Volcanic Aquifer Research Articles

Specifying groundwater recharge zones through hydrogeochemical and isotopic analyses in a multilayer volcanic aquifer: a case study in the Yogyakarta-Sleman Groundwater Basin, Indonesia

Specifying groundwater recharge zones through hydrogeochemical and isotopic analyses in a multilayer volcanic aquifer: a case study in the Yogyakarta-Sleman Groundwater Basin, Indonesia

Geological influence on groundwater quality in volcanic aquifers of Eastern Mount Cameroon, West of the Penda Mboko River

This study explores the utility of silica concentration in deciphering geological controls and hydrogeochemical processes affecting groundwater quality in Mount Cameroon’s volcanic terrain. Fifty water samples from wells, boreholes, springs, and rivers were analysed for hydrochemical properties (EC, pH, temperature, TDS) and major ion concentrations (Ca2+ > Mg2+ > K +> Na+ and HCO3− > Cl −> NO3− > SO42−). The groundwater exhibits low mineralization, with a dominance of Ca2+, Mg2+, HCO3−, and SiO2, reflecting minimal water–rock interaction and short residence times. Spatial variations in hydrochemistry suggest diverse water–rock interactions and potential mixing processes (76% of samples in rock dominance zone). Silica concentrations (5.8–58.7 mg/L) and estimated chalcedony temperatures (> 60 ℃ at five sites) indicated depths exceeding 1000 m. This research highlights silica’s effectiveness in tracking water–rock interactions across diverse geological settings, regardless of flow depth or interaction time variations. Mineral saturation indices pointed towards supersaturation with silicate minerals (quartz) but undersaturation with carbonates, sulphates, and halides. These findings contribute to a better understanding of groundwater evolution in Mount Cameroon, valuable insights into the hydrogeochemical processes shaping groundwater quality, aiding sustainable water resource management practices that can benefit local communities by ensuring a reliable source of freshwater. However, opportunities exist to improve future studies and water resource management. For a more comprehensive understanding, future analyses should include a broader range of geochemical tracers, such as nitrate (NO3−) and phosphate (PO43−), to assess potential agricultural or anthropogenic contamination. The study also found elevated levels of chloride and sodium, suggesting potential anthropogenic influences on groundwater quality, such as agricultural practices and waste disposal.

Application of surface geophysical investigations and pumping test data analysis for better characterization of aquifer hydraulic parameters, Upper Awash Sub-Basin, Central Ethiopia

Study regionUpper Awash River Sub-basin in central Ethiopia Study focusThe research aimed to estimate aquifer parameters and conduct resistivity modeling in the study area. Data were collected from 890 Schlumberger Vertical Electrical Soundings (VES) points strategically distributed across six selected zones. The VES data were analyzed using computer modeling and curve-matching techniques to interpret the resistivity responses of the geological formations. This analysis provided insights into the subsurface characteristics and identified potential aquifer zones. New insights for the regionThe interpreted curves from the VES data and Root Mean Square (RMS%) values ranging from 0.36 % to 1.67 %, indicating a good fit between observed and modeled data. Resistivity modeling and geoelectrical sections were produced along specific lines, visualizing subsurface structures and confirming the resistivity responses of the geological formations. To determine aquifer parameters, the Dar-Zarrouk parameters were calculated from the interpreted curves, yielding crucial information about hydraulic properties such as hydraulic conductivity (K) and transmissivity (T). Hydraulic conductivity values ranged from 1.1 m/day to 21.7 m/day, while transmissivity values ranged from 144.3 m²/day to 2763.3 m²/day. Validation against borehole pumping test data showed strong correlations: R² = 0.9873 for transmissivity and transverse resistance, and R² = 0.9352 for hydraulic conductivity and resistivity. These findings enhance the understanding of the complex volcanic aquifer characteristics in the Upper Awash River Sub-basin, aiding sustainable groundwater management and development in the area.

