Considering global warming as a critical challenge to human life, performance optimization of the building envelope can play a noticeable role to reduce a building's environmental footprint. Meanwhile, shading systems are considered as sustainable passive solutions to contribute to building energy efficiency, and daylight control in early-stage design. Nonetheless, a paucity of research has examined the various shading strategies in diverse climates, particularly arid desert and steppe regions, in conjunction with educational buildings. The present study aims to evaluate the role of fixed exterior shading systems (FESSs), and window-to-wall ratio (WWR) on building’ thermal and daylight performance in Iran with desert, semi-arid, and Mediterranean climates. Pareto Frontier and weighted-sum method for multi-objective optimization, and sensitivity analysis were used to study the optimum solutions, and the relationship between the design variables and the performance metrics. Three objective metrics including Spatial Daylight Autonomy (sDA), Annual Sunlight Exposure (ASE), and Energy Use Intensity (EUI), were defined as performance metrics. Shadings include vertical louver, horizontal louver, light shelf, overhang, and egg-crate. The results showed that EUI was reduced via FESS-integrated façade by 25.22%, 20.84%, 19.14%, 14.06%, and 13.47%, in Yazd, Bushehr, Kerman, Rasht, and Mashhad as selected studied cities, respectively. Based on ASE, the horizontal louver surpasses the other systems by 100% ASE value reduction in all climate zones except for Rasht. sDA level is reduced in all climate zones considering five studied FESSs excluding horizontal louver in Yazd and Rasht and overhang in Mashhad by 100% sDA level. Building energy performance simulation is validated by ASHRAE140-2020.