Using polyoxometalate moieties we are developing proton conducting membranes for proton exchange membrane fuel cells, electrolyzers and other devices that can solve the durability and environmental challenges and temperature limitations facing the state of the state-of-the-art perfluorinated sulfonic acid-based membranes. During recent work with perfluorinated membranes we have shown how to achieve stability enhancement that easily exceeds the Fuel Cell DOE accelerated stress tests (AST) for chemical stability and mechanical durability requirements for light duty vehicles. This indicates the potential of these For this perfluorinated polymer-HPA combination we obtained higher performance than the current state-of-the-art PFSAs under high humidity conditionsHPA moieties to give oxidative stability to hydrocarbon membranes as well. New membrane technology we are working on will utilize covalently bound heteropoly acids (HPA), inorganic super acids, that have both some of the highest proton conductivities when wet and have been proven to catalytically decompose oxygenated radicals that destroy existing membranes. We have already demonstrated similar membranes in fuel cells with high performance and some of the most stable long term durability ever demonstrated. In fuel cells, the materials always performed beyond state-of the-art when in humid conditions but struggled when the cells became dry, as electrolysis applications feeds water to the cell we have very high confidence that we will be able to easily exceed electrolyzer performance targets. We are improving upon this polymer chemistry and are now tailoring it specifically to electrolysis. When configured correctly within a hydrocarbon polymer membrane these HPA-hydrocarbon polymers will outperform perfluorosulfonic acid (PFSA) polymers. The correct HPA chemistry must be chosen, and we have shown that silicotungstic acid derivatives act as strong proton conducting moieties and also catalytically decompose oxygenated radicals. This will then enable hydrocarbon membranes with practical lifetimes and performance using the silicotungstic functionality. We are aiming to control the HPA channel morphology and allow for maximum proton conductivity with minimum water uptake. The engineered structures will facilitate proton conduction from ambient conditions to temperatures in excess of 120°C (the polymeric materials chosen are stable to 200°C when dry and potentially much higher when wet and pressurized), as well as achieving cost and durability targets for PEM membranes in electrolyzer applications. Our approach will also allow for development of an ionomer for optimal interfacing with the electrodes.
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