Virgin Oil Research Articles

Comparative study on preparation of hybrid WS2@GO composites and its tribological application in paraffin liquid

Purpose The anti-friction and anti-wear properties of WS2@GO composites on paraffin liquid were investigated with a four-ball tribometer. Design/methodology/approach A series of graphene oxide (GO) nano hybrid composites decorated with tungsten disulfide (WS2) were prepared in-suit by hydrothermal strategy. Findings The results showed that compared to the virgin oil, friction coefficient and diameter of wear scare of lubricant oil containing W/G = 1:1 hybrid composite was reduced by 42.7% and 31.6%, respectively. At the microscopic, the excellent lubrication performance resulted from the tribo-chemical reaction on the sliding interface, which promotes the formation of tribo-film with a thickness of 8 nm. The carbonization compound, WO3 and Fe2O3 in the tribo-film results from the tribo-chemical reactions at the sliding interface, which can improve the stability and strength of tribo-film. Thereby the metal surface was further protected from friction and wear. Originality/value A series of WS2@GO composites were prepared in-suit by a hydrothermal strategy, and the tribo-film was analyzed by the transmission electron microscope and X-ray photoelectron spectrometer. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-10-2024-0397

Investigation on the impact of CO2-Induced precipitation on microscopic pore structure of low-permeable reservoirs

CO2 injection into reservoirs might induce organic or inorganic precipitation in microscopic pores, and some of the pores are blocked by the precipitates, resulting in a decrease in the connectivity of pores and affecting oil recovery. In this paper, a set of experiments on CO2 displacement and CO2-water-oil-rock interaction are conducted to study the microscopic mechanisms of reservoir damage. In-situ Nuclear Magnetic Resonance (NMR) technology is applied to conduct the microscopic analysis of CO2-EOR and reservoir damage at real reservoir conditions. The results reveal that the particle size and the amount of inorganic precipitates formed in the formation water will increase with the rise of CO2 injection pressure, and the inorganic precipitates primarily consist of siderite and kaolinite. The change of NMR T2 spectra of the core samples reveals that the inorganic precipitates primarily block the small pores less than 0.89 μm. However, as a result of stronger mineral dissolution and solute transport, the pore volume of the large pores (greater than 0.89 μm) increases after the CO2-water-rock reaction. Ultimately, this interaction results in a 5.4% increment in pore volume. In addition, the displacement efficiency of water-saturated cores is improved after the first CO2 displacement, which indicates that CO2-water-rock interaction can effectively improve the seepage properties of reservoirs. Nevertheless, the reservoir damage caused by asphaltene precipitation during CO2 flooding is more significant. The asphaltene precipitation percentage in formation oil increases with the rise of CO2 injection pressure, reservoir temperature, and asphaltene content in virgin oil. CO2-induced asphaltene precipitation causes more severe blockage on small pores in comparison with large pores. After 2 h of CO2 injection to the oil-saturated core, permeability and oil recovery caused by CO2-induced precipitation decreased by 17.6% and 11.4%, respectively.

A new natural product derived from cyclosorus terminans provides cardiometabolic protection against obese-induced cardiac dysfunction in rats via suppressing mitochondrial dysfunctions and apoptosis

