In this paper, an exponential synchronization design method for chaotic Lur'e systems is developed. Firstly, a sampled-data based proportional-integral (PI) type controller is used in the slave system to achieve the synchronization. Next, the synchronization problem of the chaotic Lur'e system is transformed into the stabilization problem of the synchronization error system. Then, by introducing virtual vectors for reconstruction, a new augmented error system is obtained. As a result, the synchronization design based on sampled-data PI type controller can be achieved using the existing sampling system method. And based on this, a criterion for exponential synchronization design is obtained using the Lyapunov functional method. Finally, the effectiveness of the developed method is demonstrated by numerical example.