Vertical Structure Research Articles

Long‐Term Variability of Phytoplankton Primary Production in the Ulleung Basin, East Sea/Japan Sea Using Ocean Color Remote Sensing

AbstractIn recent years, significant changes in environmental conditions and marine ecosystems have been observed in the East Sea/Japan Sea. This study investigates the long‐term environmental dynamics and phytoplankton responses in the Ulleung Basin, situated in the southwestern East Sea/Japan Sea, utilizing satellite and in situ data from 2002 to 2021. Over this period, there was a noticeable increase in sea surface temperature (SST) (r = 0.5739, p < 0.01), accompanied by decreasing mixed layer depth (MLD) and chlorophyll‐a (Chl‐a) concentration (r = −0.6193 and −0.6721, respectively; p < 0.01). Nutrient concentrations within the upper 50 m significantly declined for nitrate and phosphate. A reduction in the N:P ratio indicated a shift from phosphorus‐limited to nitrogen‐limited environment. Moreover, primary production (PP) demonstrated a decreasing trend (r = −0.5840, p < 0.01), coinciding with an increase in small phytoplankton contribution (r = 0.6399, p < 0.01). Rising SST potentially altered the water column's vertical structure, hindering nutrient entrainment from the deep ocean. Consequently, this nutrient limitation may increase small phytoplankton contribution, resulting in a decline in total PP. Under the IPCC's SSP5‐8.5 scenario, small phytoplankton contribution in the Ulleung Basin is projected to rise by over 10%, resulting in a 29% average PP decrease by 2100. This suggests a diminishing energy supply to the food web in a warming ocean, impacting higher trophic levels and major fishery resources. These findings emphasize the critical need for understanding and monitoring these environmental shifts for effective fisheries management and marine ecosystem conservation.

Vertical Structure and Seasonal Variability of Chlorophyll Concentrations in the Southern Tropical Indian Ocean Revealed by Biogeochemical Argo Data

AbstractThe variability of chlorophyll (Chla) in the Southern Tropical Indian Ocean (STIO) is not fully understood. This study utilized biogeochemical Argo (BGC‐Argo) and satellite observations to investigate the seasonal Chla variations in the upper layer (above 200 m) and their relationships to physical dynamics. The results indicate the existence of a well‐developed deep Chla maximum (DCM) layer situated between depths of 50 and 150 m. The shallowest DCM was at the Seychelles‐Chagos thermocline ridge because of permanent upwelling. Both the northern (4°S–12°S, 52°E−92°E) and southern (12°S–25°S, 52°E−92°E) regions experience surface blooms during July–August. However, they exhibit distinct Chla changes in response to different physical processes and nitrate concentrations below the mixed layer. In the northern region, the thermocline plays a critical role in regulating DCM depth and intensity. From April to June, subsurface upwelling and near‐surface stratification processes promote nutrient and Chla accumulation in the subsurface layer, resulting in elevated surface Chla levels in the subsequent months. In contrast, the southern region is characterized by oligotrophic conditions, where light availability primarily governs Chla variability below the mixed layer. Specifically, from November to January, when light intensity intensifies, Chla increases below the mixed layer. Furthermore, BGC‐Argo data revealed a long‐lived cyclonic eddy that facilitated the westward transport of Chla, significantly contributing to surface Chla blooms through eddy‐pumping and eddy‐trapping mechanisms. This research elucidates the fundamental characteristics of Chla distribution from a three‐dimensional perspective and furthers our understanding of the complex biophysical interactions within the STIO.

