Vertical Heterogeneity Research Articles

Spatial distribution and migration characteristics of heavy metals at an abandoned industrial site in the Southwest of China

The rapid acceleration of global industrialization has rendered heavy metal contamination at abandoned industrial sites a severe challenge, particularly in geologically complex and fragile karst regions of Southwest China, posing significant threats to ecosystems and public health. However, existing research lacks a comprehensive understanding of the spatial distribution and migration mechanisms of heavy metals in this region. In this study, 523 soil samples and 30 groundwater samples were collected, and the pollution levels were systematically assessed using the Geo-Accumulation Index, Single Pollution Index, and Nemerow Integrated Pollution Index. Horizontal and vertical spatial heterogeneity was explored through Moran's I and Voronoi polygon analysis. Furthermore, 3D geological modeling and groundwater flow simulations were employed to investigate the influence of hydrogeological conditions on contaminant migration. The results indicate elevated concentrations of Cd, Hg, Pb, and As in the surface layer, with concentrations initially decreasing and then increasing with depth, likely due to the presence of discontinuous clay layers. Moran's I revealed significant clustering effects at depths of 0.2 meters and 4 meters, while Voronoi analysis confirmed vertical heterogeneity. This study provides a scientific basis for pollution assessment and targeted remediation in karst regions.

Evaluation and regulation methods for the utilization of Type-II oil reservoirs using ASP flooding

Abstract Existing methods for calculating oil reservoir utilization in chemical flooding rely on the instantaneous water absorption profile, which fails to provide an accurate description of the actual utilization conditions of the reservoir, making it imperative to find a method that accurately reflects the reservoir utilization. Type-II oil reservoirs often exhibit significant vertical heterogeneity. During chemical flooding, the impacts of high-permeability layer utilization, low-permeability layer utilization, and the simultaneous utilization of both layers on recovery are to be explored. Therefore, it is important to investigate the recovery requirements for different types of reservoirs. This study explores the solutions for improved reservoir utilization as well as the evaluation and regulation methods for the utilization of secondary oil reservoirs using the Alkaline-Surfactant-Polymer (ASP) flooding, which is of great significance for the adjustment of ASP flooding, injection, and production of secondary oil reservoirs.

Vertical Compositional Heterogeneity Induces Instability in All-Inorganic CsPbIBr2 Perovskites.

Understanding the vertical compositional homogeneity and defect distribution is of paramount importance in elucidating and maximizing the performance of halide-perovskite-based optoelectronic devices. This work reports the depth-dependent study of the chemical composition and metallic Pb0 content of all-inorganic CsPbIBr2 perovskite films undertaken using lab-based hard X-ray photoelectron spectroscopy and soft X-ray photoelectron spectroscopy. The presence of elemental or metallic Pb (Pb0), in the bulk and at the surface of the perovskite films highlights the formation of defect or recombination centers throughout the analyzed depth. The Pb0 content was found to be of higher concentration in the bulk of the CsPbIBr2 films compared to that at the surface. Engineering the CsPbIBr2 film growth using appropriate antisolvents resulted in the overall reduction and/or complete elimination of Pb0 at the surface and at the bulk of the perovskite films. However, the effect of antisolvent treatment was significantly pronounced in the bulk-like region as compared to that at the surface. Pb0 is synonymous with defect states/recombination centers in perovskite films and this reduction in defect density due to the antisolvent treatment corroborates the enhanced phase stability and improved solar cell performance of the corresponding CsPbIBr2 devices.

Characteristics and hydrocarbon accumulation model of Paleogene whole petroleum system in western depression of Qaidam Basin, NW China

