Volcanic Episodes Research Articles

Carbon and sulfur isotope variations through the Upper Ordovician and Lower Silurian of South China linked to volcanism

Pronounced excursions of carbon and sulfur isotopes (δ13C and δ34S) spanning the Ordovician–Silurian (O–S) transition have been recognized globally, yet the causes of these isotope events and their causal relationships to environmental changes, especially during Early Silurian time, remain the topics of debate. In this study, we present organic carbon and pyrite sulfur isotope (δ13Corg and δ34Spyr) records and elemental concentrations from a drill core spanning from the Upper Ordovician (Katian) to Lower Silurian (Aeronian) succession of the Yangtze Platform, China. The newly presented δ13Corg profile records previously recognized positive excursions, including the Hirnantian isotopic carbon excursion (HICE), the middle Rhuddanian excursion, and the early Aeronian positive carbon isotope excursion (EACIE). In addition, two negative δ13Corg excursions are recognized during the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian stages. The δ34Spyr profile exhibits a great amount of variation (−17.8‰ to +19.6‰) but mimics the δ13Corg record. Coupled positive δ13Corg and δ34Spyr excursions during the middle Hirnantian and late Rhuddanian to Aeronian are associated with decreased total organic carbon (TOC) content and less reducing water column conditions, whereas the negative δ13Corg and δ34Spyr excursions during the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian are associated with enhanced TOC values and the establishment of more strongly anoxic to euxinic conditions. The δ13C and δ34S excursions during the O–S transition, then, cannot be explained by changes in redox conditions or the burial of organic carbon and pyrite. The heavier and less variable middle Hirnantian and late Rhuddanian to Aeronian δ34Spyr values probably reflect low marine sulfate concentration. In contrast, negative Katian to early Hirnantian and late Hirnantian to middle Rhuddanian δ34Spyr excursions may reflect increased sulfate concentration. The two negative δ13Corg and δ34Spyr excursions associated with the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian correspond with episodes of volcanism. We therefore propose that volcanism was the main driver of coupled negative δ13Corg and δ34Spyr excursions. As volcanism diminished during the middle Hirnantian and late Rhuddanian to Aeronian, both δ13Corg and δ34Spyr returned to more positive values. Our results indicate that volcanism played a crucial role in triggering carbon and sulfur isotope perturbations and environmental changes during the Late Ordovician and Early Silurian.

Acritarch-based chronostratigraphic and radiometric calibration of the Cambrian volcanosedimentary Vallehondo and Playón formations in the Cambrian Ossa-Morena Rift, Spain

The detailed record of diagnostic acritarchs from the volcanosedimentary Vallehondo and Playón formations, bracketed between Cambrian Stage 4 strata bearing the trilobite Serrodiscus and Guzhangian (Miaolingian) beds with Sao aff. hirsuta, allows the establishment of a fine acritarch-based chronostratigraphy. Seven interval zones are defined by the first successive appearances of cosmopolitan index acritarchs, two in Cambrian Series 2 (Skiagia ciliosa and Heliosphaeridium notatum zones) and five in the Miaolingian (Eliasum llaniscum, Cristallinium cambriense, Adara alea, Timofeevia lancarae and Cristallinium dubium zones). The base of the E. llaniscum Zone, which approximates the first appearance of Acadoparadoxides cf. mureroensis, marks a bioevent close to the base of the Wuliuan Stage, and includes an episode of felsic volcanism in the upper member of the Vallehondo Formation. The Cristallinium cambriense Zone is underlain by rhyolites and ignimbrites previously dated at ca. 505 Ma. The base of the Adara alea Zone concurs with the last felsic volcanic episodes in the Vallehondo Formation here dated at 500.9 ± 0.9 Ma. The maximum diversification of acritarchs (A. alea–T. lancarae zones) coincides with the onset of basaltic pillow lava flows in the Playón Formation reflecting a major rifting episode. The recognized acritarch-based zonation is applicable to the Acado-Baltic (biogeographic) Province, and reinforces the great value of acritarchs in Miaolingian chronostratigaphy. The new biostratigraphic data confirm the absence of a Furongian record in the study area and the late Drumian–Guzhangian age (A. alea to C. dubium zones) for one of the main syn-rift episodes recorded in the Ossa-Morena Rift.