A multidisciplinary approach using hydrogeochemistry, δ15NNO3 isotopes, land use, and statistical tools in evaluating nitrate pollution sources and biochemical processes in Costa Rican volcanic aquifers

Nitrate pollution threatens the Barva and Colima multi-aquifer system, the primary drinking water source in the Greater Metropolitan Area of Costa Rica. In addressing nitrate contamination dynamics, this study proposes an integrated approach by combining multivariate statistical analyses, hydrochemical parameters, sewage discharge, and regional land-use and land-cover patterns to assess the extent and degree of contamination, dominant biogeochemical processes, and refine the interpretation of nitrate sources previously derived solely from δ15NNO3 information. Over seven years (2015–2022), 714 groundwater samples from 43 sites were analyzed for nitrate and major ions, including two sampling campaigns for dissolved organic and inorganic carbon, nitrite, ammonium, FeTotal, MnTotal, and δ15NNO3 analyses. The findings presented elevated nitrate concentrations in urban and agricultural/urban areas, surpassing the Maximum Concentration Levels on several occasions, and oxidizing conditions favoring mineralization and nitrification processes in unconfined Barva and locally confined Upper Colima/Lower Colima aquifers. Similar nitrate contents and spatial patterns in agricultural and urban zones in the shallow Barva aquifer suggest comparable contributions from nitrogen fertilizers and urban wastewaters despite the gradual increase in urban land cover and the reduction of agricultural areas. Isotopic analyses and dissolved organic carbon (DOC) indicate a shift in nitrate sources from agricultural to urban areas in both Barva and Colima aquifers. Principal Component and Hierarchical Cluster Analyses link land use, nitrate sources, and water quality. Three distinct sample clusters aligned with forest/grassland, agricultural/urban, and urban land use, emphasizing the impact of anthropogenic activities on groundwater quality, even in the deeper Colima aquifers. The study challenges nitrate isotope mixing models, enhancing accuracy in identifying pollution sources and assessing the spatial extent of contamination by incorporating DOC and other hydrochemical parameters. Similar outcomes, with and without the use of nitrate isotopes, reinforce the usefulness of the integrated approach, providing a practical and cost-effective alternative.

Estimation of Groundwater Recharge in a Volcanic Aquifer System Using Soil Moisture Balance and Baseflow Separation Methods: The Case of Gilgel Gibe Catchment, Ethiopia

Understanding the recharge–discharge system of a catchment is key to the efficient use and effective management of groundwater resources. The present study focused on the estimation of groundwater recharge using Soil Moisture Balance (SMB) and Baseflow Separation (BFS) methods in the Gilgel Gibe catchment where water demand for irrigation, domestic, and industrial purposes is dramatically increasing. The demand for groundwater and the existing ambitious plans to respond to this demand will put a strain on the groundwater resource in the catchment unless prompt intervention is undertaken to ensure its sustainability. Ground-based hydrometeorological 36-years data (1985 to 2020) from 17 stations and satellite products from CHIRPS and NASA/POWER were used for the SMB method. Six BFS methods were applied through the Web-based Hydrograph Analysis Tool (WHAT), SepHydro, BFLOW, and Automated Computer Programming (PART) to sub-catchments and the main catchment to estimate the groundwater recharge. The streamflow data (discharge) obtained from the Ministry of Water and Energy were the main input data for the BFS methods. The average annual recharge of groundwater was estimated to be 313 mm using SMB for the years 1985 to 2020 and 314 mm using BFS for the years 1986 to 2003. The results from the SMB method revealed geographical heterogeneity in annual groundwater recharge, varying from 209 to 442 mm. Significant spatial variation is also observed in the estimated annual groundwater recharge using the BFS methods, which varies from 181 to 411 mm for sub-catchments. Hydrogeological conditions of the catchment were observed, and the yielding capacity of existing wells was assessed to evaluate the validity of the results. The recharge values estimated using SMB and BFS methods are comparable and hydrologically reasonable. The findings remarkably provide insightful information for decision-makers to develop effective groundwater management strategies and to prioritize the sub-catchments for immediate intervention to ensure the sustainability of groundwater.