External and internal driving forces of community and functional group stability in the forest mammal community

Conserving mammal community stability in forest ecosystems is an urgent challenge in the face of global biodiversity threats and complex trophic interaction. However, understanding of the stability of mammal communities and targeted functional groups is still limited, hindering adaptive strategy development. We collected 210 120 camera trap photos across 5897 km 2 within the Amur tiger ( Panthera tigris altaica ) range in China’s natural forests. We decomposed stability into compensatory effects, statistical-averaging effects and population stability. Using structural equation modelling, we explored the impact of external factors, species diversity and vertical effects on the stability of the community and of four functional groups. As external factors, primary productivity increased the stability of top predators, while precipitation had inconsistent effects. Horizontal diversity (richness and evenness) positively impacted community stability. However, the vertical structure of the community, including trophic-level richness and functional groups’ compensatory dynamics, were the largest drivers for maintaining community stability. Horizontal diversity within functional groups and the diversity or biomass of their food resources/consumers both influenced the stability of functional groups. Our results recognize the importance of conserving and even re-establishing vertical trophic structures in forest communities. Acknowledging multiple levels of stability, from functional groups to communities, is an indispensable step for effective conservation strategies.

High-Performance Broadband Photodetectors Combining Perovskite and Organic Bulk Heterojunction Bifunctional Layers

Perovskite can be used to prepare high-performance photodetectors due to its excellent optical properties. However, the detection range of perovskite photodetectors is mostly limited to the visible light range, restricting their further development and application. In recent years, combining perovskite with organic bulk heterojunctions to prepare photodetectors with broadband detection capability has proven to be an effective strategy. Through this approach, the response spectrum of the photodetector can be flexibly regulated, and organic compounds can improve the perovskite film quality by passivating defects and inhibit the penetration of water molecules in the air, thereby improving the device performance and stability. In this work, we propose and demonstrate the feasibility of combining MAPbI3 perovskite with PTB7-Th:COTIC-4F to prepare high-performance photodetectors with wide spectral response characteristics. With the assistance of an organic bulk heterojunction, the defects of perovskite crystals are effectively passivated, and the detection spectrum of the device is successfully extended to about 1100 nm. As a result, the responsivity achieved is 0.58 A/W, 1.19 A/W, and 1.41 A/W under laser illumination of 532 nm, 808 nm, and 980 nm, with the power density of 5 μW/cm2 at the bias voltage of −0.5 V, respectively, which is one of the best performances among vertical device structures of this type. Moreover, the stability of the final hybrid film has been greatly improved. This work provides a new approach to the preparation of high-performance and broadband perovskite photodetectors.

Vascular bundle-structured polymeric composites with fire-safe, self-detecting and heat warning capabilities for power batteries thermal management

The trend of miniaturization and integration poses challenges to the thermal management of electronic devices, requiring high thermal conductivity and potential fire safety, etc. In this study, inspired by plant vascular structure, we developed a polymer composite with a vertical vascular bundle structure via a sacrificial template method and subsequent assembly of transition metal carbides/nitrides (MXene) nanosheets and phytic acid (PA) coordinated cobalt ions (Co2+) complex. The embedded MXene and PA@Co exhibit multilayer multiscale structural features, forming heat transfer channels and protective cells within the composite. The resultant composites possess high out-of-plane thermal conductivity (∼1.54 W‧m−1‧k−1) and excellent flame retardancy, including self-extinguishing, and significantly reduced heat and smoke release. Interestingly, the MXene vascular bundle structure imparts heat early warning capabilities and intelligent damage self-detection, suggesting an effective means of preventing early-stage fires and real-time monitoring of composite structural and functional integrity. Such biomimetic strategies enable new insights into the designing of multifunctional, intelligent polymer composites.

Vertical multilayer structure of MoS2 flakes prepared by thermal evaporative deposition

In this investigation, we explore the synthesis of MoS2 through thermal evaporative deposition, seeking to uncover the growth dynamics and structural evolution of MoS2 under varied experimental conditions. By adjusting the temperature and the carrier gas, this study targets the fabrication of vertical multilayer MoS2 and its growth mode. Our analysis demonstrates that thermal conditions markedly influence flake morphology and dimensions, leading to a notable shift from AA to AB stacking configurations as temperatures rise in the vacuum. Additionally, the application of carrier distinctly modifies growth behaviors, enhancing the uniformity of nucleation sites and the propensity for lateral flake expansion. The insights gained from this research highlight the adaptability and effectiveness of thermal evaporative deposition in producing MoS2, thereby enriching our understanding of the fundamental mechanisms guiding MoS2 synthesis.

