Varying Energy Density Research Articles

Tailored microstructure control in Additive Manufacturing: Constant and varying energy density approach for nickel 625 superalloy

The main challenge in the L-PBF process is finding the right combination of laser power (LP), scan speed (SS), and energy density (ED). This combination is crucial in controlling the microstructure and texture. This study introduces a new process parameter matrix (PPM) and its variation within the ED to adjust the microstructure by changing the LP/SS while keeping the ED constant or varying in the L-PBF process. Twenty-five Inconel 625 cubes were produced at different LP and SS, ranging from 230 to 350 W and 790 to 1190 mm/s. The resulting microstructure indicated that textured grains increased with ED. It also indicates that increasing the ED reduced relative density (RD) and porosity formation, while constant ED did not significantly affect them. Consequently, the hardness of the cube at the highest ED was about 21 % higher than that of the cube at the lowest ED. This study demonstrates the effectiveness of adjusting PPM to tailor the microstructure and texture using the L-PBF technique, which could be applied to complex shapes.

Influence of contour processing parameters on porosity, surface roughness, and fatigue life in laser powder bed Al-10Si-0.4Mg

Additive manufacturing (AM) enables fabrication of net-shape components with high geometric complexity, however mechanical properties of parts with as-fabricated surfaces are limited by surface roughness and subsurface porosity that may initiate fatigue cracks. This study aims to improve the utility of parts with as-fabricated surfaces by quantifying processing-surface condition-fatigue performance relationships, optimizing surface contour parameters for fatigue performance, and investigating the application of surface profilometry as a non-destructive quality control method. Eleven contour parameter sets of varying energy densities were produced in three classifications: no contour passes, single contour passes, and contours with secondary healing passes. Surface roughness was evaluated using line scan profilometry and subsurface porosity by optical microscopy. Contouring reduced the average surface roughness from Ra ≅ 25 μm to Ra ≅ 5 μm, and the layer of subsurface porosity introduced by this process could be partially eliminated by a secondary healing pass. One set of processing conditions from each contour class was selected for fatigue studies (R = -1), and their results were compared with the fatigue data from machined and polished specimens to evaluate the relative influence of surface condition. Relative to machined and polished specimens, fatigue lives are approximately five times lower for contoured specimens (with and without a healing pass) and twenty times lower for non-contoured specimens at equivalent stress levels up to 107 cycles to failure. Fractographic measurements of initial defect √area of all specimens reveal that fatigue behavior is well characterized by stress intensity factor amplitude across all surface conditions. An extreme value statistical method is developed using profilometry data to predict S-N curves, and it is concluded that non-destructive surface roughness measurements may be suitable for estimating the fatigue lives of components with as-fabricated surfaces as a rapid method for quality control.

Nano mechanical study on a single layer TiC/TI6Al4V-ELI composite manufactured with laser metal deposition

This study investigated the nano mechanical properties of Ti6Al4V-ELI embraced with TiC particles, synthesized with in situ laser metal deposition technique. The 3.85% feed ratio fraction TiC/Ti6Al4V-ELI composite samples were manufactured at four varying energy densities. The beta grain boundary and the acicular alpha primary matrix were found to have diverse morphologies of carbide particles due to the in-situ reaction. The effect of energy density is observed on the microstructure and nano mechanical properties. An average off set of 650 nm was recorded after the nano-indentation in the matrix at a maximum load of 400 mN.

Saturation of rogue wave amplification over steep shoals.

Shoaling surface gravity waves induce rogue wave formation. Though commonly reduced to water waves passing over a step, nonequilibrium physics allows finite slopes to be considered in this problem. Using nonhomogeneous spectral analysis of a spatially varying energy density ratio, we describe the dependence of the amplification as a function of the slope steepness. Increasing the slope increases the amplification of rogue wave probability until this amplification saturates at steep slopes. In contrast, the increase of the down slope of a subsequent de-shoal zone leads to a monotonic decrease in the rogue wave probability, thus featuring a strong asymmetry between shoaling and de-shoaling zones. Due to the saturation of the rogue wave amplification at steep slopes, our model is applicable beyond its range of validity up to a step, thus elucidating why previous models based on a step could describe the physics of steep finite slopes. We also explain why the rogue wave probability increases over a shoal while it is lower in shallower water.

Effect of a multicarbohydrase containing α-galactosidase in sow lactating diets with varying energy density.