Abstract Background The development of a novel pharmacological target for obesity has long been considered challenging in mitigating the global cardiovascular complications and mortality. Given the cytotoxic effects associated with various anti-obesity drugs, there is growing interest in exploring new natural products as potential sources for bioactive agents to treat obesity-associated diseases with minimal side effects. While Cyclosorus terminans extract has demonstrated anti-diabetic and anti-obese efficacies in adipose-derived stem cells, its cardioprotective effects in high-fat diet (HFD)-induced obese-insulin resistance rat models have never been elucidated. Purpose To examine the effects of long-term Cyclosorus terminans treatment on metabolic, cardiac, and mitochondrial functions and apoptosis in HFD-induced obese-insulin-resistant rat models Methods Male Wistar rats (n=10) were continually fed with HFD and treated with either vehicle (HFV, virgin oil for 2 ml/kg/day, p.o., n=5) or Cyclosorus terminans (HFC, 100 mg/kg/day, p.o., n=5) for 12 weeks. Rats fed a normal diet (NDV, n=5) were used as a control to confirm the development of HFD-induced obesity. The left ventricular ejection fraction (LVEF) and the ratio between early (E) and late atrial (A) ventricular filling velocity were measured using echocardiography, and the homeostatic model assessment for insulin resistance (HOMA-IR) was determined using blood serum. The cardiac tissue was processed to assess mitochondrial reactive oxygen species (ROS) levels, membrane potential (MMP) changes via red/green fluorescence intensity ratio, and apoptotic protein. Results HFV rats became obese and had impaired cardiometabolic function as shown by reducing LVEF, E/A ratio, and increasing HOMA-IR, respectively (Fig. 1A-C). These obese rats also had mitochondrial ROS overproduction, MMP depolarization (reduced red/green ratio), and apoptosis (increased Bax protein expression) (Fig. 1D-F). Treatment with Cyclosorus terminans (HFC) significantly mitigated mitochondrial dysfunction and apoptosis, resulting in cardiometabolic protection in HFD-fed rats (Fig. 1A-F). Conclusion A new natural product derived from Cyclosorus terminans effectively protected the heart against long-term HFD-induced cardiometabolic impairments by reducing mitochondrial dysfunction and apoptosis. These findings demonstrate Cyclosorus terminans as a novel cardiometabolic protection against obesity-related cardiac complications.

Modern quality control methods of flax seeds herbal drugs in Russia

Flax seeds are valuable medicinal and food raw materials because of their various complex of biologically active substances (BAS). They have a great potential for pharmaceutical practice and food industry. The purpose of the work is to study the possibilities for improvement of methods for standardization of flax seeds and drugs (infusion is the dietary supplement (DS), which contains fatty flax seeds extra virgin oil in gelatin capsule and fatty flax seeds oil containing in multicomponent drugs) on their basis. The following groups of BAS are studied by modern physicochemical methods: contents of polysaccharides (gravimetry), contents and composition of the fatty acids containing in fatty oils (gas flame photometric chromatography) and contents of vitamins B2, C, E, carotenoids (α- and β-carotenoids) (high-performance UV chromatography). The study establishes, that the whole flax seeds contain 8.23±0.38% of polysaccharides, 438±53 mg/g of fatty oils (the main fatty acids are α-linoleic acid (234±47 mg/g), oleic acid (60±12 mg/g), and linoleic acid (61±12 mg/g)), 31.00±4.65 mg/100g of vitamin B2, 330.00±49.50 mg/100g of vitamin C, 19.60±2.94 mg/100g of vitamin E, and 10.30±1.55 mg/100g of carotenoids. Contents of 0.62±0.04% of polysaccharides, 2.85±0.43 µg/100 ml of vitamin B2, and 45.00±6.75 µg/100 ml of vitamin C are peculiar to the infusion. We have determined that the DS “Flax seeds oil in capsules” contents three major fatty acids. They are α-linoleic acid (234±47 mg/g), oleic acid (60±12 mg/g), linoleic acid (61±1 2mg/g), 27.00±4.05 mg/100g of vitamin E (summarized tocopherols in terms of tocopherol acetate), and 14.90±2.24 mg/100g of carotenoids. Contents of fatty oil in the “Dicloran ® Plus” drug is of 277±33 mg/g (the main fatty acids are α-linoleic acid (20±4 mg/g), oleic acid (6±1 mg/g), and linoleic acid (4±1 mg/g)) and 1.10±0.17 µg/100 g of vitamin E. Ratio of major fatty acids containing in the subjects, which consist of fatty flax seeds oils, are: α-linoleic acid: oleic acid: linoleic acid is 4:1:1 is peculiar. The received data is used to update current regulatory documentation and to introduce the new one to regulate quality of flax seeds and flax drugs.

