Volcaniclastic Deposits Research Articles

Volcanoes in the estuaries: Insights into Earth’s oldest (3.22 Ga) terrestrial microbial habitats, Moodies Group, Barberton Greenstone Belt

The Moodies Group of the Paleoarchean Barberton Greenstone Belt (BGB; ca. 3.22 Ga) provides an exceptional window into Archaean sedimentary and magmatic processes interacting with microbial ecology. Its magmatic component, the Moodies Igneous Complex (MIC), has to date been largely overlooked. The MIC consists of several mafic-to-intermediate sills, peperitic dike stockworks, extensive basaltic lava flows, and various volcaniclastic deposits and tuffs, all of Moodies depositional age. Excellent outcrop exposures illustrate diverse and dynamic interactions between volcanic activities and shallow-water sedimentary processes; they constrain the conditions in which microbial communities thrived in estuarine and tidal environments: (1) When the Moodies Basaltic Lava flooded the basin, some lava fragments and pillows were reworked as boulder-sized conglomerate clasts and in gravelly sandstones while still plastic and presumably hot. (2) Aerodynamically shaped ejecta of mafic lava and common tephra shards in cross-bedded sandstones demonstrate explosive lava-water interactions. (3) Dacitic (lapilli) tuffs up to several m thick were eroded by estuarine channels and filled back-beach lagoons, modifying and smothering concurrent aqueous transport of epiclastic sediment. (4) The paleo-groundwater table and the MIC interacted vigorously by in situ fluidization of poorly to unconsolidated sediment. This led to entrainment of grains and sandstone xenoliths in mafic (sub-)volcanics, widespread peperite formation, and formation of lava-filled fractures and abundant quartz veins in surficially consolidated sandstones.The proximity of numerous shallow intrusives, lavas, and volcanic tephra to the tidal-zone habitat of abundant benthic microbial mats provided microorganisms with readily accessible thermal and chemical energy. Heavy mineral lags in the estuaries, combined with potentially aggressive weathering of felsic to ultramafic volcanic rock, released ample nutrients as colloidally-bound transition metals and phosphorus. Drying-and-wetting cycles on tidal flats and coastal plains, the high porosity and permeability of the well-sorted quartzose sand in shallow water, the variably energetic current regime, and the anoxic, reducing-to-oxidizing chemistry of these habitats also benefitted microbial communities greatly.

Origin and diagenetic priming of a potential slow-slip trigger zone in volcaniclastic deposits flanking a seamount on the subducting plate, Hikurangi margin, New Zealand

ABSTRACT Slow-slip megathrust events in the Hikurangi forearc region may be related to seamount subduction. IODP Expedition 375 drilled the flank of Tūranganui Knoll, a Cretaceous seamount east of the subduction zone containing units analogous to intervals associated with subducted seamounts. Detailed investigations of the volcaniclastic Unit V at Site U1520, based on scanned core images, petrographic observations, point-counting, and μXRF mapping, reveal that it is a mafic volcaniclastic succession rich in clay minerals which are products of a multiphased history of diagenetic alteration. This unit is interpreted as resulting from downslope transport of volcaniclastic debris from submarine eruptions. In contrast, most volcanic clasts recovered at the nearby Site U1526, near the top of Tūranganui Knoll, are interpreted as products of subaerial eruptions reworked by wave action. This shallow water sedimentary package experienced minimal clay-mineral alteration and more extensive early carbonate cementation. Differences in the clast origins, depositional settings and diagenetic histories of these volcaniclastic units highlight the heterogeneity of volcanic systems on the Hikurangi Plateau. However, the presence of voluminous hydrous clays within thick, altered flanking volcaniclastic units at Site U1520 provides a ready source for excess pore fluids that may enable slow-slip events along the Hikurangi subduction zone.

Jurassic to Early Paleogene sedimentation in the Amazon region of Ecuador: Implications for the paleogeographic evolution of northwestern South America