Based on the oil and gas exploration in western depression of the Qaidam Basin, NW China, combined with the geochemical, seismic, logging and drilling data, the basic geological conditions, oil and gas distribution characteristics, reservoir-forming dynamics, and hydrocarbon accumulation model of the Paleogene whole petroleum system (WPS) in the western depression of the Qaidam Basin are systematically studied. A globally unique ultra-thick mountain-style WPS is found in the western depression of the Qaidam Basin. Around the source rocks of the upper member of the Paleogene Lower Ganchaigou Formation, the structural reservoir, lithological reservoir, shale oil and shale gas are laterally distributed in an orderly manner and vertically overlapped from the edge to the central part of the lake basin. The Paleogene WPS in the western depression of the Qaidam Basin is believed unique in three aspects. First, the source rocks with low organic matter abundance are characterized by low carbon and rich hydrogen, showing a strong hydrocarbon generating capacity per unit mass of organic carbon. Second, the saline lake basinal deposits are ultra-thick, with mixed deposits dominating the center of the depression, and strong vertical and lateral heterogeneity of lithofacies and storage spaces. Third, the strong transformation induced by strike-slip compression during the Himalayan resulted in the heterogeneous enrichment of oil and gas in the mountain-style WPS. As a result of the coordinated evolution of source-reservoir-caprock assemblage and conducting system, the Paleogene WPS has the characteristics of “whole process” hydrocarbon generation of source rocks which are low-carbon and hydrogen-rich, “whole depression” ultra-thick reservoir sedimentation, “all direction” hydrocarbon adjustment by strike-slip compressional fault, and “whole succession” distribution of conventional and unconventional oil and gas. Due to the severe Himalayan tectonic movement, the western depression of the Qaidam Basin evolved from depression to uplift. Shale oil is widely distributed in the central lacustrine basin. In the sedimentary system deeper than 2 000 m, oil and gas are continuous in the laminated limy-dolomites within the source rocks and the alga limestones neighboring the source kitchen, with intercrystalline pores, lamina fractures in dolomites and fault-dissolution bodies serving as the effective storage space. All these findings are helpful to supplement and expand the WPS theory in the continental lake basins in China, and provide theoretical guidance and technical support for oil and gas exploration in the Qaidam Basin.

Constraints on vertical variability of geogenic ammonium in multi-layered aquifer systems

The elevated levels of geogenic (natural) ammonium in groundwater have been frequently documented in recent years. Although improving insights have been achieved in understanding the genesis of ammonium in the subsurface environment, the vertical variability of the geogenic ammonium in groundwater remains poorly understood. Here, we selected typical multi-layered aquifer systems in the central Yangtze River plain and characterized the vertical heterogeneity of geogenic ammonium through the hydrogeochemical analysis. Subsequently, the controlling factors were identified by examining the molecular composition of dissolved organic matter (DOM) and aquifer sediment features. The results indicated that the ammonium concentration in groundwater increased from the deep to shallow aquifers (2.13 to 9.88 mg/L as N), accompanied by a transition in organic matter (OM) degradation towards the methanogenic stage (δ13C-DIC: -23.07 to -0.34‰). Compared to the deeper aquifers, the DOM in the shallow aquifer was characterized by a higher abundance of the N-containing OM (15.1% > 13.13% > 12.76%) with a lower molecular lability index, corresponding to more thorough degradation extent. The characteristics of the soluble OM in depth-matched sediments were similar to those of the DOM in groundwater, suggesting the persistent water-rock interactions. Besides, the pumping tests revealed that the hydraulic conductivity decreased from deep to shallow aquifers (2.28 to 0.62 m/d), which further facilitated the more retention of geogenic ammonium in the shallow aquifer. That is, the combined effects of the abundant N-containing OM in sediments, strong degradation of the bioactive DOM, and long retention governed by hydrodynamics contributed to the increased ammonium enrichment in the shallow aquifer, thereby generating the vertical variability. The findings underscore the significance of the complex coupled factors in controlling the vertical distribution of geogenic ammonium in multi-layered aquifer systems, which was crucial for understanding the spatial heterogeneity of geogenic contaminated groundwater.

Vertical heterogeneity enhances network complexity and stability of co-occurrence microbes in the eastern Indian Ocean

Microbes are core to driving biogeochemical cycles and differ between sun-drenched surface and relatively dark deep oceans. However, their distinct contributions to the organization and association of communities are still remaining elusive. Here, their assembly and co-occurrence stability are systematically researched along the surface and vertical gradients in the eastern Indian Ocean. The distribution of surface microbes was grouped tightly with closer phylogenetic distance and broader niche breadth, and separately from those vertical samples. Clear distance-decay of community similarity was observed in surface microbes with lower richness, while more diverse microeukaryotes and prokaryotes were observed in surface and vertical environments, respectively. Co-occurrence microbes along vertical gradients had a more complex network that was dominated by prokaryotes, while exhibited a lower modularity compared to the surface network. Microbial associations along vertical gradients were more stable and resilient, with lower robustness, higher vulnerability, and a relatively consistent fragmentation. Moreover, prokaryotes contribute greatly to the network topology and stability compared to microeukaryotes in surface environments, emphasizing their distinct functions and survival strategies in maintaining community stability across spatial variations. Environmental selection and community differentiation led to the divergence in organization and potential function of microbes. This study shed light on new perspectives on how marine microbes were associated with and influenced by spatial heterogeneity and their distinct roles in community organization in the face of environmental fluctuations.