Analysis Of The Potential Of Volcanic Aquifers In Supporting The Development Of Groundwater Resources In Bogor District, West Java

This research is crucial for understanding the aquifer potential of volcanic deposits as a sustainable groundwater source, especially in regions experiencing rapid urbanization and agricultural expansion. It aims to analyze the aquifer potential of volcanic deposits in Bogor Regency, focusing on the Bogor Groundwater Basin, the upper Cisadane watershed, the eastern slopes of Mount Salak, and the western slopes of Mount Pangrango. The methods used include secondary data collection from regional geological maps and primary data collection through field surveys, geological mapping, and hydrogeological mapping. The results show that the volcanic rock units in this area, consisting of stony tuff, tuff breccia, lava, and andesite lava, have unique characteristics with significant potential as aquifers. Detailed geomorphological and hydrogeological mapping revealed different types of springs and physical properties of water that support the sustainability of groundwater resources. These findings contribute significantly to the development of better groundwater management policies, effective water infrastructure development, and environmental conservation strategies in Bogor District, ensuring clean water availability for the future.

Exploring Rare Earth Element behavior in the Mount Etna volcanic aquifers (Sicily)

This study presents the first data on REY (Rare Earth Elements plus Yttrium) in the aquifer of Mount Etna (Sicily, Italy). Patterns normalized to chondrites indicate strong water–rock interaction, facilitated by a slightly acidic pH resulting from the dissolution of magma-derived CO2. REY patterns provide insights into the processes of both mineral dissolution and the formation of secondary phases. The relative abundance of light to heavy rare earth elements is compatible with the prevailing dissolution of ferromagnesian minerals (e.g., olivine or clinopyroxenes), reinforced by its strong correlation with other proxies of mineral dissolution (e.g., Mg contents). Pronounced negative Ce anomalies and positive Y anomalies demonstrate an oxidizing environment with continuous formation of secondary iron and/or manganese oxides and hydroxides. The Y/Ho fractionation is strongly influenced by metal complexation with bicarbonate complexes, a common process in C-rich waters. In the studied system, the measured REY contents are always below the limits proposed by Sneller et al. (2000, RIVM report, Issue 601,501, p. 66) for surface water and ensure a very low daily intake from drinking water.

The influence of geology on the quality of groundwater for domestic use: a Kenyan review.

Kenya's population, akin to other Sub-Saharan countries, is rapidly growing. With the increasing unreliability of surface water, groundwater resources are becoming highly relied on for domestic and industrial use. Despite several known contaminants reported in different parts of the country, no study has attempted to correlate groundwater quality in the different geological provinces. This review critically synthesizes the influence of Kenya's diverse geology on groundwater quality for human consumption. This was achieved through a review of published journal articles and other research material through research and government databases. Groundwater was categorised based on the major geological provinces including the Archaean volcanic Nyanzian Craton, the Proterozoic metamorphic Mozambique Mobile Belt (MMB) and volcanic Kisii Group, the Palaeozoic and Mesozoic sediments, and Tertiary volcanic Rift Valley. Groundwater quality in these regions showed a characteristic high concentration of fluoride (F-) in volcanic aquifers of the Rift Valley and Nyazian Craton and metamorphic aquifers of the MMB, where mineral dissolution was the main process of F- release. High salinity was common in metamorphic aquifers in the MMB and the Palaeozoic and Mesozoic sedimentary aquifers where mineral dissolution and seawater intrusion were the common contributors to salinity. Other contaminants such as lead and iron were reported in localised areas in the sedimentary and metamorphic aquifers, respectively. Anthropogenic contaminants such as Escherichia coli (E.coli), NO3 -, and NO2 - were common in shallow groundwater resources in most informal settlements in urban areas. Due to the presence of health implications, of the highlighted contaminants, such as fluorosis, high blood pressure and diarrhoea (due to high F- and salinity) in affected regions, this review highlights the need for an active water resource management program in any country relying on groundwater resources to determine the presence of all region-specific potentially harmful chemical elements and mitigation measures in all its water resources.