Cost-effective production of Titania nanoparticles for the modification of transformer insulating oil

Nanofluids are prospective solutions for improving the transformer dielectric strengthby adding nanoparticles to the standard oils used in transformers.Oil-based titania nanofluids are becoming increasingly popular due to their superior insulating qualities and distinctive thermal performance, and they areconsideredas possible replacements in the domains of transformer insulating oils.This paper describes the industrial synthesis of titania nanoparticles for improving the insulating characteristics of virgin oil used in transformers.The titania nanoparticles were analyzed using an X-ray diffractogram (XRD), which revealed a prominent peak at Bragg angle 25O, indicating that the titania nanoparticles were generated in the anatase phase. Fourier transform infrared (FTIR) spectroscopy study endorsed the formation of Ti-O-Ti, Ti-OH, C-H and O-H stretching vibrations at 760 cm−1, 1345 cm−1, 2475 cm−1, and 3646 cm−1 wavenumbers respectively. Field emission scanning electron microscopy (FESEM) and Atomic Force Microscopy (AFM) examinations on the produced titania nanoparticles revealed that the particles had a circular shape with a diameter of 55 nm and an average roughness value of roughly 3.6 nm respectively.The viscosity of the host virgin oil and the nanoparticles-filled nanofluid were examined, and higher viscosity values were found as particle concentration increased.The effective conductivity study with the zeta potential and thermal conductivity fluctuation with temperature variation also revealed that at higher temperatures, conductivity with the zeta potential increased and thermal conductivity dropped. Furthermore, the breakdown strength of the titania nanoparticles-based virgin oil was observed to be effectively increased with the particle concentration.

Gluten-free crackers using chickpea and pumpkin seed press cake blend: Effects of gastrointestinal digestion

The use of a blend of chickpea and pumpkin seed press cake flours in the production of gluten-free crackers represents a promising strategy to address nutritional gaps and meet the growing demand for healthier gluten-free options. To test this assumption, an in vitro digestion method was employed to assess changes in total phenolic content, antioxidant activity, protein composition, electrophoretic patterns, and mineral content of gluten-free crackers formulated using these raw materials before and after digestion. The crackers were produced substituting 20% and 35% of chickpea flour by using two types of pumpkin seed press cake flour, one from virgin oil pressing (VFC) and the other from cold-pressed oil pressing (CFC). This approach aimed to assess how the treatment history of the pumpkin seed press cake flour affected the tested parameters. All samples displayed a 3- to 4-fold increase in total phenolic content after in vitro digestion. A noticeable enhancement in antioxidant activity is observed, where CFC samples showed higher values compared to VFC samples. The control sample and 35CFC sample present similar protein digestibility values (%), 76.97 and 77.05 respectively, while other crackers showed significantly lower digestibility. Incorporation of pumpkin seed press cake flours leads to a substantial increase in mineral content, notably zinc (up to 2-fold), iron (up to 40%), and magnesium (up to 2.5 fold). Overall, the study provides valuable insights into the utilization of pumpkin seed press cake as a potential source of bioactive compounds, emphasizing its significance beyond its traditional role as a by-product.

Influence of the Degree of Fruitiness on the Quality Assessment of Virgin Olive Oils Using Electronic Nose Technology.

The electronic nose is a non-invasive technology suitable for the analysis of edible oils. One of the practical applications in the olive oil industry is the classification of virgin oils based on their sensory characteristics. Notwithstanding that this technology, at this stage, cannot realistically replace the currently used methods, it is fruitful for a preliminary analysis of the oil quality. This work makes use of this technology to develop a methodology for the detection of the threshold by which an extra-virgin olive oil (EVOO) drops into the virgin olive oil (VOO) category. With this aim, two features were studied: the level of fruitiness level and the type of defect. The results showed a greater influence of the level of fruitiness than the type of defect in the determination of the detection threshold. Furthermore, three of the sensors (S2, S7 and S9) of the commercial e-nose PEN3 were identified as the most discriminating in the classification between EVOO and VOO oils.

Development of a technology of manufacturing Extra Virgin oil from seeds of different grape cultivars

It has been studied whether seeds of the grape varieties Lydia, Isabella, Moldova, Baco, Odesa Black, Cabernet, and the blends N 1 – Muscat Blanc + Noah (50:50), N 2 – Riesling + Chardonnay (50:50), and N 3 – Chardonnay + Sukholimansky (50:50) are promising raw materials for fat-and-oil products and cosmetics. The study provides a scientific basis for a technology for manufacturing oils from several grape seed varieties. For seeds from different grape cultivars, appropriate process conditions have been selected to obtain extra virgin oil by cold pressing. The most practical conditions for wet-heat treatment of crushed seeds of the cultivars Cabernet, Moldova, Baco, Odesa Black, and blend N 3 (Chardonnay + Sukholimansky, 50:50) are a temperature of 40 °C and a duration of 10 min. In contrast, seeds of Lydia, Isabella, and blends No. 1 (Muscat Blanc + Noah, 50:50) and N 2 (Riesling + Chardonnay, 50:50) should be treated at the same temperature for 20 min. While extracting oil by pressing, it is recommended to avoid heating the treated crushed seeds (extraction mash) to over 30 °C for more than 5 min. The research results have shown that in the seeds of Lydia, Isabella, Moldova, Baco, Odesa Black, and Cabernet grapes, and those of blends N 1 (Muscat Blanc + Noah, 50:50), N 2 (Riesling + Chardonnay, 50:50), and N 3 (Chardonnay + Sukholimansky, 50:50), the oil content is 14–20 %.