About this title - Volcanism in Antarctica: 200 Million Years of Subduction, Rifting and Continental Break-up

This memoir is the first to review all of Antarctica's volcanism between 200 million years ago and the Present. The region is still volcanically active. The volume is an amalgamation of in-depth syntheses, which are presented within distinctly different tectonic settings. Each is described in terms of (1) the volcanology and eruptive palaeoenvironments; (2) petrology and origin of magma; and (3) active volcanism, including tephrochronology. Important volcanic episodes include: astonishingly voluminous mafic and felsic volcanic deposits associated with the Jurassic break-up of Gondwana; the construction and progressive demise of a major Jurassic to Present continental arc, including back-arc alkaline basalts and volcanism in a young ensialic marginal basin; Miocene to Pleistocene mafic volcanism associated with post-subduction slab-window formation; numerous Neogene alkaline volcanoes, including the massive Erebus volcano and its persistent phonolitic lava lake, that are widely distributed within and adjacent to one of the world's major zones of lithospheric extension (the West Antarctic Rift System); and very young ultrapotassic volcanism erupted subglacially and forming a world-wide type example (Gaussberg).

Chapter 1.2 Antarctic volcanism: volcanology and palaeoenvironmental overview

Abstract Since Jurassic time ( c. 200 Ma), Antarctica has had a greater diversity of volcanism than other southern continents. It includes: (1) voluminous mafic and felsic volcanism associated with the break-up of Gondwana; (2) a long-lived continental margin volcanic arc, including back-arc alkaline volcanism linked to slab rollback; (3) small-volume mafic alkaline volcanism associated with slab-window formation; and (4) one of Earth's major continental rift zones, the West Antarctic Rift System (WARS), with its numerous large alkaline central volcanoes. Several of Antarctica's volcanoes are still active. This chapter is a review of the major volcanic episodes and their principal characteristics, in their tectonic, volcanological and palaeoenvironmental contexts. Jurassic Gondwana break-up was associated with large-scale volcanism that caused global environmental changes and associated mass extinctions. The volcanic arc was a major extensional arc characterized by alternating volcanic flare-ups and lulls. The Neogene rift-related alkaline volcanism is dominated by effusive glaciovolcanic eruptions, overwhelmingly as both pāhoehoe- and ‘a‘ā-sourced lava-fed deltas. The rift is conspicuously poor in pyroclastic rocks due to the advection and removal of tephra erupted during glacial intervals. Volcanological investigations of the Neogene volcanism have also significantly increased our knowledge of the critical parameters and development of the Antarctic Ice Sheet.

Martin Vaz island geochronology: Constraint on the Trindade Mantle Plume track from the youngest and easternmost volcanic episodes

The oceanic basins are dotted by seamounts, guyots and islands formed by the mantle plumes and oceanic lithosphere interaction. These plumes are responsible for several intraplate volcanisms such as the Emperor-Hawaii Chain in the Pacific Ocean with a remarkable bend at ca. 47 Ma. Comparatively, the Vitória-Trindade Ridge (VTR) in the South Atlantic Ocean was also generated by a mantle plume and in response to the lithosphere interaction and tectonic settings it shows three remarkable bends through time. One occurred after 85 Ma associated with the Trindade plume tail movement under the Archean São Francisco Craton, and another one ca. 52 Ma after the formation of the Abrolhos Bank in the Brazilian platform (Mohriak, 1989; Thompson et al., 1998) when the Trindade Plume encountered a thinner lithosphere in the Brazilian coast and formed a chain of seamounts and islands of W-E direction. The last bend marked in the Trindade plume trajectory is ca. 20°00′lat, around Davis Bank, marking a Miocene (21.07 Ma - 40Ar/39Ar whole-rock method) subtle clockwise rotation in the South American Plate. The easternmost part of this ridge is composed of Trindade-Martin Vaz Archipelago subject of this study. Located ca. 1200 km away from the Brazilian coastline at the Vitória (ES) parallel, its geology is an important preserved record of an alkaline Pliocene-Pleistocene volcanism, the youngest one recorded in the Brazilian territory. Martin Vaz and the nearby islets are located on the easternmost part of the VTR. Its geological features include phono-tephritic to tephri-phonolitic domes; nosean-phonolitic dykes and sub-horizontal layers formed by pyroclastic rocks and subordinate lava flows (melanephelinites) of Volcanian-style magmatism (mostly). 40Ar/39Ar ages yielded values ranging from 336 to 721 ka representing a young and short period of intraplate magmatic activity in the South American Plate offshore. These new ages associated with compiled radioisotopic ages from onshore and offshore volcanic rocks represent a strong decreasing age correlation related to Trindade Mantle Plume. Moreover, Trindade-Martin Vaz Archipelago is a contemporaneous product of a terminal plume expression in the offshore portion of a long-lived track (ca. 90 Ma) with a slow shear velocity (VS) placing its origin at the Upper Mantle suggesting a shallow mantle plume rising from the asthenosphere.

