<div>The article presents the results of simulation studies of pollutant emissions from passenger cars. The characteristics of emissions were determined using the vehicle driving test procedures, in consideration of differentiated average velocities as well as model traffic conditions: urban traffic jam, urban traffic with no congestion, rural, motorways, and highways. This article also presented the possibility of determining the characteristics of pollutant emission based on a singular realization of the vehicle velocities processes, as well as the intensity of pollutant emission, with the use of the Monte Carlo method. The pollutant emission characteristics enable specification of pollutant emission intensity, which can be used for the inventory of pollutant emissions from road transport (COPERT software applied as standard) and can be useful in the assessment of a degree of environmental hazard by modeling pollutant dispersion. In this article, the results related to pollutant emission characteristics were obtained with the use of the software HBEFA INFRAS AG for the cumulative category of passenger cars, in terms of their representative structure in Europe in 2020. The simulation driving tests were carried out separately for cars with spark ignition engines and for those with compression ignition engines. It was concluded that using specialized software to simulate emissions from road vehicles is an effective way to determine the characteristics of emissions from road transport.</div>