developed. To validate the feasibility and effectiveness of the strategy, three size-tailored ME samples with length ratio of split PZT segments in 1:1, 2:1, and 3:2 were modeled, fabricated and comparatively characterized. Experimental results show that the achievable maximum power conversion efficiencies (PE) reach 52%, 71%, and 59% for three tailored ME samples, respectively, and as expected the power-splitting ratios are directly proportional to the square ratio of ME voltage coefficient (MEVC) from each port of the tailored ME samples, which are in coincidence with theory under desired operation stability and favorable experiment repeatability evaluated by uncertainties of 0.25854 V cm−1 Oe−1 and 0.32979 V cm−1 Oe−1 for each port. Therefore, a prediction of evolutionary tendency for arbitrary power splitter realization was expanded in view of our experimental observations, and a great flexibility for device future design and further optimization was also provided. Therefore, the presented LF power-splitting strategy paves the ways for arbitrary power splitter realization and enriches the multi-functional ME power electronics families, as well as enables potential applications for efficient excitations of MAs in high-permeable military underwater and civilian emergency rescue distribution long-wave communication system for practical scenarios of submarine, underground railways, tunnels and collapsed residential buildings.

Mechanical Structure Design of Pressure Sensors with Temperature Self-compensation for Invasive Blood Pressure Monitoring

Abstract Invasive blood pressure (IBP) is a fundamental part of basic cardiovascular monitoring. Conventional piezoresistive pressure sensors are limited in usage due to the high cost associated with equipment and intricate fabrication processes. Meanwhile, low-cost strain gauge pressure sensors have poor performance in the gauge factor (GF) and temperature insensitivity. Here, we report a mechanical structure design for diaphragm pressure sensors (DPSs) by introducing a compensation grid to overcome the aforementioned challenges. A simplified model is established to analyze the mechanical deformation and obtain the optimal design parameters of the DPS. By rationally arranging the placement of sensitive grids to eliminate the discrepancy of relative resistance changes within four arms of the Wheatstone full-bridge circuit, the appropriate GF and high temperature insensitivity are simultaneously achieved. The blood pressure sensor with the DPS is then fabricated and characterized experimentally, which demonstrates an appropriate GF (ΔU/U0)/P = 3.56 × 10−5 kPa−1 and low temperature coefficient of voltage (ΔU/U0)/ΔT = 3.4 × 10−7 °C−1. The developed mechanical structure design offers valuable insights for other resistive pressure sensors to improve the GF and temperature insensitivity.

Medium dynamic field range linear bipolar spin valve sensor through soft pinning the sensing layer

Magnetic sensor with spin valve-GMR technology with medium dynamic range is designed for a diversity of applications, including linear and rotary position measurements, proximity switches, and current sensors. For this, the sensing layer (SL) of the spin valve stack was modified by a soft pinning layer (SPL) through an exchange bias field created by an antiferromagnetic layer which has a lower blocking temperature than the one that is kept adjacent to the pinned layer. Numerical simulation was carried out to control the bias field by keeping a non-magnetic Ru spacer layer between the SPL and SL layers and the results were experimentally verified. The magnetic sensor was fabricated with linear operating field range of the order ±100 Oe having a sensitivity of the order of 0.1 m V V−1 Oe−1 near zero field. The thermal performance confirms that the device can be operated in the temperature range of −40 ∘C to 125 ∘C and it has a thermal coefficient of voltage around 15 µV V−1∘C−1.

Engineered Lysozyme: An Eco‐Friendly Bio‐Mechanical Energy Harvester

Eco‐friendly and antimicrobial globular protein lysozyme is widely produced for several commercial applications. Interestingly, it can also be able to convert mechanical and thermal energy into electricity due to its piezo‐ and pyroelectric nature. Here, we demonstrate engineering of lysozyme into piezoelectric devices that can exploit the potential of lysozyme as environmentally friendly, biocompatible material for mechanical energy harvesting and sensorics, especially in micropowered electronic applications. Noteworthy that this flexible, shape adaptive devices made of crystalline lysozyme obtained from hen egg white exhibited a longitudinal piezoelectric charge coefficient (d ~ 2.7 pC N−1) and piezoelectric voltage coefficient (g ~ 76.24 mV m N−1) which are comparable to those of quartz (~2.3 pC N−1 and 50 mV m N−1). Simple finger tapping on bio‐organic energy harvester (BEH) made of lysozyme produced up to 350 mV peak‐to‐peak voltage, and a maximum instantaneous power output of 2.2 nW cm−2. We also demonstrated that the BEH could be used for self‐powered motion sensing for real‐time monitoring of different body functions. These results pave the way toward self‐powered, autonomous, environmental‐friendly bio‐organic devices for flexible energy harvesting, storage, and in wearable healthcare monitoring.