The closure of the Rocas Verdes Basin and early tectono-metamorphic evolution of the Magallanes Fold-and-Thrust Belt, southern Patagonian Andes (52–54°S)

The Western Domain of the Magallanes Fold-and-Thrust Belt (MFTB) between 52°-54°S is part of a poorly studied hinterland region of the southernmost Andean Cordillera. This domain consists of NNW-SSE trending tectonic slices of pre-Jurassic basement units and Upper Jurassic-Lower Cretaceous ophiolitic complexes and volcano-sedimentary successions of the Rocas Verdes Basin (RVB). New detrital zircon U–Pb ages of metatuffs and metapsammopelites constrain episodes of Late Jurassic rift-related volcanism (ca. 160 Ma) followed by Early Cretaceous sedimentation (ca. 125 Ma) during the opening of the RVB. Shear bands developed in the RVB units further record the initial phases of the Andean Orogeny. The 30-km wide thrust stack located on top of the Eastern Tobífera Thrust consists of mylonitic metatuffs, metapelites and metabasalts with a NE-verging brittle-ductile S1* foliation. Phengite-bearing metatuffs commonly record pressure-temperature (P-T) conditions between ~3–6 kbar and ~210–460 °C, consistent with underthrusting of the RVB beneath the parautochthonous magmatic arc in the west. Peak metamorphic conditions of ~6 kbar and 460 °C are derived from a metapsammopelite with textures of contact metamorphism overprinting early mylonitic structures (at least S1*). A back-arc quartz-diorite, intruded at ca. 83 Na, is in contact with the metapsammopelite and constrain the minimum age of deformation at deep crustal depths. Campanian-Maastrichtian (ca. 70–73 Ma) 40Ar/39Ar phengite dates from a mylonitic metapelite indicate the timing of thrusting and backthrusting during the initial uplift of the underthrusted crustal stack. These findings reveal a ~400 km along-strike connection of mylonite belts in a continent-verging thrust structure that became active at the onset of the Andean orogeny during the closure of the Rocas Verdes back-arc marginal basin.

Mapping New IOCG Mineral Systems in Brazil: The Vale do Curaçá and Riacho do Pontal Copper Districts

The Vale do Curaçá and Riacho do Pontal copper districts are located within the northern part of the Archaean São Francisco Craton and represent two pulses of mineralization. The copper districts have been identified as Iron-Oxide-Copper-Gold (IOCG) classes of deposits. An older metallogenic event associated with the Caraíba copper deposit, which is located in the Vale do Curaçá district, is related to Palaeoproterozoic (ca. 2 to 2.2 Ga) hydrothermal processes. A younger Neoproterozoic (ca. 750 to 570 Ma) episode of volcanism and associated plutonism is represented by the Riacho do Pontal mineral district. Seismic tomography data from across east-central Brazil show that the multiage Carajás province and Vale do Curaçá and Riacho do Pontal copper districts sit along either side of a prominent NW-trending upper lithospheric high-velocity zone. The edges of the high-velocity zone point to long-lived subparallel transcrustal structures that have been the focus of multiple reactivations and copper mineralization events. Regional gravity and magnetic maps show that the Vale do Curaçá copper district extends over an area greater than 110 km by 22 km. The magnetic and gravity values show significant variations correlated with this area. The district includes high gravity values associated with the Caraíba copper mine (>−35 mGal), which has a greater density (3.13 g/cm3) than the nonmineralized host rock density (2.98 g/cm3). The gravity anomaly signature over the Riacho do Pontal copper district is characterized by a 40-km long NW–SE trending Bouguer gravity low. The Ria4 occurrences of the Riacho do Pontal copper district are situated in these regional low-gravity domains. Data from regional airborne magnetic and ground gravity surveys were inverted to obtain a 3D magnetic susceptibility and density model, respectively, for the known districts. The results show that the Caraíba deposit is characterized by a both dense and magnetic source showing structural control by thrust shear zones. The 2D and 3D geological models show two main NNW prospective trends. Trends I and II have a sigmoidal shear shape and are positioned in the contact zone between domains with high magnetic susceptibility (SI > 0.005) and density > 0 g/cm3). Trend I is 40 km × 10 km in size and hosts the Caraíba, Surubim, and Vermelho copper mines and other minor deposits. The results obtained from the 3D magnetic inversion model for the region of the Riacho do Pontal district show weak magnetic anomaly highs extending along a NW–SE magnetic gradient trend. The gradient is related to mapped shear zones that overprint older and deeper NE–SW features of the São Francisco cratonic root. The area includes high gravity values associated with the Caraíba copper deposit, which has a greater density (3.13 g/cm3) than the nonmineralized host rock density (2.4 g/cm3).