A geothermal doublet in a single well: application of the recirculation well concept to reuse wells to be abandoned

The depletion of oil and gas reservoirs leaves many deep and expensive wells with no option but to be abandoned. However, these wells could have a second chance to extend their life as a source of geothermal energy, especially if they are located next to urban or industrial areas in need of heating. This article shows a technical analysis of the well recirculation or geothermal doublet in a single well approach as a strategy to reuse wells that cross aquifers. Different aspects of this strategy are highlighted, including the technical conditions required for the application, the well completion, and the geothermal performance. The latest is assessed via numerical reservoir simulations using geological data from an existing well. The results show that vertical petrophysical heterogeneities play an important role in the performance and feasibility of this approach.

Brownfield Topsoil Vertical Heterogeneity: Implications for Germination and Soil Microbial Functioning.

Soil vertical heterogeneity refers to the variation in soil properties and composition with depth. In uncontaminated soils, properties including the organic matter content and nutrient concentrations typically change gradually with depth due to natural processes such as weathering, leaching, and organic matter decomposition. In contaminated soils, heavy metals and organic contaminants can migrate vertically through leaching or root uptake and translocation by plants and macrobiota, if present, leading to vertical heterogeneity in contaminant concentrations at different depths. Contaminants can alter soil properties, and we investigated the implications of soil vertical heterogeneity for germination and microbial functioning. We collected soil from an urban brownfield and created two conditions: structured soil samples collected with the soil core intact and mixed (unstructured) samples. When planted, the germination rate was significantly lower in the structured conditions (3.1 ± 1.7%) compared to mixed soils (17 ± 4.6%), suggesting that the vertical heterogeneity of contaminated soil influenced plant germination. To map the vertical distribution of contaminants and nutrient cycling rates in the structured soil samples, we collected 10 cm-deep soil cores from the barren site and a neighboring vegetated reference site and measured heavy metal concentrations, soil enzyme activities, and organic matter content in five 2 cm vertical layers. In the barren soil cores, metals were found concentrated in the top 2 cm layer, while in the vegetated soil cores, metals were uniformly distributed. No significant differences were observed for the organic matter content or moisture along depth. Published studies on vertical distribution of enzyme activities and metal concentrations have treated the top 10-20 cm as a single layer and thus would have not revealed the thin (<2 cm thick) metal cap on the surface of the barren soil core. Despite the metal cap, enzyme activities in the top layer were similar to those in the lower layers of the barren soil core, suggesting that high metal concentrations do not limit soil enzyme activity under all circumstances. Investigating vertical heterogeneity in postindustrial soils can inform efforts to convert industrial barrens to vegetated environments.

Dilation Potential Analysis of Low-Permeability Sandstone Reservoir under Water Injection in the West Oilfield of the South China Sea

At present, many offshore oil fields are facing problems, such as pollution-induced near-well zone blockage, poor inter-well connectivity, and strong vertical heterogeneity, which lead to insufficient formation energy and low production in the middle and late stages of development. It is necessary to develop a new technology to overcome these issues. In this regard, water-injection-induced dilation technology, which was already proven to have positive effects on loose sandstone reservoirs, was controversially applied to an offshore low-permeability reservoir. To investigate whether the water-injection-induced dilation technology is suitable, experiments were conducted to analyze the dilation potential of offshore low-permeability sandstone reservoirs, namely, X-ray diffraction, laser particle size analysis, physical simulation, computed tomography scan, and electron microscope scanning experiments. The X-ray diffraction experiments showed that the samples had more than 80% non-clay mineral content and a high brittleness index, which meant more complex microfractures under water injection. Particle size analysis experiments revealed that the particle size was mainly between 10 μm and 100 μm, and thus belonged to coarse silty sand. According to the sorting grade, the sample particle size distribution was uniform and the reservoir was more prone to dilation. The true triaxial physical simulation showed that a volumetric dilation zone occurred around the wellbore, where complicated microfractures occurred. This paper provides adequate evidence and mechanisms of dilation potential for an offshore low-permeability sandstone reservoir.