Physico-chemical and nutritional characteristics of kernels oil from two mangoes varieties (Amélie and Kent) harvested at Orodara in Burkina Faso

The mango tree (Mangifera indica) plays an important role for Burkina Faso people. This importance is due to its consumption, its pharmaceutical properties and its shade. However, all this importance is limited to the fleshy parts, leaves, bark and roots, whereas the mango tree's kernels are full of potential that can be exploited, but remain little known. Two mango varieties (Amélie and Kent) were sampled at the Bobo-Dioulasso fruit and vegetable market from Orodara. The fat content and physico-chemical parameters of the mangoes were determined using conventional methods. The results obtained show that the oil's biochemical composition gives it its full importance. This oil meets most of the standards set by the Codex Alimentarius for virgin oils. Mango kernels do indeed contain a fat content of between 3.039 and 6.486%. For moisture content, we found 56.095% and 56.070%, which already exceeds half the kernel's constitutional weight. In terms of chemical parameters, the highest acid value was 2.664 mg KOH/g, compared with 4.0 mg KOH/g as the maximum limit of the Codex Alimentarius standard. The peroxide value was equal to 9.523 mEqO₂/kg against 10 mEqO₂/kg as the maximum limit of the standard. We have a good concentration of saturated fatty acids at least 47% for the lowest concentration and 24% of unsaturated fatty acids for the lowest concentration. In view of these results, mango kernels should be valorized in order to add value to mango waste, with a view to use in cosmetics or medicine, as well as to depollute the environment.

Screening tools combined with multivariate data analysis to predict or confirm virgin olive oil classification by the Panel test

AbstractA particular aspect of quality control of virgin olive oil (VOO) is the mandatory application, together with chemical and instrumental determinations, of a standardized and official method for sensory assessment. The latter, known as Panel test, is carried out by trained assessors and contributes to the classification of VOOs into three commercial categories (extra virgin, virgin, and lampante). One drawback of this method is related to the large number of samples to be analyzed, compared to the work capacity of a sensory panel, especially during the selection for purchase by companies that blend and market virgin oils and the quality control conducted by the authorities to verify the declared commercial category. For this reason, it is helpful to develop and validate robust and rapid screening methods, based on volatile fingerprints, to preclassify each sample into one of the three commercial categories. Considering the strict relation between volatile compounds and the main sensory attributes (fruity and defects), a gas‐chromatographic volatile fingerprint can be the right choice. In this paper, the comparison of two emerging techniques, namely, headspace‐gas chromatography‐ion mobility spectrometry (HS‐GC‐IMS) and flash‐gas chromatography (FGC), applied on a sample set of 49 VOOs, using calibrations previously built with a larger number of samples, is presented. The number of correctly classified samples, with respect to the commercial category determined by the Panel test, was satisfactory and comparable (92% for HS‐GC‐IMS, and 94% for FGC), confirming the effectiveness of both methods and the robustness of the predictive models.Practical Applications: The demand for rapid screening tools to reduce the number of samples to be assessed by the Panel test has increased in recent years. The validation of robust models and their joint adoption by companies that market VOOs as well as official control bodies could reduce nonconformities and increase the batches of VOO being controlled, thus better protecting the consumer. Therefore, it is desirable to have different tools available to analyze volatile compounds, together with the associated calibration models, along with detailed instructions for their application, to have different alternatives that suit the equipment of individual laboratories.

Experimental Investigation and Performance Evaluation of Jatropha Oil-Biodiesel Blending with Kerosene for Domestic Cooking and Lighting Applications.