The retroarc Amazon region of Ecuador recorded distinct events that are preserved in the Mesozoic-Cenozoic sedimentary record of the Subandean Zone and Oriente Basin. In this contribution, we review the Jurassic to Paleocene geologic and paleogeographic evolution of the Ecuadorian foreland using stratigraphic, sedimentologic, provenance, and geochronological data. Our results provide new insights into the sedimentary systems, stratigraphic framework, depositional ages, and sediment dispersal patterns of retroarc basin fill. During the Early Jurassic, marine deposits of the Santiago Formation formed a carbonate platform in eastern Ecuador. At ~180 Ma, an eastward-prograding deltaic system transported volcaniclastic material from a western volcanic arc. Nonmarine conditions prevailed during most of the Middle to Late Jurassic, characterized by deposition of red beds and intercalated volcanic and volcaniclastic deposits of the Chapiza Formation. Clastic and volcanic deposition dated from ~160 to 130 Ma was coeval with regional extension, as suggested by sedimentologic and seismic data from the Oriente Basin. Provenance results show that a ~ 120 Ma fluvial system at the base of the Hollín Formation was initially sourced from the west and progressively evolved to a mixed source with contributions from the Amazonian Craton and incipient Andean topography. Deposition of the Hollín Formation occurred in a northwest-flowing fluvial system that evolved into an estuary system confined by the Andes to the west and the Amazonian Craton to the east. Coastal to shallow marine deposits of the Napo Formation accumulated during regional sea-level variations throughout the Late Cretaceous. The geometry of coastal deposits and supporting provenance data suggest a drainage system characterized by west-flowing rivers derived chiefly from the Amazonian Craton. The latest Cretaceous (~70 Ma) onset of shortening in the Northern Andes coincided with collision of the Caribbean Plateau. This tectonic episode induced a continental-scale drainage reorganization documented in provenance data showing an Andean origin of the east-directed fluvial deposits of the Maastrichtian–Paleocene Tena Formation.

High Preservation Potential Volcaniclastic Sedimentation in the Serravallian Sequence of the Amantea Basin (Coastal Chain, North-Western Calabria)

Evidence of volcaniclastic sedimentation occurs in the first depositional sequence of the sedimentary succession of the Amantea Basin. Volcaniclastic deposits are intercalated in the upper part of a sandstone formation and these show a maximum thickness of about 8 m. The Amantea Basin is a Neogene depozone located along the Tyrrhenian margin of Calabria whose onset started during the Upper Serravallian. The source volcano to these materials had to have been located within or near to the marine basin in order to supply it with significant amounts of pyroclastic fragments emplaced by either pyroclastic fall/or flows during one or more explosive eruptions. The marine environment of volcaniclastic flows made up of pyroclastic fragments mixed with minor siliciclastic and carbonate material. The textural and structural features of the deposits and the composition of the volcanic glass fragments indicate an origin from a sub-aerial coeval explosive eruption, with initial sedimentation in a shallow marine environment, mixing with non-volcanic materials, reworking and final re-sedimentation into the basin. The age of the volcaniclastic/sedimentary sequence makes these deposits a marker for the geodynamic evolution of the area, and the lack of such horizons in the other coeval peri-Tyrrhenian basins allows us to consider the Amantea Basin as a confined elongated coastal basin area, whose tectonostratigraphic architecture denotes a structural partitioning of the eastern nascent Tyrrhenian Basin.

The Rosebank Field, NE Atlantic: Volcanic characterisation of an inter‐lava hydrocarbon discovery

AbstractThe Rosebank Field is located in the Faroe‐Shetland Basin and hosts hydrocarbons within siliciclastic sediments interlayered with volcanic packages of the Late Paleocene to Early Eocene aged Flett Formation. Within this study the volcanic sequences are investigated based on an integrated appraisal of available drill cuttings, sidewall cores, core and wireline logs including image log and geochemical logs from eight wells supported by 3D seismic data. The Rosebank lower (RLV), middle (RMV) and upper (RUV) volcanic sequences are inter‐layered with Colsay Member (C1–C4) fluvial to shallow marine siliciclastic intervals. A comprehensive cross‐field borehole based lithofacies interpretation is presented characterising simple, compound and ponded effusive lava flow facies along with pillow lavas, invasive lava flows, volcaniclastic sediments and complex lava–sediment interactions. Geochemical analyses of core, sidewall core, and hand‐picked cuttings spanning the field reveal separate high‐titanium (RHT) and relatively lower‐titanium (RLT) basaltic magma suites. These compositions can be identified and correlated across much of the field utilising geochemical logging data which, in combination with the geochemical analyses, reveals a two‐part stratigraphic sub‐division of each of the RLV, RMV and RUV. Geochemical logging data is also used to define a volcanic proxy (Fe/10+Ti) which utilises the elevated iron (Fe) and titanium (Ti) within all effusive and volcaniclastic basaltic lithologies to differentiate siliciclastic from volcaniclastic sediments where other logging parameters overlap. By comparing the borehole analyses with seismic data, a localised eruptive vent is interpreted within the north of the field. Finally, a cross‐field volcanic model is presented and compared with relevant global field analogues, providing a constrained spatial framework for sub‐surface modelling of inter‐volcanic sequences.