A comprehensive analysis of new particle formation across the northwest Atlantic: Analysis of ACTIVATE airborne data

New particle formation (NPF) is a critical source of particles and cloud condensation nuclei, yet there are scarce vertically-resolved measurements addressing NPF across different seasons in marine regions. This study leverages a multi-season set of airborne data from the NASA ACTIVATE mission between 2020 and 2022 to examine NPF characteristics over the northwest Atlantic ranging from the polluted U.S. East Coast to as far downwind (>1000 km) as Bermuda. Using the number concentration ratio above 3 and 10 nm (N3:N10) as a NPF indicator, we observe the highest ratios in the coldest months and comparable ratios over Bermuda relative to the U.S. East Coast. Within seasons, the highest and lowest ratios are found immediately above cloud tops and at the lowest possible flight altitudes (∼150 m above sea level), respectively. The ratio of (N3-N10)/N3 ranges from 0.16 to 0.29 depending on altitude, proximity to clouds, and season. The N3:N10 and (N3-N10)/N3 ratios increase with altitude up to as high as 9 km, with a case study showing favorable conditions around relatively thicker and precipitating cloud systems presumably due to high actinic fluxes and reduced aerosol surface area. Regression modeling reveals that increased N3:N10 is influenced most by reductions in temperature, relative humidity, and aerosol surface area. This work emphasizes the importance of both NPF in remote marine regions like Bermuda and vertical heterogeneity that exists in its contribution to aerosol and cloud condensation nuclei number budgets.

Significance of well placement and degree of hydrate reserve recovery for synergistic CH4 recovery and CO2 storage in marine heterogeneous hydrate-bearing sediments

The synergistic CH4 recovery and CO2 storage in marine natural gas hydrate reservoirs presents an emerging strategic solution for energy and environment challenges, yet the efficiency requires innovative engineering designs to enhance. In this study, a water-saturated CH4 hydrate-bearing sediment (HBS, V = 22 L, T = 284 K, and P = 11.2 MPa) was synthesized to investigate the pilot-scale combined processes of CH4 recovery by depressurization followed by CO2 storage through CO2/N2 injection. The synthesized HBS exhibited vertical heterogeneity with higher hydrate saturation observed in the upper sediment and a decreasing saturation trend in the lower sediment. The effect of well placement designs on CH4 recovery and hydrate restoration by mixed CH4/CO2/N2 hydrate (Mix-H) formation was investigated, considering two scenarios: upper well for recovery while lower well for injection (URLI), and lower well for recovery while upper well for injection (LRUI). Additionally, the impact of the degree of hydrate reserve recovery (100% and 80% hydrate dissociated) on subsequent Mix-H formation was also studied. Results indicate that the URLI setting achieves a higher CH4 recovery ratio and rate during depressurization compared to the LRUI setting which encounters low-T shielding. The T variation between upper and lower sediment highlights the influence of heterogeneity on fluid behaviors. Halting the CH4 recovery after 80% hydrate dissociation results in a halved recovery time and water production. During later CO2/N2 injection and Mix-H formation process, the LRUI setting achieves a 13–54% higher Mix-H saturation and a 33–56% higher CO2 hydrate encapsulation than the URLI setting. Moreover, 80% dissociation proves more favorable for Mix-H formation achieving nearly twice higher final amount than 100% hydrate dissociation. However, it results in a lower CO2 encapsulation. This study provides insights into the trade-off between CH4 recovery and CO2 storage efficiency, emphasizing the need for optimized well placement and controlled hydrate extraction.

Study on the influence of rock vertical heterogeneity on the vertical extension law of hydraulic fractures

The vertical expansion of fractures during hydraulic fracturing in low-permeability bottom-water oil and gas reservoirs is a crucial factor that significantly influences stimulation effectiveness. Fractures propagate concurrently in three dimensions; however, as operation time for fracturing and fracture length increase, there is a gradual reduction in fracture height. In the absence of a barrier layer or with inadequate strength and thickness, fractures may extend vertically or oscillate through it leading to an “unyielding” fractured state that impedes successful operations. This study introduces a mathematical model delineating the vertical expansion of hydraulic fractures (HFs) while computing stress intensity factors at upper and lower tips of each individual fracture. We use numerical methods to examine how vertical heterogeneity within reservoir rocks impacts laws governing vertical fracture propagation while conducting sensitivity analysis for making informed decisions on design parameters for hydraulic fracturing operations. The research results indicate that an escalation in stress disparity and increased toughness results in diminished height for HFs. Hydraulic fracturing augments fracture lengths along their respective axes. Nevertheless, if gap stress disparity surpasses net fluid pressure, a reduction in fracture length is observed. With an increasing ratio between local stress gradient versus fluid gravity gradient, HFs persistently advance vertically across cap and bed formations.