Insulation Design of High Voltage and Large Capacity Power Supply Transformer

Abstract At present, the highest voltage level of DC circuit breakers in the world is 535kV. With the construction of 800kV multi-terminal flexible DC project, the demand for DC circuit breaker with higher voltage level is put forward. The voltage level of valve base power supply transformer as the power supply component of the DC circuit breaker is increased to 800kV. Single-section pendulum structure, single-section 100kV and 50kV schemes used at 535kV cannot meet the demand. An 800kV valve base power supply transformer scheme of four 200kV gas-insulated transformers in series is proposed. Its insulation design is also carried out. Firstly, the topology of hybrid DC circuit breaker power supply system and the structure of power supply transformer were described. Secondly, the design of power supply transformer insulation was carried out. Finally, the power supply transformer insulation was tested and verified. The results show that: SF6 power supply transformer internal insulation withstand voltage needs to be multiplied by the multiplication factor. The electric field strength limit of SF6 obtained by experiments is more than 1.5 times of the empirical design value. The internal field strength design of the 200kV power supply transformer takes into account the operating and seismic conditions, and the maximum electric field strength is 15kV/mm and 16.2kV/mm respectively. The curvature radius of the top shielding ring needs to be larger than that of other layers, after optimization, the maximum field strength is 2.68kV /mm when the curvature radius is 300mm. The internal insulation design of 200kV power supply transformer according to lightning impulse. The simulated and measured values of non-uniform voltage coefficient of 800kV power supply transformer under lightning impulse are 1.048 and 1.0488 respectively, in which the voltage equalizing capacitance is 3000pF. The insulation tests of 200kV and 800kV power supply transformer were all passed, and it can be operated safely. Effectively support the development of UHV DC circuit breaker.

Flexible, biodegradable ultrasonic wireless electrotherapy device based on highly self-aligned piezoelectric biofilms.

Biodegradable piezoelectric devices hold great promise in on-demand transient bioelectronics. Existing piezoelectric biomaterials, however, remain obstacles to the development of such devices due to difficulties in large-scale crystal orientation alignment and weak piezoelectricity. Here, we present a strategy for the synthesis of optimally orientated, self-aligned piezoelectric γ-glycine/polyvinyl alcohol (γ-glycine/PVA) films via an ultrasound-assisted process, guided by density functional theory. The first-principles calculations reveal that the negative piezoelectric effect of γ-glycine originates from the stretching and compression of glycine molecules induced by hydrogen bonding interactions. The synthetic γ-glycine/PVA films exhibit a piezoelectricity of 10.4 picocoulombs per newton and an ultrahigh piezoelectric voltage coefficient of 324 × 10-3 volt meters per newton. The biofilms are further developed into flexible, bioresorbable, wireless piezo-ultrasound electrotherapy devices, which are demonstrated to shorten wound healing by ~40% and self-degrade in preclinical wound models. These encouraging results offer reliable approaches for engineering piezoelectric biofilms and developing transient bioelectronics.

Tracking the maximum power point of solar panels through direct estimation of optimum voltage with temperature

Abstract Electricity production from photovoltaic (PV) panels is maximized when the operating point is located at the maximum power point thanks to dedicated controllers. These controllers are driven to track the maximum power by using various algorithms within distributed or centralized architectures accounting for factors such as partial irradiation and temperature changes. The effect of irradiance on the optimal panel voltage is weak or even negligible, while it is strong and quasi-linear-dependent on temperature. Based on this observation, this article introduces a straightforward method for tracking the maximum power of a PV panel by using an optimizer, focusing solely on its temperature response as an input variable. The proposed approach hinges on linearizing the relationship between panel temperature and operating voltage. This relationship enables the estimation of the maximum power point through temperature measurement alone. Thus, after determination of the linear temperature coefficient of the voltage requiring only the knowledge of two optimal voltages at different temperatures, for example from the datasheet of the panel, the power tracking involves only one temperature sensor placed on the panel alongside a voltage sensor for regulation. The principle, modelling, and validation post-panel ageing of the method are detailed in this paper. Simulation, conducted using real experimental irradiation and temperature data, attests to the effectiveness of the control. Results indicate an average effectiveness of the method of >99.1% in tracking the maximum power, with the panel generating 2.33 kWh out of a possible 2.35 kWh. This performance is comparable to that of tracking devices employing more complex algorithms. The simplicity and efficiency of the method make it a promising option for maximizing the power production at low cost from PV systems in small or residential, on- or off-grid connected applications.