Ice-nucleating particle concentrations of the past: insights from a 600-year-old Greenland ice core

Abstract. Ice-nucleating particles (INPs) affect the microphysics in cloud and precipitation processes. Hence, they modulate the radiative properties of clouds. However, atmospheric INP concentrations of the past are basically unknown. Here, we present INP measurements from an ice core in Greenland, which dates back to the year 1370. In total 135 samples were analyzed with the FRIDGE droplet freezing assay in the temperature range from −14 to −35 ∘C. The sampling frequency was set to 1 in 10 years from 1370 to 1960. From 1960 to 1990 the frequency was increased to one sample per year. Additionally, a few special events were probed, including volcanic episodes. The typical time coverage of a sample was on the order of a few months. Historical atmospheric INP concentrations were estimated with a conversion factor, which depends on the snow accumulation rate of the ice core, particle dry deposition velocity, and wet scavenging ratio. Typical atmospheric INP concentrations were on the order of 0.1 L−1 at −25 ∘C. The INP variability was found to be about 1–2 orders of magnitude. Yet, the short-term variability from samples over a seasonal cycle was considerably lower. INP concentrations were significantly correlated to some chemical tracers derived from continuous-flow analysis (CFA) and ion chromatography (IC) over a broad range of nucleation temperatures. The highest correlation coefficients were found for the particle concentration (spherical diameter dp > 1.2 µm). The correlation is higher for a time period of seasonal samples, where INP concentrations follow a clear annual pattern, highlighting the importance of the annual dust input in Greenland from East Asian deserts during spring. Scanning electron microscopy (SEM) analysis of selected samples found mineral dust to be the dominant particle fraction, verifying their significance as INPs. Overall, the concentrations compare reasonably well to present-day INP concentrations, albeit they are on the lower side. However, we found that the INP concentration at medium supercooled temperatures differed before and after 1960. Average INP concentrations at −23, −24, −25, −26, and −28 ∘C were significantly higher (and more variable) in the modern-day period, which could indicate a potential anthropogenic impact, e.g., from land-use change.

U-series histories of magmatic volatile phase and enclave development at Soufrière Hills Volcano, Montserrat

Injection of volatile-rich mafic magma prior to an eruption may trigger episodes of volcanism and can act to transfer metals from depth. However, petrologic knowledge of the timescales from mafic injection to eruption have thus far been focussed on mineral-scale studies of chemical zoning patterns. The study of mafic enclaves dispersed within eruption products can provide insights into the interaction between deep and shallow reservoirs. We combine 238U-230Th-226Ra-210Pb isotope data with trace element concentrations across the interface of two contrasting mafic enclaves in contact with their host andesite from the 2010 eruption at Soufrière Hills Volcano (SHV), Montserrat to investigate the history of mass exchange between the mafic enclave and the andesite host. The application of these time-sensitive isotopes highlights complexities in the transfer of volatiles and metal elements between magmas and the enclaves' potential as eruption triggers. The enclaves exhibit (210Pb/226Ra)0 ratios >1 consistent with volatile input to the subsurface plumbing system a few decades prior to eruption. Samples of the andesitic host, however, which make up the bulk of the eruptive products, have (210Pb/226Ra)0 ≤ 1 suggesting no net volatile gain in the decades leading up to eruption, or that melt-volatile interaction is on a timescale unresolvable by 210Pb226Ra systematics (i.e. <2 years). Variations in trace elements such as Cu, Pb and Ba show loss of a magmatic volatile phase and transport of metals within the deeper part of the plumbing system during differentiation of magmas feeding SHV. Our results do not support that volatile transfer into the andesite via enclaves is a direct trigger of explosive eruptions although the enclaves are likely syn-eruptively formed. 238U-230Th-226Ra-210Pb and trace element systematics at SHV support a role for fresh magma influx during periods of unrest, but long-term accumulation of the andesite.