Eruptive and magma feeding system evolution of Sośnica Hill Volcano (Lower Silesia, SW Poland) revealed from Volcanological, Geophysical, and Rock Magnetic Data

The Sośnica Hill volcano is part of the Oligocene to Miocene (30.9–20.0 Ma) Strzelin volcanic field. It is located 100 km east of the Ohře Rift in the eastern part of the Fore-Sudetic Block, south of the town of Strzelin, Poland. Modern quarrying has exposed the sub-volcanic magma feeder system of the central part of the volcano and an extrusive volcanic succession that includes a 40 m thick sequence of lava flows and pyroclastic deposits that collectively form a complex scoria cone. Geophysical data (ground magnetometry and electric resistivity tomography (ERT)) reveal sharp linear anomalies that are interpreted to reflect normal faults dissecting the volcano. The ERT data map both high and low resistivity bodies, likely representing coherent clay-free dry rocks and partly argilized volcaniclastic deposits, respectively. Paleomagnetic data from 20 intrusive sites reveal two populations of reverse polarity site mean data; 11 sites are of low dispersion and yield a group mean direction that is discordant to the expected field direction, while six sites are highly scattered. Three sites did not yield interpretable results. We interpret the 11 sites as time-averaged field directions that are discordant to the expected field. The high dispersion of the remaining six sites are interpreted to indicate sub-volcanic deformation associated with the growth of the volcanic construct or multiple magma pulses over an extended period of time relative to secular variation. AMS data from 35 sites show a range of flow directions that vary across the quarry without an orderly pattern of fabric orientations. The flow pattern identified from dike paired margin data exhibits sub-vertical upward flow, sub-vertical downward, and moderately inclined northwest flow. Field observations and mapping indicate a complex development of the system in terms of styles of eruptive activity and structure of the final volcanic edifice. The activity included Strombolian and effusive phases, followed by phreatomagmatic, Hawaiian and again effusive eruptions. Such diversity of eruptive styles shows that the origin of the volcano is more complex than a simple, ‘textbook’ monogenetic scoria cone. Palaesoil on top of Strombolian deposits document a longer break in activity, after which eruptions resumed with different style; this is also not typical of monogenetic cones. The lateral variation in the volcanic succession suggests eruptions from several smaller, local vents. The complex subvolcanic magma flow patterns recorded in dikes match the variation of surface eruptive products and documents dynamically changing magma distribution paths in the near-surface and intra-cone part of the feeding system of the volcano.

Caldera Collapse and Volcanic Resurfacing in Arabia Terra Provide Hints of Vast Under‐Recognized Early Martian Volcanism

AbstractArabia Terra is an ancient, geologically complex region of Mars. It is not typically described as volcanic because it lacks prominent, easily recognizable shield volcanoes. However, Arabia Terra contains flood lavas and widespread layered materials that might represent airfall pyroclastics from unknown sources. Here we explore the geology of some complex topographic depressions in Arabia Terra previously hypothesized to represent collapse features termed “plains style caldera complexes,” an enigmatic category of volcanic feature on Mars characterized by surface collapse rather than construction of topographic shields. Geomorphological observations and geologic mapping carried out here support a volcanic origin of these features, providing a possible source for volcaniclastic sediments. The identification of caldera complexes in Arabia Terra raises the questions of how they are linked to the geotectonic setting of the region and whether similar features might be much more abundant in the ancient Martian crust than is currently recognized.

Environment and taphonomy of an intrabasinal upland flora preserved in lower Permian volcaniclastic sediments

Environment and taphonomy of an intrabasinal upland flora preserved in lower Permian volcaniclastic sediments

Elucidating stratovolcano construction from volcaniclastic mass‐flow deposits: The medial ring‐plain of Taranaki Volcano, New Zealand

AbstractLong‐lived stratovolcanoes display a thick volcanic apron surrounding the edifice. This sedimentary succession incorporates the majority of the deposits from both growth and destruction phases of a volcanic massif. The ring plain of Taranaki Volcano (>200 ka) is composed of volcaniclastic mass‐flow deposits that are exceptionally well‐exposed along its coastal‐cliff shoreline, at 20 to 30 km distance from the edifice. Overall, the volcaniclastic deposits in the southern and south‐western sector record three growth phases (65 to 34 ka) which can be investigated due to access and stratigraphic control of the ring‐plain section. Each cyclic growth phase is represented by a sequence of mass‐flow deposits. Lithostratigraphic units or repeated packages with similar properties were identified in order to understand the depositional sequences. The mass‐flow units within these growth phases can be described by three criteria subdivided into nine distinct sedimentological textural types (for example, massive, graded, etc.), five different lithological types (for example, lithic‐dominated, polylithological, etc.) and three main physiographic facies types (sheet, overbank and channel). The mass‐flow deposits can then be further categorized through a classification scheme by assigning these three criteria. Widely distributed lithic‐dominated hyperconcentrated‐flow deposits were recognized, which are thought to be directly or indirectly associated with eruption‐fed events (remobilized from 'block and ash' flows) providing evidence for eruptive activity occurring on a 4 to 10 kyr cycle. Therefore, this study proposes classification criteria for mass‐flow deposits in volcanic ring‐plains using a developed three‐part coding system. The study also aims to clarify the order of sedimentary and volcanic events by establishing a stratigraphic model for the investigated time‐period offering a better understanding for future research.