Depth dimension in seepage detection: Insights for exploration and geological gas storage surveillance

The search for surface hydrocarbon seeps has historically served as a fundamental tool in the early stages of oil and gas exploration. However, as easily detectable surface hydrocarbon seeps become increasingly scarce, advancement in analytical capabilities have shifted the focus towards detecting ultra-trace levels of hydrocarbons, commonly referred to as microseepages. While it is critical to understand the distribution of hydrocarbon microseepage for assessing petroleum systems and optimizing exploration efforts, the role of sampling depth in the detection of microseepage remains poorly understood. In this study, we investigated the influence of sampling depth on microseepage detection, using passive soil-gas sampling techniques at depths ranging from 0.5 to 10 m at sites with hydrocarbon-bearing reservoirs and dry wells. Organic geochemical analysis, including thermal desorption-gas chromatography-mass spectrometry (GC-MS), was employed to identify and quantify hydrocarbon and nonhydrocarbon compounds.The study result demonstrates that sampling at the Minimal Interference Zone (MIZ) depths of 5 m or greater significantly mitigates the risk of interference signals, thereby enabling the identification and quantification of hydrocarbon microseepages at trace and ultra-trace concentrations. At these depths, the attenuation of non-hydrocarbon compounds was observed, making the hydrocarbon signal markedly more distinguishable. Geochemical characterization of the samples revealed spatial and vertical heterogeneity in the distribution of hydrocarbon compounds, indicative of variations in the microseepage mechanisms potentially influenced by factors such as sedimentary basin settings and secondary alterations associated with the vadose zone. By utilizing passive soil-gas sampling techniques coupled with GC-MS, this study emphasizes the importance of sampling depth to improve the detection of reliable microseepage signal while reducing interference and background noise. The proposed technique not only refines existing methodologies for petroleum system assessments but also paves the way for broader geological applications. Specifically, the approach offers critical insights for the development of high-resolution geochemical surveys adaptable for surface background profiling in CO2 sequestration projects to monitor for storage efficiency and seal integrity.

An interpretable ensemble machine-learning workflow for permeability predictions in tight sandstone reservoirs using logging data

Tight sandstone reservoirs exhibit strong vertical heterogeneity and complex pore structures, challenging conventional permeability evaluation methods based on well-logging data. Although rising machine-learning (ML) techniques have demonstrated excellent accuracy for industrial applications, the physics and rationality within such a powerful “black box” remain less clear. Hence, reliable permeability prediction would benefit from an interpretable ML-based workflow that could reveal the controlling factors. To compare the models and examine the underlying features, 16 different ML submodels are tested after data preprocessing, feature selection, and hyperparameter optimization. By comparing the fitting accuracy and tuning time, the light gradient boosting machine optimized by the whale optimization algorithm, referred to as LGB-WOA, is determined to be the optimal model with the best fitting accuracy and relatively short tuning time. A field data application demonstrates that even in highly heterogeneous reservoir sections, the LGB-WOA model outperformed conventional petrophysical models by being the most consistent with reservoir permeability directly measured from the core samples ([Formula: see text]). The Shapley additive explanation values are then used to interpret the predictions of our LGB-WOA model. As expected, the porosity curve exhibits the highest feature importance among all input features, significantly contributing to permeability predictions. Conversely, a wellbore diameter and compensated neutron log contribute the least and need not be used for subsequent model improvements. These experiments and workflow provide a powerful method for accurately assessing the permeability in complex reservoirs and contribute to a broader understanding of the application of ML in reservoir characterization, paving the way for establishing more interpretable and reliable prediction models.