Strain Pattern and Kinematics of the Canary Islands from GNSS Time Series Analysis

Following the 2004 seismic unrest at Tenerife and the 2011–2012 submarine eruption at El Hierro, the number of Global Navigation Satellite System (GNSS) observation sites in the Canary Islands (Spain) has increased, offering scientists a useful tool with which to infer the kinematics and present-day surface deformation of the Canary sector of the Atlantic Ocean. We take advantage of the common-mode component filtering technique to improve the signal-to-noise ratio of the velocities retrieved from the daily solutions of 18 permanent GNSS stations distributed in the Canaries. The analysis of GNSS time series spanning the period 2011–2017 enabled us to characterize major regions of deformation along the archipelago through the mapping of the 2D infinitesimal strain field. By applying the triangular segmentation approach to GNSS velocities, we unveil a variable kinematic behaviour within the islands. The retrieved extension pattern shows areas of maximum deformation west of Tenerife, Gran Canaria and Fuerteventura. For the submarine main seismogenic fault between Tenerife and Gran Canaria, we simulated the horizontal deformation and strain due to one of the strongest (mbLg 5.2) earthquakes of the region. The seismic areas between islands, mainly offshore Tenerife and Gran Canaria, seem mainly influenced by the regional tectonic stress, not the local volcanic activity. In addition, the analysis of the maximum shear strain confirms that the regional stress field influences the E–W and NE–SW tectonic lineaments, which, in accordance with the extensional and compressional tectonic regimes identified, might favour episodes of volcanism in the Canary Islands.

Komatiites From Mantle Transition Zone Plumes

During the Archean, periods of volcanism on both individual cratons and globally occurred sporadically between long periods of volcanic inactivity. The episodic volcanism commonly included both plume- and arc-type magmatism, raising the issue of a possible link between “bottom up” and “top down” geodynamic processes. Rather than being cases of plume-initiated subduction, the best-preserved cratons demonstrate that komatiitic magmatism postdated at least some of the subduction-linked volcanism. Several factors suggest that komatiite-generating plumes may have been sourced in the mantle transition zone. Komatiites contain 0.6 wt. % or more H2O, which is contrary to earlier predictions for plume ascent through through the transition zone. Geodynamic reconstructions indicate that multiple subducted slabs penetrated the transition zone in the region of future plume ascent and the related trench configurations limit the size of any associated plume heads. The implied size of the plume heads is inconsistent with that required for a plume to ascend from the core-mantle boundary but matches that predicted for plumes sourced from the lower transition zone. Transition zone plumes have mainly been advocated for two types of geodynamic scenarios. They are common in post-Archean “big wedge” scenarios involving the consequences of subducted slabs that stall at the base of the transition zone and they are also an outcome of the “basalt barrier” featured in some geodynamic models for the Archean and early Proterozoic. The latter models suggest that the basaltic components of Archean subducted slabs were too buoyant to descend into the lower mantle and formed a boundary layer that isolated the upper mantle and lower mantle on the early Earth, except in times of mantle overturns. The basalt barrier was a significant thermal boundary layer that, in principle, could act as the nucleation site of upwelling plumes anywhere on the globe. The evidence discussed here, however, suggests that the mainly peridotitic mantle upwellings were enhanced by the nearby injection of closely associated slabs into the transition zone.

Post-rift submarine volcanic complexes and fault activities in the Baiyun Sag, Pearl River Mouth Basin: New insights into the breakup sequence of the northern South China Sea