Earthquakes, Volcanic Eruptions, and Other Geological Disasters During Historical Records In Yogyakarta Special Region, Indonesia

DOI:10.17014/ijog.8.2.197-212Yogyakarta, Indonesia, is a very fast developing area. The Yogyakarta historical time is divided into PreOld Mataram Era (1st - 8th century), Old Mataram Era (8th - 12th century), and Young Mataram Era (since 16th century). Geology has recorded many intermittent natural disasters within those historical time: volcanism, earthquakes, and rock movements as well. Those natural disasters have caused lots of damages, shown by buried and collapsed old buildings. Larger volcanic eruptions were known to occur once in 50 - 150 years ago, which were mostly followed by lahars as far as 32 km from the crater of Merapi Volcano, of which the last eruption was in 2010. Earthquakes were identified based on bumpy foundations that particularly occurred in the first pile of temple stones, i.e. at the temples of Kedulan, Plaosan, Morangan, Gampingan, and Boko Palace. Surface fractures are also present on the base of the palace floors. During 18th - 21st century, larger earthquakes with magnitude of 5 - 8 Richter scale occurred once in 20 - 70 years, of which the last earthquake was in 2006. A geological study clarified that there was a marine volcanism during the Tertiary with radial normal faults. The normal faults have been potential to reactivate since Plio-Pleistocene untill now, shown by surface deformations at Sudimoro Hills with a mass movement occurence as happened in Imogiri (March, 17th 2019), Pleret (2018), Piyungan, and Dlingo (March, 17th - 18th 2019). A stratigraphic study of volcaniclastic deposits around Gendol, Opak, Kuning, and Bedog Rivers shows potential floods around the rivers.

U-Pb Age Dating and Geochemistry of Soft-Sediment Deformation Structure-Bearing Late Cretaceous Volcano-Sedimentary Basins in the SW Korean Peninsula and Their Tectonic Implications

Cretaceous volcano-sedimentary basins and successions in the Korean Peninsula are located along NE-SW- and NNE-SSW-trending sinistral strike–slip fault systems. Soft-sediment deformation structures (SSDS) of lacustrine sedimentary strata occur in the Wido, Buan, and Haenam areas of the southwestern Korean Peninsula. In this study, systematic geological, geochronological, and geochemical investigations of the volcanic-sedimentary successions were conducted to constrain the origin and timing of SSDS-bearing lacustrine strata. The SSDS-bearing strata is conformably underlain and overlain by volcanic rocks, and it contains much volcaniclastic sediment and is interbedded with tuffs. The studied SSDSs were interpreted to have formed by ground shaking during syndepositional earthquakes. U-Pb zircon ages of volcanic and volcaniclastic rocks within the studied volcano-sedimentary successions were ca. 87–84 Ma, indicating that active volcanism was concurrent with lacustrine sedimentation. Geochemical characteristics indicate that these mostly rhyolitic rocks are similar to subduction-related calc-alkaline volcanic rocks from an active continental margin. This suggests that the SSDSs in the study area were formed by earthquakes related to proximal volcanic activity due to the oblique subduction of the Paleo-Pacific Plate during the Late Cretaceous.

Trace Element Signatures in Pyrite and Marcasite From Shallow Marine Island Arc-Related Hydrothermal Vents, Calypso Vents, New Zealand, and Paleochori Bay, Greece