Reducing indoor air pollution and the related costs requires developing efficient cooking and lighting technologies as well as alternative energy sources. The appropriateness of virgin jatropha (Jatropha curcas) oil, its biodiesel, and the blending of these fuels with kerosene for wick stove lighting and cooking was examined in this study. To describe the fuel performance, a range of blending ratios were examined and characterizations were made of the fuel's density, calorific value, boiling point, viscosity, and rate of fuel consumption. To assess the fuels' thermal degradation behaviors, thermogravimetric and water boiling tests were performed. An air pollution meter was used to describe the levels of indoor air pollution. According to the findings, the virgin oil from Jatropha has a kinematic viscosity of 30.1 mm2/s. The 50% jatropha oil and 80% biodiesel blended with kerosene showed a reduction in viscosity of 72.6% and 46.8%, respectively. The thermal efficiency of the virgin oil, its biodiesel, and blending of these fuels with kerosene was in the range of 10-48%. Complete degradation of jatropha oil, its biodiesel, and 40 : 60 ratio of jatropha biodiesel and kerosene blend was conducted in the temperature range of 480-700 k, 185-280.6 K, and 100-300 K, respectively. The activation energies of jatropha oil, biodiesel, and kerosene blend (40 : 60) were 191.3, 73, and 25 kJ/mol, respectively. The average concentrations of particulate matter and carbon monoxide for pure jatropha oil biodiesel were 209.71 µg/m3 and 5.5 mg/kg, respectively. Thus, jatropha biodiesel and its blending with kerosene are suitable fuels for cooking and lighting operations in rural communities who are living far from the electrical grid compared with virgin oil fuel.

Waste cooking oil into sustainable and lucrative bio-diesels and their blend with diesel

The necessity to find an alternate fuel has arisen due to the rapid spike in cost of crude oil. In terms of economics, the alternative fuel should be more appealing than fossil fuels. Vegetable oils are used to make costly yet environmentally beneficial biodiesels. Utilizing leftover cooking oil to produce biodiesel is less expensive than using virgin oil. The bio-diesel have prepared from Waste cooking oil (WCO), collected from GITAM University hostel mess. This reaction has accelerated by the base catalysed the transesterification reaction with using ethanol. 1HNMR and IR spectrum analyses were used to describe the biodiesel that was produced. Numerous physico-chemical characteristics of biodiesels and their mixes with petroleum diesel were examined. The results of the investigation indicate that the blends from B10 to B40 have high flash points, lower pour points, and kinematic viscosity in the range of 2 to 5 cSt at 40 oC.

The characteristics of PUFAs-rich virgin fish oil as affected by size of tuna eye

Abstract. Trilaksani W, Riyanto B, Ramadhan W, Sinulingga F, Fauziah S. 2023. The characteristics of PUFAs-rich virgin fish oil as affected by size of tuna eye. Biodiversitas 24: 6545-6556. The food supplement market expects growth in demand for long-chain omega-3 fatty acids, particularly Eicosapentaenoic Acid (EPA) and Docosahexaenoic Acid (DHA), which play crucial for brain development and can lower the chances of health issues like depression, Myocardial Infarction (MI), thromboembolism, and cardiac arrhythmias, and have anti-viral effects, boosting the immune system during the pandemic. Therefore, to meet this demand, exploring new sources is crucial. Tuna eyes have emerged as a potential source of DHA; however, quality and standardized sizes pose a challenge as they are by-products. The purpose of this research was to determine how the eye size of tuna affected the quality and yield of fish oil, which is a novel source of omega-3 fatty acids. This study determined the virgin oil profile of tuna eyes, which met the quality standards. The investigation covered morphology, chemical composition, heavy metal content, oil yield and quality, fatty acid composition, and related health lipid indices (Atherogenicity Index (AI) and Thrombogenicity Index (TI)). For the size specifications, tuna eyes were classified into three groups based on their diameter, namely 'small' (<6 cm), 'medium' (6-9 cm), and 'large' (>9 cm). The results showed that eye size directly influenced the weight, fat content, and oil yield, with negligible disparity in chemical composition except for the fat content; the larger the eyes, the higher the oil yield. Tuna eye oil had a safe composition for consumption with low or undetected heavy metals, the oil's oxidative level met CODEX standards, and the fatty acid profile revealed DHA as the most abundant fatty acid, reaching 36.95%. The predominance of n-3 series values in the fatty acid composition of tuna's eye was 9-12 times greater than that of n-6 fatty acid values. The values of AI and TI were 0.33 and 0.12; 0.47 and 0.20; 0.55 and 0.20 for large, small, and medium eyes, respectively. The study highlights tuna eyes' unique characteristics and potential applications in the food supplement industry.