Post-rift volcanisms and fault activities are significant for understanding the tectonic-sedimentary evolution of rifted continental margins and associated hydrocarbon entrapments. In this study, a series of post-rift fault-associated volcanic activities have been found in the northern continental margin of the South China Sea (SCS). However, their episodes and relationships with the progressive continental breakup are still doubtful. Here, new 2D/3D seismic, borehole, dating, and biostratigraphic data are used to investigate the characteristics of the post-rift volcanism and fault activities in the Baiyun Sag (BYS), Pearl River Mouth Basin. The newly-found fault-associated volcanic complexes include thirteen submarine volcanic mounds and associated lava flows, together with igneous sills that are mainly composed of basalts and tuffs. Seismic stratigraphic analysis combined with KAr dating from cores confirms that post-rift volcanism in the BYS climaxed along with the breakup of the SCS mainly in three episodes: (1) the first episode near Oligocene/Miocene boundary (23.3 Ma); (2) the second at the middle Early Miocene (17.6 Ma); and (3) the new-found third episode at the late Early Miocene (17.1 Ma). Also, fifty-three syn-sedimentary faults are interpreted, which are characterized by a WNW trending normal fault group separated by an ENE trending transcurrent fault group. And there is evidence that these fifty-three faults were long-lived from ca. 32–17.1 Ma and served as important conduits for the upward migration of the magma. The three episodes of volcanism and tectonic fault activities are related to the progressive continental breakup in the northern SCS margin, and they represent the tectonic signature of the early stage of the post-rift subsidence after the lithospheric breakup which extends to the top of a hypothetical breakup sequence (32–17.1 Ma) in the BYS. Furthermore, this study proves that the diachronous continental breakup in the SCS margin can result in corresponding changes in depositional architectures, along with a breakup sequence characterized by the deposition of a ‘sandstone‑carbonate-shale’ regressive-transgressive cycle. The sedimentological changes and associated tectonic features recorded in the Baiyun Sag suggest an exceptionally active tectonic setting in the time of the formation of the breakup sequence (Early Oligocene-Early Miocene) along the northern SCS margin.

Volcanic rocks in Lower Jurassic marine carbonate successions in the southeastern Iberian Range (Spain): biochronostratigraphic dating

The Ligurian Tethys began to open in a roughly NE–SW direction in Pliensbachian times. West of the Ligurian oceanic crust, a carbonate-platform system constituted the eastern Iberian paleomargin. Lower and Middle Jurassic marine sediments deposited in these shallow platforms are well exposed today in the southeastern Iberian Range and host multiple volcanogenic deposits, mainly volcaniclastic in nature. Regional mapping reveals that volcanic outcrops show NW and NE (or NNE) oriented lineaments following tracks of cortical weakness. Volcanic ages were estimated by using biochronostratigraphic methods and sequence-stratigraphic correlations. As a result, ten Lower Jurassic volcanic episodes have been identified. The chronostratigraphic positions of the volcanic deposits span from the early Pliensbachian (Jamesoni Zone or later) to the late Toarcian (Thouarsense Zone). The extension-dominated regime of the eastern Iberian paleomargin also affected the southern Iberian paleomargin (Betic Cordillera) as a result of the eastward prolongation of the central Pangea fragmentation. The break-up of wide platforms and the first volcanic emissions seem to be roughly coeval in the Betic and Iberian domains and synchronous with the onset of rifting and spreading events of the Ligurian Tethys Ocean.

Mafic volcanic rocks of western Iron Ore Group, Singhbhum Craton, eastern India: Geochemical evidence for ocean–continent convergence

Precambrian mafic magmatism is an important global episode which played a significant role in the crustal evolution. In India, Singhbhum Craton being the oldest craton, witnessed significant occurrences of Precambrian geological activity, marked by several episodes of volcanism, plutonism, sedimentation spanning from Palaeoarchean to Mesoproterozoic age. Here we present petrological and geochemical characteristics of Precambrian mafic volcanic rocks (occurring in western Iron Ore Group (IOG), Singhbhum Craton, eastern India) to evaluate their petrogenetic aspects, tectonic setting, and magma generation. The mafic volcanic rocks are porphyritic in nature with the phenocrysts of plagioclase and groundmass composed of clinopyroxene, plagioclase, ilmenite, and volcanic glass. These rocks are mostly tholeiitic, sometimes with a transitional behaviour towards calc‐alkaline nature and display basalt‐basaltic andesite affinity. These mafic volcanic rocks also preserve geochemical signatures (high Nb/U, Nb/La, [Nb/Th]pm ratios) in support of Nb‐enriched basalts and are classified as Nb‐enriched basalts (NEB; Nb &gt; 7 ppm) and high‐Nb basalts (HNB; Nb &gt; 20 ppm) on the basis of Nb concentrations and mantle normalized Nb/La ratios (&gt;0.5). The NEBs and HNBs are marked by lesser magnitude of negative Nb anomalies with high (Nb/Th)pm, (Nb/La)pm, and Nb/U ratios as compared to normal arc basalts. Several major element oxides, trace elements, and selected element ratios (like SiO2, CaO/Al2O3, Y, V/Cr, Zr/Nb, and ∑REE) show systematic variations with MgO which suggests role of magmatic fractionation. Chondrite‐normalized REE patterns for NEB and HNB rocks exhibit uniform LREE enrichment with distinct Eu negative anomalies while primitive mantle‐normalized incompatible trace element patterns reflect enrichment in LILE and LREE with prominent Nb‐Ta anomalies. Different HFSE ratios corroborate a subduction related setting for magma generation formed by ∼10%–20% melting in the domain of garnet lherzolite. Relative enrichment of LILE and LREE with depleted HFSE characteristics attest a garnet‐bearing mantle source and melt extraction with garnet in the residue. Geochemical signatures suggest that the genesis of NEB and HNB is attributable to slab‐melting and wedge hybridization processes during matured stages of subduction. Selected incompatible trace element ratios for the studied mafic volcanic rocks invoke an enriched (EM1‐EM2 type) mantle source and unequivocally suggest effects of continental crustal assimilation of the parent magma. Liquid immiscibility has played an important role as a differentiation mechanism leading to presence of high and low FeO types. The IOG mafic volcanic rocks preserve distinct geochemical signatures of matured stage of subduction, slab melting, crustal contamination and magma generation at an Archean ocean–continent convergent margin setting.