Fluid conditions of shallow marine hydrothermal vent sites (<200 mbsl) in island arcs resemble those of subaerial epithermal systems. This leads to a distinct mineralization-style compared to deeper arc/back-arc (>200 mbsl) and mid-ocean ridge-related environments (>2000 mbsl). At Calypso Vents in the Bay of Plenty and Paleochori Bay at the coast of Milos Island, fluids with temperatures <200°C are emitted through volcaniclastic sediments in water depths <200 mbsl. The hydrothermal mineralization from these fluids is dominated by pyrite and marcasite showing diverse textures, including colloform alternations, semi-massive occurrences surrounding detrital grains, vein-type pyrite, and disseminated fine-grained assemblages. Pyrite and marcasite from Calypso SE show elevated concentrations of volatile elements (e.g., As, Sb, Tl, Hg) implying a vapor-rich fluid phase. By contrast, elements like Zn, Ag, and Pb are enriched in hydrothermal pyrite and marcasite from Calypso SW, indicating a high-Cl liquid-dominated fluid discharge. Hence, vapor-liquid element fractionation induced by fluid boiling is preserved in the seafloor mineralization at Calypso Vents. Hydrothermal mineralization at very shallow vent sites (<10 mbsl), like Paleochori Bay, are affected by wave action causing a seasonal migration of the seawater-fluid interface in the sediment cover. The δ34S composition of native S crusts and crystalline S (0.7–6.7‰) is indicative for host rock leaching and thermochemical reduction of seawater sulphate. By contrast, the highly negative δ34S signature of native S globules in sediments (−7.6 to −9.1‰) is related to microbial sulphate reduction or a subordinate magmatic fluid influx. Alunite-jarosite alteration (Paleochori Bay) and a mineral assemblage consisting of orpiment, realgar, and native S (Calypso Vents) may also suggest a contribution by an oxidised (sulphate-rich) low pH fluid of potential magmatic origin. However, fluid boiling is pervasive at Calypso Vents and Paleochori Bay, and the condensation of vapor-rich fluids in a steam-heated environment may produce a similar alteration and mineralization assemblage without a significant magmatic fluid influx, as known from some subaerial epithermal systems.

From geomorphology to shape-fabric: The interplay of geomorphological controls and their spatial variability in the Teteltzingo lahar deposit, Citlaltépetl volcano (Mexico)

The distribution and characteristics of volcaniclastic deposits are the result of the interplay among numerous factors acting at different and multileveled scales of space and time. Such complexity requires multiple techniques for the study of volcanic regions. This approach provides a strong basis for understanding volcanic processes and their relationship with the resulting landforms or deposits and for reconstructing dynamic properties of flows. The aim of this paper is thus to understand the interplay between the geomorphologic environment and the origin and transport of large-magnitude debris flows. For this reason, we selected the eastern sector of the Citlaltépetl volcano and the Teteltzingo lahar event (Veracruz, Mexico). Information from geomorphological and morphometric analysis (including the linear features) was linked with field and shape-fabric data on selected outcrops. The study area was divided into three morphometric zones based on their elevation, slope, drainage network, and the trend in linear features. These zones are volcanic mountain zone, minor folded ranges and cumulative volcaniclastic plain. The geomorphological map enabled us to understand the origin of the landforms observed in each of the three morphometric zones. The characteristics of the Teteltzingo lahar deposit (i.e., geographic distribution, thickness and components) are associated with the morphologic and morphometric characteristics of the landscape. The particle shape-fabric analysis gave evidence that particle iso-orientation is consistent with the flow direction and orientation of some regional linear features, especially in the medial and distal zones. Moreover, the degree of iso-orientation was shown to be dependent on travel distance and particle diameter. The highest degree of iso-orientation was found in the coarse particles (gravel grain-size) throughout the entire deposit, being more developed in the distal zone. The evidence presented here suggests an interplay between geomorphological–structural controls and their spatial variability with the distribution of large-magnitude lahars. This highlights the importance of a multi-scale vision of mass movement phenomena that show how morphological and sedimentological characteristics are linked and could affect the generation and dynamics of future flows.

Facies analysis and stratigraphy across the Jurassic-Cretaceous boundary in a new basinal Tithonian–Berriasian section of the Vaca Muerta Formation, Las Tapaderas, Southern Mendoza Andes, Argentina