Sow productivity improvements are associated with high energetic demand due to increasing prolificity. The reproductive life and longevity of sows, and the readiness for weaning of the offspring may be impaired when sows loose significant body weight (BW) during lactation. The impact of a multicarbohydrase containing α-galactosidase on a low energy dense lactation diet was evaluated in this study. Two-hundred and eight sows (208 ± 25.2 kg) were blocked by parity and BW to one of four treatments, in which a corn-soybean meal diet was formulated to have varying levels of added fat (0, 1.5%, and 3%) to titrate an energy density model. A fourth treatment replicated the 0% added fat formulation with enzyme supplementation at 250 g/tonne. Sows were weighed individually on entry, post-farrow (by calculation) and at weaning. Daily feed intakes (ADFI) and caloric intake were used for calculation of sow feed efficiency (FE) and caloric efficiency. Litter performance was characterized at birth, and size was standardized within 24h of farrow and within treatment to ensure uniform litter sizes. Average wean weight and pre-weaning mortality were determined. Piglets were weighted individually to study litter weight distribution. Data was analyzed as a randomized completely block design, using sow as the experimental unit, treatment as the main effect, and standardized average weight and litter sizes as covariates where appropriate. Although sows fed a multicarbohydrase had lower standardized litter size (P < 0.001), average wean weight was higher in this group and equivalent to the 3% added fat treatment. Enzyme supplementation tended to reduce the proportion of light weight pigs (BW < 4.1kg) within the litter, when compared with the 0% added fat diet (P < 0.1). The multicarbohydrase tended to increased sow ADFI (P < 0.10), although sows from all treatments had equivalent caloric intakes during lactation (P > 0.1). Enzyme supplementation yielded significant improvements in sow FE (P < 0.01), similar to the 3% added fat group. Thus, the carbohydrase degrading enzyme tested in this study improved the efficiency of sows, while increasing average wean weights of the offspring, suggesting an improvement in nutrient digestion and/or metabolic efficiency from typical lactation diets.

Effect of energy density on the superelastic property of Ni-rich NiTi alloy fabricated by laser powder bed fusion

Laser powder bed fusion (LPBF) has proved to be a promising process for tuning the microstructure and mechanical response in NiTi-shaped memory alloys using a varied energy density input by modifying the process parameters such as laser power or scanning speed. The microstructure, precipitation, chemical composition, and their relationship with austenite–martensite transformation temperatures (TTs) and superelastic properties have been extensively investigated in Ni-rich NiTi alloys processed at varying volume energy densities (52–110 J/mm3) through LPBF. A specific amount of Ni3Ti precipitation was observed and primarily located along the boundary and at the center of the melt pool, and nanoscale spherical NiTi2/Ni2Ti4OX precipitation was homogeneously dispersed in the B2 matrix and B19’ martensite, but no Ni4Ti3 was observed as frequently reported in the literature. Decreasing the volume energy density (VED) led to lower TTs and a higher recovery strain ratio. However, there is an exception for the sample built with the highest laser power of 250 W that possesses the largest Ni/Ti atomic ratio and therefore the highest superelastic property despite the mediated VED (∼87 J/mm3) employed. We concluded that the variation in TTs and superelastic properties among the samples is caused by the varying amounts of Ni, which causes competition among alloying elements in evaporation, condensation, and precipitation during LPBF.

Atomic force microscopy observation of the effect of laser ablation on the nanostructures of the dentin surface.

An atomic force microscope (AFM) was used to analyze the changes in organic matter in human dentin and the effects of laser irradiation with different energy densities on the surface micro-nanostructures of human dentin. Extracted human third molars were used in this study. Human dentin were scanned with an Er, Cr:YSGG laser (6.18, 8.04, 9.89, 11.1 J·cm-2). The 12 samples were randomly allocated. AFM phase imaging technology and energy-dispersive spectroscopy (EDS) were applied to detect the proportional changes in the organic components on the dentine surface before and after Er,Cr:YSGG laser irradiation. AFM was capable of observing the morphological changes of the dentine surface and hydroxyapatite crystals before and after Er, Cr:YSGG laser irradiation. After laser irradiation, the proportion of collagen with low contrast in the phase images remarkably reduced. Accordingly, the proportion of the inorganic phase significantly increased. EDS results showed that dentine was composed of Ca, P, O, and C and some trace elements of Na, Mg and Cl. After Er, Cr:YSGG laser irradiation, the C, O, and Na contents and C/Ca ratio declined significantly (P<0.05), whereas the Ca and P contents and the Ca/P ratio obviously increased (P<0.05). Irradiating human dentine with an Er, Cr:YSGG laser at varying energy densities from 6.18 to 11.1 J·cm-2 did not significantly influence the inorganic phase structure of the surface dentine layer. However, thermal ablation occurred in the organic component.

