Abstract High-performance vertical-channel flash (HVF) memory cells were fabricated on the single crystalline Si (c-Si) sidewalls of the cylindrical deep wells in c-Si substrate. To investigate the diameter effects of the cylindrical deep wells, namely channel holes, on HVF cells, the channel holes with different diameters, ranging from 65 nm to 260 nm, were made. Memory gate stacks of SiO2/ Al2O3/HfO2/Al2O3/TiN/W were formed by ozone oxidation and then ALD with the deposition thicknesses of 1/5/7/8/2/150 nm, respectively. For the devices with their diameters equal to or greater than 150 nm, their electrical properties, such as Vt, SS, DIBL, and program/erase characteristics, are close. As expected, DIBL and SS become better as the diameter increasing due to better gate control with larger diameter. However, large changes were occurred for the devices with the diameters of 90 nm and 65 nm. A simple model based on cylinder bulk for vertical flash memory devices was presented to obtain an approximate analytical solution for depletion-width and explain our experimental data. For the devices with the diameters of 150 nm, the high On/Off current ratio of 107 and relatively large memory window of 4.5 V were achieved. However, programming/erasing efficiency were degraded with hole diameter decreasing.