Review: Andesitic aquifers—hydrogeological conceptual models and insights relevant to applied hydrogeology

Research on the hydrogeology of andesitic volcanic aquifers in subduction areas is reviewed. Andesitic aquifers are of high interest in volcanic arc islands and subduction zones, where they constitute a strategic water resource. This review gathers a compilation of worldwide results and case studies to propose a generic hydrogeological conceptual model (GHCM). It is based on the geological conceptual model splitting the volcanic edifice, from upstream to downstream, into central, proximal, medial and distal zones. In this geological structure, the GHCM identifies where the main aquifer types (fractured lava, pyroclastic flows, and the volcano-sedimentary basins downstream) and the typical aquitards (lahars, fine pyroclastic falls and surges, indurated pyroclastic flow, and weathered rocks) are structured and organized. To integrate the evolution of volcanoes and some specific volcanic activities, a specific GHCM for old andesitic volcanoes or andesitic shield volcanoes is detailed. The paper also describes how the GHCM results are of use to hydrogeologists in terms of scale (from the lithological units to the regional scale), to effectively site water wells, and to sustainably manage groundwater resources in such aquifers. Among these various scales, the volcanic “flank continuum” is presented as the most adapted to support groundwater resources management. Several ways to improve this GHCM are suggested, notably to better consider the geological complexity of these aquifers.

Groundwater recharge sources and mechanisms in the Ethiopian central Afar rift: Insights from isotopic and hydrogeochemical tracers.

Groundwater flow and recharge mechanisms in the central Afar rift and the associated western marginal grabens and Northwestern Plateau (NWP) are poorly understood because of the complex geology and spatial heterogeneity in the aquifer systems. The major aquifers in the region include the Oligocene and Pliocene to recent volcanics and recent alluvio-lacustrine sediments. We employed hydrogeochemical, stable isotopes of water (18O and 2H), and geological structures insights to identify groundwater recharge sources and mechanisms, aiming to develop a representative conceptual groundwater flow model. Water samples from groundwater and surface water were collected based on lithological/aquifer variation and geomorphological setup for isotope and hydrochemical analysis. Findings reveal distinct isotopic differences between the deep (>350 m) and shallow groundwater systems of the Afar rift, with deep systems showing relative isotopic depletion, indicating varying recharge sources. The deep groundwater exhibited a similar isotopic signature to that of the marginal grabens and NWP. The distribution of major ion chemistry and electric conductivity (EC) of groundwaters from the western plateau to the Afar rift show significant spatial variability. However, in some corridors of western parts of the rift, there is a clear geochemical evolution along the flow paths inferring groundwater flow continuity between aquifers. The results revealed the existence of preferential deep groundwater recharge from the NWP through the highly fractured linking zones, interacting fault zones in between the marginal grabens, to the deeper volcanic aquifers of the central Afar rift. The proposed groundwater flow model of this study illustrates the deep groundwater flow from the NWP to the Afar rift is primarily directed by the orientations of the faulted marginal grabens and the highly fractured interacting zones. This model is pivotal for understanding groundwater dynamics in similar continental rift environments, offering insights for effective groundwater management.

Geochemical Evolution in Historical Time of Thermal Mineral Springs at Campetti Southwest (Veii, Central Italy) through Geoarcheological Investigation

A multidisciplinary study, involving hydrogeological, geochemical, and mineralogical analyses, was conducted to define the evolution of thermal mineral springs in the Sabatini Volcanic District (SVD) (Central Italy) in a historic period. The outcomes were integrated with the archeological findings to improve the knowledge of the evolution of Veii, a settlement established since the Iron Age and later expanded by Etruscans and Romans. During the archeological excavations, water-related buildings were identified, especially at the Campetti Southwest site in the Veii settlement. Votive inscriptions also suggest the presence of buildings linked to sacred waters, even if a clear definition of the source and type of water is missing. In the SVD, some low-flow thermal mineral springs are present as a result of the mixing of thermal and CO2-rich groundwater from the deep carbonate aquifer and the cold, shallow volcanic aquifer. Mineralogical and chemical analyses characterized the travertine and Fe-hydroxide deposits on Roman tanks and walls in Campetti Southwest and in a nearby ancient Roman bath along the Valchetta River. These deposits showed different relative concentrations of sedimentary and volcanic-related elements, testifying a geochemical evolution of the groundwater mixing and the presence of a paleothermal mineral spring in Campetti Southwest.