Effect of short-term light irradiation with varying energy densities on the activities of nitrifiers in wastewater

Microalgal-bacterial consortium (MBC) process has been proposed as an alternative to conventional activated sludge process for nitrogen removal from wastewater. As one of the most influencing parameters, light irradiation effects on microalgae have been extensively investigated. However, light influence on the performance of nitrifiers in activated sludge and its mechanism remains unclear. In this study, the effects of three factors (light irradiation power, irradiation time and sludge concentration) on activities and physiological characteristics of ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) were systematically studied through both the Design of Experiments driven response surface methodology (RSM) approach and light-nitrification kinetic modeling. Results indicated that light irradiation with the specific light energy density (Es) at 0.0203–0.1571 kJ·mg−1 VSS (80–160 W/400–1000 μmol·m−2·s−1, 2.0–5.0 h and 2750–4250 mg·L−1) stimulated the relative AOB activities (rAOB) by 120.0%. This was supported by the increased electron transport system activity, key enzyme activity (AMO) , gene expression (amoA) and energy generation (ATP consumption) in the light treatment. Moreover, further Es increasing up to 0.18 kJ·mg−1 VSS inhibited both AOB and NOB activities. The inhibition was ascribed to the joint light responses of metabolic disorders and lipid peroxidation. The findings enhance our understanding of nitrifiers’ physiological responses to short-term light irradiation, and promote the development of MBC as a sustainable approach for wastewater treatment.

Efficacy of deep tissue laser therapy in pressure ulcer healing in patient with quadriplegia: Case Report

CONTEXT: Pressure ulcers (PU) are the most common complication noted in bed-ridden patients. The purpose of this case report is to explore the efficacy of class IV near-infrared laser therapy in the treatment of large and severe pressure ulcers. FINDINGS: A 53-years-old male diagnosed with quadriplegia due to cervical spine tuberculosis at level C5-C6 was admitted to a hospital with an unstageable pressure ulcer over the sacrum and National Pressure Ulcer Advisory Panel Pressure stage 3 ulcers over the right trochanteric area for pressure injury. No associated comorbidities like diabetes mellitus and hypertension were present. The Lite Cure Gallium-Aluminum-Arsenide (GaAlAs) class IV near-infrared laser, non-contact, continuous beam emission (non-pulsing) at 980nm wavelength, was used. The dosage parameters used were: 7.5 - 10 watts power; dose range 7 J/cm2 - 9 J/cm2; sacral area (13×9) cm2 and trochanteric area (10×8) cm2; at varying energy densities; treatment time ranges between 8 to 15 minutes for each ulcer. Total 19 sessions over 6 weeks were given to treat pressure ulcers. Dimensions (area) and severity stage of pressure ulcer were noted pre-intervention and after the intervention. The post-treatment data revealed the clinical improvement in both outcomes. CONCLUSION/CLINICAL SIGNIFICANCE: This case report demonstrates the anti-inflammatory, analgesic, and bio-stimulative healing effects of Class IV laser therapy treatment showing a reduction in the dimensions and severity of pressure ulcers.

Comprehensive study on the influence of different pretreatment methods and structural adhesives on the shear strength of hybrid CFRP/aluminum joints

ABSTRACT The aim of this study was to investigate the influence of laser treatments with varying energy density and wavelength on the surface structure, shear strength and fracture behavior of hybrid compounds of thermoset carbon fiber-reinforced polymer (CFRP) and aluminum (Al) bonded with three different structural adhesives. The CFRP was pretreated by laser with near-infrared (NIR) and ultraviolet (UV) wavelengths and applying different energy densities. Aluminum surfaces were structured with NIR. Reference CFRP/Al-specimens were prepared by acetone cleaning, low pressure oxygen/argon plasma or sand blasting. The surfaces were investigated microscopically before bonding and after mechanical testing. In addition, the surfaces were examined with white light interferometer and sessile droplet test methods. The bonded compounds were characterized in standardized single lap shear tests to reveal the influence of the pretreatment strategies on the joint strength. Suitable process windows for laser pretreatments were identified, including NIR-pretreatment methods that can compete with an UV-laser source. For every adhesive, a suitable pretreatment method was found.