Educational heterogeneity of the founding team of innovative start-ups: confirmations and denials

This paper focuses on the value drivers of innovative start-ups (ISUs). Few companies can overcome the start-up stage; often, the early performance is insufficient, and the potential contribution of innovation to economic development is very poor. Studies based on a firm-level perspective show mixed results on the factors affecting the growth of ISUs. Most studies emphasize the role of “external” drivers of ISUs growth, while more knowledge is required of “internal” drivers. Consequently, this research focuses on the relationship between the features of the founding teams and the early performance of ISUs. Specifically, it concentrates on education heterogeneity and analyzes whether the heterogeneity of the founding team in terms of educational level (vertical heterogeneity) and field of studies (horizontal heterogeneity) affects the Italian ISUs performance. Growth regression and unconditional quantile regression models confirm the prior literature: the educational level affects the performance and the vertical heterogeneity in the composition of the founding team is relevant for ISUs performance. However, the results also suggest interesting denials: horizontal heterogeneity does not play any role, and no moderating effect of heterogeneity is shown. These findings are strongly attractive for new ventures and policymakers.

Evaluating effects of silvicultural treatments on forest canopy structure outcomes

Traditional forest management can homogenize forests, and management strategies that can restore complexity and promote adaptive capacity to global change are needed. However, effects of different silvicultural practices on complexity of forest structural components, such as the canopy, are not well understood mechanistically. We conducted a coupled field and simulation-modeling study to evaluate: 1) how near-term effects of silviculture on canopy structure and complexity differ across treatment types, and 2) how outcomes of common silvicultural treatments compare to a spectrum of randomly implemented removals. Thirteen different silvicultural treatments replicated across 12 study plots were simulated within 3D models derived from terrestrial lidar data. Treatment types often differed in their multi-dimensional structural outcomes, including vertical heterogeneity and canopy structural complexity. Moderate intensity thinning treatments that preferentially removed smaller trees increased near-term canopy structural complexity, while diameter-limit cutting often reduced complexity. Silvicultural treatments collectively produced a wide range of residual canopy conditions; however, variability among structural outcomes within individual treatment types or categories was limited relative to the range of possible outcomes from random removals. Most treatments induced shifts in canopy structure outside the spectrum of random removal, suggesting ample space for adapting management to promote forest heterogeneity.

Analysis of nitrogen migration and transformation in the typical deep and large reservoir of the Lancang River — Evidence from nitrogen and oxygen isotopes

The environmental effect resulting from dam construction and the formation of large reservoirs has long been a topic of significant concern. While current research at a macro scale provides a well understanding regarding the evolution of nitrogen nutrient status in river-reservoir ecosystems, the vertical migration and transformation characteristics of nitrogen in reservoirs under changing runoff remain less defined. This study centers on a typical deep reservoir along the Lancang River-Nuozhadu (NZD) Reservoir in April and December. The monitoring reveals a distinct vertical stratification phenomenon in the NZD Reservoir in the vertical profile in April, which can be categorized into a mixed layer (ML) (0–5 m), a thermocline layer (TL) (5–40 m), and an isothermal layer (IL) (>40 m) based on the water temperature. However, little stratification in the profile is occurred in December. The results of nitrogen and oxygen isotopes in April indicate that the biochemical process of nitrogen in the NZD Reservoir is predominantly driven by nitrification. However, different nitrogen biochemical processes are coupled in various stratified regions in the vertical direction. In the ML, simultaneous assimilation of ammonia nitrogen by phytoplankton occurs. In the TL, there is a process of oxidation and decomposition of particulate organic nitrogen due to a significant stratification effect and an extended hydraulic retention time. In the region of minimal dissolved oxygen (30–40 m), simultaneous denitrification may take place. In December, the main process is nitrogen assimilation in reservoir surface (ML). Statistical analysis of environmental factors highlights water temperature (T) and dissolved oxygen (DO) as crucial environmental factors influencing nitrogen migration and transformation within the reservoir. This study suggests that in deep reservoirs experiencing vertical thermal stratification, the characteristics of DO and nitrogen migration and transformation exhibit significant vertical spatial heterogeneity. This phenomenon may lead to diverse ecological environmental effects. Future efforts should focus on enhancing the fine monitoring of stratified water bodies in deep and large reservoirs and analyzing the ecological environmental effects of material cycling in greater detail.