Room-temperature giant magnetotranstance effect in Y-type hexaferrite Ba0.8Sr1.2Co2Fe11.1−xAl0.9CrxO22 (x ≤ 0.4)

We have investigated the magnetoelectric effect of a series of Y-type hexaferrite Ba0.8Sr1.2Co2Fe11.1−xAl0.9CrxO22 (x ≤ 0.4) at room temperature. Although the magnetoelectric voltage coefficient αE of these multiferroic hexaferrites is not high, it changes rapidly with an applied DC magnetic field, a phenomenon known as the giant magnetotranstance (GMT) effect. It is found that the GMT effect is enhanced with increasing content of Cr and reaches the maximum for x = 0.2. Specifically, the magnetotranstance ratio in the x = 0.2 sample is as high as −96% at 2000 Oe and −84% at 500 Oe. Further addition of Cr content causes a decay of the GMT effect. This kind of room-temperature GMT effect in Y-type hexaferrites opens up a route toward practical applications for the single-phase multiferroics.

A CA-LBM framework for simulating the lithium dendrite growth process

The Lithium metal batteries with high energy density are limited for further commercial applications by the formation of Lithium dendrites, which is difficult to regulate due to its complex growth mechanism. In order to investigate the relationship between the dendritic morphology inside the electrode and the external operation conditions, a two-dimensional simulation framework based on the cellular automaton (CA) and the Lattice Boltzmann method (LBM) is proposed. In this framework, the simulation region is divided into discrete grids and each grid includes a cell to record the phase state and the concentration at the position. Meanwhile, the phase transition rule is set in the CA model and the concentration field is solved by LBM. Based on this framework, the impact of the applied voltage and the diffusion coefficient on the dendritic morphology is investigated. The simulation results indicate that the growth rate and the bifurcation rate of Lithium dendrites can both be reduced by applying lower operating voltage and higher diffusion coefficient which is critical in regulating the morphology of Lithium dendrites.

Evidence of self-biased magnetoelectric coupling in eco-friendly (Na0.41K0.09Bi0.5TiO3-Ba0.85Ca0.15Zr0.1Ti0.9O3)-(CoFe2O4) particulate composites

The magnetoelectric (ME) properties of eco-friendly 1-x(0.94Na0.41K0.09Bi0.5TiO3-0.06Ba0.85Ca0.15Zr0.1Ti0.9O3)-x (CoFe2O4) (NKBCZT-CFO) with x = 0, 0.1, 0.2, 0.3 and 0.4 particulate composites were investigated. The X-ray diffraction studies provided evidence for the simultaneous existence of constituent phases (ferroelectric and ferromagnetic) in the composite. The structural and surface morphology analysis of the composite affirmed the homogeneous and densely packed distribution of CFO grains within the NKBCZT matrix. The composite's multiferroic behavior at room temperature was confirmed through the characterization of P vs E and M vs H hysteresis loops. The observed values of remnant polarization (Pr) and coercive field (Ec) are 26.7 μC/cm2 and 35.5 kV/cm, respectively, for 10 mol% of CFO. The increase in CFO content resulted in a decrease in the ferroelectric properties, possibly due to the conductive behaviour exhibited by CFO, and correlated with leakage current measurement. For the composite containing 40 mol% of CFO, the estimated values of remanent (Mr), saturation (Ms) magnetization, coercive field (Hc), and magnetic moment (µB) are 2.35 emu/g, 21.85 emu/g, 104.2 Oe, and 0.86 µB, respectively. The non-Debye type dielectric relaxation processes have been observed in the composites, and the electron hopping mechanism resulted in a higher dielectric constant (εʹ). Enhancement in relaxor nature had been observed through Vogel-Fulcher analysis with CFO content. The evidence of ME coupling was revealed through the direct ME voltage coefficient (αME) and magnetocapacitance (MC) measurement. The observed maximum value of MC measured at 1 kHz for the 20 mol% CFO is ∼5.6 %. Self-biased ME coupling (non-zero αME at HDC = 0 Oe) was observed in 20 and 30 mol% of CFO composite. The highest measured value of αME for 20 and 30 mol% CFO is 3.63 mV/cm.Oe and 4.09 mV/cm.Oe at HDC = 0 Oe respectively. The strong ME interaction and significant value of self-biased ME αME suggest that these composites can be explored for magnetic sensor and ME memory device applications.