Heat and mass transfer in the boundary-layer flow of unsteady viscous nanofluid along a vertical stretching sheet in the presence of magnetic field, thermal radiation, heat generation, and chemical reaction are presented in this paper. The sheet is situated in the xz-plane and y is normal to the surface directing towards the positive y-axis. The sheet is continuously stretching in the positive x-axis and the external magnetic field is applied to the system parallel to the positive y-axis. With the help of similarity transformations, the partial differential equations are transformed into a couple of nonlinear ordinary differential equations. The new problem is then solved numerically by a finite-difference scheme known as the Keller-box method. Effects of the necessary parameters in the flow field are explicitly studied and briefly explained graphically and in tabular form. For the selected values of the pertinent parameters appearing in the governing equations, numerical results of velocity, temperature, concentration, skin friction coefficient, Nusselt number, and Sherwood number are obtained. The results are compared to the works of others (from previously published journals) and they are found in excellent agreement.