The Composition Diagram of a Complex Process: Enhancing Understanding of Hierarchical Business Processes

The article presents the Composition Diagram of a Complex Process (CDCP), a new diagramming method for modelling business processes with complex vertical structures. This Method addresses the limitations of traditional modelling techniques such as BPMN, Activity Diagrams (AD), and Event-Driven Process Chains (EPC).The experiment was carried out on 277 students from different study programs and grades to determine the effectiveness of the methods. The main objective was to evaluate the usability and effectiveness of CDCP compared to established methods, focusing on two primary tasks: interpretation and diagram creation. The participant's performance was evaluated based on the objective results of the tasks and the subjective feedback of the questionnaire. The results indicate that CDCP was the effective method for the reading and drawing tasks, outperforming BPMN and EPC in terms of understanding and ease of use. Statistical analysis of variance showed that while the year of the study did not significantly affect performance, the study program and Method used had a significant effect. These findings highlight the potential of CDCP as a more accessible and intuitive business process modelling tool, even for users with minimal prior experience.

Recent Progress of Thin Crystal Engineering for Perovskite Solar Cells.

Metal halide perovskite single crystals hold promise for photovoltaics with high efficiency and stability due to their superior optoelectronic properties and weak bulk ion migration. The past several years have witnessed rapid development of single-crystal perovskite solar cells (PSCs) with efficiency rocketed from 6.5% to 24.3%, however, which still lags behind their polycrystalline counterparts. Moreover, the poor device stability under light illumination is contrary to the high ion migration barrier of perovskite single crystals. The key limiting factors should be the low crystalline quality and high surface defect density of solution-grown thin single crystals. Under this circumstance, a review paper summarizing the recent progress and challenges will be instructive for future development of this emerging field. In this manuscript, the crystal engineering used to enhance carrier transport and suppress carrier recombination in vertical single-crystal PSCs will be summarized initially, including crystal growth, component control, surface and interface modification. Subsequently, the application of perovskite single crystals in lateral single-crystal PSCs will be discussed and compared with the conventionally vertical structure. Finally, the challenges and proposed strategies for the development of single-crystal PSCs are provided.

Subsurface Marine Heatwaves in the South China Sea

AbstractMarine heatwaves (MHWs), extreme warm ocean temperature events, greatly impact marine ecosystems. While most MHW studies in the South China Sea (SCS) focus on the sea surface, subsurface characteristics remain less explored. This study uses high‐resolution (1/12°) ocean reanalysis data sets to assess MHW properties with depth in the SCS from 1993 to 2022. We find that MHW intensities are typically stronger at subsurface levels (30–150 m) than at the surface, with significant spatial variations. The vertical structures of MHW maximum and cumulative intensities peak between 70 and 100 m with 2.7°C and 63°C days, respectively; MHW annual days and duration increase gradually from 10 to 2,000 m with duration peaks at 2,000 m (∼60 days), four times longer than that at the surface. The SCS experienced two major periods of extensive El Niño‐related subsurface MHWs from 1997 to 2002 and 2008 to 2014, with MHWs reaching depths of 150 m and covering 70% of the upper 40 m. Strong El Niño events strengthen the western Pacific subtropical high, reducing summer monsoon winds, weakening coastal upwelling east of Vietnam, and increasing water temperatures. Regions of elevated eddy kinetic energy in the SCS suggest that significant mesoscale eddy activities are situated east of Vietnam. In addition, notable eddy heat transport was observed in the above region and west of the Luzon Strait in the upper 1,000 m. This may help to explain the high maximum and cumulative intensities of MHWs exceeding 100 m in the northern SCS.