This paper presents a multidisciplinary study of a new basinal section of Tithonian-Berriasian the Vaca Muerta Formation at Las Tapaderas area, including detailed, biostratigraphic, sedimentologic, sequence stratigraphic and cyclostratigraphic analysis. Biostratigraphy based on ammonite, calpionellids and calcareous dinoflagellate cysts indicate that Las Tapaderas section spans through the Lower Tithonian - lowermost Upper Berriasian, however, its upper part is covered through an erosive unconformity by Pleistocene volcaniclastic deposits, and therefore Las Tapaderas section could reach the Lower Valanginian. Two facies associations were identified, corresponding to basinal and distal outer ramp subenvironments. Recognition of flooding surfaces allowed the identification of three composite depositional sequences and eight high-frequency depositional sequences, which can be correlated with other sections throughout the basin. Cyclostratigraphic analysis based on the recognition of marlstone/limestone couples (elementary cycles) allowed to build a time series based on bed thickness. Fourier analysis indicates the characteristic mid latitude precession-eccentricity syndrome, with 220 precessional cycles (~20.4 and ~23 kyr), 53 low frequency eccentricity cycles (~79, ~90 and ~140 kyr) and 11 high frequency eccentricity cycles (~400 kyr). Spectral analysis also allowed to recognize the presence of the obliquity cycle (38.5 kyr), which has been erratically recorded in the Vaca Muerta Formation. Our data allowed the construction of an orbital scale, calibrated by cosmopolitan markers (calpionellids and calcareous dinoflagellate cysts), for this section. The precise bio- and cyclostratigraphic location of the Jurassic-Cretaceous boundary was established for this section. The sedimentation rate was studied at the scale of the precession cycle, showing values between 0.6 and 3 cm/kyr, while at the low-frequency eccentricity scale it shows values between 1 and 2 cm/kyr.

The Tarim Basin, China, a prospect for plume-related Zr(Hf)-Nb(Ta)-REY-Ga-U mineralization

This study is based on published data from the Tarim and Emeishan Large Igneous Provinces (TLIP and ELIP, respectively). The data are interpreted in a comparative manner, using the well-studied ELIP’s mineralization as a reference. Some additional information on related U and REY-carbonate ores from Far Eastern Russia are also included in this comparison. The results show that the Tarim Basin has both positive and negative indicators for tuffaceous Zr(Hf)–Nb(Ta)–REY–Ga–U ores. Like in ELIP, the source of the mineralization in the Tarim Basin is likely to be the Permian volcaniclastic deposits. The volcaniclastic deposits in the Tarim are not well studied geochemically; however, since the composition of the parent magmatic rocks are similar between TLIP and ELIP, the volcaniclastic material is also thought to be similar. Positive indications are that the TLIP’s deposits are larger (volumetrically), more felsic than the ELIP’s volcaniclastics. In addition, the former are concentrated in an almost closed terrestrial basin (Tarim Basin), whereas the latter are disseminated throughout a wide continental margin. The Paleozoic strata of the Tarim Basin are deeply altered in and around fracture zones, which are widespread. The alteration is caused by acidic volcanic-related fluids that are a key factor in metal mobilization and redistribution. However, in contrast to the ELIP’s area, the Tarim Basin was under influence of semi-arid climate that probably resulted in a weak activity of meteoric waters and poorly developed vegetation during deposition of the Permian volcaniclastic strata, which have a relatively low content of organic matter (<5%, commonly <2%) and contain no coal seam. These may be considered negative indicators for tuffaceous Zr(Hf)–Nb(Ta)–REY–Ga–U ores because organic acids might play a significant role in the leaching, redistribution, and the finishing processes that concentrated Zr, Hf, Nb, Ta, REY, Ga, and U within rocks with clay alteration. Finally, the Permian tuffaceous mudstones located in and around deep faults of the Tarim Basin may be a likely target for geochemical prospecting for Zr(Hf)–Nb(Ta)–REY–Ga–U ores similar to those found in southwestern China. In addition, the fracture zones in the Tarim Basin are likely to contain REY-carbonate and U ores similar to those discovered in Primorye, the Far Eastern Russia.

Ground-Penetrating Radar Modeling Across the Jezero Crater Floor

This article assesses how the ground-penetrating radar RIMFAX will image the crater floor at the Mars 2020 landing site, where lithological compositions and stratigraphic relationships are under discussion prior to mission operation. A putative mafic unit (lava flow, volcanic ash, or volcaniclastic deposit) on the crater floor will be crucial in piecing together the chronology of deposition and for understanding the volcanic history in the region. In order to see how lithological properties and subsurface geometries affect radar sounding, a synthetic radargram is generated through forward modeling with a finite-difference time-domain method. The acquisition is simulated across the mafic unit as a succession of lava flows, exploring detection of internal structures and contacts to adjacent lithologies. To compare modeling results with the alternative formation scenarios, a discussion about sounding over a tephra or volcaniclastic material is presented. Similarities and differences between Martian and terrestrial lithologies can be related to electromagnetic properties relevant for radar sounding. This article, therefore, evaluates potential scientific insights gained from acquisition across the disputed mafic unit, in light of proposed hypotheses of lithological generation.