Hydrogeochemical evolution and water–rock interaction processes in the multilayer volcanic aquifer of Yogyakarta-Sleman Groundwater Basin, Indonesia

Volcanic aquifers have become valuable resources for providing water to approximately 2.5 million people in the Yogyakarta-Sleman Groundwater Basin, Indonesia. Nevertheless, hydrogeochemical characteristics at the basin scale remain poorly understood due to the complexity of multilayered aquifer systems. This study collected sixty-six groundwater samples during the rainy and dry seasons for physicochemical analysis and geochemical modeling to reveal the hydrogeochemical characteristics and evolution in the Yogyakarta-Sleman Groundwater Basin. The results showed that groundwater in the unconfined and confined aquifers exhibited different hydrogeochemical signatures. The Ca–Mg–HCO3 facies dominated groundwater from the unconfined aquifer. The groundwater facies evolved into a mixed Ca–Mg–Cl type along the flow direction towards the discharge zone. Meanwhile, groundwater from the confined aquifer showed mixed Ca–Na–HCO3, Na–HCO3, and Na–Cl–SO4 facies. The presence of Mg in the confined aquifer was replaced by Na, which was absorbed in the aquifer medium, thus showing the ion exchange process. The main geochemical processes can be inferred from the Gibbs diagram, where most groundwater samples show an intensive water–rock interaction process mainly influenced by the weathering of silicate minerals. Additionally, only groundwater samples from the confined aquifer were saturated with certain minerals (aragonite, calcite, and dolomite), confirming that the groundwater followed the regional flow system until it had sufficient time to reach equilibrium and saturation conditions. This study successfully explained the hydrogeochemical characteristics and evolution of a multilayer volcanic aquifer system that can serve as a basis for groundwater basin conservation.

MaxEnt machine learning model predicts high groundwater potential areas in a fractured volcanic aquifer system

Groundwater constitutes a vital resource for public water supply, and thus, it is imperative to recognize the areas of highest potential for increasing availability. The present study employs the MaxEnt model to discern the most favorable areas for locating high-yield wells in Caxias do Sul, Rio Grande do Sul, southern Brazil, where the Serra Geral Aquifer System, a fractured volcanic aquifer, emerges. This aquifer system is characterized by its heterogeneous, discontinuous, and highly anisotropic nature. A dataset comprising 83 wells with high flow rates (≥10 m³/h) was selected from the municipal registry of deep tubular wells, along with 14 factors that influence groundwater occurrence (specific capacity, transmissivity, altitude, slope, horizontal curvature, vertical curvature, relief dissection index, drainage density, distance to drainage, topographic wetness index, distance to lineament, lineament density, precipitation, and soil hydrological group). The model output was a Groundwater Potential Map, which stochastically expresses the probability of obtaining flow rates ≥10 m³/h. The map was validated through cross-validation, resulting in an average accuracy of 65.14%, and by the Receiver Operating Characteristic analysis, resulting in an Area Under the Curve value of 0.911, indicating satisfactory validation. While the MaxEnt model is widely used in ecology to model species distribution, its application in groundwater prediction remains limited, particularly in fractured aquifers associated with volcanic rocks. Apart from optimizing the use of groundwater resources, this study also enhances the understanding of natural phenomena in this type of aquifer.

Commentary on the role of polyoxometalates in nature cybernetic loop

AbstractThe interplay between extraterrestrial, atmospheric, aqueous, interfacial, and hydrothermal processes is crucial for Earth's prebiotic chemistry. Volcanic terrains contain polyoxometalates (POMs). Some polyoxocuprates were identified as building blocks of fumarole minerals produced from high‐temperature gases. The existence of polyoxovanadate anions in acidified reducing volcanic aquifers cannot be excluded. At present, it can only be speculated whether life arose around natural POM deposits and/or around their aqueous phase chemistry through acid‐base and/or redox reactions. This Commentary spans different fields of sciences in nature cybernetic loop to provide impetus to explore gas‐phase chemical reactions of multiply charged POM ions, catalysis by POM‐containing mineral phases, the behavior of POMs under plasma‐initiated ultraviolet photolysis, interactions of POMs with microorganisms, bioorthogonal chemistry of POMs, and engineering POM‐based bionic functions inspired by living organisms.