Virgin Oil Lands Conquered?

Abstract The historical memory of Siberia is heterogeneous and diverse; different parts of this region have their own emphases in the politics of historical memory. This article focuses on the historical memory of Yugra (a historical territory roughly coterminous with the Khanty-Mansiiskii Autonomous Okrug), as it is from this territory that the development of Siberian oil lands began. Oil has become the central focus of memory for the northern region of Western Siberia, and oil workers are symbols of territorial development in Yugra. The creation of the oil and gas complex is portrayed as a victory over nature, and oil workers are portrayed not only as pioneers who opened the region, but also as soldiers.

Does the Harvest Type Affect Olive Health? Influence of the Harvesting System and Storage Time on the Chemical, Volatile and Sensory Qualities of Extra Virgin Olive Oils.

With the aim of investigating the effect of bruising and its development during the postharvest time, olive fruits (Frantoio and Moraiolo), manually and mechanically harvested, were stored in climatic chambers at two different temperatures (5 °C and 18 °C) for five days. Visual observations highlighted changes in the olive peel with discoloration in the damaged areas and tissue bruising. Olive fruit polyphenols, volatile organic compounds (VOCs) and other oil quality parameters (phenolic content, free acidity and peroxide index) and sensory assessment were evaluated. Analyses were carried out on fruits and experimental extra virgin oils at harvesting and after 5 days of fruit storage. The results highlight that low-temperature storage (5 °C for 5 days) may contribute to the maintenance of high olive oil quality, and the quality of olives stored at room temperature drastically decreases after 5 days of storage. Moreover, mechanical harvesting, compared to manual harvesting, does not seem to affect the final oil quality, at least at harvesting, but seems to determine differences in the long-term storage period. Finally, the samples stored at 18 °C showed a quality deterioration with the development of sensorial defects.

Pengolahan Kelapa Menjadi Virgin Coconut Oil (VCO) dengan Metode Fermentasi Sederhana

Coconut plant is frequently referred to as the plant of life since every part of it may be utilized and turned into a product. One of the commercial processed product by coconut is virgin coconut oil (VCO), which has many benefits to health properties. VCO is extracted from coconut milk from coconut fresh. The introduction of virgin oil (VCO) to partners aimed about VCO's advantages and development of appropriate technology that can be applied to local communities in Negeri Katon, Lampung Selatan. This community service activity program introduced fermentation method using yeast to convert coconut milk into VCO. The activity were conducted in three steps: i.e presentation of VCO process production and discussion, demonstration of making VCO together, and evaluation based on pre and post-test form results. Several analysis have been conducted including the percentage yield, density, viscosity and pH of the VCO. The evaluation of this activity was obtained from pre and post-test results. The results of the pre-test showed that among 50% the people of Negeri Katon really needs to the activity of making VCO by fermentation together. Based on the highest post-test result of 91%, it can be concluded that the VCO-making activities are very useful. Further development of activities, such as intensive practice in making VCO and training in packaging and selling VCO is very needed. Based on the results obtained, it can be concluded that the activity of making VCO by fermentation for the community of Negeri Katon is very necessary to be carried out in terms of utilizing coconut into VCO and creating business opportunities for the future.

Data standardization strategy to correct the effect of seasonality in the authentication of virgin olive oil

This study proposes a standardization strategy for dealing with seasonal variability in the authentication of extra virgin oils from the PDOs Les Garrigues and Siurana. Samples from four harvests were measured by fluorescence spectroscopy. A PLS-DA two-class model was developed and validated from samples from one of the harvests. When samples from three other harvests were predicted with the model developed, it was observed that the sensitivity and specificity were lower than when the model was validated. For the standardization process, we adapted the PDS technique to obtain the transfer function. The results obtained from the transformed spectra show that standardization is a good strategy for extending the usefulness of the models if the samples to be predicted are subject to seasonal variability.