Marine Os isotopic evidence for multiple volcanic episodes during Cretaceous Oceanic Anoxic Event 1b

The Aptian–Albian boundary is marked by one of the major oceanic perturbations during the Cretaceous, called Oceanic Anoxic Event (OAE) 1b. Extensive volcanic episodes at the Southern Kerguelen Plateau has been suggested as the trigger of OAE1b, but compelling evidence remains lacking. Here, we reconstructed the temporal variations of marine Os isotopic ratios across the Aptian–Albian boundary in the Tethyan and Pacific pelagic sedimentary records to elucidate the causal links between OAE1b, the biotic turnover, and volcanic episodes. Our new Os isotopic records show two negative spikes that correlate with a period of planktonic foraminiferal turnover across the Aptian–Albian boundary during OAE1b and suggest multiple submarine volcanic events. By comparing our Os isotopic profile with carbon isotopic compositions of carbonate, CaCO3 content, and the relative abundances of agglutinated foraminifera, we conclude that ocean acidification caused by the massive release of CO2 through extensive volcanic episodes could have promoted the major planktonic foraminiferal turnover during OAE1b.

A 32-million year cycle detected in sea-level fluctuations over the last 545 Myr

Spectral analyses of past relative sea-level oscillations as represented by the ages of 57 Phanerozoic (the last 545 Myr) stratigraphic sequence boundaries from the Canadian Arctic show a strong spectral peak at 32 Myr (>99.9% confidence). These findings concur with previous reports of significant cycles with periods of around 30 Myr in various records of fluctuations of sea level, and in potentially related episodes of tectonism, volcanism, climate, and biotic extinctions. Sequence boundaries commonly coincide with stage boundaries based on biostratigraphy, and are correlated with episodes of extinction and times of flood-basalt volcanism. The connection between tectonics and sea-level variations may come from changes in rates of ocean-floor spreading and subduction, intraplate stresses from plate-reorganizations, and pulsations of hotspot volcanism. These coordinated periodic fluctuations in tectonics, sea level and climate may be modulated by cyclical activity in the Earth’s mantle, although some pacing by astronomical cycles is suspected.

Palynological evidence supporting widespread synchronicity of Early Jurassic silicic volcanism throughout the Transantarctic Basin

Throughout the Transantarctic Mountains, Early Jurassic silicic magmatism preceding the emplacement of the Ferrar flood-basalt province (Heimann et al. 1994) is documented by the increasing input of silicic ash into otherwise epiclastic, fluviolacustrine deposits of the Beacon Supergroup (see Elliot et al. 2017). Vertebrate biostratigraphy and radiometric analyses indicate a Sinemurian to Pliensbachian age span for silicic volcaniclastic deposits in the central Transantarctic Mountains (CTMs) (Elliot et al. 2017). For northern Victoria Land (NVL), radiometric geochronology and palynostratigraphy revealed that explosive silicic volcanism began with minor pulses during the early Sinemurian (c. 195 Ma) and reached a peak phase beginning in the middle Pliensbachian (c. 187 Ma) (Bomfleur et al. 2014). A basin-wide correlation of these widely separated age frameworks has so far been hampered by the scarcity of data on coeval deposits in southern Victoria Land (SVL). Here, we present new palynostratigraphic data from mixed epiclastic–volcaniclastic deposits in the Prince Albert Mountains that provide supporting evidence for the widespread synchronicity of silicic volcanic episodes preceding Ferrar magmatism.