Assessment of Medical Geology from Major Element Trilinear Diagrams Cl-SO4-HCO3 and Na-K-Mg from Geothermal and Non-Geothermal Springs; Case Study the Wayang Windu Geothermal Area, West Java, Indonesia

Medical geology research involves the processes, deficiencies, and excessive exposure of significant elements and minerals to present solutions to health problems. Minerals from volcanic aquifers from geothermal and non-geothermal springs interest medical geology research. Major elements in source rocks essential for our health come from the rocks beneath the earth’s surface. This study aims to evaluate the medical geology of major elements in the water from volcanic aquifers in the Wayang Windu Geothermal Area. The methods used are trilinear analysis of major elements, Piper diagram, and statistical analysis. We have investigated six cold springs, four hot springs, and three dug wells surrounding the Wayang Windu geothermal area. The results of hydrochemical study and field checking identified the location of water sources that have potential uses in medical geology and balneotherapy. The primary relationship elements in the Piper Diagram defined five major water types: CaCl, MgCl, CaMgHCO3, and CaHCO3. Results from hydrochemical analyses, statistics, and trilinear diagrams were used to identify springs suitable for medical geology and balneotherapy. Hot springs with good health criteria that meet the balneotherapy requirements are found at locations H1, H2, H3, and H4. Hydrochemical data shows that hot springs in several areas of Pangalengan are suitable for bathing and body contact activities but not for drinking water. Cold springs at locations C1, C2, C3, C4, C5, and C6 meet the drinking water criteria surrounding the Wayang Windu geothermal area.

Hydrochemical and hydrodynamic study to explore the origin of water in a volcanic aquifer

Abstract The current research aimed to determine the origin of ions and the type of flow system in groundwater flowing out through two types of atmospheric and hydrothermal springs by hydrochemical and hydrodynamic approaches in a volcanic aquifer. Findings revealed that the major ion types in atmospheric waters are calcic and magnesium bicarbonate, whereas hydrothermal springs predominantly indicated chloride–sodic composition, showing an evolving pattern resulting from hydrothermal and atmospheric waters mixing. Investigating the ionic ratios and the saturation index to determine the origin of ions suggests that the presence of ions in the waters can be attributed to the weathering of silicates and plagioclase-bearing minerals in the volcanic units, and in some cases, ionic exchange also plays a role. The recession curve analysis revealed a predominant conduit flow with α = 0.144 in the system feeding the representative hydrothermal spring. Two micro-regimes with α1 = 0 = 0.46 and α2 = 2.68 were detected on the hydrograph of the atmospheric representative spring, indicating the development of systems with two types of flow regimes. Estimating the Qmax/Qmin ratio for selected hydrothermal and atmospheric springs as 2.3 and 36.8, respectively, and calculating the electrical conductivity coefficient as 11% and 18% respectively, confirmed the recession curve analysis result.

Identification of recharge processes and mixing patterns by using CFC's and isotopic multi-tracing (δ18O, δ2H) of groundwater in a stratified volcanoclastic aquifer of the semiarid Amazcala Basin in Central Mexico

Understanding groundwater flow is essential for quantifying recharge and identifying relevant processes in an aquifer. Hydrogeochemical models have proven to be successful in identifying origin and processes during water recharge. We integrated the hydrogeochemistry, environmental isotopes and CFC technique to develop a conceptual and a groundwater mixing model of the Amazcala aquifer in Central Mexico. Results demonstrate that groundwater recharge consists of local meteoric recharge and a regional geothermal input. The local resident groundwater component represents the primary source of groundwater contributing with an average of 56% (σ = 0.07). The second crucial component of groundwater is the contribution of the local meteoric component contribution with averages to 23% (σ = 0.05). The third component is the regional geothermal component, which on average contributes to 21% (σ = 0.03). Regional geothermal influence has been reported in several aquifers in volcanic regions. This geothermal input influences volcanic aquifers located in the Trans-Mexican Volcanic Belt and should be considered in the water balance budget. Excessive groundwater extraction raises the vulnerability of the aquifer to natural and/or anthropogenic pollution, affecting the quality of water. Understanding the hydrogeological system offers a useful framework for developing and executing Managed Aquifer Recharge strategies (MAR).