Dynamics of Bubble Plumes Produced by Breaking Waves

Abstract Bubble plumes play a significant role in the air–sea interface by influencing processes such as air–sea gas exchange, aerosol production, modulation of oceanic carbon and nutrient cycles, and the vertical structure of the upper ocean. Using acoustic Doppler current profiler (ADCP) data collected off the west coast of Ireland, we investigate the dynamics of bubble plumes and their relationship with sea state variables. In particular, we describe the patterns of bubble plume vertical extension, duration, and periodicity. We establish a power-law relationship between the average bubble penetration depth and wind speed, consistent with previous findings. Additionally, the study reveals a significant association between whitecapping coverage and observed acoustic volume backscatter intensity, underscoring the role of wave breaking in bubble plume generation. The shape of the probability distribution of bubble plume depths reveals a transition toward stronger and more organized bubble entrainment events during higher wind speeds. Furthermore, we show that deeper bubble plumes are associated with turbulent Langmuir number Lat ∼ 0.3, highlighting the potential role of Langmuir circulation on the transport and deepening of bubble plumes. These results contribute to a better understanding of the complex interactions between ocean waves, wind, and bubble plumes, providing valuable insights for improving predictive models and enhancing our understanding of air–sea interactions. Significance Statement This research contributes to understanding bubble plume dynamics in the upper ocean and their relationship with sea state variables. The establishment of a power-law relationship between the bubble penetration depth and wind speed, along with the association between whitecapping coverage and acoustic backscatter intensity, contributes to improved predictive capabilities for air–sea interactions and carbon dioxide exchange. The identification of the potential influence of Langmuir circulation on bubble plume dynamics expands our understanding of the role of coherent circulations in transporting bubble plumes. Additionally, this study presents a clear methodology using commercial sensors such as an ADCP, which can be easily replicated by researchers worldwide, leading to potential advancements in our comprehension of bubble plume dynamics.

Direct Entrainment as a Measure of Dilution

Abstract The turbulent transport of mass, energy, moisture, and momentum between the clouds and the surrounding environment plays a central role in determining the vertical structure of the troposphere. This article investigates the connection between net entrainment, defined here as the net transport of air into individual clouds, and net dilution, defined as the tendencies of passive tracers such as static energy or total water mixing ratio. Entrainment and detrainment rates for 2.6 × 106 individual cloud samples are obtained from a large-eddy simulation of shallow convective boundary layer atmosphere that explicitly calculates the turbulent fluxes across the cloud boundaries. The equations describing the tendencies of cloud mass and tracer concentrations are derived as a function of directly calculated entrainment and detrainment rates of the individual clouds, and used to calculate net entrainment and dilution rates. Directly calculated net entrainment and dilution rates agree well with cloud mass and tracer tendencies and give a dilution time scale of 13 min. In contrast, the traditional bulk-plume approximation overestimates the effect of entrainment and detrainment on the dilution of cloud field properties due to the differential tracer transport through the moist shell surrounding the cloud. Using direct measures of entrainment and detrainment for individual clouds separates different processes that influence the turbulent mass transport between the clouds and their environment.

Estimating the In Situ Stratification via Remotely Sensed Internal Wave Speeds

Abstract This work tests a methodology for estimating the ocean stratification gradient using remotely sensed, high temporal and spatial resolution field measurements of internal wave propagation speeds. The internal wave (IW) speeds were calculated from IW tracks observed using a shore-based, X-band marine radar deployed at a field site on the south-central coast of California. An inverse model, based on the work of Kar and Guha, utilizes the linear internal wave dispersion relation, assuming a constant vertical density gradient is the basis for the inverse model. This allows the vertical gradient of density to be expressed as a function of the internal wave phase speed, local water depth, and a background average density. The inputs to the algorithm are the known cross-shore bathymetry, the background ocean density, and the remotely sensed cross-shore profiles of IW speed. The estimated density gradients are then compared to the synchronously measured vertical density profiles collected from an in situ instrument array. The results show a very good agreement offshore in deeper water (∼50–30 m) but more significant discrepancies in shallow water (20–10 m) closer to shore. In addition, a sensitivity analysis is conducted that relates errors in measured speeds to errors in the estimated density gradients. Significance Statement The propagation speed of ocean internal waves inherently depends on the vertical structure of the water density, which is termed stratification. In this work, we evaluate and test with real field observations a technique to infer the ocean density stratification from internal wave propagation speeds collected from remote sensing images. Such methods offer a way to monitor ocean stratification without the need for extensive in situ measurements.

