The fundamental processes involved in the sintering of ionic solids are highly complex. Of particular significance are the initial stages of sintering during which surface effects are of prime importance. The sintering of zinc oxide has been studied by the method of changes in surface area at temperatures from 300° to 1000°C. and with varying oxygen pressures (from 10‐5 to 760 mm. of Hg). It has been demonstrated that significant sintering occurs at temperatures far below the Tammann temperature. It also has been shown that under specific conditions a very high defect concentration may exist in the surface of the material and that this is closely related to the phenomenon of sintering. Correlation has been made with an electron‐microscope investigation. Detailed X‐ray studies on single‐crystal specimens of zinc oxide have shown that interstitial zinc constitutes the defects. Activation energies have been deduced for the sintering process which suggest that the rate‐controlling step is diffusion in the surface zone in the low‐temperature region which changes to lattice or complex diffusion and viscous‐flow mechanisms about the Tammann temperature.