Arsenian Pyrite and Cinnabar from Active Submarine Nearshore Vents, Paleochori Bay, Milos Island, Greece

Active, shallow-water (2–10 m below sea level) and low temperature (up to 115 °C) hydrothermal venting at Paleochori Bay, nearshore Milos Island, Greece, discharges CO2 and H2S rich vapors (e.g., low-Cl fluid) and high-salinity liquids, which leads to a diverse assemblage of sulfide and alteration phases in an area of approximately 1 km2. Volcaniclastic detritus recovered from the seafloor is cemented by hydrothermal pyrite and marcasite, while semi-massive to massive pyrite-marcasite constitute mounds and chimney-like edifices. Paragenetic relationships indicate deposition of two distinct mineralogical assemblages related to the venting of high-Cl and low-Cl fluids, respectively: (1) colloform As- and Hg-bearing pyrite (Py I), associated with marcasite, calcite, and apatite, as well as (2) porous and/or massive As-rich pyrite (Py II), associated with barite, alunite/jarosite, and late-stage hydrous ferric oxides. Mercury, in the form of cinnabar, occurs within the As-rich pyrite (Py I) layers, usually forming distinct cinnabar-enriched micro-layers. Arsenic in colloform pyrite I shows a negative correlation with S indicating that As1− dominates in the pyrite structure suggesting formation from a relatively reducing As-rich fluid at conditions similar to low-sulfidation epithermal systems. On the contrary, As3+ dominates in the structure of porous to massive pyrite II suggesting deposition from a sulfate-dominated fluid with lower pH and higher fO2. Bulk sulfide data of pyrite-bearing hydrothermal precipitates also show elevated As (up to 2587 ppm) together with various epithermal-type elements, such as Sb (up to 274 ppm), Tl (up to 513 ppm), and Hg (up to 34 ppm) suggesting an epithermal nature for the hydrothermal activity at Paleochori Bay. Textural relationships indicate a contemporaneous deposition of As and Hg, which is suggested to be the result of venting from both high-salinity, liquid-dominated, as well as CO2- and H2S-rich vapor-dominated fluids that formed during fluid boiling. The CO2- and H2S-rich vapor that physically separated during fluid boiling from the high-salinity liquid led to calcite formation upon condensation in seawater together with the precipitation of As- and Hg-bearing pyrite I. This also led to the formation of sulfuric acid, thereby causing leaching and dissolution of primary iron-rich minerals in the volcaniclastic sediments, finally resulting in pyrite II precipitation in association with alunite/jarosite. The Paleochori vents contain the first documented occurrence of cinnabar on the seafloor in the Mediterranean area and provide an important link between offshore hydrothermal activity and the onshore mercury and arsenic mineralizing system on Milos Island. The results of this study therefore demonstrate that metal and metalloid precipitation in shallow-water continental arc environments is controlled by epithermal processes known from their subaerial analogues.

Seismic stratigraphy and the sedimentation history in the Laxmi Basin of the eastern Arabian Sea: Constraints from IODP Expedition 355

Detailed interpretation of seismic stratigraphic sequences in the Laxmi Basin of the eastern Arabian Sea are presented in this study using closely spaced high resolution multi-channel seismic (MCS) data. Our stratigraphic interpretation is further corroborated using recent drilling results in the Laxmi Basin, derived from the long sediment cores collected during International Ocean Discovery Program (IODP) Expedition 355. Integrated core-log interpretation discussed in the present study, offer important insights about the lithostratigraphic variations in this region. Analyses of multi-channel seismic reflection data reveal five depositional sequences (ranging from Paleocene to Recent) that led to the development of this marginal basin since the Cenozoic period. Regional igneous basement is successfully imaged, which was also validated by deep sea coring during the IODP Expedition 355. In the present study, we primarily focus on the post-rift sedimentation in the Laxmi Basin and its possible mechanisms. Our detailed interpretation in the prevailing tectonic framework of the basin suggests that near-shelf oldest volcaniclastic sedimentation immediately overlying the acoustic basement is linked to the onset of India–Madagascar and India–Seychelles rifting activities during the Late Cretaceous period. Eventually, during the Early-Mid to Late Miocene, the basin received maximum sedimentation dominantly through an extensive mass transport mechanism implying possible large-scale deformation on the Indian shelf. Subsequent sediment input to the basin appears to have been fed variably via the Indus Fan as well as coastal discharge from the Indian mainland. The total sediment thickness in the Laxmi Basin ranges from 1.1 to 3.5 km. New stratigraphic information and sediment isopach maps presented here provide vital information about syn- and post-rift sedimentation pattern in the region and their long term tectonic implications.