Seasonal Variability in Baffin Bay

AbstractThree dominant characteristics and underlying dynamics of the seasonal cycle in Baffin Bay are discussed. The study is based on a regional, high‐resolution coupled sea ice‐ocean numerical model that complements our understanding drawn from observations. Subject to forcing from the atmosphere, sea ice, Greenland, and other ocean basins, the ocean circulation exhibits complex seasonal variations that influence Arctic freshwater storage and export. The basin‐scale barotropic circulation is generally stronger (weaker) in summer (winter). The interior recirculation (∼2 Sv) is primarily driven by oscillating along‐topography surface stress. The volume transport along the Baffin Island coast is also influenced by Arctic inflows (∼0.6 Sv) via Smith Sound and Lancaster Sound with maximum (minimum) in June‐August (October‐December). In addition to the barotropic variation, the Baffin Island Current also has changing vertical structure with the upper‐ocean baroclinicity weakened in winter‐spring. It is due to a cross‐shelf circulation associated with spatially variable ice‐ocean stresses that flattens isopycnals. Greenland runoff and sea ice processes dominate buoyancy forcing to Baffin Bay. Opposite to the runoff that freshens the west Greenland shelf, stronger salinification by ice formation compared to freshening by ice melt enables a net densification in the interior of Baffin Bay. Net sea ice formation in the past 30 years contributes to ∼25% of sea ice export via Davis Strait. The seasonal variability in baroclinicity and water mass transformation changes in recent decades based on the simulation.

On the impact of the vertical structure of Martian water ice clouds on nadir atmospheric retrievals from simultaneous EMM/EXI and TGO/ACS-MIR observations.

Retrieving the optical depth of the Martian clouds (τcld) is a powerful way to monitor their spatial and temporal evolution. However, such retrievals from nadir imagery rely on several assumptions, including the vertical structure of the clouds in the atmosphere. Here we compare the results of cloud optical depth retrievals at 320 nm from the Emirates eXploration Imager (EXI) onboard the Emirates Mars Mission (EMM) “Hope” orbiter performed using a basic uniform cloud profile used in previous studies and using derived cloud profiles obtained from near-simultaneous Solar Occultation observations in the 3.1–3.4 μm spectral range from the Middle-Infrared channel of the Atmospheric Chemistry Suite (ACS) instrument onboard the ESA Trace Gas Orbiter (TGO). We show that the latitudinal dependence of the cloud vertical profiles can have a strong impact on the nadir retrievals; neglecting it can lead to a significant underestimation of τcld in the polar regions (up to 25 % to 50 %, depending on the vertical distribution of the dust in the atmosphere) and to a lesser extent, to an overestimation of τcld around the equator. We also discuss the impact of a vertically-dependent particle size profile, as previous studies have shown the presence of very small water ice particles at the top of the clouds. From this analysis, we provide recommendations for the improvement of water ice cloud parameterization in radiative transfer algorithms in nadir atmospheric retrievals.

Enhanced heat transfer performance in vapor chambers via fabrication of novel regular composite porous wick structures using selective laser melting

The composite structure wick has been proven to significantly enhance the heat transfer performance of vapor chambers. Aluminum vapor chambers offer advantages such as being lightweight and cost-effective, meeting the requirements for lightweight cooling in fields like aviation. This study presented two novel composite porous wick structures with regular-shaped pores, designed and controlled via selective laser melting (SLM): the vertical square pore composite wick structure and the round-vertical square pore composite wick structure. A water-cooling test platform was built to investigate the effects of parameters such as wick structure thickness, round pore diameter, and round pore depth on the heat transfer performance and thermal resistance of the vapor chambers. The results indicate that the optimal thickness for the vertical square pore composite wick structure was 1.5 mm, yielding a minimum thermal resistance of 0.04 K/W. When the thickness was below 1.5 mm, it caused a reduction in the density of the vaporized core and insufficient liquid transport capacity. Conversely, when the thickness exceeded 1.5 mm, the primary limiting factor for heat transfer shifts to vapor-liquid flow resistance. Furthermore, the round-vertical square pore composite wick structure can provide further improvements in vapor-liquid transport within the structure.