Water–Rock Interactions across Volcanic Aquifers of the Lece Andesite Complex (Southern Serbia): Geochemistry and Environmental Impact

The study of aquifers of the Lece andesite complex (LAC) and its surroundings yielded a new procedural stepwise analysis that allowed the assessment of the origin of elements, particularly in areas affected by both anthropogenic and natural influences. The methodology uses the mineralogical composition of the rocks, including the elements available in rocks and groundwater. This study analyzes the element ratios B/Cl−, Na+/Ca2+, Ca2+/Mg2+, HCO3−/Cl−, and Na+/Na+ + Cl−; the correlations are coupled with a statistical analysis. In addition to reevaluating the already published water content, we provide an important new dataset. The results show that the main source of the water contamination with the elements B, F, U, As, Cu, Fe, Zn, Co, and Ni is the processes occurring at the contact between the groundwaters and non-altered/altered (propylitized) andesite rocks. This is also observed in the waters extracted from crystalline schists. The results may help develop an efficient use and assessment of the qualitative water potential of the LAC reservoirs. Similarly, the results highlight the applicability of the groundwaters, facilitating their regional research and use, further encouraging new initiatives for the preservation and protection of human and animal health.

Estimating Groundwater Flow Velocity in Shallow Volcanic Aquifers of the Ethiopian Highlands Using a Geospatial Technique

The shallow volcanic aquifer is the major rural water supply source in the Ethiopian highlands. A significant number of hand pump wells in these aquifers experience a rapid decline in yield and poor performance within a short period of time after construction. Hence, reliable estimation of groundwater flow velocity is important to understand groundwater flow dynamics, aquifer responses to stresses and to optimize the sustainable management of groundwater resources. Here, we propose the geospatial technique using four essential input raster maps (groundwater elevation head, transmissivity, effective porosity and saturated thickness) to investigate groundwater flow velocity magnitude and direction in the shallow volcanic aquifers of the Ethiopian highlands. The results indicated that the high groundwater flow velocity in the Mecha site, ranging up to 47 m/day, was observed in the fractured scoraceous basalts. The Ejere site showed groundwater flow velocity not exceeding 7 m/day in the fractured basaltic aquifer and alluvial deposits. In the Sodo site, the groundwater flow velocity was observed to exceed 22 m/day in the fractured basaltic and rhyolitic aquifers affected by geological structures. The Abeshege site has a higher groundwater flow velocity of up to 195 m/day in the highly weathered and fractured basaltic aquifer. In all study sites, aquifers with less fractured basalt, trachyte, rhyolite, welded pyroclastic, and lacustrine deposits exhibited lower groundwater flow velocity values. The groundwater flow velocity directions in all study sites are similar to the groundwater elevation head, which signifies the local and regional groundwater flow directions. This work can be helpful in shallow groundwater resource development and management for rural water supply.

Nitrate Legacy in a Tropical and Complex Fractured Volcanic Aquifer System

AbstractNitrate legacy is affecting groundwater sources across the tropics. This study describes isotopic and ionic spatial trends across a tropical, fractured, volcanic multi‐aquifer system in central Costa Rica in relation to land use change over four decades. Springs and wells (from 800 to 2,400 m asl) were sampled for NO3− and Cl− concentrations, δ18Owater, δ15NNO3, and δ18ONO3. A Bayesian isotope mixing model was used to estimate potential source contributions to the nitrate legacy in groundwater. Land use change was evaluated using satellite imagery from 1979 to 2019. The lower nitrate concentrations (<1 mg/L NO3−N) were reported in headwater springs near protected forested areas, while greater concentrations (up to ∼63 mg/L) were reported in wells (mid‐ and low‐elevation sites in the unconfined unit) and low‐elevation springs. High‐elevation springs were characterized by low Cl− and moderate NO3−/Cl− ratios, indicating the potential influence of soil nitrogen (SN) inputs. Wells and low‐elevation springs exhibited greater NO3−/Cl− ratios and Cl− concentrations above 100 μmol/L. Bayesian calculations suggest a mixture of sewage (domestic septic tanks), SN (forested recharge areas), and chemical fertilizers (coffee plantations), as a direct result of abrupt land use change in the last 40 years. Our results confirm the incipient trend in increasing groundwater nitrogen and highlight the urgent need for a multi‐municipal plan to transition from domestic septic tanks to regional sewage treatment and sustainable agricultural practices to prevent future groundwater quality degradation effectively.