Cretaceous arc volcanism of Palmer Land, Antarctic Peninsula: Zircon U-Pb geochronology, geochemistry, distribution and field relationships

The Cretaceous marks an episode of enhanced magmatism, sedimentation and tectonic processes along the entire proto-Pacific convergent margin of West Gondwana. Cretaceous magmatism across the Antarctic Peninsula is dominated by the intrusive Lassiter Coast intrusive suite which developed as episodic ‘flare-up’ events during the mid-Cretaceous, at a time of increased convergence. Volcanic rocks of this age are poorly defined, as a consequence of limited field observations and an absence of accurate geochronology. Recent field mapping, combined with unpublished field observations has identified a region >10,000 km2 of dominantly subaerial rhyolitic pyroclastic and epiclastic successions from northern Palmer Land of the Antarctic Peninsula. Volcanic successions up to 1500 m in thickness consist of dominantly silicic ignimbrites, lavas, heterolithic breccias and lahar deposits, fed by caldera-forming eruptions. The volcanic rocks of this region were widely considered to be Early Cretaceous in age based on field relationships and early geochronology. New U-Pb zircon ages identify three distinct volcanic episodes during the Late Cretaceous/Early Cenozoic at ~108 Ma, ~93 Ma and ~64 Ma. Lu-Hf data indicate significant proportions of ancient crust in the petrogenesis of the volcanic rocks and the slightly negative εHf values are consistent with a mid-position (~120 km) within the magmatic arc, relative to more juvenile compositions close to the trench.

The latitudinal diversity gradient of tetrapods across the Permo-Triassic mass extinction and recovery interval.

The decline in species richness from the equator to the poles is referred to as the latitudinal diversity gradient (LDG). Higher equatorial diversity has been recognized for over 200 years, but the consistency of this pattern in deep time remains uncertain. Examination of spatial biodiversity patterns in the past across different global climate regimes and continental configurations can reveal how LDGs have varied over Earth history and potentially differentiate between suggested causal mechanisms. The Late Permian-Middle Triassic represents an ideal time interval for study, because it is characterized by large-scale volcanic episodes, extreme greenhouse temperatures and the most severe mass extinction event in Earth history. We examined terrestrial and marine tetrapod spatial biodiversity patterns using a database of global tetrapod occurrences. Terrestrial tetrapods exhibit a bimodal richness distribution throughout the Late Permian-Middle Triassic, with peaks in the northern low latitudes and southern mid-latitudes around 20-40° N and 60° S, respectively. Marine reptile fossils are known almost exclusively from the Northern Hemisphere in the Early and Middle Triassic, with highest diversity around 20° N. Reconstructed terrestrial LDGs contrast strongly with the generally unimodal gradients of today, potentially reflecting high global temperatures and prevailing Pangaean super-monsoonal climate system during the Permo-Triassic.

Metal isotope signatures from lava-seawater interaction during the 2018 eruption of Kīlauea

The 2018 eruption of Kīlauea was associated with massive input of molten lava into the coastal ocean, which altered seawater chemistry and increased phytoplankton production. In seawater plumes advected away from the site of lava entry, we observed elevated concentrations of over a dozen metals relative to background seawater and unique isotopic compositions of Fe, Cu, Ni, Cd and Zn. The δ56Fe of iron released from lava was lower than basaltic, riverine and coastal iron from Hawaiʻi, but similar to observations of other high-temperature hydrothermal vent fluids. However, rapid precipitation led to only modest enrichments in dissolved iron (<10 nM), with increasing dissolved δ56Fe likely due to fractionation associated with ligand-mediated dissolution of particulate Fe. The isotopic composition of copper and nickel show evidence for two-endmember mixing between background seawater and a lava source. While the Ni isotopic endmember reflected basaltic δ60Ni, endmember δ65Cu, δ66Zn, and δ114Cd were isotopically lighter than basalt. We hypothesize that high diffusivity and volatility of chalcophile elements leads to strong kinetic fractionation in rapidly cooling lavas, similar to Cu, Zn and Cd isotopic patterns observed in tektites. The isotopic signatures of Cu and Ni observed during the 2018 eruption of Kīlauea far exceed their normal seawater range and may be useful for identifying large-scale lava input into ocean waters during the formation of large igneous provinces and other episodes of volcanism.