Study on an Interpenetrating Artificial SEI for Lithium Metal Anode Modification and Fast Charging Characterization.

Artificial SEI is one of the effective strategies to improve lithium dendrites and suppress side reactions. However, the role of SEI components and distribution on the modification of the lithium metal anode remains unclear. Therefore, in this study, the oxygen-sulfur (O-S) component and its distribution in SEI were modulated by designing experiments, and then the mechanism of its action was deeply investigated. The study is based on an in-depth analysis of the properties of lithium sulfide (Li2S) and lithium oxide (Li2O) as SEI layer materials and effectively combines them in an ether electrolyte environment to form an innovative SEI structure. The experimental results show that the optimal SEI modulation condition is O120-S10. O120-S10 significantly improves the kinetic performance of electrochemical reactions, reduces the film resistance, and achieves cycling stability of up to 2100 h during high-capacity lithium deposition/stripping at 5 mAh cm-2. When used in conjunction with a ternary cathode material (NCM811), the O120-S10 demonstrates excellent performance under high rate charge/discharge conditions at 10C. After 1500 cycle tests, the battery's specific capacity was maintained at 90 mAh g-1 and the Coulombic efficiency reached 98.52%. Through X-ray photoelectron spectroscopy (XPS) analysis, the vertical structure and ratio distribution of components in SEI were revealed in detail, and the optimal component ratios of Li2S 46.48%, Li2O 46.02%, and Li2CO3 7.50% were determined. The mechanism of action is to achieve a 1 + 1 > 2 superlinear synergistic effect and fast charging performance by combining the ability of Li2O's low lithium ion diffusion barrier with Li2S's ability to inhibit the growth of lithium dendrites.

Toward Comprehensive Understanding of Air‐Sea Interactions Under Tropical Cyclones: On the Importance of High Resolution and Multi‐Modal Observations

AbstractThe three‐dimensional structure of the Tropical Cyclone's baroclinic wake is synthesized as an averaged baroclinic‐dominant response of the upper ocean. The resulting persisting sea surface depression can easily be monitored using the present‐day altimeter constellation. Following a semi‐empirical framework, these baroclinic wake signatures are linked to the inner core TC dynamic and the ocean stratification. To collect these fine‐scale parameters, spaceborne SAR instruments and Argo fleet are used, to precisely capture the maximum wind region and the irregularities of the ocean vertical structure. This combination of high‐resolution information is found paramount to fully capture the modulation of sea surface height anomalies, and its mean trend, especially for major hurricanes. Baroclinic signatures mostly range around 10–20 cm and peak at 40 cm. Deeper anomalies correspond to barotropic response, removed from the present analysis.

Influence of quasi-biennial oscillations (QBO) on the stratospheric polar vortex in the Antarctic