Effects of sesame dehulling on physicochemical and sensorial properties of its oil.

At present, sesame oil is extracted from un-hulled white sesame seeds by using cold press lubrication machines in local stores in Iran. This study aimed to evaluate the physicochemical properties and safety parameters of the hulled and un-hulled white sesame oils. The fatty acid composition, antioxidant activity, oxalates content, total phenolic content, carotenoid content, acid value, peroxide value, p-anisidine value, value total oxidation value (TOTOX), aflatoxins and pesticides residue, smoke point, color, relative density, and refractive index of oil sample were examined immediately after extracting the oil. The peroxide, p-anisidine, and TOTOX value of the hulled and un-hulled sesame oil samples were also examined periodically. After 7 months, the quality parameters were high and the oil samples were not consumable. Linoleic and oleic acids were the predominant fatty acids in the hulled and un-hulled sesame oils. The results of this study showed that the oil extracted from raw un-hulled sesame had a lower initial quality than hulled sesame oil and was oxidized more rapidly than it during the storage period. Virgin oils contained impurities acting like prooxidants and reduced their stability and shelf life. In addition, the un-hulled sesame oil contained higher amounts of antinutrient compounds (e.g., oxalate and pesticide residues) than the hulled sesame oil. Aflatoxin was not detected in our oil samples.

Impact of ultrasonic mixing on virgin and waste vegetable oils for biodiesel production

This paper investigates the use of waste vegetable oil (WVO) for production of biodiesel. The study explores the improvement of biodiesel production using ultrasonic mixing to achieve high yields. Different oil streams, including virgin canola oil and WVO, were used as the raw material for the transesterification processes. These oils had different fatty acid contents as a result of environmental or previous processing conditions. The impact of free fatty acid (FFA) content on the resulting yield was assessed. It was demonstrated that the yield was influenced by production parameters such as reaction time, reaction temperature, molar/volume ratios of oil to alcohol, catalyst amount, and mechanical mixing. This was accomplished by automating the biodiesel production from WVO, thereby achieving improved processing and requiring minimal direct human involvement. A biodiesel production apparatus was developed with a Raspberry Pi 3 microcomputer to control the process. The particular choice of these process parameters depended on the particular oil type. This research used mixtures of virgin and waste vegetable oils at different volume ratios (oil to alcohol) of 4:1, 6:1, and 8:1, which was determined by the FFA content of the oil. In addition to mechanical mixing, ultrasonication rated at 500 W, 20 kHz was used to enhance mixing by adding 450 kJ to the process, thereby reducing both the processing time and the amount of methoxide needed to perform a base-catalyzed transesterification. This research demonstrated that optimal yield depends on temperature, catalyst concentration, FFA content of the oil, and the energy introduced by sonication.

Aromatic Fingerprints: VOC Analysis with E-Nose and GC-MS for Rapid Detection of Adulteration in Sesame Oil.

Food quality assurance is an important field that directly affects public health. The organoleptic aroma of food is of crucial significance to evaluate and confirm food quality and origin. The volatile organic compound (VOC) emissions (detectable aroma) from foods are unique and provide a basis to predict and evaluate food quality. Soybean and corn oils were added to sesame oil (to simulate adulteration) at four different mixture percentages (25-100%) and then chemically analyzed using an experimental 9-sensor metal oxide semiconducting (MOS) electronic nose (e-nose) and gas chromatography-mass spectroscopy (GC-MS) for comparisons in detecting unadulterated sesame oil controls. GC-MS analysis revealed eleven major VOC components identified within 82-91% of oil samples. Principle component analysis (PCA) and linear detection analysis (LDA) were employed to visualize different levels of adulteration detected by the e-nose. Artificial neural networks (ANNs) and support vector machines (SVMs) were also used for statistical modeling. The sensitivity and specificity obtained for SVM were 0.987 and 0.977, respectively, while these values for the ANN method were 0.949 and 0.953, respectively. E-nose-based technology is a quick and effective method for the detection of sesame oil adulteration due to its simplicity (ease of application), rapid analysis, and accuracy. GC-MS data provided corroborative chemical evidence to show differences in volatile emissions from virgin and adulterated sesame oil samples and the precise VOCs explaining differences in e-nose signature patterns derived from each sample type.