Analytical model for the mitigation of VOC vapor with horizontal permeable reactive barrier in the contaminated site considering non-uniform source

Volatile organic compounds (VOCs) contamination at the groundwater may cause vapor intrusion and pose significant threats to human health. As a novel low-carbon mitigation technology, a horizontal permeable reactive barrier (HPRB) is proposed to remove the VOC vapor in the vadose zone and mitigate the vapor intrusion risk. To estimate the performance of HPRB in the contaminated site with a non-uniform source, a transient two-dimensional analytical model is developed in this study to simulate the VOC vapor migration and oxidation processes in the layered soil. The analytical model is verified against the experimental results and numerical simulation first and the parameter study is then conducted. The HPRB has good performance for the contaminated sites involving factors including deep source and local soil with low effective diffusivity. To consider the vertical heterogeneity of the local soil, the traditional equivalent homogeneity method has limitations in considering the horizontal migration of VOC vapor and is not suitable for the two-dimensional model. On the contrary, the artificial layered method based on the proposed analytical model has better accuracy and is recommended to be adopted in practice. Leading to the exponential decrease in the VOC vapor concentration at the ground surface, increasing the thickness of HPRB is an effective measure to enhance the performance of HPRB. The fitting exponential function can be applied to determine the minimum design value of the thickness of HPRB in practice.

Classification of rock types of porous limestone reservoirs: case study of the A oilfield

Rock types with similar lithological components and pore structures form the basic units of porous limestone reservoirs; this influences the reservoir evaluation efficiency and water injection development. As the main oil and gas pay zone in central Iraq, the Cretaceous Khasib Formation reservoirs are influenced by deposition, dissolution, and cementation. There is strong vertical heterogeneity in the most important zone of the Kh2 layer, with diverse rock types and complex pore structures. Based on core observation and casting thin-section identification, the Kh2 layer in the study area was divided into eight lithofacies types as argillaceous bioclastic wackestone, planktic foraminiferium wackestone, lamellar bioclastic wackestone, intraclastic–bioclastic packstone, patchy green algae packstone, green algae and pelletoid packstone, benthic foraminiferium–bioclastic packstone, and intraclastic grainstone. Along with the reservoir void space types of the lithofacies, capillary pressure curves are used to quantitatively analyze the throat and pore features of the different lithofacies. From the porosity–permeability cross-plot characteristics and distribution of pore types, 14 petrophysical facies are obtained. Finally, based on the differences between the lithofacies and petrophysical facies, the Kh2 member is divided into 13 rock types with different geological origins and petrophysical characteristics. Among these, the rock type RT1-8-14 has the best and rock type RT1-1-1 has the worst physical properties among the reservoir rock types. This study provides an optimization method for carbonate reservoir evaluation and is expected to be beneficial for efficient development of similar carbonate reservoirs.

Research on Gas Injection Limits and Development Methods of CH4/CO2 Synergistic Displacement in Offshore Fractured Condensate Gas Reservoirs

Gas injection for enhanced oil and gas reservoir recovery is a crucial method in offshore Carbon Capture, Utilization, and Storage (CCUS). The B6 buried hill condensate gas reservoir, characterized by high CO2 content, a deficit in natural energy, developed fractures and low-pressure differentials between formation and saturation pressures, requires supplementary formation energy to mitigate retrograde condensation near the wellbore area through gas injection. However, due to the connected fractures, the B6 gas reservoir exhibits strong horizontal and vertical heterogeneity, resulting in severe gas channeling and a futile cycle, which affects the gas injection efficiency at various levels of fracture development. Based on these findings, we conducted gas injection experiments and numerical simulations on fractured cores. A characterization method for oil and gas relative permeability considering dissolution was established. Additionally, the gas injection development boundary for this type of condensate gas reservoir was quantified according to the degree of fracture development, and the gas injection mode of the B6 reservoir was optimized. Research indicates that the presence of fractures leads to the formation of a dominant gas channel; the greater the permeability difference, the poorer the gas injection effect. The permeability gradation (fracture permeability divided by matrix permeability) in the gas injection area should be no higher than 15; gas injection in wells A1 and A2 is likely to achieve a better development effect under the existing well pattern. Moreover, early gas injection timing and pulse gas injection prove beneficial in enhancing the recovery rate of condensate oil. The study offers significant guidance for the development of similar gas reservoirs and for reservoirs with weakly connected fractures; advancing the timing of gas injection can mitigate the retrograde condensation phenomenon, whereas initiating gas injection after depletion may reduce the impact of gas channeling for reservoirs with strongly connected fractures.