For many years, the dominant opinion in the literature has been that the stratospheric polar vortex is weaker in the easterly phase of the QBO than in the westerly phase, which is known as the Holton–Tan effect. While for the Northern Hemisphere vortex this is true during winter, for the Southern Hemisphere vortex the dependence on the QBO is observed only in spring. This feature is usually explained by the greater intensity of the Southern Hemisphere vortex compared to the Northern Hemisphere vortex, and the QBO can modulate its strength only during the vortex breaking season in October-November. Usually, the vortex response to the QBO is determined based on the equatorial wind direction at a certain vertical level, and the conclusions depend strongly on the level at which the QBO phase is determined. However, it has long been shown that using the equatorial wind sign at one or even a combination of several levels is not quite correct because it does not take into account the time of descent of the QBO wind relative to the seasons of the year, and it is not known at what altitudes the QBO wind has the strongest influence on the extratropical stratosphere. Due to the variable period of the QBO cycles, the phase relationship between the seasonal cycle and the QBO cycle is constantly changing, resulting in many variants of the vertical structure of the wind QBO during the Antarctic winter vortex and ozone hole. However, the seasonal regularities of QBO used in this work lead to a strictly limited number of possible variants of coincidence of the phases of the QBO cycles with the seasons of the year, which allows us to reveal typical features of interannual variations of the polar vortex and ozone hole in the Antarctic that are due to the QBO. The analysis of observational data indicates unexpected peculiarities of the QBO modulation of the stratospheric polar vortex in the Antarctic. The QBO effect in the vortex intensity is observed not only in spring during the weakening phase of the winter vortex, but also during the vortex maximum in June–August. At the same time, changes in the wind speed of the vortex during its maximum in winter are opposite to those in the spring during the ozone hole period. If the winter vortex is more intense (weak), then during the ozone hole period the vortex is weaker (more intense) than the average level.

Climate variability shifts the vertical structure of phytoplankton in the Sargasso Sea

AbstractMarine phytoplankton are essential to ocean biogeochemical cycles. However, our understanding of changes in phytoplankton rely largely on satellite data, which can only assess changes in surface phytoplankton. How climate variability is impacting their vertical structure remains unclear. Here we use 33 years’ worth of data from the Sargasso Sea to show distinct seasonal and long-term phytoplankton climate responses in the surface mixed layer compared with the subsurface. Seasonally, the surface community alters their carbon-to-chlorophyll ratio without changing their carbon biomass, whereas the chlorophyll a and carbon of the subsurface community covaries with no change in their carbon-to-chlorophyll ratio. Over the last decade, the subsurface phytoplankton biomass has increased in response to warming, whereas the surface phytoplankton have altered their carbon-to-chlorophyll ratio with minimal change in their carbon biomass. Given that satellites can only view the surface ocean, sustained subsurface monitoring is required to provide a full understanding of how phytoplankton are responding to climate change.

Improving photoelectrochemical performance of transferred TiO2 nanotubes onto FTO substrate with Mo2C and NiS as Co-catalyst

The photoelectrochemical (PEC) performance of titanium dioxide nanotube (TiO2 NT) photoelectrodes for sustainable hydrogen production has garnered significant research interest. Despite the advantages of TiO2 NT fabricated via anodization of titanium metal, such as their well-ordered vertical structure, challenges persist including the thick oxide barrier layer, limited optical transparancy, and the wide energy band gap (∼3.0 eV), which constrain their practical efficiency in PEC applications. This study addresses these limitations by introducing a novel approch to transfer TiO2 NT onto a fluorine-doped tin oxide (FTO) substrate. TiO2 NTs were synthesized with varying anodization times and steps to achieve optimal free-standing structures. To further enhance PEC performance, co-catalyst including molybdenum carbide (Mo2C) and nickel sulfide (NiS) were incorporated using immersion and successive ionic layer adsorption reaction (SILAR) methods, respectively. Comprehensive characterization using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), ultraviolet–visible–near infrared (UV–Vis–NIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS) provided insights into the crystal phase, morphological structure, band gap, and elemental composition of the photoelectrodes. Photoelectrochemical and photostability evaluations were conducted through linear scan voltammetry (LSV) and chronoamperometry under dark and light conditions. Results indicate that transferring TiO2 NTs onto FTO significantly enhanced photocurrent density, achieving a 2.5-fold increase at 0.7 V versus a TiO2 NT/Ti substrate. The incorporating of co-catalysts Mo2C, NiS and the combined NiS/Mo2C further enhanced the photocurrent density to 2.20, 3.00 and 8.00 mA cm−2 respectively, with a remarkable 31-fold enhancement compared to the TiO2 NT/Ti substrate. This findings underscore the potential of the TiO₂ NT/FTO photoelectrode with optimized co-catalyst integration for advanced photoelectrochemical applications.