11 and 15-month-old infants do not compensate immediately for energy variation, and no further adjustment occurs 12 or 24 hours later

Previously, we demonstrated that, in the short term, infants undercompensated for the energy from a preload given 25 min before an ad libitum meal. However, although not consistent, there is evidence in young children that caloric adjustment may occur over longer periods. We investigated the extent to which further energy adjustment occurs up to 24 h after a single meal preceded by preloads of varying energy density (ED) in infants that are 11 and 15 months old. Short-term caloric adjustment was measured in 11- and 15-month-old infants through a preload paradigm meal in the laboratory. To assess their caloric adjustment over longer periods (12 and 24 h), we used 24 h dietary records to evaluate the energy intake (EI) after each visit to the laboratory. Three COMPX scores were calculated according to three different time periods after preload consumption (0 h [i.e., short-term], 12 h or 24 h). Our main result was that, on average, regardless of the time period considered, the infants undercompensated their EI after preload consumption: at 11 and 15 months, caloric adjustment was partial and similar overtime. Considering that a slight repeated imbalance of the energy balance may promote rapid weight gain over the first months, this study calls for further research focusing on facilitators and barriers of efficient appetite control abilities in infancy.

225 Crude protein-content of fat-free muscle and viscera in sheep

Abstract The nutritional effects of variation in feed supply and subsequent compensatory gain can play a significant role in cattle and beef production, due to their effects on carcass quality and feed costs. A system that predicts changes in fat and protein content of muscle and viscera in animals of different life stages and nutritional histories could therefore assist management to optimize performance and reduce costs of feed. A method has been developed to simultaneously estimate body composition and nutrient requirements of ruminants. This method estimates body composition from the difference in energy balance derived from ME intake, and heat production from ME intake and protein content of muscle and viscera, but requires information on protein content of fat free mass in viscera and non-viscera “muscle” tissue. Data from the literature was combined with unpublished data from a study conducted in growing lambs. This experiment tested the effects of ad libitum intake of diets of varying energy density and added RUP on performance and carcass composition of lambs that had been previously restricted or unrestricted prior to a 12–13 week finishing phase, and both carcass and viscera components were chemically analyzed on an individual basis. On a fat-free basis, muscle crude protein averaged 20.8%; this value is in agreement with literature values, which lie between the range of 20–24% and which do not appear to vary substantially with age in postweaning sheep. In the same sheep, crude protein content of viscera averaged 15.6% on a fat-free basis; while data on visceral composition in the literature is limited, these values are within the range of available data. This data is use to parameterize functions describing growth of viscera and changes in heat production over time. This contributes to the method we have developed to estimate nutritional effects on body composition.

Brain Responses to Food Odors Associated With BMI Change at 2-Year Follow-Up.

The understanding of food cue associated neural activations that predict future weight variability may guide the design of effective prevention programs and treatments for overeating and obesity. The current study investigated the association between brain response to different food odors with varied energy density and individual changes of body mass index (BMI) over 2 years. Twenty-five participants received high-fat (chocolate and peanut), low-fat (bread and peach) food odors, and a nonfood odor (rose) while the brain activation was measured using functional magnetic resonance imaging (fMRI). BMIs were calculated with participant’s self-reported body weight and height collected at the time of the fMRI scan and again at 2 years later. Regression analyses revealed significant negative correlations between BMI increase over 2 years and brain activation of the bilateral precuneus and the right posterior cingulate cortex (PCC) in response to high-fat vs. low-fat food odors. Also, brain activation of the right supplementary motor area (SMA) in response to food vs. non-food odor was negatively correlated to subsequent BMI increase over 2 years. Taken together, the current findings suggest that individual differences in neural responsivity to (high calorie) food odors in brain regions of the default mode and motor control network serve as a neural marker for future BMI change.