A PHOTOGRAPHIC ATLAS OF THE ARCHITECTURE, FLOW GEOMETRY AND MORPHOLOGY, AND FACIES OF SERRA GERAL GROUP (PARANÁ IGNEOUS PROVINCE) IN THE STATE OF PARANÁ, BRAZIL

The rocks that make up the Serra Geral Group spread over approximately 100,000 km2 of the State of Parana, which represent about 10% of the Parana Igneous Province. The geologic mapping of the Serra Geral Group in the State of Parana was carried on from 2003 to 2018, and revealed a great diversity of features and facies of basic and acidic lava lows, as well as the presence of interbedded volcaniclastic deposits. This paper presents an inventory of this geodiversity along with brief descriptions, a wealth of photographic documentation, and the georeferenced location of each outcrop, making it easy to access the documented sites, in order to assist the development of scientiic research in this geologic compartment, which occupies nearly half of the Parana territory. The processes responsible for the lithologic features are interpreted in compliance to the knowledge accumulated on the various continental basaltic provinces by many researchers, including the authors of this paper, so to build up a genetic system for the Serra Geral Group more complete and coherent with the paleogeography of Gondwana in its initial breakup stage. In the early Cretaceous, during ca. 1.2 Ma with the paroxysm at 134.7 Ma, a huge magma amount, which is estimated at least in 600,000 km3, lowed over the thick sedimentary Paleozoic sequence of the Parana Basin, stacking up a volcanic sequence. The interaction between the rising magma with the sedimentary sequence up to 7,000 m thick, gave rise also to thousands of intrusive bodies, such as sills and dikes, almost all of a basic nature. Furthermore, the ascending magma interacting with aquifer systems gave rise to explosive volcanism – hydrovolcanism – which produced many maic volcaniclastic deposits MVDs, interbedded to the basic lows. Thus, in South America, during this relatively short lapse of time, basic and acidic lows covered the Parana Basin, being reported in Brazil, Argentina, Paraguay, and Uruguay under diverse names. In the present article, it will be simply referred as Serra Geral Group (SGG). The lithological inventory represented by the present photographic atlas comprises diagnostic features of basalt, andesi-basalt, rhyolite and dacite lava lows, maic volcaniclastic deposits MVDs, and dykes of basic composition.

Mesozoic Paleo-Pacific Subduction Beneath SW Borneo: U-Pb Geochronology of the Schwaner Granitoids and the Pinoh Metamorphic Group

The Schwaner Mountains in southwestern Borneo form a large igneous province with a complex magmatic history and poorly known tectonic history. Previously it was known that Cretaceous granitoids intruded metamorphic rocks of the Pinoh Metamorphic Group assumed to be of Paleozoic age. Jurassic granitoids had been reported from the southern Schwaner Mountains. Most ages were based on K-Ar dating. We present new geochemistry, zircon U-Pb and40Ar/39Ar age data from igneous and metamorphic rocks from the Schwaner Mountains to investigate their tectono-magmatic histories. We subdivide the Schwaner Mountains into three different zones which record rifting, subduction-related and post-collisional magmatism. The Northwest Schwaner Zone (NWSZ) is part of the West Borneo Block which in the Triassic was within the Sundaland margin. It records Triassic to Jurassic magmatism during early Paleo-Pacific subduction. In contrast, the North Schwaner Zone (NSZ) and South Schwaner Zone (SSZ) are part of the SW Borneo (Banda) Block that separated from NW Australia in the Jurassic. Jurassic granitoids in the SSZ are within-plate (A-type) granites interpreted to have formed during rifting. The SW Borneo (Banda) Block collided with eastern Sundaland at c. 135 Ma. Following this, large I-type granitoid plutons and arc volcanics formed in the NWSZ and NSZ between c. 90 and 132 Ma, associated with Cretaceous Paleo-Pacific subduction. The largest intrusion is the c. 110 to 120 Ma Sepauk Tonalite. After collision of the East Java-West Sulawesi (Argo) Block, subduction ceased and post-collisional magmatism produced the c. 78 to 85 Ma Sukadana Granite and the A-type 72 Ma Sangiyang Granite in the SSZ. Rocks of the Pinoh Metamorphic Group mainly exposed in the NSZ, previously assumed to represent Paleozoic basement, contain abundant Early Cretaceous (110 to 135 Ma) zircons. They are interpreted as volcaniclastic sediments that formed contemporaneously with subduction-related volcanic rocks of the NSZ subsequently metamorphosed during intrusion of Cretaceous granitoids. There are no igneous rocks older than Cretaceous in the NSZ and older than Jurassic in the SSZ and there is no evidence for a continuation of a Triassic volcanic arc crossing Borneo from Sundaland to the east.