Radial extracorporeal shock wave therapy in flexor tendon pathology of the hand: A feasibility study

Radial extracorporeal shock wave therapy (rESWT) is an effective and safe non-invasive therapeutic option for various musculoskeletal pathologies. However, data on possible application of radial extracorporeal shock waves (rESWs) on soft tissue components of fingers is still scarce. We now aimed to analyze the feasibility of applying rESWs to human fingers ex vivo. Fresh frozen human cadaveric fingers were exposed to rESWs of varying energy density. The penetration of the rESWs into the soft tissue was determined using pressure sensitive Fuji films that were placed underneath the flexor tendons and other soft tissue components at the proximal phalanx. Then, rESWs were applied and activation of the Fuji film was recorded. Software based image analysis was performed on all films treated with rESWT under ultrasound gel. Penetration of the rESWs through the soft tissue was detected in all settings. Increasing energy density of the rESWs resulted in increasing film activation. Image analysis of films used under ultrasound showed a significant difference among the groups. The results of this study demonstrate that rESWs can penetrate soft tissues including the flexor tendons of human cadaveric fingers. rESWT should be considered as a valuable potential therapeutic option of different finger pathologies. Further studies focusing on the clinical application of rESWT for finger pathologies are required.

The ablation of plastics by intense pulsed ion beam

With strong flash heating effects, intense pulsed ion beam (IPIB) may induce ablation on the solid surface and it is the basis of applications such as surface cleaning, nanopowder preparation and thin-film synthesis with IPIB. In this study, the ablation of polymethyl methacrylate (PMMA) by IPIB was investigated with varied beam energy density on pulsed ion beam accelerator BIPPAB-450 to study the ablation of IPIB under strong ablation. With thermal imaging measurement, it is revealed that when energy reaches a certain threshold, the ablation plume generated on the target surface may impose a shielding effect on the ion beam energy from depositing in the target. It is verified by thermal field simulation that for the low evaporation temperature and high thermal resistance, intense ablation plume may be generated on the surface of plastics under low IPIB energy density or at the early stage of IPIB irradiation. Ablation mass measurement demonstrated that under irradiation of IPIB with a pulse length of 120 ns, ion energy up to 450 keV, energy density up to 3.8 J/cm2, the mass loss of the target increases with the rise of IPIB energy density. Under the irradiation of a series of pulses, the mass loss of PMMA increases proportionally. Unlike ablation on metals by direct beam energy deposition, the ablation of plastics by IPIB endures more stages and the ablation may be more achieved by the heated ablation plasma by beam irradiation.

Effect of a multicarbohydrase containing α-galactosidase enzyme on the performance, carcass yield, and humoral immunity of broilers fed corn–soybean meal–based diets of varying energy density

Nutrient availability is critical for the development of poultry digestive function and immune responses. Carbohydrase formulations, containing α-galactosidase (CAG) enzyme with specificity for galacto-oligosaccharides from soybean meal (SBM), have been shown to increase dietary ME in monogastric diets. This exploratory study aimed at evaluating the effect of CAG on the growth performance and humoral immunity of broilers fed corn–SBM diets with varying energy density. A total of 640 male 1-day-old chicks were allocated at random to one of 64 floor pens, with 10 birds each. Replicates were assigned to a 4 × 2 factorial experimental design. Four dietary energy density levels were formulated, namely control and with a −70, −100, and −120 kcal/kg of feed ME downspecification to the control. Each of these diets was treated with 2 levels of CAG supplementation, either none (−) or at a dose of 200 g/tonne (+). Growth performance was determined over a 35-D period. At the end of the study, carcass processing parameters, organ weight, and dimensions of the intestine were determined in 1 randomly selected bird per replicate. Humoral immunity was measured by quantification of antibody titers to Newcastle disease vaccination, in 1 bird per replicate, at 21 and 35 d of age. Dietary ME had a significant effect on BW and feed conversion ratio (FCR) ( P < 0.05). Regression analysis confirmed differences in the linear response of CAG groups (− or +) in terms of elevation ( P < 0.05) for BW gain and FCR. Significant interaction of the main effects confirmed that CAG maintained carcass dressing percentage equivalent to the control diet ( P < 0.05). CAG increased antibody titers of broilers at 35 d, irrespective of the dietary energy density ( P < 0.001). In conclusion, the impact on broiler growth performance from feeding low-energy-density diets can be ameliorated with a CAG enzyme.

Optical in-situ monitoring and correlation of density and mechanical properties of stainless steel parts produced by selective laser melting process based on varied energy density

In-situ monitoring systems for additive manufacturing processes drive the possibility for identification of defects during printing, rendering both time and cost savings as the process can be stopped if a failure is detected. However, the relationship between defects identified during printing to the actual mechanical performance of the printed part has yet to be established. In this paper, we report the design and development of an optical based image processing in-situ monitoring system implemented on the selective laser melting process. The system consisted of an optical camera, a mirror and a set of light emitting diode lights. 316 L stainless steel specimens were fabricated with varying energy densities. Features captured in the optical images during printing were identified and quantified by image processing techniques. Results from density tests based on Archimedes’ principle and mechanical properties from tensile tests have demonstrated a correlation with the processed optical images of the specimens, validating the potential of inferring mechanical performance of printed parts based on features identified through the optical based image processing in-situ monitoring system.

Effect of processing parameters on dimensional accuracy and bending strength of graphite flake/phenolic resin powder mixture in SLS process

Graphite flake/phenolic resin powder mixture had been prepared via selective laser sintering process. A dimensional analysis involving radial and axial deviation was performed, and the effect of SLS process parameters (laser power, scan spacing, scan speed, layer thickness) in both radial and axial directions were investigated. Laser power is found to be the most significant process variable in radial dimensional accuracy, while in axial direction layer thickness and laser power are the most significant process variable by range analysis based on orthogonal experiment. The optimum combination of parameters in graphite flake/phenolic resin powders mixture SLS process for high dimensional accuracy in radial direction was laser power, scan speed, scan spacing, and layer thickness of 20 W, 1500 m/s, 0.1 mm, and 0.1 mm, respectively, while the optimum combination of parameters in axial direction was laser power, scan speed, scan spacing, and layer thickness of 20 W, 2000 mm/s, 0.1 mm, and 0.15 mm, respectively. Energy density was introduced to better incorporate the processing parameters with dimensional accuracy and mechanical properties, and both dimensional accuracy and bending strength were analyzed under varying energy density and layer thickness, and results showed that in the range of energy density of 0.075–0.15 J/mm2, layer thickness of 0.1–0.2 mm, a graphite flake/phenolic resin laser sintered part with appropriate bending strength and dimensional accuracy could be prepared.

Multiscale Molecular Dynamics Approach to Energy Transfer in Nanomaterials

After local transient fluctuations are dissipated, in an energy transfer process, a system evolves to a state where the energy density field varies slowly in time relative to the dynamics of atomic collisions and vibrations. Furthermore, the energy density field remains strongly coupled to the atomic scale processes (collisions and vibrations), and it can serve as the basis of a multiscale theory of energy transfer. Here, a method is introduced to capture the long scale energy density variations as they coevolve with the atomistic state in a way that yields insights into the basic physics and implies an efficient algorithm for energy transfer simulations. The approach is developed based on the N-atom Liouville equation and an interatomic force field and avoids the need for conjectured phenomenological equations for energy transfer and other processes. The theory is demonstrated for sodium chloride and silicon dioxide nanoparticles immersed in a water bath via molecular dynamics simulations of the energy transfer between a nanoparticle and its aqueous host fluid. The energy density field is computed for different sets of symmetric grid densities, and the multiscale theory holds when slowly varying energy densities at the nodes are obtained. Results strongly depend on grid density and nanoparticle constituent material. A nonuniform temperature distribution, larger thermal fluctuations in the nanoparticle than in the bath, and enhancement of fluctuations at the surface, which are expressed due to the atomic nature of the systems, are captured by this method rather than by phenomenological continuum energy transfer models.

Novel Quaternary TlGaSn2Se6 Single Crystal as Promising Material for Laser Operated Infrared Nonlinear Optical Modulators

The studies of the laser operated third order nonlinear optical features of novel TlGaSn2Se6 crystal were done. The main efforts were devoted to a search of a possibility to apply these crystals as laser operated optoelectronic material. For this reason, the third harmonic generation of the Nd:YAG pulse laser 1064 nm as the fundamental beam with varied energy density of up to 200 J/m2 was studied. As a source of laser operated light, we have used the cw laser (532 nm), exciting the material above the energy gap. Additionally, the influence of middle-energy Ar+ ions on the XPS spectra of the TlInSn2Se6 surface has been explored. We have shown that the main contribution of the Se4p states is manifested in the upper part of the valence band of TlInSn2Se6 We have established that for the TlGaSn2Se6 crystal there exists a possibility of variation of the third harmonic generation efficiency using illumination by external continuous wave laser beam. The discovered effect makes it possible to utilize TlGaSn2Se6 crystal in advanced optoelectronic laser operated devices.